MX348089B - Método para la síntesis de catalizadores quirales heterogeneos sólidos y su uso en reacciones estereoselectivas. - Google Patents

Método para la síntesis de catalizadores quirales heterogeneos sólidos y su uso en reacciones estereoselectivas.

Info

Publication number
MX348089B
MX348089B MX2012013420A MX2012013420A MX348089B MX 348089 B MX348089 B MX 348089B MX 2012013420 A MX2012013420 A MX 2012013420A MX 2012013420 A MX2012013420 A MX 2012013420A MX 348089 B MX348089 B MX 348089B
Authority
MX
Mexico
Prior art keywords
synthesis
solid heterogeneous
chiral catalysts
stereoselective reactions
heterogeneous chiral
Prior art date
Application number
MX2012013420A
Other languages
English (en)
Other versions
MX2012013420A (es
Inventor
Rene Galindo Esquivel Ignacio
Manuel Juárez Ruiz Juan
Regalado Oliva Orlando
Original Assignee
Univ Guanajuato
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Guanajuato filed Critical Univ Guanajuato
Priority to MX2012013420A priority Critical patent/MX348089B/es
Priority to EP13193738.5A priority patent/EP2732874B1/en
Priority to US14/085,003 priority patent/US9598348B2/en
Priority to PL13193738T priority patent/PL2732874T3/pl
Publication of MX2012013420A publication Critical patent/MX2012013420A/es
Priority to US15/427,179 priority patent/US9957286B2/en
Publication of MX348089B publication Critical patent/MX348089B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/061—Chiral polymers
    • B01J31/062—Polymeric amino acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/069—Hybrid organic-inorganic polymers, e.g. silica derivatized with organic groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00—Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06—Preparation of nitro compounds
    • C07C201/12—Preparation of nitro compounds by reactions not involving the formation of nitro groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
    • C07D209/04—Indoles; Hydrogenated indoles
    • C07D209/30—Indoles; Hydrogenated indoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to carbon atoms of the hetero ring
    • C07D209/32—Oxygen atoms
    • C07D209/34—Oxygen atoms in position 2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B01J2231/342—Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B01J2231/346—Mannich type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues to aldimines or ketimines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/348—1,4-additions, e.g. conjugate additions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/061—Chiral polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

En la presente invención se describe la metodología para producir organocatalizadores heterogéneos quirales sólidos que pueden ser utilizados en reacciones de condensación. Los catalizadores pueden ser recuperados de manera sencilla por filtración y además pueden ser reutilizados.
MX2012013420A 2012-11-20 2012-11-20 Método para la síntesis de catalizadores quirales heterogeneos sólidos y su uso en reacciones estereoselectivas. MX348089B (es)

Priority Applications (5)

Application Number Priority Date Filing Date Title
MX2012013420A MX348089B (es) 2012-11-20 2012-11-20 Método para la síntesis de catalizadores quirales heterogeneos sólidos y su uso en reacciones estereoselectivas.
EP13193738.5A EP2732874B1 (en) 2012-11-20 2013-11-20 Method for synthesising heterogeneous solid chiral catalysts and their use in stereoselective reactions
US14/085,003 US9598348B2 (en) 2012-11-20 2013-11-20 Method for the synthesis of solid heterogeneous chiral catalysts and their use in stereoselective reactions
PL13193738T PL2732874T3 (pl) 2012-11-20 2013-11-20 Sposób syntezy stałych, heterogenicznych katalizatorów chiralnych i ich zastosowanie w reakcjach stereo selektywnych
US15/427,179 US9957286B2 (en) 2012-11-20 2017-02-08 Method for the synthesis of solid heterogeneous chiral catalysts and their use in stereoselective reactions

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
MX2012013420A MX348089B (es) 2012-11-20 2012-11-20 Método para la síntesis de catalizadores quirales heterogeneos sólidos y su uso en reacciones estereoselectivas.

Publications (2)

Publication Number Publication Date
MX2012013420A MX2012013420A (es) 2014-05-22
MX348089B true MX348089B (es) 2017-05-25

Family

ID=49639751

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012013420A MX348089B (es) 2012-11-20 2012-11-20 Método para la síntesis de catalizadores quirales heterogeneos sólidos y su uso en reacciones estereoselectivas.

Country Status (4)

Country Link
US (2) US9598348B2 (es)
EP (1) EP2732874B1 (es)
MX (1) MX348089B (es)
PL (1) PL2732874T3 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113210015A (zh) * 2021-05-08 2021-08-06 宁波经济技术开发区弘翔生化科技有限公司 一种醛酮缩合催化剂及其制备方法和应用
CN113559926A (zh) * 2021-05-25 2021-10-29 北方民族大学 一种不对称Aldol反应催化剂及其制备方法与应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6028025A (en) 1996-10-21 2000-02-22 Massachusetts Institute Of Technology Metalloporphyrin oxidation catalyst covalently coupled to an inorganic surface and method making same
US5990318A (en) 1998-03-06 1999-11-23 The Hong Kong Polytechnic University Soluble polyester-supported chiral phosphines
GB9928222D0 (en) 1999-11-30 2000-01-26 Univ Sheffield Chiral catalysts for asymmetric acylation and related transformations
WO2003089396A1 (en) 2002-04-19 2003-10-30 California Institute Of Technology Direct, enantioselective aldol coupling of aldehydes using chiral organic catalysts
EP1479439A1 (en) * 2003-05-22 2004-11-24 Universiteit van Amsterdam Coordination complex system comprising building blocks and use thereof as a catalyst
US8084641B2 (en) 2005-10-11 2011-12-27 Stc.Unm Organocataslysts and methods of use in chemical synthesis
EP2139870A4 (en) 2007-03-22 2010-04-28 Agency Science Tech & Res CATALYSER IMMOBILIZATION ON SILICON-DIOXIDE-CONTAINING MESOCELLULAR FOAM BY CLICKING CHEMISTRY
ES2349604B1 (es) 2009-05-14 2011-11-02 Consejo Superior De Investigaciones Cientificas (Csic) Polimeros de hidroxiprolina, procedimiento de obtencion y su uso comocatalizadores.

Also Published As

Publication number Publication date
US20170145041A1 (en) 2017-05-25
EP2732874A1 (en) 2014-05-21
PL2732874T3 (pl) 2016-03-31
MX2012013420A (es) 2014-05-22
US9598348B2 (en) 2017-03-21
EP2732874B1 (en) 2015-05-27
US9957286B2 (en) 2018-05-01
US20140213796A1 (en) 2014-07-31

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