MD243C2 - Method of cis-dihalogenvinylcyclopropan derivatives preparation - Google Patents
Method of cis-dihalogenvinylcyclopropan derivatives preparationInfo
- Publication number
- MD243C2 MD243C2 MD94-0274A MD940274A MD243C2 MD 243 C2 MD243 C2 MD 243C2 MD 940274 A MD940274 A MD 940274A MD 243 C2 MD243 C2 MD 243C2
- Authority
- MD
- Moldova
- Prior art keywords
- general formula
- chlorine
- mixture
- cis
- alkali
- Prior art date
Links
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention relates to the new method of cis-dihalogenvinylcyclopropan derivatives preparation of the general formula:where x1 and x2 - the same and means atoms of chloride or bromine or different and means atoms of fluor or chlorine.These compounds are applied for preparation of ethers having insecticiding activity. The purpose of invention is simplicity of process.The method is realized by interaction of 2,2-dimethyl-35-formylcyclopropan-1R-carbonic acid derivative, namely its lacton with haloidderivative of methan, as the latter are used haloform of the general formula:where X1-X3 - the same and means atom of chlorine or bronine or different and means atom of fluor or chlorine in addition the atomic weights are increased from X1 to X3.The process is leaded at presence of the alkali agent, selected from alkali tertbutlat in the mixture with tertbutanol, dimethylformanuide and tetrahydrofuran or alkali hydroxide in the mixture with methanol and tetrahydroferon at (-10)-(55)°C and obtained cis-compound of general formula:where X1-X3 have indicated means, are undergone dehydration by sulfuric acid or paratolucnsulfoacid or acetic anhydride or its mixture with acetic acid and lacton obtaining by this way of the general formula:where X1-X3 have indicated means is undergood the recovery by zinc in the acetic acid or activated zinc on the ethanol or magnesium in the tetrahydrofuran at the temperature of boiling of the reactive mass.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR7719612A FR2396006A1 (en) | 1977-06-27 | 1977-06-27 | NEW CYCLOPROPANIC CORE COMPOUNDS, PREPARATION PROCESS AND APPLICATION TO THE PREPARATION OF CYCLOPROPANIC DERIVATIVES WITH DIHALOVINYL CHAIN |
SU782624348A SU1075970A3 (en) | 1977-06-27 | 1978-06-09 | Process for preparing cis-derivatives of dihaloidvinylcyclopropane |
Publications (2)
Publication Number | Publication Date |
---|---|
MD243B1 MD243B1 (en) | 1995-07-31 |
MD243C2 true MD243C2 (en) | 1995-12-31 |
Family
ID=26220103
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MD94-0274A MD243C2 (en) | 1977-06-27 | 1994-09-08 | Method of cis-dihalogenvinylcyclopropan derivatives preparation |
Country Status (1)
Country | Link |
---|---|
MD (1) | MD243C2 (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2185612A1 (en) * | 1972-05-25 | 1974-01-04 | Nat Res Dev |
-
1994
- 1994-09-08 MD MD94-0274A patent/MD243C2/en unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2185612A1 (en) * | 1972-05-25 | 1974-01-04 | Nat Res Dev |
Also Published As
Publication number | Publication date |
---|---|
MD243B1 (en) | 1995-07-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Bechgaard et al. | Synthesis of 1, 3-diselenole-2-selones and-2-thiones | |
ES410062A1 (en) | Procedure for the preparation of a phenolic derivative replaced by a cycle of five carbon atoms. (Machine-translation by Google Translate, not legally binding) | |
ES483410A1 (en) | Process for the preparation of Chlorambucil derivatives | |
MD243C2 (en) | Method of cis-dihalogenvinylcyclopropan derivatives preparation | |
Smith et al. | Partial synthesis of chlorophyll-a from rhodochlorin | |
Santiago et al. | Photostimulated reaction of 1-halo-and 1, 4-dihalobicyclo [2.2. 2] octanes with diphenylphosphide ions by the SRN1 mechanism | |
US3102133A (en) | 1-[5-(6-methoxy-2-naphthyl)-2-oxycyclopentyl]-2-propanone derivatives | |
Smith et al. | Relative nucleophilicities of carbanions derived from a-substituted phenylacetonitriles | |
GB1436357A (en) | Tri-iodo benzene derivatives and their use as x-ray contrast | |
Puterbaugh et al. | The Carboxyalkylation of Ketones with α-Halo Acids to Yield γ-Keto Acids by Means of Lithium Amide. Influence of Metallic Cation1 | |
ES441257A1 (en) | Heterocyclic compounds | |
Jones et al. | Conformational free energy differences in steroids. Part I. Equilibration of 3β-substituted 5α-and 5β-cholestan-6-ones | |
ES428449A1 (en) | 2-hydroxynicotinic acid derivative and methods of preparing same | |
SU540864A1 (en) | Method for producing α-fluorodicarbocyanines | |
Nasipuri et al. | Cyclohexenone derivatives. Part VI. C-3 and C-1 alkylation of Hagemann's ester (ethyl 2-methyl-4-oxocyclohex-2-enecarboxylate) with alkyl halides and Michael acceptors | |
JPS55108838A (en) | Preparation of arkyl-1-chloro-2-oxocycloalkane carboxylate | |
De La Mare et al. | 694. The kinetics and mechanisms of nucleophilic displacements in allylic systems. Part III. The reactions of 3: 3: 3-trichloro-2-methylprop-1-ene with nucleophilic reagents | |
SU139833A1 (en) | The method of producing alkyl esters of alpha-trialkylstannyl acrylic acid | |
ES396825A1 (en) | Selected 5-substituted-5-phenylalkyl barbituric acids analgetic compositions and method based thereon | |
SU682131A3 (en) | Method of the preparation of (d,1-2-/6,11-dihydrobenzo thiepinovon-11-y-3)propionic acid | |
JPS5620560A (en) | Production of 2-halogenobenzonitrile derivative | |
KR830001840B1 (en) | Advanced bromination method | |
ES476405A1 (en) | Methylthiofluorothioxanthene derivative, its preparation and compositions containing it. | |
JPS61225195A (en) | Synthesis of tritium-labeled steroid | |
JPS5466640A (en) | Novel acrylophenone derivative and its preparation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
1K4A | Payment of annual fees |