MX3355E - METHOD OF PREPARATION OF MALO-2-PYRROLIDINONES N-SUBSTITUTED ACICLIC ALICYCLIC AND AROMATIC - Google Patents

METHOD OF PREPARATION OF MALO-2-PYRROLIDINONES N-SUBSTITUTED ACICLIC ALICYCLIC AND AROMATIC

Info

Publication number
MX3355E
MX3355E MX000109U MX10976U MX3355E MX 3355 E MX3355 E MX 3355E MX 000109 U MX000109 U MX 000109U MX 10976 U MX10976 U MX 10976U MX 3355 E MX3355 E MX 3355E
Authority
MX
Mexico
Prior art keywords
pyrrolidinones
aromatic
substituted
aciclic
malo
Prior art date
Application number
MX000109U
Other languages
Spanish (es)
Inventor
Eugene Gordon Teach
Original Assignee
Stauffer Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/647,962 external-priority patent/US4069038A/en
Priority claimed from US05/647,963 external-priority patent/US4110105A/en
Application filed by Stauffer Chemical Co filed Critical Stauffer Chemical Co
Publication of MX3355E publication Critical patent/MX3355E/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D207/00Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/22Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/24Oxygen or sulfur atoms
    • C07D207/262-Pyrrolidones
    • C07D207/2732-Pyrrolidones with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to other ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D207/00Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/18Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member
    • C07D207/22Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D207/24Oxygen or sulfur atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pyrrole Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente inveción se refiere a método de preparar halo-2-pirrolidinonas n-substituídas acíclicas y aromáticas de la fórmula: (ver gaseta) en donde R es alquilo inferior, alohalquilo, alquenilo, cicloalquilo, cicloalquilalquilo, bencilo y corobencilo, X es un hidrógeno o cloro; y es un cloro o bromo, y Z es un cloro o bromo caracterizada N-alquenila haloacilo de la fórmula: (ver gaseta) en donde R, X y Z son como se define antes en la presecia de una cantidad catalítica de ión ferroso a una temperatura entre aproximadamente 50°C, y aproximadamente 190°C y recuperar el producto resultante.The present invention relates to a method of preparing acyclic and aromatic n-substituted halo-2-pyrrolidinones of the formula: (see gasket) wherein R is lower alkyl, allohalkyl, alkenyl, cycloalkyl, cycloalkylalkyl, benzyl and chorobenzyl, X is a hydrogen or chlorine; y is a chlorine or bromine, and Z is a chlorine or bromine characterized N-alkenyl haloacyl of the formula: (see gasket) where R, X and Z are as defined above in the presence of a catalytic amount of ferrous ion at a temperature between about 50 ° C, and about 190 ° C and recover the resulting product.

MX000109U 1975-03-28 1976-03-24 METHOD OF PREPARATION OF MALO-2-PYRROLIDINONES N-SUBSTITUTED ACICLIC ALICYCLIC AND AROMATIC MX3355E (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US56327975A 1975-03-28 1975-03-28
US56328075A 1975-03-28 1975-03-28
US05/647,962 US4069038A (en) 1975-03-28 1976-01-09 Acyclic and alicyclic N-substituted halo-2-pyrrolidinones and their utility as herbicides
US05/647,963 US4110105A (en) 1975-03-28 1976-01-09 Aromatic N-substituted halo-substituted-2-pyrrolidinones and their utility as herbicides

Publications (1)

Publication Number Publication Date
MX3355E true MX3355E (en) 1980-10-13

Family

ID=27504836

Family Applications (1)

Application Number Title Priority Date Filing Date
MX000109U MX3355E (en) 1975-03-28 1976-03-24 METHOD OF PREPARATION OF MALO-2-PYRROLIDINONES N-SUBSTITUTED ACICLIC ALICYCLIC AND AROMATIC

Country Status (25)

Country Link
JP (1) JPS6011695B2 (en)
AU (1) AU502662B2 (en)
BE (1) BE839977A (en)
BG (2) BG29122A3 (en)
BR (1) BR7601774A (en)
CA (1) CA1076588A (en)
CH (1) CH625394A5 (en)
DD (1) DD126149A5 (en)
DE (2) DE2661042C2 (en)
DK (1) DK145891C (en)
ES (1) ES446388A1 (en)
FR (1) FR2305434A1 (en)
GB (1) GB1522869A (en)
HU (1) HU179058B (en)
IL (1) IL49289A (en)
IN (1) IN143281B (en)
IT (1) IT1057396B (en)
MX (1) MX3355E (en)
MY (1) MY8000091A (en)
NL (1) NL187313C (en)
NZ (1) NZ180424A (en)
PH (1) PH15176A (en)
PL (2) PL102693B1 (en)
SU (1) SU942590A3 (en)
YU (1) YU40279B (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU527254B2 (en) * 1979-02-26 1983-02-24 Stauffer Chemical Company Synergistic herbicides
EP0055215B1 (en) * 1980-12-19 1985-01-30 Ciba-Geigy Ag Fluoropyrrolidinones, process for their preparation, herbicides containing them and their use
DK162087C (en) * 1983-06-16 1992-02-24 Stauffer Chemical Co PROCEDURE FOR THE PREPARATION OF N-ARYLHALOGEN PYROLIDONES
FI74385C (en) * 1983-12-05 1988-02-08 Stauffer Chemical Co SYNERGISTIC HERBICIDBLANDNINGAR AV TIOKARBAMAT OCH PYRROLIDONFOERENING.
FR2589150B2 (en) * 1985-10-25 1987-11-20 Rhone Poulenc Spec Chim PROCESS FOR THE PREPARATION OF N ALCENE-2 YL M.TRIFLUOROMETHYLANILINES
EP0205391B1 (en) * 1985-05-22 1988-10-26 Rhone-Poulenc Chimie Process for the preparation of n-alkenyl-m-trifluoromethyl anilines
FR2582300B1 (en) * 1985-05-22 1987-07-10 Rhone Poulenc Spec Chim PROCESS FOR THE PREPARATION OF N-2 ALCENE-2 YL M-TRIFLUOROMETHYLANILINES
FR2625197B1 (en) * 1987-12-23 1990-04-27 Rhone Poulenc Chimie PROCESS FOR ACYLATION OF N, N-DIALLYLANILINE
US5189220A (en) * 1988-07-29 1993-02-23 Rhone-Poulenc Chimie Process for preparing N-alkylanilines and N-allylanilines catalyzed by iodides
FR2634761B1 (en) * 1988-07-29 1990-11-23 Rhone Poulenc Chimie PROCESS FOR THE PREPARATION OF N-ALLYL AND N-ALKYLANILINES
US5210305A (en) * 1988-07-29 1993-05-11 Rhone-Poulenc Chimie Process for preparing n-alkylanilines and n-allylanilines
FR2634762B1 (en) * 1988-07-29 1990-11-02 Rhone Poulenc Chimie PROCESS FOR THE PREPARATION OF N-ALLYL AND ALKYL-ANILINES
FR2643902B1 (en) * 1989-03-03 1991-10-11 Rhone Poulenc Chimie PROCESS FOR THE PREPARATION OF N-ALLYLMETATRIFLUOROMETHYLANILINE
JPH02237970A (en) * 1989-03-13 1990-09-20 Mitsui Toatsu Chem Inc 4-ethyl-1-(3-trifluoromethylphenyl)-2-pyrrolidinone derivative and herbicide containing the derivative as active component
FR2663927A1 (en) * 1989-06-05 1992-01-03 Rhone Poulenc Chimie PROCESS FOR THE PREPARATION OF N MONOALKYL- OR ALKENYLANILINES.
JP2728937B2 (en) * 1989-06-14 1998-03-18 三井東圧化学株式会社 1- (3-Substituted benzyl) -3-halogen-4- (1-halogenoalkyl) -2-pyrrolidinone derivatives and herbicides containing these as active ingredients
FR2665439B1 (en) * 1990-08-02 1992-11-06 Rhone Poulenc Chimie N-ALLYLATION REAGENT AND METHOD FOR SYNTHESIS OF N ACYL, N ALLYLANILINE.
ATE160140T1 (en) * 1990-08-02 1997-11-15 Rhone Poulenc Chimie ALLYLATION REAGENT AND A PRODUCTION METHOD USING IT
US5538985A (en) * 1994-01-27 1996-07-23 Mitsui Toatsu Chemicals, Inc. Pyrrolidinone derivatives
EP2052612A1 (en) 2007-10-24 2009-04-29 Bayer CropScience AG Herbicide combination
DE102008037629A1 (en) 2008-08-14 2010-02-18 Bayer Cropscience Ag Herbicide combination with dimethoxytriazinyl-substituted difluoromethanesulfonylanilides
CN114031536A (en) * 2021-12-14 2022-02-11 青海省农林科学院 Pure optical isomer compound for inhibiting weed seed germination and seedling growth and application
WO2023233367A1 (en) 2022-06-03 2023-12-07 Adama Agan Ltd. Herbicidal mixtures for crop protection

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS49134835A (en) * 1973-05-08 1974-12-25

Also Published As

Publication number Publication date
NL7603193A (en) 1976-09-30
JPS6011695B2 (en) 1985-03-27
BE839977A (en) 1976-09-24
IT1057396B (en) 1982-03-10
YU80076A (en) 1983-01-21
DE2661042C2 (en) 1989-11-09
GB1522869A (en) 1978-08-31
AU1241376A (en) 1977-09-29
BG29122A3 (en) 1980-09-15
YU40279B (en) 1985-12-31
CA1076588A (en) 1980-04-29
DK145891C (en) 1983-09-12
NL187313C (en) 1991-08-16
PL100036B1 (en) 1978-08-31
PL102693B1 (en) 1979-04-30
IL49289A0 (en) 1976-05-31
HU179058B (en) 1982-08-28
JPS5289666A (en) 1977-07-27
PH15176A (en) 1982-08-31
AU502662B2 (en) 1979-08-02
FR2305434A1 (en) 1976-10-22
ES446388A1 (en) 1977-10-01
DD126149A5 (en) 1977-06-22
CH625394A5 (en) 1981-09-30
DE2612731A1 (en) 1976-10-07
BR7601774A (en) 1977-10-25
SU942590A3 (en) 1982-07-07
DE2612731C2 (en) 1986-06-26
IL49289A (en) 1979-09-30
DK135776A (en) 1976-09-29
FR2305434B1 (en) 1981-08-07
NL187313B (en) 1991-03-18
IN143281B (en) 1977-10-29
DK145891B (en) 1983-04-05
NZ180424A (en) 1978-03-06
MY8000091A (en) 1980-12-31
BG29135A3 (en) 1980-09-15

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