MX2020001449A - Proceso de varias etapas para convertir alquilenoureas ciclicas en sus correspondientes alquilenaminas. - Google Patents
Proceso de varias etapas para convertir alquilenoureas ciclicas en sus correspondientes alquilenaminas.Info
- Publication number
- MX2020001449A MX2020001449A MX2020001449A MX2020001449A MX2020001449A MX 2020001449 A MX2020001449 A MX 2020001449A MX 2020001449 A MX2020001449 A MX 2020001449A MX 2020001449 A MX2020001449 A MX 2020001449A MX 2020001449 A MX2020001449 A MX 2020001449A
- Authority
- MX
- Mexico
- Prior art keywords
- alkyleneamines
- alkyleneureas
- removal step
- cyclic alkyleneureas
- step process
- Prior art date
Links
- 125000004122 cyclic group Chemical group 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 150000001412 amines Chemical class 0.000 abstract 3
- -1 amine compound Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 150000003141 primary amines Chemical class 0.000 abstract 1
- 150000003335 secondary amines Chemical class 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/62—Preparation of compounds containing amino groups bound to a carbon skeleton by cleaving carbon-to-nitrogen, sulfur-to-nitrogen, or phosphorus-to-nitrogen bonds, e.g. hydrolysis of amides, N-dealkylation of amines or quaternary ammonium compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1475—Removing carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/82—Purification; Separation; Stabilisation; Use of additives
- C07C209/86—Separation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/14—Amines containing amino groups bound to at least two aminoalkyl groups, e.g. diethylenetriamines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C213/00—Preparation of compounds containing amino and hydroxy, amino and etherified hydroxy or amino and esterified hydroxy groups bound to the same carbon skeleton
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/202—Alcohols or their derivatives
- B01D2252/2021—Methanol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
- B01D2252/20—Organic absorbents
- B01D2252/204—Amines
- B01D2252/20436—Cyclic amines
- B01D2252/20447—Cyclic amines containing a piperazine-ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
La invención se refiere a un proceso para convertir una materia prima que comprende alquilenoureas cíclicas en sus correspondientes alquilenoaminas, que comprende - una etapa de eliminación del CO2 en la que las alquilenoureas cíclicas se convierten en sus correspondientes alquilenoaminas mediante la reacción de alquilenoureas cíclicas en la fase líquida, con agua, habiendo eliminación del CO2, - una etapa de eliminación de aminas en la que las alquilenoureas cíclicas se convierten en un proceso de separación reactiva en sus correspondientes alquilenoaminas mediante reacción con un compuesto de amina seleccionado a partir del grupo de aminas primarias o aminas secundarias que tienen una temperatura de ebullición más elevada que las alquilenoaminas formadas durante el proceso. Se ha descubierto que la combinación de una etapa de eliminación de CO2 y una etapa de eliminación de aminas permite convertir alquilenureas en las aminas correspondientes de manera eficiente en una elevada velocidad de reacción.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP17185945 | 2017-08-11 | ||
PCT/EP2018/071319 WO2019030190A1 (en) | 2017-08-11 | 2018-08-07 | MULTI-STEP PROCESS FOR CONVERTING CYCLIC ALKYLENE UREA TO THEIR CORRESPONDING ALKYLENE AMINES |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2020001449A true MX2020001449A (es) | 2020-03-20 |
Family
ID=59592932
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2020001449A MX2020001449A (es) | 2017-08-11 | 2018-08-07 | Proceso de varias etapas para convertir alquilenoureas ciclicas en sus correspondientes alquilenaminas. |
Country Status (10)
Country | Link |
---|---|
US (1) | US11236039B2 (es) |
EP (1) | EP3665153A1 (es) |
JP (2) | JP2020530455A (es) |
KR (1) | KR20200036011A (es) |
CN (1) | CN111032616B (es) |
BR (1) | BR112020002389B1 (es) |
CA (1) | CA3071903A1 (es) |
MX (1) | MX2020001449A (es) |
TW (1) | TWI761570B (es) |
WO (1) | WO2019030190A1 (es) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110072841B (zh) | 2016-12-15 | 2022-04-19 | 阿克苏诺贝尔化学品国际有限公司 | 制备羟乙基亚乙基胺的方法 |
CN110072838B (zh) * | 2016-12-15 | 2022-04-15 | 阿克苏诺贝尔化学品国际有限公司 | 制备亚乙基胺的方法 |
US11267792B2 (en) * | 2017-07-10 | 2022-03-08 | Nouryon Chemicals International B.V. | Process to prepare ethylene amines and ethylene amine derivatives |
EP3665152A1 (en) * | 2017-08-11 | 2020-06-17 | Nouryon Chemicals International B.V. | Process for converting cyclic alkylene ureas into their corresponding alkylene amines |
WO2019030193A1 (en) * | 2017-08-11 | 2019-02-14 | Akzo Nobel Chemicals International B.V. | TWO-CYCLE ALKYLENE-UREA CONVERSION PROCESS INTO THEIR ALKYLENE AMINOUS CORRESPONDENTS |
MX2020001448A (es) * | 2017-08-11 | 2020-07-13 | Nouryon Chemicals Int Bv | Proceso para convertir monourea ciclica de un compuesto de etilenamina en un compuesto etilenaminico. |
JPWO2021153650A1 (es) * | 2020-01-28 | 2021-08-05 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2812333A (en) * | 1954-09-27 | 1957-11-05 | Union Carbide Corp | Process for the preparation of 1-(2-hydroxyethyl) imidazolidine-2 |
US4503250A (en) | 1981-09-30 | 1985-03-05 | Union Carbide Corporation | Preparation of polyalkylene polyamines |
US4387249A (en) * | 1981-12-18 | 1983-06-07 | The Dow Chemical Company | Process for the manufacture of diethylenetriamine |
SE513250C2 (sv) | 1997-11-11 | 2000-08-07 | Akzo Nobel Nv | Amineringsförfarande för framställning av polyaminer |
DE102004011320A1 (de) * | 2004-03-09 | 2005-09-22 | Degussa Ag | Verfahren zur Herstellung von Aminen aus Carbodiimidgruppen aufweisenden Verbindungen durch Hydrolyse mit Wasser |
US9278905B2 (en) * | 2012-03-02 | 2016-03-08 | Kyushu University, National University Corporation | Production method for compound comprising amino group and/or hydroxyl group |
WO2017137529A1 (en) * | 2016-02-12 | 2017-08-17 | Akzo Nobel Chemicals International B.V. | Process to convert cyclic alkylene ureas into their corresponding alkylene amines |
MX2020001448A (es) * | 2017-08-11 | 2020-07-13 | Nouryon Chemicals Int Bv | Proceso para convertir monourea ciclica de un compuesto de etilenamina en un compuesto etilenaminico. |
-
2018
- 2018-08-07 TW TW107127377A patent/TWI761570B/zh active
- 2018-08-07 KR KR1020207006607A patent/KR20200036011A/ko not_active Application Discontinuation
- 2018-08-07 CN CN201880050928.7A patent/CN111032616B/zh active Active
- 2018-08-07 BR BR112020002389-2A patent/BR112020002389B1/pt active IP Right Grant
- 2018-08-07 EP EP18756385.3A patent/EP3665153A1/en active Pending
- 2018-08-07 MX MX2020001449A patent/MX2020001449A/es unknown
- 2018-08-07 CA CA3071903A patent/CA3071903A1/en active Pending
- 2018-08-07 JP JP2020506819A patent/JP2020530455A/ja active Pending
- 2018-08-07 US US16/638,389 patent/US11236039B2/en active Active
- 2018-08-07 WO PCT/EP2018/071319 patent/WO2019030190A1/en unknown
-
2022
- 2022-10-31 JP JP2022173891A patent/JP2023017864A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
CN111032616A (zh) | 2020-04-17 |
RU2020109528A3 (es) | 2021-09-14 |
JP2020530455A (ja) | 2020-10-22 |
TWI761570B (zh) | 2022-04-21 |
CA3071903A1 (en) | 2019-02-14 |
KR20200036011A (ko) | 2020-04-06 |
US11236039B2 (en) | 2022-02-01 |
BR112020002389A2 (pt) | 2020-09-01 |
TW201920065A (zh) | 2019-06-01 |
EP3665153A1 (en) | 2020-06-17 |
BR112020002389B1 (pt) | 2023-03-21 |
RU2020109528A (ru) | 2021-09-14 |
US20200165187A1 (en) | 2020-05-28 |
JP2023017864A (ja) | 2023-02-07 |
WO2019030190A1 (en) | 2019-02-14 |
CN111032616B (zh) | 2024-01-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MX2020001449A (es) | Proceso de varias etapas para convertir alquilenoureas ciclicas en sus correspondientes alquilenaminas. | |
MX2021010075A (es) | Variantes de arn polimerasa para la formacion de casquetes cotranscripcionales. | |
MX2018009316A (es) | Proceso para convertir alquilenureas ciclicas en sus correspondientes alquilenaminas. | |
MX2019013232A (es) | Proceso para preparar microcapsulas. | |
WO2016205411A3 (en) | Ethylene-to-liquids systems and methods | |
SA517390453B1 (ar) | عملية من أجل فصل رواسب لإنتاج زيوت وقود | |
WO2015183411A3 (en) | Upgrading pyrolysis tar | |
MY190659A (en) | Method for producing biohydrocarbons | |
WO2016043462A3 (ko) | 칼코부트롤의 제조방법 | |
AP2017009704A0 (en) | Method for producing reaction product in which phases interface reaction is employed, phases interface reactor, and method for producing secondary reaction product | |
MX2017004162A (es) | Metodo para ciclizar biocataliticamente el geranillinalool y productos de ciclizacion obtenidos de este modo. | |
SG11202104697QA (en) | Process for c5+ hydrocarbon conversion | |
MX2016009118A (es) | Procedimiento de produccion de e-1-cloro-3,3,3-trifluoropropeno a partir de 1,1,3,3-tetracloropropeno. | |
MX2016013897A (es) | Proceso de produccion de gasolina que comprende una etapa de isomerizacion seguida de al menos dos etapas de separacion. | |
MX2017013100A (es) | Proceso para aislar y purificar ambrox. | |
MX2017005630A (es) | Metodo para preparar bifenilaminas a partir de azobencenos mediante catalisis de rutenio. | |
MX2018002031A (es) | Proceso para la preparacion de 1,4-bis (etoximetil) ciclohexano. | |
IL271943B (en) | A method for improving the efficiency of a gas plant for the synthesis of ammonia | |
HUE054322T2 (hu) | Módszer folyadék betáplálására gázfázisú polimerizációt végzõ reaktorba | |
ZA202002054B (en) | Processes for improving the efficiency of hydrocarbon production | |
MX2020006910A (es) | Metodo de plegamiento de laminas de vidrio. | |
MX2017005810A (es) | Nueva sintesis telescopica de 2-metoximetil-p-fenilenediamina. | |
HUE057330T2 (hu) | Eljárás allulóz konverziós reakciótermék tisztítására | |
SG11202012143PA (en) | Method for improving reaction yield | |
MX2017005809A (es) | Nueva sintesis telescopica de 2-metoximetil-p-fenilenediamina. |