MX362353B - Proceso integrado para coproducir trans - 1 - cloro - 3,3,3 trifluoropropeno, trans - 1,3,3,3 - tetrafluoropropeno y 1,1,1,3,3, - pentafluoropropano. - Google Patents
Proceso integrado para coproducir trans - 1 - cloro - 3,3,3 trifluoropropeno, trans - 1,3,3,3 - tetrafluoropropeno y 1,1,1,3,3, - pentafluoropropano.Info
- Publication number
- MX362353B MX362353B MX2014011415A MX2014011415A MX362353B MX 362353 B MX362353 B MX 362353B MX 2014011415 A MX2014011415 A MX 2014011415A MX 2014011415 A MX2014011415 A MX 2014011415A MX 362353 B MX362353 B MX 362353B
- Authority
- MX
- Mexico
- Prior art keywords
- trans
- chloro
- tetrafluoropropene
- propene
- produce
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/208—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being MX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/383—Separation; Purification; Stabilisation; Use of additives by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/395—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to a chemical modification of at least one compound
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Se describe un proceso de manufactura integrado para co-producir (E) 1-cloro-3,3,3-trifluoropropeno, (E) 1,3,3,3-tetrafluoropropeno y 1,1,1,3,3-pentafluoro propano a partir de un único material de alimentación de partida o una mezcla de materiales de alimentación hidroclorotiazida-carbono insaturados que comprende 1,1,1,3-tetracloropropeno y/o 1,1,3,3-tetracloro-propeno. El proceso incluye una operación combinada de fase líquida o vapor de reacción/purificación que produce directamente (E) 1-cloro-3,3,3-trifluoro-propeno (1233zd (E)) a partir de estos materiales de alimentación, que también pueden incluir 240fa. En el segundo reactor de fluoración en fase líquida 1233zd (E) se pone en contacto con HF en presencia de un catalizador para producir 1,1,1,3, 3-pentafluoropropano (245fa) con una alta conversión y selectividad. Un tercer reactor se utiliza para la deshidrofluoración de 245fa (E) para producir 1,3,3,3-tetrafluoro-propeno (1234ze (E)) poniéndose en contacto en la fase líquida con una solución cáustica o en la fase de vapor usando un catalizador de deshidrofluoración. Esta operación puede ir seguido de uno o más procesos de purificación para recuperar el producto 1234ze (E).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/432,300 US9938212B2 (en) | 2012-03-28 | 2012-03-28 | Integrated process to coproduce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane |
PCT/US2013/031869 WO2013148300A1 (en) | 2012-03-28 | 2013-03-15 | Integrated process to coproduce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2014011415A MX2014011415A (es) | 2014-11-25 |
MX362353B true MX362353B (es) | 2019-01-11 |
Family
ID=49235887
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2014011415A MX362353B (es) | 2012-03-28 | 2013-03-15 | Proceso integrado para coproducir trans - 1 - cloro - 3,3,3 trifluoropropeno, trans - 1,3,3,3 - tetrafluoropropeno y 1,1,1,3,3, - pentafluoropropano. |
Country Status (7)
Country | Link |
---|---|
US (1) | US9938212B2 (es) |
EP (1) | EP2831024A4 (es) |
JP (1) | JP2015515464A (es) |
CN (1) | CN104185616A (es) |
IN (1) | IN2014DN07744A (es) |
MX (1) | MX362353B (es) |
WO (1) | WO2013148300A1 (es) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9938212B2 (en) | 2012-03-28 | 2018-04-10 | Honeywell International Inc. | Integrated process to coproduce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane |
US9272968B2 (en) | 2013-03-14 | 2016-03-01 | Honeywell International Inc. | Process to suppress the formation of 3,3,3-trifluoropropyne in fluorocarbon manufacture |
CN110845295A (zh) | 2014-08-14 | 2020-02-28 | 科慕埃弗西有限公司 | 通过脱氟化氢来制备E-1,3,3,3-四氟丙烯(HFC-1234ze)的方法 |
US9764998B2 (en) * | 2015-05-12 | 2017-09-19 | Honeywell International Inc. | Process for making HCFO-1233zd |
FR3048429B1 (fr) * | 2016-03-04 | 2019-09-27 | Arkema France | Composition azeotropique ou quasi-azeotropique comprenant de la trifluoropropyne |
FR3081158B1 (fr) | 2018-05-16 | 2020-07-31 | Arkema France | Procede de production du 1-chloro-3,3,3-trifluoropropene. |
FR3083232B1 (fr) * | 2018-06-27 | 2021-11-12 | Arkema France | Procede de production du 1-chloro-3,3,3-trifluoropropene |
FR3086287B1 (fr) | 2018-09-26 | 2020-09-18 | Arkema France | Stabilisation du 1-chloro-3,3,3-trifluoropropene |
JP2022512806A (ja) * | 2018-10-26 | 2022-02-07 | ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー | Hfo-1234ze及びhfo-1234yf組成物及び組成物を製造及び使用するためのプロセス |
US11209196B2 (en) | 2018-10-26 | 2021-12-28 | The Chemours Company Fc, Llc | HFO-1234ZE, HFO-1225ZC and HFO-1234YF compositions and processes for producing and using the compositions |
BR112021022059A2 (pt) | 2018-10-26 | 2021-12-28 | Chemours Co Fc Llc | Composições de fluoropropeno, métodos de produção de uma mistura e de resfriamento, processos para transferência de calor, para tratamento de uma superfície e para formação de uma composição, sistema de refrigeração, aparelhos de refrigeração, uso da composição de fluoropropeno e método para substituição de um refrigerante |
FR3094714B1 (fr) * | 2019-04-03 | 2021-04-23 | Arkema France | Procédé de purification du 1-chloro-3,3,3-trifluoropropène |
US12116332B2 (en) * | 2021-12-03 | 2024-10-15 | Honeywell International Inc. | High purity HFO-E-1,3,3,3-tetrafluoropropene (trans-HFO-1234ze) and methods for producing same |
Family Cites Families (26)
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ATE175180T1 (de) | 1994-07-11 | 1999-01-15 | Allied Signal Inc | Verfahren zur herstellung von 1,1,1,3,3- pentafluorpropan |
EP0729932A1 (en) * | 1995-03-03 | 1996-09-04 | Central Glass Company, Limited | Method of producing halopropane |
US5616819A (en) | 1995-08-28 | 1997-04-01 | Laroche Industries Inc. | Process for preparing fluorinated aliphatic compounds |
JP3818398B2 (ja) | 1995-12-29 | 2006-09-06 | ダイキン工業株式会社 | 1,1,1,3,3−ペンタフルオロプロパンの製造方法 |
US5895825A (en) | 1997-12-01 | 1999-04-20 | Elf Atochem North America, Inc. | Preparation of 1,1,1,3,3-pentafluoropropane |
US5811603A (en) * | 1997-12-01 | 1998-09-22 | Elf Atochem North America, Inc. | Gas phase fluorination of 1230za |
US5877359A (en) | 1998-01-27 | 1999-03-02 | Elf Atochem North America, Inc. | Uncatalyzed liquid phase fluorination of 1230ZA |
BE1011765A3 (fr) | 1998-02-26 | 2000-01-11 | Solvay | Procede d'hydrofluoration d'hydrocarbures. |
US6013846A (en) | 1998-03-05 | 2000-01-11 | Elf Atochem North America, Inc. | Azeotrope of HF and 1233zd |
JP3518321B2 (ja) | 1998-03-23 | 2004-04-12 | ダイキン工業株式会社 | 1,1,1,3,3−ペンタフルオロプロパンの製造方法 |
JP3804289B2 (ja) | 1998-09-22 | 2006-08-02 | ダイキン工業株式会社 | 1,1,1,3,3−ペンタフルオロプロパン及び/又は1−クロロ−3,3,3−トリフルオロプロペンの製造方法 |
US6166274A (en) | 1999-12-15 | 2000-12-26 | Atofina Chemicals, Inc. | Catalyzed liquid phase fluorination of 1230za |
US7230146B2 (en) | 2003-10-27 | 2007-06-12 | Honeywell International Inc. | Process for producing fluoropropenes |
US7592494B2 (en) * | 2003-07-25 | 2009-09-22 | Honeywell International Inc. | Process for the manufacture of 1,3,3,3-tetrafluoropropene |
US7563936B2 (en) * | 2006-10-27 | 2009-07-21 | Honeywell International Inc | Processes for geometric isomerization of halogenated olefins |
US6844475B1 (en) * | 2003-08-08 | 2005-01-18 | Honeywell International Business Machines | Low temperature production of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) |
US8067650B2 (en) * | 2006-08-24 | 2011-11-29 | Honeywell International Inc. | Process for the production of HFO trans-1234ze from HFC-245fa |
US7485760B2 (en) | 2006-08-24 | 2009-02-03 | Honeywell International Inc. | Integrated HFC trans-1234ze manufacture process |
CN103553871A (zh) | 2006-10-31 | 2014-02-05 | 纳幕尔杜邦公司 | 氟丙烷、卤代丙烯以及2-氯-3,3,3-三氟-1-丙烯与hf的共沸组合物和1,1,1,2,2-五氟丙烷与hf的共沸组合物的制备方法 |
EP2091896A1 (en) | 2006-10-31 | 2009-08-26 | E.I. Du Pont De Nemours And Company | Processes for the production of fluoropropanes and halopropenes |
US8642819B2 (en) | 2008-11-19 | 2014-02-04 | Arkema Inc. | Process for the manufacture of hydrochlorofluoroolefins |
US9045386B2 (en) * | 2010-02-18 | 2015-06-02 | Honeywell International Inc. | Integrated process and methods of producing (E)-1-chloro-3,3,3-trifluoropropene |
US8426656B2 (en) * | 2010-04-05 | 2013-04-23 | Honeywell International Inc. | Integrated process to co-produce trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene |
US9334207B2 (en) | 2010-09-03 | 2016-05-10 | Honeywell International Inc. | Integrated process to coproduce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane |
US8436217B2 (en) | 2011-04-25 | 2013-05-07 | Honeywell International Inc. | Integrated process to co-produce 1,1,1,3,3-pentafluoropropane, trans-1-chloro-3,3,3-trifluoropropene and trans-1,3,3,3-tetrafluoropropene |
US9938212B2 (en) | 2012-03-28 | 2018-04-10 | Honeywell International Inc. | Integrated process to coproduce trans-1-chloro-3,3,3-trifluoropropene, trans-1,3,3,3-tetrafluoropropene, and 1,1,1,3,3-pentafluoropropane |
-
2012
- 2012-03-28 US US13/432,300 patent/US9938212B2/en active Active
-
2013
- 2013-03-15 IN IN7744DEN2014 patent/IN2014DN07744A/en unknown
- 2013-03-15 MX MX2014011415A patent/MX362353B/es active IP Right Grant
- 2013-03-15 CN CN201380016225.XA patent/CN104185616A/zh active Pending
- 2013-03-15 JP JP2015503320A patent/JP2015515464A/ja active Pending
- 2013-03-15 WO PCT/US2013/031869 patent/WO2013148300A1/en active Application Filing
- 2013-03-15 EP EP13768998.0A patent/EP2831024A4/en not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
JP2015515464A (ja) | 2015-05-28 |
US20130261353A1 (en) | 2013-10-03 |
WO2013148300A1 (en) | 2013-10-03 |
CN104185616A (zh) | 2014-12-03 |
MX2014011415A (es) | 2014-11-25 |
US9938212B2 (en) | 2018-04-10 |
EP2831024A1 (en) | 2015-02-04 |
IN2014DN07744A (es) | 2015-05-15 |
EP2831024A4 (en) | 2015-11-11 |
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