MX2022014501A - Sistema de catalizadores binarios (cocatalizadores) de ácido o base de lewis o de bronsted y fosfuro de níquel para la reducción electroquímica directa de c02 hacia hidrocarburos. - Google Patents

Sistema de catalizadores binarios (cocatalizadores) de ácido o base de lewis o de bronsted y fosfuro de níquel para la reducción electroquímica directa de c02 hacia hidrocarburos.

Info

Publication number
MX2022014501A
MX2022014501A MX2022014501A MX2022014501A MX2022014501A MX 2022014501 A MX2022014501 A MX 2022014501A MX 2022014501 A MX2022014501 A MX 2022014501A MX 2022014501 A MX2022014501 A MX 2022014501A MX 2022014501 A MX2022014501 A MX 2022014501A
Authority
MX
Mexico
Prior art keywords
cocatalyst
sub
lewis
hydrocarbons
nickel phosphide
Prior art date
Application number
MX2022014501A
Other languages
English (en)
Inventor
Charles G Dismukes
Anders Bo Laursen
Karin Ute Doehl Calvinho
Original Assignee
Univ Rutgers
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US16/878,165 external-priority patent/US12286714B2/en
Application filed by Univ Rutgers filed Critical Univ Rutgers
Publication of MX2022014501A publication Critical patent/MX2022014501A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/07—Oxygen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/054—Electrodes comprising electrocatalysts supported on a carrier
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/095—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one of the compounds being organic
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/25—Reduction
    • C25B3/26—Reduction of carbon dioxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Catalysts (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se divulgan cátodos que comprenden un sustrato de soporte conductor que tiene un recubrimiento de electrocatalizador que contiene nanopartículas de fosfuro de níquel y un cocatalizador. El sustrato de soporte conductor es capaz de incorporar un material que se ha de reducir, como 002 o 00. Un cocatalizador, incorporado en la solución de electrolito o en el soporte conductor 0 adsorbido, depositado o incorporado en el material de cátodo a granel, altera las propiedades del electrocatalizador mediante el aumento de la selectividad del producto carbono a través de interacciones con los compuestos intermedios. También se divulgan métodos electroquímicos para generar en forma selectiva productos hidrocarburos y/o carbohidratos a partir de 002 o 00 mediante el uso de agua como una fuente de hidrógeno.
MX2022014501A 2020-05-19 2021-05-19 Sistema de catalizadores binarios (cocatalizadores) de ácido o base de lewis o de bronsted y fosfuro de níquel para la reducción electroquímica directa de c02 hacia hidrocarburos. MX2022014501A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US16/878,165 US12286714B2 (en) 2015-10-09 2020-05-19 Nickel phosphide catalysts for direct electrochemical CO2 reduction to hydrocarbons
PCT/US2021/033119 WO2021236746A1 (en) 2020-05-19 2021-05-19 Lewis/bronsted acid/base and nickel phosphide binary catalyst-system (co-catalysts) for direct electrochemical co2 reduction to hydrocarbons

Publications (1)

Publication Number Publication Date
MX2022014501A true MX2022014501A (es) 2023-02-09

Family

ID=78708029

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2022014501A MX2022014501A (es) 2020-05-19 2021-05-19 Sistema de catalizadores binarios (cocatalizadores) de ácido o base de lewis o de bronsted y fosfuro de níquel para la reducción electroquímica directa de c02 hacia hidrocarburos.

Country Status (10)

Country Link
EP (1) EP4154340A4 (es)
JP (1) JP2023527760A (es)
KR (1) KR20230012603A (es)
CN (1) CN116235326A (es)
AU (1) AU2021276383B2 (es)
BR (1) BR112022023582A2 (es)
CA (1) CA3179219A1 (es)
IL (1) IL298358A (es)
MX (1) MX2022014501A (es)
WO (1) WO2021236746A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102022207521A1 (de) * 2022-07-22 2024-01-25 Volkswagen Aktiengesellschaft Verfahren zur Herstellung von Propylen und Polypropylen aus CO2
WO2024137997A1 (en) * 2022-12-21 2024-06-27 Renewco2 Inc. System and method for single-conversion-step electrocatalytic reduction of co2 to ethylene glycol in liquid phase dual membrane electrolyzer
WO2024137897A1 (en) * 2022-12-21 2024-06-27 Renewco2 Inc. Liquid phase dual membrane single-conversion-step electrolyzer for reduction of co 2 to ethylene glycol
WO2024137895A1 (en) * 2022-12-21 2024-06-27 Renewco2 Inc. Proton exchange membrane electrolyzer for single- conversion-step electrocatalytic reduction of co2 to ethylene glycol
DE102023204127A1 (de) * 2023-05-04 2024-11-21 Volkswagen Aktiengesellschaft Polyethylen aus CO2
DE102023208909A1 (de) 2023-09-13 2025-03-13 Volkswagen Aktiengesellschaft Elektrodenmaterial für die elektrochemische Reduktion von Kohlenstoffdioxid, Elektrode und elektrochemische Zelle umfassend ein solches Elektrodenmaterial
WO2025101899A1 (en) * 2023-11-08 2025-05-15 Renewco2 Inc. Apparatus and methods for electrocatalytic and hydrogenation conversion of hydrocarbon fuels from carbon dioxide
WO2025101853A1 (en) * 2023-11-08 2025-05-15 Renewco2 Inc. Apparatus and method for producing formate salt brines from carbon dioxide and alkali brines
CN119932635A (zh) * 2025-01-24 2025-05-06 中国科学院生态环境研究中心 一种阴离子离聚物修饰银基电极及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200810210A (en) * 2006-04-14 2008-02-16 Applied Materials Inc Reliable fuel cell electrode design
US20110237830A1 (en) * 2010-03-26 2011-09-29 Dioxide Materials Inc Novel catalyst mixtures
JP2015513616A (ja) * 2012-03-06 2015-05-14 リキッド・ライト・インコーポレーテッドＬｉｑｕｉｄ Ｌｉｇｈｔ Ｉｎｃｏｒｐｏｒａｔｅｄ 二酸化炭素の生成物への還元
EP3014695B1 (en) * 2013-06-27 2019-01-16 The Board of Trustees of the University of Illionis Catalysts for carbon dioxide conversion
DE102015202258A1 (de) * 2015-02-09 2016-08-25 Siemens Aktiengesellschaft Reduktionsverfahren und Elektrolysesystem zur elektrochemischen Kohlenstoffdioxid-Verwertung
US10676833B2 (en) * 2015-10-09 2020-06-09 Rutgers, The State University Of New Jersey Nickel phosphide catalysts for direct electrochemical CO2 reduction to hydrocarbons
US20180171492A1 (en) * 2016-12-20 2018-06-21 Board Of Trustees Of The University Of Illinois Photoelectrochemical cell for carbon dioxide conversion

Also Published As

Publication number Publication date
JP2023527760A (ja) 2023-06-30
AU2021276383A1 (en) 2023-01-19
WO2021236746A1 (en) 2021-11-25
BR112022023582A2 (pt) 2023-01-03
IL298358A (en) 2023-01-01
CN116235326A (zh) 2023-06-06
EP4154340A4 (en) 2024-07-31
EP4154340A1 (en) 2023-03-29
CA3179219A1 (en) 2021-11-25
AU2021276383B2 (en) 2025-09-11
KR20230012603A (ko) 2023-01-26

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