MX3355E - METHOD OF PREPARATION OF MALO-2-PYRROLIDINONES N-SUBSTITUTED ACICLIC ALICYCLIC AND AROMATIC - Google Patents
METHOD OF PREPARATION OF MALO-2-PYRROLIDINONES N-SUBSTITUTED ACICLIC ALICYCLIC AND AROMATICInfo
- Publication number
- MX3355E MX3355E MX000109U MX10976U MX3355E MX 3355 E MX3355 E MX 3355E MX 000109 U MX000109 U MX 000109U MX 10976 U MX10976 U MX 10976U MX 3355 E MX3355 E MX 3355E
- Authority
- MX
- Mexico
- Prior art keywords
- pyrrolidinones
- aromatic
- substituted
- aciclic
- malo
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
- C07D207/26—2-Pyrrolidones
- C07D207/273—2-Pyrrolidones with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to other ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/18—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
- C07D207/22—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/24—Oxygen or sulfur atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pyrrole Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente inveción se refiere a método de preparar halo-2-pirrolidinonas n-substituídas acíclicas y aromáticas de la fórmula: (ver gaseta) en donde R es alquilo inferior, alohalquilo, alquenilo, cicloalquilo, cicloalquilalquilo, bencilo y corobencilo, X es un hidrógeno o cloro; y es un cloro o bromo, y Z es un cloro o bromo caracterizada N-alquenila haloacilo de la fórmula: (ver gaseta) en donde R, X y Z son como se define antes en la presecia de una cantidad catalítica de ión ferroso a una temperatura entre aproximadamente 50°C, y aproximadamente 190°C y recuperar el producto resultante.The present invention relates to a method of preparing acyclic and aromatic n-substituted halo-2-pyrrolidinones of the formula: (see gasket) wherein R is lower alkyl, allohalkyl, alkenyl, cycloalkyl, cycloalkylalkyl, benzyl and chorobenzyl, X is a hydrogen or chlorine; y is a chlorine or bromine, and Z is a chlorine or bromine characterized N-alkenyl haloacyl of the formula: (see gasket) where R, X and Z are as defined above in the presence of a catalytic amount of ferrous ion at a temperature between about 50 ° C, and about 190 ° C and recover the resulting product.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US56327975A | 1975-03-28 | 1975-03-28 | |
US56328075A | 1975-03-28 | 1975-03-28 | |
US05/647,962 US4069038A (en) | 1975-03-28 | 1976-01-09 | Acyclic and alicyclic N-substituted halo-2-pyrrolidinones and their utility as herbicides |
US05/647,963 US4110105A (en) | 1975-03-28 | 1976-01-09 | Aromatic N-substituted halo-substituted-2-pyrrolidinones and their utility as herbicides |
Publications (1)
Publication Number | Publication Date |
---|---|
MX3355E true MX3355E (en) | 1980-10-13 |
Family
ID=27504836
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX000109U MX3355E (en) | 1975-03-28 | 1976-03-24 | METHOD OF PREPARATION OF MALO-2-PYRROLIDINONES N-SUBSTITUTED ACICLIC ALICYCLIC AND AROMATIC |
Country Status (25)
Country | Link |
---|---|
JP (1) | JPS6011695B2 (en) |
AU (1) | AU502662B2 (en) |
BE (1) | BE839977A (en) |
BG (2) | BG29122A3 (en) |
BR (1) | BR7601774A (en) |
CA (1) | CA1076588A (en) |
CH (1) | CH625394A5 (en) |
DD (1) | DD126149A5 (en) |
DE (2) | DE2661042C2 (en) |
DK (1) | DK145891C (en) |
ES (1) | ES446388A1 (en) |
FR (1) | FR2305434A1 (en) |
GB (1) | GB1522869A (en) |
HU (1) | HU179058B (en) |
IL (1) | IL49289A (en) |
IN (1) | IN143281B (en) |
IT (1) | IT1057396B (en) |
MX (1) | MX3355E (en) |
MY (1) | MY8000091A (en) |
NL (1) | NL187313C (en) |
NZ (1) | NZ180424A (en) |
PH (1) | PH15176A (en) |
PL (2) | PL102693B1 (en) |
SU (1) | SU942590A3 (en) |
YU (1) | YU40279B (en) |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU527254B2 (en) * | 1979-02-26 | 1983-02-24 | Stauffer Chemical Company | Synergistic herbicides |
EP0055215B1 (en) * | 1980-12-19 | 1985-01-30 | Ciba-Geigy Ag | Fluoropyrrolidinones, process for their preparation, herbicides containing them and their use |
DK162087C (en) * | 1983-06-16 | 1992-02-24 | Stauffer Chemical Co | PROCEDURE FOR THE PREPARATION OF N-ARYLHALOGEN PYROLIDONES |
FI74385C (en) * | 1983-12-05 | 1988-02-08 | Stauffer Chemical Co | SYNERGISTIC HERBICIDBLANDNINGAR AV TIOKARBAMAT OCH PYRROLIDONFOERENING. |
FR2589150B2 (en) * | 1985-10-25 | 1987-11-20 | Rhone Poulenc Spec Chim | PROCESS FOR THE PREPARATION OF N ALCENE-2 YL M.TRIFLUOROMETHYLANILINES |
EP0205391B1 (en) * | 1985-05-22 | 1988-10-26 | Rhone-Poulenc Chimie | Process for the preparation of n-alkenyl-m-trifluoromethyl anilines |
FR2582300B1 (en) * | 1985-05-22 | 1987-07-10 | Rhone Poulenc Spec Chim | PROCESS FOR THE PREPARATION OF N-2 ALCENE-2 YL M-TRIFLUOROMETHYLANILINES |
FR2625197B1 (en) * | 1987-12-23 | 1990-04-27 | Rhone Poulenc Chimie | PROCESS FOR ACYLATION OF N, N-DIALLYLANILINE |
US5189220A (en) * | 1988-07-29 | 1993-02-23 | Rhone-Poulenc Chimie | Process for preparing N-alkylanilines and N-allylanilines catalyzed by iodides |
FR2634761B1 (en) * | 1988-07-29 | 1990-11-23 | Rhone Poulenc Chimie | PROCESS FOR THE PREPARATION OF N-ALLYL AND N-ALKYLANILINES |
US5210305A (en) * | 1988-07-29 | 1993-05-11 | Rhone-Poulenc Chimie | Process for preparing n-alkylanilines and n-allylanilines |
FR2634762B1 (en) * | 1988-07-29 | 1990-11-02 | Rhone Poulenc Chimie | PROCESS FOR THE PREPARATION OF N-ALLYL AND ALKYL-ANILINES |
FR2643902B1 (en) * | 1989-03-03 | 1991-10-11 | Rhone Poulenc Chimie | PROCESS FOR THE PREPARATION OF N-ALLYLMETATRIFLUOROMETHYLANILINE |
JPH02237970A (en) * | 1989-03-13 | 1990-09-20 | Mitsui Toatsu Chem Inc | 4-ethyl-1-(3-trifluoromethylphenyl)-2-pyrrolidinone derivative and herbicide containing the derivative as active component |
FR2663927A1 (en) * | 1989-06-05 | 1992-01-03 | Rhone Poulenc Chimie | PROCESS FOR THE PREPARATION OF N MONOALKYL- OR ALKENYLANILINES. |
JP2728937B2 (en) * | 1989-06-14 | 1998-03-18 | 三井東圧化学株式会社 | 1- (3-Substituted benzyl) -3-halogen-4- (1-halogenoalkyl) -2-pyrrolidinone derivatives and herbicides containing these as active ingredients |
FR2665439B1 (en) * | 1990-08-02 | 1992-11-06 | Rhone Poulenc Chimie | N-ALLYLATION REAGENT AND METHOD FOR SYNTHESIS OF N ACYL, N ALLYLANILINE. |
ATE160140T1 (en) * | 1990-08-02 | 1997-11-15 | Rhone Poulenc Chimie | ALLYLATION REAGENT AND A PRODUCTION METHOD USING IT |
US5538985A (en) * | 1994-01-27 | 1996-07-23 | Mitsui Toatsu Chemicals, Inc. | Pyrrolidinone derivatives |
EP2052612A1 (en) | 2007-10-24 | 2009-04-29 | Bayer CropScience AG | Herbicide combination |
DE102008037629A1 (en) | 2008-08-14 | 2010-02-18 | Bayer Cropscience Ag | Herbicide combination with dimethoxytriazinyl-substituted difluoromethanesulfonylanilides |
CN114031536A (en) * | 2021-12-14 | 2022-02-11 | 青海省农林科学院 | Pure optical isomer compound for inhibiting weed seed germination and seedling growth and application |
WO2023233367A1 (en) | 2022-06-03 | 2023-12-07 | Adama Agan Ltd. | Herbicidal mixtures for crop protection |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS49134835A (en) * | 1973-05-08 | 1974-12-25 |
-
1976
- 1976-03-17 HU HU76SA2904A patent/HU179058B/en unknown
- 1976-03-17 FR FR7607683A patent/FR2305434A1/en active Granted
- 1976-03-19 JP JP51030778A patent/JPS6011695B2/en not_active Expired
- 1976-03-23 BR BR7601774A patent/BR7601774A/en unknown
- 1976-03-23 IN IN510/CAL/1976A patent/IN143281B/en unknown
- 1976-03-23 GB GB11627/76A patent/GB1522869A/en not_active Expired
- 1976-03-24 CH CH368776A patent/CH625394A5/en not_active IP Right Cessation
- 1976-03-24 PH PH18252A patent/PH15176A/en unknown
- 1976-03-24 BE BE7000801A patent/BE839977A/en not_active IP Right Cessation
- 1976-03-24 MX MX000109U patent/MX3355E/en unknown
- 1976-03-25 DE DE2661042A patent/DE2661042C2/de not_active Expired
- 1976-03-25 BG BG032702A patent/BG29122A3/en unknown
- 1976-03-25 DE DE2612731A patent/DE2612731C2/en not_active Expired
- 1976-03-25 BG BG033675A patent/BG29135A3/en unknown
- 1976-03-25 NZ NZ180424A patent/NZ180424A/en unknown
- 1976-03-25 IL IL49289A patent/IL49289A/en unknown
- 1976-03-25 DD DD192041A patent/DD126149A5/xx unknown
- 1976-03-26 YU YU800/76A patent/YU40279B/en unknown
- 1976-03-26 AU AU12413/76A patent/AU502662B2/en not_active Expired
- 1976-03-26 NL NLAANVRAGE7603193,A patent/NL187313C/en not_active IP Right Cessation
- 1976-03-26 IT IT48736/76A patent/IT1057396B/en active
- 1976-03-26 DK DK135776A patent/DK145891C/en not_active IP Right Cessation
- 1976-03-26 CA CA248,947A patent/CA1076588A/en not_active Expired
- 1976-03-26 ES ES446388A patent/ES446388A1/en not_active Expired
- 1976-03-27 PL PL1976200412A patent/PL102693B1/en unknown
- 1976-03-27 PL PL1976188292A patent/PL100036B1/en unknown
- 1976-11-23 SU SU762421801A patent/SU942590A3/en active
-
1980
- 1980-12-30 MY MY91/80A patent/MY8000091A/en unknown
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