MD244C2 - Method of preparation of ester of alcohol (S)-a-cyai-3-fenoxybenzol and 1R, cis-2,2-domethyl-3-(2'2'-dibromvinil)-cyclopropan-1-carbonic acid - Google Patents
Method of preparation of ester of alcohol (S)-a-cyai-3-fenoxybenzol and 1R, cis-2,2-domethyl-3-(2'2'-dibromvinil)-cyclopropan-1-carbonic acidInfo
- Publication number
- MD244C2 MD244C2 MD94-0272A MD940272A MD244C2 MD 244 C2 MD244 C2 MD 244C2 MD 940272 A MD940272 A MD 940272A MD 244 C2 MD244 C2 MD 244C2
- Authority
- MD
- Moldova
- Prior art keywords
- fenoxybenzol
- dibromvinil
- cyai
- cyclopropan
- cis
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title 1
- 150000002148 esters Chemical class 0.000 title 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 4
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 238000006266 etherification reaction Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention relates to the method of preparation of ether (S)- )-α-cyai-3-fenoxybenzol having insecticide activity.The purpose of invention is the increasing of the destine yield.In conformity with the method, the preparation of ether (S)- )-α-cyai-3-fenoxybenzol and 1R cis-2,2-domethyl-3-(2′2′-dibromvinil)-cyclopropan-1-carbonic acid is carried out by etherification of α-cian-3-fenorybenzol by chloranhydride 1R, cis-2,2-dimethyl-3-2′2′-dibromvinil)-cyclopropan-1-carbonic acid in the medium of monoaromatic hydrocarbon. As the α-cyan-3- fenoxybenzol is used its isomer and process is led at the temperature from (-10)°C to (+20)°C.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7802621A FR2421875A1 (en) | 1978-01-31 | 1978-01-31 | OPTICALLY ACTIVE SUBSTITUTE BENZYL ALCOHOL AND ITS PREPARATION PROCESS |
| SU792714653A SU957764A3 (en) | 1978-01-31 | 1979-01-19 | Process for producing (s)=alpha-cyano-3-phenoxybenzyl alcohol |
| SU792832611A SU1116978A3 (en) | 1978-01-31 | 1979-10-15 | Method of obtaining ester of (s)-alpha-cyano-3-phenoxybenzyl alcohol and ir, cis-2,2-dimethyl-3 (2,2-dibromvinyl)-cyclopropane-1-carboxylic acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| MD244B1 MD244B1 (en) | 1995-07-31 |
| MD244C2 true MD244C2 (en) | 1995-12-31 |
Family
ID=27250805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MD94-0272A MD244C2 (en) | 1978-01-31 | 1994-09-08 | Method of preparation of ester of alcohol (S)-a-cyai-3-fenoxybenzol and 1R, cis-2,2-domethyl-3-(2'2'-dibromvinil)-cyclopropan-1-carbonic acid |
Country Status (1)
| Country | Link |
|---|---|
| MD (1) | MD244C2 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2240914A2 (en) * | 1973-08-15 | 1975-03-14 | Nat Res Dev | Insecticidal stereoisomeric esters - of 2,2-dimethyl-3-(2,2-di-halovinyl) cyclopropane carboxylic acid which are very toxic to houseflies |
-
1994
- 1994-09-08 MD MD94-0272A patent/MD244C2/en unknown
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2240914A2 (en) * | 1973-08-15 | 1975-03-14 | Nat Res Dev | Insecticidal stereoisomeric esters - of 2,2-dimethyl-3-(2,2-di-halovinyl) cyclopropane carboxylic acid which are very toxic to houseflies |
Also Published As
| Publication number | Publication date |
|---|---|
| MD244B1 (en) | 1995-07-31 |
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| 1K4A | Payment of annual fees |