MD419C2 - Process for stereoselective allyl chlorides Z-1,2-diaryl preparation - Google Patents

Process for stereoselective allyl chlorides Z-1,2-diaryl preparation

Info

Publication number
MD419C2
MD419C2 MD95-0220A MD950220A MD419C2 MD 419 C2 MD419 C2 MD 419C2 MD 950220 A MD950220 A MD 950220A MD 419 C2 MD419 C2 MD 419C2
Authority
MD
Moldova
Prior art keywords
preparation
halogen
stereoselective
diaryl
ether
Prior art date
Application number
MD95-0220A
Other languages
Romanian (ro)
Russian (ru)
Inventor
Rainer Seele
Kober Reiner
Isak Heinz
Hickmann Eckhard
Gotz Nobert
Zierke Thomas
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of MD419C2 publication Critical patent/MD419C2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/35—Preparation of halogenated hydrocarbons by reactions not affecting the number of carbon or of halogen atoms in the reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C25/00—Compounds containing at least one halogen atom bound to a six-membered aromatic ring
    • C07C25/24—Halogenated aromatic hydrocarbons with unsaturated side chains
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/20—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
    • C07C43/225—Ethers having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
    • C07C43/29—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/08—Compounds containing oxirane rings with hydrocarbon radicals, substituted by halogen atoms, nitro radicals or nitroso radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)

Abstract

The problem of the present invention consists in the process elaboration corresponding to which it is possible to obtain allyl chloride Z-1,2-diaryl high yield of the general formulaused as intermediate products at preparation of the pharmacologic, fungicide and anti-fungal primary nutrient basis.The process for stereoselective materials preparation of the general formula (I) consists in the fact, that the chlorhydrines of formula (II)where the rests R1 and R2 independently from each other represent hydrogene, halogen, alkyl, halogen alkyl, alkoxy, halogen alkoxy or unsubstituted or substituted aromatic rest, and n and m represent 1,2 or 3 are dehydrated in the inerte ether or ether of carboxylic acid as solvent in presence of carboxylic acid anhydride or corresponding ketone and organic or unorganic acid or oleum at the temperature up to 50°C.
MD95-0220A 1989-07-18 1994-12-13 Process for stereoselective allyl chlorides Z-1,2-diaryl preparation MD419C2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE3923674A DE3923674A1 (en) 1989-07-18 1989-07-18 New 1,2-di:aryl-3-chloro-propene cpds.

Publications (1)

Publication Number Publication Date
MD419C2 true MD419C2 (en) 1996-07-31

Family

ID=6385245

Family Applications (1)

Application Number Title Priority Date Filing Date
MD95-0220A MD419C2 (en) 1989-07-18 1994-12-13 Process for stereoselective allyl chlorides Z-1,2-diaryl preparation

Country Status (4)

Country Link
DE (1) DE3923674A1 (en)
MD (1) MD419C2 (en)
RU (2) RU2014317C1 (en)
UA (1) UA37175C2 (en)

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
Brevet nr. 3218129, DE, Int. Cl. C 07 D 405/06, 1983. *
Brevet nr. 3218130, DE, Int. Cl. C 07 D 405/06, 1983. *
Brevet, nr. 196038, Ep, Int. Cl. C 07 D 405/06, 1983. *
Houben-Weyl. Meth. der organ. Chemie, ediţia 4, vol. 5/1, 1972, p. 62-71. *

Also Published As

Publication number Publication date
RU2014317C1 (en) 1994-06-15
DE3923674A1 (en) 1991-01-31
UA37175C2 (en) 2001-05-15
RU2125997C1 (en) 1999-02-10

Similar Documents

Publication Publication Date Title
DK469589A (en) 7-SUBSTITUTED DERIVATIVES OF 3,5-DIHYDROXYHEPT-6-ACID ACID, THEIR PREPARATION AND USE, AND THE PRODUCTION USED INTERMEDIATES
RO104615B1 (en) Preparation method of 7-fluor-1-methyl-3-methylsulphonyl -4-quinoline
DE69122866D1 (en) PRODUCTION OF SUBSTITUTED PIPERIDINES
DE2961012D1 (en) Fluor-containing 1,4-dihydropyridines, pharmaceuticals containing them and process for their preparation
ATE192743T1 (en) METHOD FOR PRODUCING 2-(2',4'-DIHYDROXYPHENYL)-4,6-DIARYL-S-TRIAZINE
MD419C2 (en) Process for stereoselective allyl chlorides Z-1,2-diaryl preparation
ES2143459T3 (en) 4,5-DIHIDRO-1H-PIRAZOL-1-CARBOXAMIDAS N-ARIL-3-ARIL-4 SUBSTITUTED AND PROCEDURES FOR ITS PRODUCTION.
HU904344D0 (en) Process for stereoselective production of 2-1,2-diaryl-allylchlorides as well as for transformation of these compounds into azolyl-methyl-oxyranes
KR870005954A (en) Improved process for preparing 5- (2,5-dimethylphenoxy) -2,2-dimethylpentanoic acid
EP0187674A2 (en) Process for the preparation of polyhalogenated carbinols
FR2377382A1 (en) NEW PHENYLAZACYCLOALCANES USEFUL AS MEDICINAL PRODUCTS
EP0230948A3 (en) Benzoylacetic acid ester derivatives and process for their preparation
GB1189514A (en) New Cyclic Ketones
JPS577438A (en) Production of acid chloride
US5360919A (en) Polycyclic dyes
JPS5540653A (en) Perhydropyrroloimidazole derivative, and agricultural and horticultural fungicide comprising it
DK0801897T3 (en) Composition and process for the preparation of the composition, as well as raw materials, products and means of production
US3125582A (en) Phenylvinylene cyclic carbonates
JPS55108828A (en) Preparation of chlorination product and ethyl benzene
SU404824A1 (en) PTB
ES2045098T3 (en) PROCEDURE FOR THE PREPARATION OF THIAZOLOBENCIMIDAZOLES AND INTERMEDIATE PRODUCTS USED IN THE.
DE3575419D1 (en) METHOD FOR THE PRODUCTION OF ALPHA HYDROXYAL CALCAR CARBON ACIDS.
KR970707134A (en) Process for the Preparation of 1-Halo-3-Trialkylsilanyl-Benzene Derivatives
JPS5659727A (en) Preparation of substituted phenol
KR890701511A (en) Dehydrobromination of Substituted α-halocumen

Legal Events

Date Code Title Description
KA4A Patent for invention lapsed due to non-payment of fees (with right of restoration)
MM4A Patent for invention definitely lapsed due to non-payment of fees