MX3415E - IMPROVEMENTS IN THE HYDROFORMILATION OF AN OLEPHINE - Google Patents

IMPROVEMENTS IN THE HYDROFORMILATION OF AN OLEPHINE

Info

Publication number
MX3415E
MX3415E MX000184U MX18476U MX3415E MX 3415 E MX3415 E MX 3415E MX 000184 U MX000184 U MX 000184U MX 18476 U MX18476 U MX 18476U MX 3415 E MX3415 E MX 3415E
Authority
MX
Mexico
Prior art keywords
hydroformylation
around
hydrogen
carbon
olefin
Prior art date
Application number
MX000184U
Other languages
Spanish (es)
Inventor
Jerry Dean Unruh
William Joshua Wells
Original Assignee
Celanese Corp
New York N Y Us
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Corp, New York N Y Us filed Critical Celanese Corp
Publication of MX3415E publication Critical patent/MX3415E/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1895—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing arsenic or antimony

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

La presente invención se refiere a mejoras en la hidroformilación de una olefina que tiene hasta alrededor de 25 átomos de carbono y siendo reaccionado con hidrogeno y monoxido de carbono en una zona de reacción de fade líquida para producir un derivado aldehido de la olefina, llevandose a cabo la hidroformilación a una temperatura que va desde alrededor de 50ºC., hasta alrededor de 200ºC., bajo una presión parcial combinada de hidrógeno y monóxido de carbono de alrededor de 68 atmósferas, y con una relación de presión parcial de hidrogenorespecto a aquella de monóxido de carbono desde alrededor de 10:1 hasta 1:10 en que la mejora comprende catalizar la hidroformilación con un hidruro de carbonilo de rodio en una combinación compleja con un derivado ferroceno de las siguientes estructuras: (ver figura). En que Q es P, As o Sb y R es fenilo o un alquilo inferior.The present invention relates to improvements in hydroformylation of an olefin having up to about 25 carbon atoms and being reacted with hydrogen and carbon monoxide in a liquid fade reaction zone to produce an aldehyde derivative of the olefin, leading to Hydroformylation is carried out at a temperature ranging from around 50ºC to around 200ºC, under a combined partial pressure of hydrogen and carbon monoxide of around 68 atmospheres, and with a ratio of partial pressure of hydrogen relative to that of monoxide. carbon from about 10: 1 to 1:10 where the improvement involves catalyzing hydroformylation with a rhodium carbonyl hydride in a complex combination with a ferrocene derivative of the following structures: (see figure). Where Q is P, As or Sb and R is phenyl or lower alkyl.

MX000184U 1975-04-21 1976-04-21 IMPROVEMENTS IN THE HYDROFORMILATION OF AN OLEPHINE MX3415E (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US56973875A 1975-04-21 1975-04-21
US65040576A 1976-01-19 1976-01-19

Publications (1)

Publication Number Publication Date
MX3415E true MX3415E (en) 1980-11-11

Family

ID=27075133

Family Applications (1)

Application Number Title Priority Date Filing Date
MX000184U MX3415E (en) 1975-04-21 1976-04-21 IMPROVEMENTS IN THE HYDROFORMILATION OF AN OLEPHINE

Country Status (9)

Country Link
JP (1) JPS51127052A (en)
CA (1) CA1082722A (en)
DE (1) DE2617306A1 (en)
FR (1) FR2308635A1 (en)
GB (4) GB1537918A (en)
IT (1) IT1059224B (en)
MX (1) MX3415E (en)
NL (1) NL7604204A (en)
SE (1) SE7604604L (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4536589A (en) * 1981-11-09 1985-08-20 The Dow Chemical Company Polymers of ferrocene
CA1327365C (en) * 1988-06-29 1994-03-01 Stephen R. Stobart Process for catalytic hydroformylation
JP5960577B2 (en) * 2012-10-23 2016-08-02 Jnc株式会社 Method for extracting electrons from hydrogen molecule using hydride metal complex and method for reducing substrate
EP4074683A1 (en) * 2021-04-16 2022-10-19 Evonik Operations GmbH Method for the hydroxymethylation and hydroformylation of alkenes by means of cu-catalysts

Also Published As

Publication number Publication date
GB1537917A (en) 1979-01-10
CA1082722A (en) 1980-07-29
FR2308635B1 (en) 1978-05-19
DE2617306A1 (en) 1976-11-04
FR2308635A1 (en) 1976-11-19
SE7604604L (en) 1976-10-22
JPS51127052A (en) 1976-11-05
GB1537919A (en) 1979-01-10
GB1537920A (en) 1979-01-10
GB1537918A (en) 1979-01-10
IT1059224B (en) 1982-05-31
NL7604204A (en) 1976-10-25

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