MX383995B - Aparato y método para determinar el estado de carga en batería de flujo redox mediante corrientes limitantes. - Google Patents

Aparato y método para determinar el estado de carga en batería de flujo redox mediante corrientes limitantes.

Info

Publication number
MX383995B
MX383995B MX2016005442A MX2016005442A MX383995B MX 383995 B MX383995 B MX 383995B MX 2016005442 A MX2016005442 A MX 2016005442A MX 2016005442 A MX2016005442 A MX 2016005442A MX 383995 B MX383995 B MX 383995B
Authority
MX
Mexico
Prior art keywords
solution
ratio
currents
oxidized
charge
Prior art date
Application number
MX2016005442A
Other languages
English (en)
Other versions
MX2016005442A (es
Inventor
Adam Morris-Cohen
Evan R King
John Goeltz
Kean Duffey
Steven Y Reece
Original Assignee
Lockheed Martin Energy Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lockheed Martin Energy Llc filed Critical Lockheed Martin Energy Llc
Publication of MX2016005442A publication Critical patent/MX2016005442A/es
Publication of MX383995B publication Critical patent/MX383995B/es

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/96Carbon-based electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04186Arrangements for control of reactant parameters, e.g. pressure or concentration of liquid-charged or electrolyte-charged reactants
    • H01M8/04194Concentration measuring cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201Reactant storage and supply, e.g. means for feeding, pipes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04313Processes for controlling fuel cells or fuel cell systems characterised by the detection or assessment of variables; characterised by the detection or assessment of failure or abnormal function
    • H01M8/0444Concentration; Density
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04791Concentration; Density
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/18Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
    • H01M8/184Regeneration by electrochemical means
    • H01M8/188Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/20Indirect fuel cells, e.g. fuel cells with redox couple being irreversible
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/22Fuel cells in which the fuel is based on materials comprising carbon or oxygen or hydrogen and other elements; Fuel cells in which the fuel is based on materials comprising only elements other than carbon, oxygen or hydrogen
    • H01M8/222Fuel cells in which the fuel is based on compounds containing nitrogen, e.g. hydrazine, ammonia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Fuel Cell (AREA)

Abstract

La presente invención se refiere a métodos y aparatos para la determinación de la relación de las formas oxidada y reducida de un par de redox en solución, cada método que comprende: (a) poner en contacto un primer electrodo activo estacionario y un primer contraelectrodo a la solución; (b) aplicar un primer potencial al primer electrodo activo y medir una primera corriente constante; (c) aplicar un segundo potencial en el primer electrodo activo y medir una segunda corriente constante; en donde el signo de las primera y segunda corrientes no es el mismo; y en donde la relación de los valores absolutos de las primera y segunda corrientes refleja la relación de las formas oxidada y reducida del par de redox en solución. Cuando se usa en el contexto de la supervisión/control de celdas electroquímicas, las modalidades adicionales incluyen las que comprenden además (d) oxidar o reducir la solución, con el fin de alterar el balance de las formas oxidada y reducida del par de redox en solución, en un grado que depende de la relación de los valores absolutos de las primera y segunda corrientes. Estas modalidades se pueden usar en el contexto de mantener una celda, pila, o sistema electroquímicos.
MX2016005442A 2013-11-01 2014-10-31 Aparato y método para determinar el estado de carga en batería de flujo redox mediante corrientes limitantes. MX383995B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361898635P 2013-11-01 2013-11-01
PCT/US2014/063290 WO2015066398A1 (en) 2013-11-01 2014-10-31 Apparatus and method for determining state of charge in a redox flow battery via limiting currents

Publications (2)

Publication Number Publication Date
MX2016005442A MX2016005442A (es) 2016-08-03
MX383995B true MX383995B (es) 2025-03-11

Family

ID=53005151

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2016005442A MX383995B (es) 2013-11-01 2014-10-31 Aparato y método para determinar el estado de carga en batería de flujo redox mediante corrientes limitantes.

Country Status (11)

Country Link
US (3) US10833340B2 (es)
EP (1) EP3063820B1 (es)
JP (1) JP6685901B2 (es)
KR (1) KR102253906B1 (es)
CN (1) CN105993091B (es)
CA (1) CA2927793C (es)
DK (1) DK3063820T3 (es)
ES (1) ES2837836T3 (es)
MX (1) MX383995B (es)
PL (1) PL3063820T3 (es)
WO (1) WO2015066398A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK3058608T3 (da) 2013-10-16 2020-03-23 Lockheed Martin Energy Llc Fremgangsmåde og indretning til måling af forbigående ladningstilstand under anvendelse af indgangs/udgangs-potentialer
JP2016540347A (ja) 2013-11-15 2016-12-22 ロッキード・マーティン・アドバンスト・エナジー・ストレージ・エルエルシーLockheed Martin Advanced Energy Storage, LLC レドックスフロー電池の充電状態確定方法及び基準電極の較正方法
US10153502B2 (en) 2014-12-08 2018-12-11 Lockheed Martin Energy, Llc Electrochemical systems incorporating in situ spectroscopic determination of state of charge and methods directed to the same
AU2017290026A1 (en) * 2016-07-01 2019-01-24 Sumitomo Electric Industries, Ltd. Redox flow battery, electrical quantity measurement system, and electrical quantity measurement method
US10903511B2 (en) 2016-11-29 2021-01-26 Lockheed Martin Energy, Llc Flow batteries having adjustable circulation rate capabilities and methods associated therewith
US11539061B2 (en) * 2019-04-12 2022-12-27 Raytheon Technologies Corporation Cell for electrochemically determining active species concentrations in redox flow batteries
DE102019003994A1 (de) * 2019-06-07 2020-12-10 Dräger Safety AG & Co. KGaA Elektrochemische Brennstoffzelle, Verfahren zum Warten einer elektrochemischen Brennstoffzelle und Atemalkoholmessgerät
EP4523270A4 (en) 2022-05-09 2026-04-22 Lockheed Martin Energy Llc CIRCULATING BATTERY INCLUDING A DYNAMIC FLUID NETWORK
EP4726368A1 (en) * 2024-10-11 2026-04-15 VoltStorage GmbH Optical sensor for iron salt battery operation

Family Cites Families (48)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1990003666A1 (en) 1988-09-23 1990-04-05 Unisearch Limited State of charge of redox cell
US8075760B2 (en) * 1995-06-19 2011-12-13 Lifescan, Inc. Electrochemical cell
US6413410B1 (en) * 1996-06-19 2002-07-02 Lifescan, Inc. Electrochemical cell
AUPN661995A0 (en) * 1995-11-16 1995-12-07 Memtec America Corporation Electrochemical cell 2
EP1442289A2 (en) * 2001-10-10 2004-08-04 Lifescan, Inc. Electrochemical cell
US20030170906A1 (en) 2002-01-23 2003-09-11 Board Of Trustees Of Michigan State University Conductive diamond spectrographic cells and method of use
KR100483580B1 (ko) 2002-04-27 2005-04-18 한국바이오시스템(주) 미생물연료전지를 이용한 수질 내 독극물 감지 장치
GB0211449D0 (en) * 2002-05-17 2002-06-26 Oxford Biosensors Ltd Analyte measurement
AU2002351836A1 (en) 2002-11-04 2004-06-07 Janssen Pharmaceutica N.V. Process for electrochemical oxidation of ferrocyanide to ferricyanide
JP2004336734A (ja) 2003-04-17 2004-11-25 Sharp Corp 無線端末、ベース機器、ワイヤレスシステム、無線端末の制御方法、無線端末の制御プログラム、およびそれを記録したコンピュータ読み取り可能な記録媒体
US8758593B2 (en) * 2004-01-08 2014-06-24 Schlumberger Technology Corporation Electrochemical sensor
US8277964B2 (en) 2004-01-15 2012-10-02 Jd Holding Inc. System and method for optimizing efficiency and power output from a vanadium redox battery energy storage system
GB0405823D0 (en) 2004-03-15 2004-04-21 Evanesco Ltd Functionalised surface sensing apparatus and methods
EP2365073A1 (en) * 2005-03-25 2011-09-14 Ikeda Food Research Co. Ltd. Coenzyme-linked glucose dehydrogenase and polynucleotide encoding the same
JP2006351346A (ja) 2005-06-15 2006-12-28 Kansai Electric Power Co Inc:The レドックスフロー電池システム
EP1998163A4 (en) 2006-03-16 2010-12-15 Kurashiki Boseki Kk OPTICAL PROBE WITH TOTAL REFLEXION WASHING AND SPECTROMETRY DEVICE FOR AQUEOUS SOLUTION
US7846571B2 (en) * 2006-06-28 2010-12-07 Robert Bosch Gmbh Lithium reservoir system and method for rechargeable lithium ion batteries
US7866026B1 (en) * 2006-08-01 2011-01-11 Abbott Diabetes Care Inc. Method for making calibration-adjusted sensors
WO2008047842A1 (en) * 2006-10-19 2008-04-24 Panasonic Corporation Method for measuring hematocrit value of blood sample, method for measuring concentration of analyte in blood sample, sensor chip and sensor unit
US7855005B2 (en) * 2007-02-12 2010-12-21 Deeya Energy, Inc. Apparatus and methods of determination of state of charge in a redox flow battery
US20090026094A1 (en) * 2007-05-11 2009-01-29 Home Diagnostics, Inc. Two-pulse systems and methods for determining analyte concentration
CN202144772U (zh) 2007-06-07 2012-02-15 韦福普泰有限公司 产生和储存电力的发电系统
EP2206190A4 (en) * 2007-09-14 2012-07-11 A123 Systems Inc RECHARGEABLE LITHIUM CELL WITH REFERENCE ELECTRODE FOR INTEGRITY STATE MONITORING
CN102119461B (zh) 2008-06-12 2016-08-03 麻省理工学院 高能量密度氧化还原液流装置
US20130011702A1 (en) 2008-07-07 2013-01-10 Enervault Corporation Redox Flow Battery System with Divided Tank System
US8785023B2 (en) 2008-07-07 2014-07-22 Enervault Corparation Cascade redox flow battery systems
US20130011704A1 (en) 2008-07-07 2013-01-10 Enervault Corporation Redox Flow Battery System with Multiple Independent Stacks
EP2417435A4 (en) 2009-04-07 2014-09-10 Rare Light Inc DEVICES, SYSTEMS AND METHODS FOR PERI-CRITICAL REFLECTION SPECTROSCOPY
CN102460811B (zh) 2009-05-28 2015-11-25 艾默吉电力系统股份有限公司 氧化还原流通单元电池再平衡
US8587255B2 (en) 2009-05-28 2013-11-19 Deeya Energy, Inc. Control system for a flow cell battery
US8771856B2 (en) 2010-09-28 2014-07-08 Battelle Memorial Institute Fe-V redox flow batteries
US10139361B2 (en) * 2011-01-07 2018-11-27 The University Of Queensland Proteolysis detection
JP5007849B1 (ja) 2011-03-25 2012-08-22 住友電気工業株式会社 レドックスフロー電池、及びその運転方法
US8916281B2 (en) * 2011-03-29 2014-12-23 Enervault Corporation Rebalancing electrolytes in redox flow battery systems
US8980484B2 (en) * 2011-03-29 2015-03-17 Enervault Corporation Monitoring electrolyte concentrations in redox flow battery systems
US20130029185A1 (en) 2011-07-27 2013-01-31 Primus Power Corporation Electrochemical System Having a System for Determining a State of Charge
EP2762873A4 (en) 2011-09-26 2015-05-20 Toto Ltd METHOD FOR SPECIFIC DETECTION OF A TEST SUBSTANCE
JP2014532284A (ja) 2011-10-14 2014-12-04 ディーヤ エナジー,インコーポレーテッド バナジウムフローセル
US8789473B2 (en) 2012-02-24 2014-07-29 Electro-Motive Diesel Inc. Flow battery control system for a locomotive
US9300000B2 (en) * 2012-02-28 2016-03-29 Uchicago Argonne, Llc Organic non-aqueous cation-based redox flow batteries
DE102012006776A1 (de) 2012-04-04 2013-10-10 Bozankaya BC&C Ladestandsüberwachung einer Durchflussbatterie
US9027483B2 (en) 2012-04-11 2015-05-12 Electro-Motive Diesel, Inc. Flow battery power converter
US9865893B2 (en) 2012-07-27 2018-01-09 Lockheed Martin Advanced Energy Storage, Llc Electrochemical energy storage systems and methods featuring optimal membrane systems
WO2014184617A1 (en) 2013-05-16 2014-11-20 Hydraredox Technologies Holdings Ltd. Estimation of the state of charge of a positive electrolyte solution of a working redox flow battery cell without using any reference electrode
DK3058608T3 (da) 2013-10-16 2020-03-23 Lockheed Martin Energy Llc Fremgangsmåde og indretning til måling af forbigående ladningstilstand under anvendelse af indgangs/udgangs-potentialer
JP2016540347A (ja) 2013-11-15 2016-12-22 ロッキード・マーティン・アドバンスト・エナジー・ストレージ・エルエルシーLockheed Martin Advanced Energy Storage, LLC レドックスフロー電池の充電状態確定方法及び基準電極の較正方法
EP3077791B1 (en) 2013-12-02 2021-05-26 University of Limerick Method for determining the state of charge of a vanadium redox flow battery
US10153502B2 (en) 2014-12-08 2018-12-11 Lockheed Martin Energy, Llc Electrochemical systems incorporating in situ spectroscopic determination of state of charge and methods directed to the same

Also Published As

Publication number Publication date
EP3063820B1 (en) 2020-12-02
US20160293979A1 (en) 2016-10-06
WO2015066398A8 (en) 2016-06-23
CN105993091A (zh) 2016-10-05
CA2927793A1 (en) 2015-05-07
DK3063820T3 (da) 2020-12-14
MX2016005442A (es) 2016-08-03
WO2015066398A1 (en) 2015-05-07
JP6685901B2 (ja) 2020-04-22
CA2927793C (en) 2023-10-24
EP3063820A1 (en) 2016-09-07
US20240113313A1 (en) 2024-04-04
US10833340B2 (en) 2020-11-10
CN105993091B (zh) 2020-05-29
US20200381751A1 (en) 2020-12-03
US11929528B2 (en) 2024-03-12
KR102253906B1 (ko) 2021-05-18
PL3063820T3 (pl) 2021-06-14
EP3063820A4 (en) 2017-05-24
KR20160081928A (ko) 2016-07-08
ES2837836T3 (es) 2021-07-01
JP2016535405A (ja) 2016-11-10

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