MX337780B - Proceso para producir el contenido de benceno de la gasolina. - Google Patents

Proceso para producir el contenido de benceno de la gasolina.

Info

Publication number
MX337780B
MX337780B MX2013008351A MX2013008351A MX337780B MX 337780 B MX337780 B MX 337780B MX 2013008351 A MX2013008351 A MX 2013008351A MX 2013008351 A MX2013008351 A MX 2013008351A MX 337780 B MX337780 B MX 337780B
Authority
MX
Mexico
Prior art keywords
alkylation reaction
gasoline stream
refinery gasoline
reaction zone
benzene
Prior art date
Application number
MX2013008351A
Other languages
English (en)
Other versions
MX2013008351A (es
Inventor
Shyh-Yuan H Hwang
Ronald Birkhoff
Richard F Guarino
J Erik Moy
Joseph C Peters
Original Assignee
Badger Licensing Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Badger Licensing Llc filed Critical Badger Licensing Llc
Publication of MX2013008351A publication Critical patent/MX2013008351A/es
Publication of MX337780B publication Critical patent/MX337780B/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G63/00—Treatment of naphtha by at least one reforming process and at least one other conversion process
    • C10G63/02—Treatment of naphtha by at least one reforming process and at least one other conversion process plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G57/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G57/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process
    • C10G57/005—Treatment of hydrocarbon oils, in the absence of hydrogen, by at least one cracking process or refining process and at least one other conversion process with alkylation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
    • C10G69/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only
    • C10G69/12—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step
    • C10G69/123—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural serial stages only including at least one polymerisation or alkylation step alkylation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4081—Recycling aspects
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe un proceso para alquilar benceno contenido en una corriente de gasolina de refinería que contiene benceno, que también comprende por lo menos 0.1 % en peso de por lo menos una olefina C6 a C8. En el proceso, la corriente de gasolina de refinería se pone en contacto bajo condiciones de alquilación con un agente alquilante seleccionado de una o más olefinas C2 a C5 en por lo menos una primera zona de reacción de alquilación y una segunda zona de reacción de alquilación conectadas en serie para producir un efluente alquilado que tiene contenido de benceno reducido en comparación con la corriente de gasolina de refinería. Toda la corriente de gasolina de refinería es introducida en la primera etapa de reacción de alquilación, mientras que una alícuota del efluente alquilado después es reciclada e introducida a la segunda pero no la primera zona de reacción de alquilación.
MX2013008351A 2011-02-07 2011-11-30 Proceso para producir el contenido de benceno de la gasolina. MX337780B (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
USPCT/US2011/023912 2011-02-07
PCT/US2011/062648 WO2012108926A1 (en) 2011-02-07 2011-11-30 Process for reducing the benzene content of gasoline

Publications (2)

Publication Number Publication Date
MX2013008351A MX2013008351A (es) 2013-11-04
MX337780B true MX337780B (es) 2016-03-18

Family

ID=43662049

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2013008351A MX337780B (es) 2011-02-07 2011-11-30 Proceso para producir el contenido de benceno de la gasolina.

Country Status (9)

Country Link
EP (1) EP2673247B1 (es)
JP (1) JP2014513151A (es)
KR (1) KR20140037040A (es)
CN (1) CN103402952B (es)
AU (1) AU2011358570B2 (es)
MX (1) MX337780B (es)
TW (1) TW201247598A (es)
WO (1) WO2012108926A1 (es)
ZA (1) ZA201305320B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103562161B (zh) 2011-02-07 2015-08-19 巴杰许可有限责任公司 通过在烷烃稀释剂存在下使用较低烯烃烷基化苯降低汽油的苯含量的方法
US9200215B2 (en) 2011-02-07 2015-12-01 Badger Licensing Llc Process for reducing the benzene content of gasoline
US9598330B2 (en) 2011-08-19 2017-03-21 Badger Licensing Process for reducing the benzene content of gasoline
CA2968063C (en) * 2014-11-25 2021-06-01 Badger Licensing Llc Process for reducing the benzene content of gasoline
WO2017188934A1 (en) * 2016-04-26 2017-11-02 Badger Licensing Llc Process for reducing the benzene content of gasoline
CN107602330A (zh) * 2017-09-15 2018-01-19 武汉凯顺石化科技有限公司 一种从汽油副产物中分离苯的装置及方法

Family Cites Families (19)

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US3755483A (en) 1972-04-28 1973-08-28 Mobil Oil Vapor phase alkylation in presence of crystalline aluminosilicate catalyst
US4393262A (en) 1978-12-14 1983-07-12 Mobil Oil Corporation Production of isopropylbenzene
IT1127296B (it) * 1979-12-19 1986-05-21 Euteco Impianti Spa Procedimento perfezionato per la produzione di cumene
US4582815A (en) 1984-07-06 1986-04-15 Mobil Oil Corporation Extrusion of silica-rich solids
US5149894A (en) 1986-01-29 1992-09-22 Chevron Research And Technology Company Alkylation using zeolite SSZ-25
US4954325A (en) 1986-07-29 1990-09-04 Mobil Oil Corp. Composition of synthetic porous crystalline material, its synthesis and use
US4908120A (en) 1987-08-20 1990-03-13 Mobil Oil Corporation Catalytic dewaxing process using binder-free zeolite
US4891458A (en) 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US5250777A (en) 1990-04-02 1993-10-05 Inductotherm Corp. Method and apparatus for variable phase induction heating and stirring
US5229341A (en) 1991-01-11 1993-07-20 Mobil Oil Corp. Crystalline oxide material
US5545788A (en) 1991-06-19 1996-08-13 Mobil Oil Corporation Process for the alkylation of benzene-rich reformate using MCM-49
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US5284643A (en) 1992-12-10 1994-02-08 Mobil Oil Corp. Gallium-containing zeolite MCM-22
WO1994020437A1 (en) * 1993-03-08 1994-09-15 Mobil Oil Corporation Benzene reduction in gasoline by alkylation with higher olefins
US5362697A (en) 1993-04-26 1994-11-08 Mobil Oil Corp. Synthetic layered MCM-56, its synthesis and use
US6479721B1 (en) * 1997-06-16 2002-11-12 Uop Llc Alkylation process operating at low olefin ratios
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US7420098B2 (en) * 2007-01-12 2008-09-02 Uop Llc Dual zone aromatic alkylation process
US8395006B2 (en) * 2009-03-13 2013-03-12 Exxonmobil Research And Engineering Company Process for making high octane gasoline with reduced benzene content by benzene alkylation at high benzene conversion

Also Published As

Publication number Publication date
CN103402952A (zh) 2013-11-20
AU2011358570B2 (en) 2016-04-14
EP2673247B1 (en) 2020-05-06
TW201247598A (en) 2012-12-01
AU2011358570A1 (en) 2013-07-18
ZA201305320B (en) 2018-12-19
KR20140037040A (ko) 2014-03-26
CN103402952B (zh) 2015-07-15
EP2673247A1 (en) 2013-12-18
JP2014513151A (ja) 2014-05-29
WO2012108926A1 (en) 2012-08-16
MX2013008351A (es) 2013-11-04

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Legal Events

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