MX389819B - Metodos y sistemas para producir hierro reducido directo y gas combustible de planta de acero. - Google Patents

Metodos y sistemas para producir hierro reducido directo y gas combustible de planta de acero.

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Publication number
MX389819B
MX389819B MX2016016047A MX2016016047A MX389819B MX 389819 B MX389819 B MX 389819B MX 2016016047 A MX2016016047 A MX 2016016047A MX 2016016047 A MX2016016047 A MX 2016016047A MX 389819 B MX389819 B MX 389819B
Authority
MX
Mexico
Prior art keywords
gas
gas stream
coke oven
stream
fuel gas
Prior art date
Application number
MX2016016047A
Other languages
English (en)
Other versions
MX2016016047A (es
Inventor
Robert Cheeley
Travis Wright
Original Assignee
Midrex Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Midrex Technologies Inc filed Critical Midrex Technologies Inc
Publication of MX2016016047A publication Critical patent/MX2016016047A/es
Publication of MX389819B publication Critical patent/MX389819B/es

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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/0073Selection or treatment of the reducing gases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/22Production of hydrogen; Production of gaseous mixtures containing hydrogen by decomposition of gaseous or liquid organic compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B27/00Arrangements for withdrawal of the distillation gases
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/20Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
    • C10K1/22Apparatus, e.g. dry box purifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B13/00Making spongy iron or liquid steel, by direct processes
    • C21B13/02Making spongy iron or liquid steel, by direct processes in shaft furnaces
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042Purification by adsorption on solids
    • C01B2203/043Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/048Composition of the impurity the impurity being an organic compound
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0485Composition of the impurity the impurity being a sulfur compound
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/20Increasing the gas reduction potential of recycled exhaust gases
    • C21B2100/28Increasing the gas reduction potential of recycled exhaust gases by separation
    • C21B2100/282Increasing the gas reduction potential of recycled exhaust gases by separation of carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60Process control or energy utilisation in the manufacture of iron or steel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/122Reduction of greenhouse gas [GHG] emissions by capturing or storing CO2
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/10Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Manufacture Of Iron (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
  • Separation Of Gases By Adsorption (AREA)

Abstract

Un proceso para producir un gas reductor para su uso en la producción de hierro de reducción directa (DRI) y gas combustible para usarse en una planta de acero, que comprende: comprimir una corriente de gas de horno de coque (COG) en un compresor; pasar la corriente de gas de horno de coque comprimida a través de un lecho de carbón vegetal activado para eliminar el alquitrán de la corriente de gas de horno de coque comprimida; separar una corriente de gas rico en hidrógeno de la corriente de gas de horno de coque comprimida limpia con el uso de una unidad de absorción de presión oscilante; proporcionar la corriente de gas rico en hidrógeno hacia un horno de eje de reducción directa como un gas reductor; y proporcionar un resto de corriente de gas desde la unidad de absorción de presión oscilante hacia una planta de acero como gas combustible. Se presentan ambas opciones, la de un sólo paso y de reciclado. Opcionalmente, se agrega gas de horno de oxígeno básico (BOFG) al gas reductor.
MX2016016047A 2014-07-15 2015-07-15 Metodos y sistemas para producir hierro reducido directo y gas combustible de planta de acero. MX389819B (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462024767P 2014-07-15 2014-07-15
PCT/US2015/040516 WO2016011122A1 (en) 2014-07-15 2015-07-15 Methods and systems for producing direct reduced iron and steel mill fuel gas
US14/799,850 US9938594B2 (en) 2014-07-15 2015-07-15 Methods and systems for producing direct reduced iron and steel mill fuel gas using coke oven gas and basic oxygen furnace gas

Publications (2)

Publication Number Publication Date
MX2016016047A MX2016016047A (es) 2017-03-28
MX389819B true MX389819B (es) 2025-03-20

Family

ID=55074081

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016016047A MX389819B (es) 2014-07-15 2015-07-15 Metodos y sistemas para producir hierro reducido directo y gas combustible de planta de acero.

Country Status (7)

Country Link
US (1) US9938594B2 (es)
CN (1) CN106573771A (es)
MX (1) MX389819B (es)
RU (1) RU2675581C2 (es)
UA (1) UA119566C2 (es)
WO (1) WO2016011122A1 (es)
ZA (1) ZA201608111B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106755692A (zh) * 2017-03-03 2017-05-31 江苏省冶金设计院有限公司 天然气水蒸汽重整后还原红土镍矿球团的系统和方法
CN109399564B (zh) * 2018-11-07 2020-05-05 中国矿业大学 一种直接利用高温焦炉荒煤气制取高纯氢的装置及方法
SE543341C2 (en) 2019-04-01 2020-12-08 Greeniron H2 Ab Method and device for producing direct reduced metal
CN109971906A (zh) * 2019-04-11 2019-07-05 中冶赛迪技术研究中心有限公司 一种超低碳排放生产海绵铁的还原方法
SE543642C2 (en) * 2019-09-23 2021-05-11 Greeniron H2 Ab Method and device for producing direct reduced, carburized metal
IT201900021228A1 (it) * 2019-11-14 2021-05-14 Danieli Off Mecc Metodo e relativo apparato per la produzione di ferro da riduzione diretta di minerale ferroso

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2873183A (en) * 1954-07-07 1959-02-10 Kenneth B Ray And The St Trust Continuous iron ore reduction process
JPS5891003A (ja) * 1981-11-27 1983-05-30 Kawasaki Steel Corp Psa法による純水素製造を目的とするcog精製法
JPS58190801A (ja) * 1982-04-28 1983-11-07 Kansai Coke & Chem Co Ltd コ−クス炉ガスからの高純度水素回収方法
RU2190022C2 (ru) * 1997-10-10 2002-09-27 Ильса, С.А. Де К.В. Способ получения железа прямым восстановлением и устройство для его осуществления
US6146442A (en) * 1999-01-08 2000-11-14 Midrex International B.V. Rotterdam, Zurich Branch Apparatus and method for introducing gas into a shaft furnace without disturbing burden flow
US6478841B1 (en) 2001-09-12 2002-11-12 Techint Technologies Inc. Integrated mini-mill for iron and steel making
DE112005001881T5 (de) * 2004-08-03 2007-06-21 Hylsa S.A. De C.V., Monterrey Verfahren und Vorrichtung zum Herstellen von reinen reduzierenden Gasen aus Koksofengas
CN1995402B (zh) * 2006-01-06 2011-11-16 伊尔技术有限公司 利用焦炉气等将氧化铁直接还原成金属铁的方法
DE102009022509B4 (de) * 2009-05-25 2015-03-12 Thyssenkrupp Industrial Solutions Ag Verfahren zur Herstellung von Synthesegas
US9028585B2 (en) 2010-05-14 2015-05-12 Midrex Technologies, Inc. System and method for reducing iron oxide to metallic iron using coke oven gas and oxygen steelmaking furnace gas

Also Published As

Publication number Publication date
US9938594B2 (en) 2018-04-10
WO2016011122A1 (en) 2016-01-21
RU2017102718A (ru) 2018-08-15
RU2675581C2 (ru) 2018-12-19
ZA201608111B (en) 2019-12-18
CN106573771A (zh) 2017-04-19
US20160017445A1 (en) 2016-01-21
UA119566C2 (uk) 2019-07-10
MX2016016047A (es) 2017-03-28

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