MX337013B - Catalizadores masicos y soportados de sulfuro de rutenio promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtencion. - Google Patents
Catalizadores masicos y soportados de sulfuro de rutenio promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtencion.Info
- Publication number
- MX337013B MX337013B MX2011013531A MX2011013531A MX337013B MX 337013 B MX337013 B MX 337013B MX 2011013531 A MX2011013531 A MX 2011013531A MX 2011013531 A MX2011013531 A MX 2011013531A MX 337013 B MX337013 B MX 337013B
- Authority
- MX
- Mexico
- Prior art keywords
- catalytic activity
- high catalytic
- unsupported
- catalysts
- hydrotreatments
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 230000003197 catalytic effect Effects 0.000 title abstract 3
- DUDJJJCZFBPZKW-UHFFFAOYSA-N [Ru]=S Chemical compound [Ru]=S DUDJJJCZFBPZKW-UHFFFAOYSA-N 0.000 title abstract 2
- 229930195733 hydrocarbon Natural products 0.000 title abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 title 1
- 238000001308 synthesis method Methods 0.000 abstract 2
- 230000007613 environmental effect Effects 0.000 abstract 1
- -1 hydrodesulfuration Chemical class 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/043—Sulfides with iron group metals or platinum group metals
- B01J27/045—Platinum group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/10—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing platinum group metals or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
La presente invención proporciona un método para la síntesis de una familia de catalizadores de sulfuro de rutenio promovido, es decir, con un metal adicional añadido, másicos (M/RuS2) y soportados (M/RuS2/soporte). Los catalizadores obtenidos exhiben una alta actividad catalítica en reacciones de hidrotratamiento o hidroprocesamiento (HDT), principalmente hidrodesulfuración, hidrodenitrogenación e hidrodeoxigenación de hidrocarburos. El impacto de la presente invención para su aplicación en el contexto comercial, reside en la alta actividad catalítica de los catalizadores obtenidos, muy superior a la de los catalizadores comerciales existentes, así como la simplicidad del método de síntesis, lo cual repercutirá en la calidad de los productos obtenidos en la industria petrolera, permitiendo cumplir los estándares ambientales dispuestos por las legislaciones actuales.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2011013531A MX337013B (es) | 2011-12-14 | 2011-12-14 | Catalizadores masicos y soportados de sulfuro de rutenio promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtencion. |
US13/444,534 US8853119B2 (en) | 2011-12-14 | 2012-04-11 | Unsupported and supported promoted ruthenium sulfide catalyst with high catalytic activity for hydrocarbon hydrotreatments and its method |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
MX2011013531A MX337013B (es) | 2011-12-14 | 2011-12-14 | Catalizadores masicos y soportados de sulfuro de rutenio promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtencion. |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2011013531A MX2011013531A (es) | 2013-06-17 |
MX337013B true MX337013B (es) | 2015-12-15 |
Family
ID=48610706
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2011013531A MX337013B (es) | 2011-12-14 | 2011-12-14 | Catalizadores masicos y soportados de sulfuro de rutenio promovido con alta actividad catalitica para reacciones de hidrotratamiento de hidrocarburos y su metodo de obtencion. |
Country Status (2)
Country | Link |
---|---|
US (1) | US8853119B2 (es) |
MX (1) | MX337013B (es) |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3055840A (en) * | 1958-01-13 | 1962-09-25 | Engelhard Ind Inc | Ruthenium-containing catalysts and methods of making said catalysts and increasing their activity |
US4279737A (en) * | 1978-02-23 | 1981-07-21 | Exxon Research & Engineering Co. | Hydrodesulfurization over catalysts comprising chalcogenides of group VIII prepared by low temperature precipitation from nonaqueous solution |
US4288422A (en) * | 1979-02-23 | 1981-09-08 | Exxon Research & Engineering Co. | Method of preparing chalcogenides of group VIII by low temperature precipitation from monaqueous solution, the products produced by said method and their use as catalysts |
FR2678179B1 (fr) * | 1991-06-26 | 1995-01-13 | Elf Antar France | Catalyseur d'hydroraffinage renfermant des sulfures de ruthenium et d'au moins un autre metal sur un support d'oxydes refractaires et procede d'hydroraffinage mettant en óoeuvre ledit catalyseur. |
AU7270896A (en) * | 1995-10-13 | 1997-05-07 | K.U. Leuven Research & Development | Chiral solid catalyst, its preparation and its use for the production of substantially enantiomerically pure products |
US6299760B1 (en) * | 1999-08-12 | 2001-10-09 | Exxon Research And Engineering Company | Nickel molybodtungstate hydrotreating catalysts (law444) |
EP1313559B2 (en) * | 2000-08-10 | 2012-10-24 | Trustees of Boston College | Recyclable metathesis catalysts |
US6426437B1 (en) * | 2000-12-13 | 2002-07-30 | Arco Chemical Technology, L.P. | Hydroformylation process |
US7879753B2 (en) * | 2003-05-27 | 2011-02-01 | Industrie De Nora S.P.A. | Catalyst for oxygen reduction |
US7812251B2 (en) * | 2003-10-17 | 2010-10-12 | Sharp Kabushiki Kaisha | Photosensitizing transition metal complex and its use for photovoltaic cell |
US6967185B2 (en) * | 2004-01-28 | 2005-11-22 | De Nora Elettrodi S.P.A. | Synthesis of noble metal, sulphide catalysts in a sulfide ion-free aqueous environment |
EP1767524B1 (en) * | 2004-07-02 | 2013-05-22 | Japan Science and Technology Agency | Process for production of optically active aziridines and amines, complexes used in the process, and intermediates thereof |
CN1325384C (zh) * | 2005-03-31 | 2007-07-11 | 南京大学 | 多孔硫化钌纳米球及其制法 |
CN1325385C (zh) * | 2005-03-31 | 2007-07-11 | 南京大学 | 一种硫化钌纳米颗粒的制法 |
BRPI0601787B1 (pt) * | 2006-05-17 | 2016-06-07 | Petroleo Brasileiro Sa | processo de hidrodessulfurização seletiva de nafta |
US7772445B2 (en) * | 2007-07-06 | 2010-08-10 | Kanata Chemical Technologies Inc. | Ruthenium catalysts for catalytic hydrogenation |
CN101544904B (zh) * | 2008-03-28 | 2012-11-14 | 中国科学院大连化学物理研究所 | 一种复合金属氧化物催化剂及制备和应用 |
JP5191972B2 (ja) * | 2008-10-30 | 2013-05-08 | 高砂香料工業株式会社 | ルテニウム錯体の製造方法 |
EP2196260A1 (en) * | 2008-12-02 | 2010-06-16 | Research Institute of Petroleum Industry (RIPI) | Hydrodesulphurization nanocatalyst, its use and a process for its production |
JP5276043B2 (ja) * | 2009-05-19 | 2013-08-28 | 高砂香料工業株式会社 | 含ケイ素置換基で置換された芳香環を配位子とするルテニウム錯体及びその製造方法 |
US7893290B1 (en) * | 2010-04-13 | 2011-02-22 | W.C. Heraeus Gmbh | Process for the preparation of bis(pentadienyl)-complexes of iron group metals |
-
2011
- 2011-12-14 MX MX2011013531A patent/MX337013B/es active IP Right Grant
-
2012
- 2012-04-11 US US13/444,534 patent/US8853119B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US20130157842A1 (en) | 2013-06-20 |
MX2011013531A (es) | 2013-06-17 |
US8853119B2 (en) | 2014-10-07 |
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Legal Events
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FG | Grant or registration |