MX362499B - Produccion de acido acetico con estabilidad mejorada del catalizador. - Google Patents
Produccion de acido acetico con estabilidad mejorada del catalizador.Info
- Publication number
- MX362499B MX362499B MX2014007190A MX2014007190A MX362499B MX 362499 B MX362499 B MX 362499B MX 2014007190 A MX2014007190 A MX 2014007190A MX 2014007190 A MX2014007190 A MX 2014007190A MX 362499 B MX362499 B MX 362499B
- Authority
- MX
- Mexico
- Prior art keywords
- production
- acetic acid
- catalyst stability
- enhanced catalyst
- reaction medium
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Los procedimientos para la producción de ácido acético por carbonilación de metanol y derivados reactivos del mismo en un medio de reacción de fase líquida, en donde el medio de reacción comprende una cantidad finita de agua, de un catalizador homogéneo, de un promotor de haluro de alquilo, y de un estabilizador/co-promotor de catalizador que comprende un catión disimétrico de fosfonio.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201161576514P | 2011-12-16 | 2011-12-16 | |
PCT/US2012/069748 WO2013090720A1 (en) | 2011-12-16 | 2012-12-14 | Production of acetic acid with enhanced catalyst stability |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014007190A MX2014007190A (es) | 2014-08-27 |
MX362499B true MX362499B (es) | 2019-01-21 |
Family
ID=47520272
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014007190A MX362499B (es) | 2011-12-16 | 2012-12-14 | Produccion de acido acetico con estabilidad mejorada del catalizador. |
Country Status (8)
Country | Link |
---|---|
US (1) | US8916727B2 (es) |
EP (1) | EP2791099B1 (es) |
JP (1) | JP5771336B2 (es) |
CN (1) | CN104080764B (es) |
BR (1) | BR112014014610A2 (es) |
MX (1) | MX362499B (es) |
SG (1) | SG11201403174RA (es) |
WO (1) | WO2013090720A1 (es) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20160159720A1 (en) * | 2014-12-09 | 2016-06-09 | Lyondellbasell Acetyls, Llc | Use of phosphate salts in the production of carboxylic acids |
US10758838B2 (en) * | 2015-02-25 | 2020-09-01 | Sabic Global Technologies B.V. | Process for removing impurities from acetic acid |
ES2744537T3 (es) | 2016-10-28 | 2020-02-25 | Daicel Corp | Método para la producción de ácido acético |
EP3617180B1 (en) * | 2018-07-02 | 2023-09-06 | Daicel Corporation | Method for producing acetic acid |
Family Cites Families (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3769329A (en) | 1970-03-12 | 1973-10-30 | Monsanto Co | Production of carboxylic acids and esters |
US4433166A (en) | 1980-12-29 | 1984-02-21 | Monsanto Company | Process for stabilizing carbonylation catalyst in soluble form |
US5391821A (en) | 1983-09-02 | 1995-02-21 | Daicel Chemical Industries, Ltd. | Process for producing carboxylic acids |
GB8404136D0 (en) | 1984-02-16 | 1984-03-21 | Bp Chem Int Ltd | Carbonylation process |
US5026908A (en) | 1984-05-03 | 1991-06-25 | Hoechst Celanese Corporation | Methanol carbonylation process |
CA1228867A (en) * | 1984-05-03 | 1987-11-03 | G. Paull Torrence | Methanol carbonylation process |
US5144068A (en) | 1984-05-03 | 1992-09-01 | Hoechst Celanese Corporation | Methanol carbonylation process |
US5001259A (en) | 1984-05-03 | 1991-03-19 | Hoechst Celanese Corporation | Methanol carbonylation process |
DE3520003A1 (de) | 1985-06-04 | 1986-12-04 | Texas Instruments Deutschland Gmbh, 8050 Freising | Elektrisch programmierbare verknuepfungsmatrix |
CA1299195C (en) | 1986-06-16 | 1992-04-21 | G. Paull Torrence | Addition of hydrogen to carbon monoxide feed gas in producing acetic acid by carbonylation of methanol |
DE3823645C1 (es) | 1988-07-13 | 1989-11-30 | Hoechst Ag | |
US5442107A (en) | 1989-04-06 | 1995-08-15 | Bp Chemicals Limited | Preparing carboxylic acids |
DE4014073A1 (de) | 1990-05-02 | 1991-11-07 | Hoechst Ag | Verfahren zur herstellung von methanolischer methyl-tri-n-alkyl-phosphoniumiodid-loesung |
GB9211671D0 (en) | 1992-06-02 | 1992-07-15 | Bp Chem Int Ltd | Process |
USRE35377E (en) | 1993-05-27 | 1996-11-12 | Steinberg; Meyer | Process and apparatus for the production of methanol from condensed carbonaceous material |
US6031129A (en) | 1995-10-03 | 2000-02-29 | Quantum Chemical Corporation | Use of pentavalent group VA oxides in acetic acid processing |
US5817869A (en) | 1995-10-03 | 1998-10-06 | Quantum Chemical Corporation | Use of pentavalent Group VA oxides in acetic acid processing |
US6303813B1 (en) | 1999-08-31 | 2001-10-16 | Celanese International Corporation | Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile |
US6323364B1 (en) | 1999-08-31 | 2001-11-27 | Celanese International Corporation | Rhodium/inorganic iodide catalyst system for methanol carbonylation process with improved impurity profile |
CA2308896A1 (en) | 2000-05-18 | 2001-11-18 | Allan James Robertson | Phosphonium salts |
TW567183B (en) | 2001-10-05 | 2003-12-21 | China Petrochemical Dev Corp | Process for producing carboxylic acids |
US6677480B2 (en) | 2002-01-28 | 2004-01-13 | Celanese International Corporation | Process control in production of acetic acid via use of heavy phase density measurement |
DE60330658D1 (de) * | 2002-05-06 | 2010-02-04 | Eastman Chem Co | Kontinuierlicher carbonylierungsprozess |
FR2839972B1 (fr) | 2002-05-23 | 2005-08-19 | Inst Francais Du Petrole | Procede de carbonylation des alcools utilisant un catalyseur a base de rhodium ou d'iridium dans un liquide ionique non-aqueux,avec un recyclage efficace du catalyseur |
US7005541B2 (en) | 2002-12-23 | 2006-02-28 | Celanese International Corporation | Low water methanol carbonylation process for high acetic acid production and for water balance control |
US7053241B1 (en) | 2005-02-24 | 2006-05-30 | Celanese International Corporation | Acetic acid production methods incorporating at least one metal salt as a catalyst stabilizer |
EP1741692A1 (en) | 2005-07-06 | 2007-01-10 | BP Chemicals Limited | Process for the conversion of hydrocarbons to C2-oxygenates |
CA2614094C (en) | 2005-07-06 | 2014-01-14 | Bp Chemicals Limited | Process for the conversion of synthesis gas to oxygenates containing c2+ alcohols |
US7582792B2 (en) | 2006-06-15 | 2009-09-01 | Eastman Chemical Company | Carbonylation process |
US7629491B2 (en) | 2006-06-26 | 2009-12-08 | Eastman Chemical Company | Hydrocarboxylation process |
EP1916233A1 (en) | 2006-10-20 | 2008-04-30 | BP Chemicals Limited | Process for the conversion of hydrocarbons to alcohols |
EP1914219A1 (en) | 2006-10-20 | 2008-04-23 | BP Chemicals Limited | Process for the conversion of hydrocarbons to alcohols |
EP1923380A1 (en) | 2006-10-20 | 2008-05-21 | BP Chemicals Limited | Process for the conversion of hydrocarbons to alcohols |
EP2060555A1 (en) | 2007-11-14 | 2009-05-20 | BP p.l.c. | Process for the production of alcohol from a carbonaceous feedstock |
EP2060553A1 (en) | 2007-11-14 | 2009-05-20 | BP p.l.c. | Process for the conversion of hydrocarbons into alcohol |
EP2072488A1 (en) | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of hydrocarbon to ethanol |
EP2072486A1 (en) | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of hydrocarbons to ethanol |
EP2072490A1 (en) | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of hydrocarbons to alcohols |
EP2072487A1 (en) | 2007-12-17 | 2009-06-24 | BP p.l.c. | Process for the conversion of hydrocarbons to ethanol |
US20090247783A1 (en) | 2008-04-01 | 2009-10-01 | Eastman Chemical Company | Carbonylation process |
US8471075B2 (en) | 2008-07-31 | 2013-06-25 | Celanese International Corporation | Processes for making ethanol from acetic acid |
US8338650B2 (en) | 2008-07-31 | 2012-12-25 | Celanese International Corporation | Palladium catalysts for making ethanol from acetic acid |
US7863489B2 (en) | 2008-07-31 | 2011-01-04 | Celanese International Corporation | Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst |
US8304586B2 (en) | 2010-02-02 | 2012-11-06 | Celanese International Corporation | Process for purifying ethanol |
US7608744B1 (en) | 2008-07-31 | 2009-10-27 | Celanese International Corporation | Ethanol production from acetic acid utilizing a cobalt catalyst |
US8309773B2 (en) | 2010-02-02 | 2012-11-13 | Calanese International Corporation | Process for recovering ethanol |
EP2186787A1 (en) | 2008-11-13 | 2010-05-19 | BP p.l.c. | Hydrogenation of ethanoic acid to produce ethanol |
US7884253B2 (en) | 2008-12-11 | 2011-02-08 | Range Fuels, Inc. | Methods and apparatus for selectively producing ethanol from synthesis gas |
US8318988B2 (en) | 2010-05-07 | 2012-11-27 | Celanese International Corporation | Process for purifying a crude ethanol product |
-
2012
- 2012-12-14 MX MX2014007190A patent/MX362499B/es active IP Right Grant
- 2012-12-14 BR BR112014014610A patent/BR112014014610A2/pt not_active Application Discontinuation
- 2012-12-14 US US13/715,168 patent/US8916727B2/en active Active
- 2012-12-14 WO PCT/US2012/069748 patent/WO2013090720A1/en active Application Filing
- 2012-12-14 SG SG11201403174RA patent/SG11201403174RA/en unknown
- 2012-12-14 JP JP2014547483A patent/JP5771336B2/ja active Active
- 2012-12-14 EP EP12812459.1A patent/EP2791099B1/en not_active Not-in-force
- 2012-12-14 CN CN201280062337.4A patent/CN104080764B/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
CN104080764A (zh) | 2014-10-01 |
EP2791099B1 (en) | 2017-02-01 |
WO2013090720A1 (en) | 2013-06-20 |
SG11201403174RA (en) | 2014-09-26 |
US8916727B2 (en) | 2014-12-23 |
JP2015500838A (ja) | 2015-01-08 |
EP2791099A1 (en) | 2014-10-22 |
CN104080764B (zh) | 2016-09-14 |
MX2014007190A (es) | 2014-08-27 |
JP5771336B2 (ja) | 2015-08-26 |
BR112014014610A2 (pt) | 2017-06-13 |
US20130184491A1 (en) | 2013-07-18 |
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Legal Events
Date | Code | Title | Description |
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FG | Grant or registration |