MA61729A1 - Méthode de préparation de matériau de cathode ternary avec du sel fondu et son utilisation - Google Patents

Méthode de préparation de matériau de cathode ternary avec du sel fondu et son utilisation

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Publication number
MA61729A1
MA61729A1 MA61729A MA61729A MA61729A1 MA 61729 A1 MA61729 A1 MA 61729A1 MA 61729 A MA61729 A MA 61729A MA 61729 A MA61729 A MA 61729A MA 61729 A1 MA61729 A1 MA 61729A1
Authority
MA
Morocco
Prior art keywords
salt
molten salt
cathode material
bismuth
precursor
Prior art date
Application number
MA61729A
Other languages
English (en)
Inventor
Haijun Yu
Yinghao Xie
Xuemei Zhang
Changdong Li
Aixia Li
Original Assignee
Guangdong Brunp Recycling Technology Co Ltd
Hunan Brunp Recycling Tech Co Ltd
Hunan Brunp Ev Recycling Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN202210546053.8A external-priority patent/CN114853087B/zh
Application filed by Guangdong Brunp Recycling Technology Co Ltd, Hunan Brunp Recycling Tech Co Ltd, Hunan Brunp Ev Recycling Co Ltd filed Critical Guangdong Brunp Recycling Technology Co Ltd
Publication of MA61729A1 publication Critical patent/MA61729A1/fr

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/04Oxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • C01G53/40Complex oxides containing nickel and at least one other metal element
    • C01G53/42Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G29/00Compounds of bismuth
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G30/00Compounds of antimony
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00Compounds of nickel
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/058Construction or manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1391Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/366Composites as layered products
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/50Solid solutions
    • C01P2002/52Solid solutions containing elements as dopants
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/03Particle morphology depicted by an image obtained by SEM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028Positive electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Composite Materials (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inert Electrodes (AREA)

Abstract

La présente invention concerne une méthode de préparation d'un matériau de cathode ternaire avec un sel fondu et son utilisation. La méthode comprend les étapes suivantes : mélanger un sel de nickel, un sel de cobalt, un sel de manganèse, un oxyde métallique et une liqueur acide pour obtenir une solution de sel mélangé ; ajouter simultanément la solution de sel mélangé, une solution d'hydroxyde de sodium et de l'eau d'ammoniaque à une solution de base pour permettre une réaction et obtenir un précurseur ; et mélanger le précurseur, une source de lithium et un sel fondu, puis soumettre le mélange résultant à une frittage, un lavage à l'eau et un recuit pour obtenir le matériau de cathode ternaire. Dans la présente divulgation, un précurseur ternaire dopé au bismuth/antimoine est préparé, qui est fritté avec un sel fondu, au cours duquel l'oxyde de bismuth/antimoine est fondu dans le sel fondu, puis le mélange résultant est lavé à l'eau pour éliminer le sel fondu résiduel et l'oxyde de bismuth/antimoine, et recuit pour former une couche de revêtement sur une surface du matériau, ce qui peut améliorer les performances de cyclage du matériau.
MA61729A 2022-05-19 2023-03-15 Méthode de préparation de matériau de cathode ternary avec du sel fondu et son utilisation MA61729A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN202210546053.8A CN114853087B (zh) 2022-05-19 2022-05-19 熔融盐制备三元正极材料的方法及其应用
PCT/CN2023/081688 WO2023221624A1 (fr) 2022-05-19 2023-03-15 Procédé de préparation d'un matériau de cathode ternaire à partir d'un sel fondu et son utilisation

Publications (1)

Publication Number Publication Date
MA61729A1 true MA61729A1 (fr) 2024-01-31

Family

ID=89429428

Family Applications (1)

Application Number Title Priority Date Filing Date
MA61729A MA61729A1 (fr) 2022-05-19 2023-03-15 Méthode de préparation de matériau de cathode ternary avec du sel fondu et son utilisation

Country Status (6)

Country Link
US (1) US20240014391A1 (fr)
DE (1) DE112023000016T5 (fr)
ES (1) ES2957485A2 (fr)
GB (1) GB2622915A (fr)
HU (1) HU231661B1 (fr)
MA (1) MA61729A1 (fr)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106299348B (zh) * 2016-08-25 2019-06-21 合肥国轩高科动力能源有限公司 一种复合材料包覆镍锰酸锂的方法
CN111533183B (zh) * 2020-05-09 2024-02-20 中伟新材料股份有限公司 一种熔融金属包覆型的三元前驱体及其制备方法
CN111682174B (zh) * 2020-06-10 2022-12-13 广东邦普循环科技有限公司 一种锑包覆的锂电池正极材料及其制备方法和应用
CN112301428B (zh) * 2020-09-24 2022-01-07 广东邦普循环科技有限公司 一种三元单晶正极材料及其制备方法和应用
CN113130877B (zh) * 2021-06-18 2021-09-24 长沙理工大学 一种掺杂与浸渍包覆同步修饰的多晶正极材料及其固相制备方法与应用
CN114853087B (zh) * 2022-05-19 2023-06-13 广东邦普循环科技有限公司 熔融盐制备三元正极材料的方法及其应用

Also Published As

Publication number Publication date
GB2622915A8 (en) 2024-05-15
HU231661B1 (hu) 2025-05-28
HUP2400108A1 (hu) 2024-06-28
GB202310923D0 (en) 2023-08-30
DE112023000016T5 (de) 2024-01-25
ES2957485A2 (es) 2024-01-19
US20240014391A1 (en) 2024-01-11
GB2622915A (en) 2024-04-03

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