LU102451B1 - Aluminum (al) anode plate material for al-air battery and preparation method thereof, al anode plate for al-air battery and preparation method and use thereof - Google Patents
Aluminum (al) anode plate material for al-air battery and preparation method thereof, al anode plate for al-air battery and preparation method and use thereof Download PDFInfo
- Publication number
- LU102451B1 LU102451B1 LU102451A LU102451A LU102451B1 LU 102451 B1 LU102451 B1 LU 102451B1 LU 102451 A LU102451 A LU 102451A LU 102451 A LU102451 A LU 102451A LU 102451 B1 LU102451 B1 LU 102451B1
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- LU
- Luxembourg
- Prior art keywords
- air battery
- anode plate
- plate material
- disclosure
- metal
- Prior art date
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- 239000000463 material Substances 0.000 title claims abstract description 55
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 8
- 238000002360 preparation method Methods 0.000 title abstract description 13
- 239000011777 magnesium Substances 0.000 claims abstract description 35
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 7
- 229910052738 indium Inorganic materials 0.000 claims abstract description 6
- 229910052718 tin Inorganic materials 0.000 claims abstract description 6
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052751 metal Inorganic materials 0.000 claims description 43
- 239000002184 metal Substances 0.000 claims description 43
- 238000000034 method Methods 0.000 claims description 26
- 229910000636 Ce alloy Inorganic materials 0.000 claims description 16
- 238000000137 annealing Methods 0.000 claims description 15
- 238000005096 rolling process Methods 0.000 claims description 13
- 239000011888 foil Substances 0.000 claims description 12
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- 238000005266 casting Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 15
- 238000005260 corrosion Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 239000003792 electrolyte Substances 0.000 abstract description 7
- 229910045601 alloy Inorganic materials 0.000 abstract description 5
- 239000000956 alloy Substances 0.000 abstract description 5
- 230000010287 polarization Effects 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 4
- 230000002195 synergetic effect Effects 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 229910052761 rare earth metal Inorganic materials 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000002910 rare earth metals Chemical class 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005097 cold rolling Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/026—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/047—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/043—Processes of manufacture in general involving compressing or compaction
- H01M4/0435—Rolling or calendering
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0471—Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0483—Processes of manufacture in general by methods including the handling of a melt
- H01M4/0485—Casting
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0483—Processes of manufacture in general by methods including the handling of a melt
- H01M4/0488—Alloying
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
- H01M4/08—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/46—Alloys based on magnesium or aluminium
- H01M4/463—Aluminium based
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Hybrid Cells (AREA)
Claims (9)
1. Aluminium (Al) -Anodenplattenmaterial für eine Al-Luft-Batterie, umfassend die folgenden Elemente in Massenprozent: 0,02-0,2% Cer (Ce), 0.02-0,2% Indium (In), 0,02-0.2% Zinn (Sn), 0,3-0,7% Magnesium (Mg), wobei der Rest Al ist.
2. Al-Anodenplattenmaterial für eine Al-Luft-Batterie nach Anspruch 1, wobei das Al einen Gehalt von über 99% aufweist.
3. Verfahren zur Herstellung des Al-Anodenplattenmaterials für eine Al-Luft-Batterie nach Anspruch | oder Anspruch 2, umfassend dic folgenden Schritte: Schmelzen von reinem Al, um geschmolzenes Al zu erhalten; Zugabe von Al-Ce-Legierung, Metall In, Metall Sn und Metall Mg, die mit Al-Folie umwickelt sind, zu dem geschmolzenen Al, um eine gemischte Schmelze zu erhalten; Gießen der gemischten Schmelze, um ein Al-Anodenplattenmaterial für eine Al-Luft-Batterie zu bilden; wobei die Mengen des reinen Al, der Al-Ce-l.egierung, des Metalls In, des Metails Sn, des Metalls Mg und der Al-Folie der Elementzusammensetzung des Al-Anodenplattenmaterials fiir eine Al-Luft-Batterie gemäß Anspruch | oder Anspruch 2 entsprechen.
4. Verfahren nach Anspruch 3, wobei ein Massenprozentsatz des Ce in der Al-Ce-Legierung 5 bis 20% beträgt.
5. Al-Anodenplatte für eine Al-Luftbatterie, wobei die Al-Anodenplatte für eine Al-Luftbatterie hergestellt ist aus dem Al-Anodenplattenmaterial für eine Al-Luftbatterie nach Anspruch 1 oder Anspruch 2, oder aus einem Al-Anodenplattenmaterial für eine Al-Luft-Batterie, hergestellt nach dem Verfahren nach Anspruch 3 oder Anspruch 4.
6. Verfahren zur Herstellung einer Al-Anodenplatte für eine Al-Luft-Batterie, umfassend die folgenden Schritte: nacheinander Walzen und Glühen cines Al-Anodenplattenmaterials für eine Al-Luft-Batterie, um eine Al-Anodenplatte für eine Al-Luft-Batterie zu erhalten; wobei das Al-Anodenplattenmaterial für eine Al-Luftbatterie das Al-Anodenplattenmateriai für cine Al-Luftbatterie nach Anspruch | oder Anspruch 2 ist, oder durch das Verfahren nach
Anspruch 3 oder Anspruch 4 hergestellt ist.
7. Verfahren nach Anspruch 6, wobei das Glühen während 3-15 Stunden bei 300-400°C durehgeführt wird.
8. Verfahren nach Anspruch 6, wobei das Glühen ein Kaltglühen ist.
9. Verwendung der Al-Anodenplatte für eine Al-Luft-Batterie nach Anspruch 5 oder einer Al-Anodenplatie für eine Al-Luft-Batterie gemäß dem Verfahren nach einem der Ansprüche 6 bis 8 als Anode in einer Al-Luft-Batterie .
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010629608.6A CN111740094A (zh) | 2020-07-01 | 2020-07-01 | 一种铝空气电池铝阳极板材料及其制备方法、铝空气电池铝阳极板及其制备方法和应用 |
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| Publication Number | Publication Date |
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| LU102451B1 true LU102451B1 (en) | 2021-08-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| LU102451A LU102451B1 (en) | 2020-07-01 | 2021-01-27 | Aluminum (al) anode plate material for al-air battery and preparation method thereof, al anode plate for al-air battery and preparation method and use thereof |
Country Status (3)
| Country | Link |
|---|---|
| CN (1) | CN111740094A (de) |
| LU (1) | LU102451B1 (de) |
| NL (1) | NL2026590B1 (de) |
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| CN112310383A (zh) * | 2020-10-10 | 2021-02-02 | 合肥综合性国家科学中心能源研究院(安徽省能源实验室) | 一种高能量密度型铝空气电池铝合金负极材料及制备方法 |
| CN113604710A (zh) * | 2021-07-07 | 2021-11-05 | 烟台南山学院 | 一种放电平稳高电流率的铝合金阳极材料及其制备方法 |
| CN117187634A (zh) * | 2023-08-09 | 2023-12-08 | 郑州佛光发电设备股份有限公司 | 一种含钛铝空燃料电池用铝阳极材料及其制备方法 |
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| JP4051686B2 (ja) * | 2004-09-30 | 2008-02-27 | ソニー株式会社 | 負極活物質およびそれを用いた電池 |
| CN102820472B (zh) * | 2012-08-07 | 2015-03-18 | 河南科技大学 | 含锰铝合金阳极材料及其制备方法及使用该阳极材料制备的空气电池 |
| CN103280565A (zh) * | 2013-06-06 | 2013-09-04 | 北京西区码头商贸有限公司 | 一种铝合金阳极材料及其制备方法 |
| CN106191571B (zh) * | 2016-08-16 | 2018-07-03 | 中国科学院宁波材料技术与工程研究所 | 铝合金电极材料、其制备方法及其应用 |
| CN106676343B (zh) * | 2016-11-29 | 2018-03-13 | 中国电子科技集团公司第十八研究所 | 一种海水电池用铝合金阳极材料及其制备方法 |
| CN108179325A (zh) * | 2018-01-26 | 2018-06-19 | 河南科技大学 | 一种稀土微合金化铝合金阳极材料及其制备方法和应用 |
| CN109136598A (zh) * | 2018-09-28 | 2019-01-04 | 河南科技大学 | 一种镁铝铟稀土阳极材料及其制备方法、镁空气电池 |
| CN110042278A (zh) * | 2019-05-14 | 2019-07-23 | 上海汉行科技有限公司 | 一种铝空气电池阳极材料及其制备方法 |
| CN110484788B (zh) * | 2019-09-06 | 2021-04-27 | 宁波烯铝新能源有限公司 | 铝空气电池阳极材料及其制备方法和铝空气电池 |
| CN111057914B (zh) * | 2019-12-30 | 2021-02-09 | 广东省材料与加工研究所 | 一种阳极合金材料、其制备方法、铝空气电池用阳极以及铝空气电池 |
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2020
- 2020-07-01 CN CN202010629608.6A patent/CN111740094A/zh active Pending
- 2020-09-30 NL NL2026590A patent/NL2026590B1/en active
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- 2021-01-27 LU LU102451A patent/LU102451B1/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| NL2026590A (en) | 2022-02-22 |
| NL2026590B1 (en) | 2022-12-20 |
| CN111740094A (zh) | 2020-10-02 |
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Effective date: 20210811 |