KR980002028A - 벤질옥시 치환된 방향족 화합물 및 이를 이용한 균류 및 곤충제어방법 - Google Patents

벤질옥시 치환된 방향족 화합물 및 이를 이용한 균류 및 곤충제어방법 Download PDF

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KR980002028A
KR980002028A KR1019970023114A KR19970023114A KR980002028A KR 980002028 A KR980002028 A KR 980002028A KR 1019970023114 A KR1019970023114 A KR 1019970023114A KR 19970023114 A KR19970023114 A KR 19970023114A KR 980002028 A KR980002028 A KR 980002028A
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alkyl
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halophenyl
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로날드 로스
테드 쯔토무 후지모토
스티븐 호워드 쉐버
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에들러 마크 에스.
롬 앤드 하스 캄파니
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    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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    • C07D—HETEROCYCLIC COMPOUNDS
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    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/04—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
    • C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
    • C07D261/06—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
    • C07D261/08—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
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    • C07—ORGANIC CHEMISTRY
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    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
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    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
    • C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
    • C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
    • C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond

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  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
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Abstract

하기 화학식(Ⅰ)의 살균성 및 살충성을 갖는 화합물.
단, 상기식에서 A는 N 혹은 CH ; V는 O 혹은 NH이며 ; m과 n은 m+n이 2가 되지 않도록 독립적으로 0 및 1이고 U 및 W는 독립적으로 O 혹은 N이며, U와 W가 모두 N인이고 n은 0, m은 1인 경우, 상기 1번째 원자와 5번째 원자사이의 결합은 이중결합이고 C3-C4원자사이의 결합은 단일 혹은 이중결합이며, n이 1이고 m이 0인 경우, 2번째와 3번째 원자 사이의 결합은 이중결합이며, C4-C5원자사이의 결합은 단일 혹은 이중결합이며 ; U는 O이고 W는 N이며, n=m=0인 경우, 1번째와 5번째 원자사이의 결합은 이중결합이고 C3-C4사이의 결합은 단일 혹은 이중결합이며; U는 N이고 W는 0, n=m=0인 경우, 2번째 원자와 3번째 원자사이의 결합은 이중결합이고 C4-C5사이의 결합은 단일 혹은 이중결합이며 ; X는 수소, 할로, (C1-C4)알킬 및 (C1-C4)알콕시로부터 독립적으로 선택되며 ; R은 수소, (C1-C12)알킬, 할로(C1-C12)알킬, (C2-C8)알케닐, (C2-C8)알키닐, (C1-C12)알콕시(C1-C12)알킬, (C3-C7)시클로알킬, (C3-C7)시클로알킬(C1-C4)알킬, 아릴, 아랄킬, 헤테로고리로부터 독립적으로 선택되며 ; R1은 수소, (C1-C8)알킬 및 아릴로부터 독립적으로 선택되고 ; Z는 (C1-C6)알킬, 할로(C1-C6)알킬, (C3-C7)시클로알킬, (C3-C7)시클로알킬(C1-C4)알킬, 아릴, 아랄킬로부터 선택된다.

Description

벤질옥시 치환된 방향족 화합물 및 이를 이용한 균류 및 곤충제어방법
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Claims (20)

  1. 하기 화학식(Ⅰ)의 구조를 갖는 화합물.
    단, 상기식에서 A는 N 혹은 CH ; V는 O 혹은 NH이며 ; m과 n은 m+n이 2가 되지 않도록 독립적으로 0 및 1이고 U 및 W는 독립적으로 O 혹은 N이며, U와 W가 모두 N인이고 n은 0, m은 1인 경우, 상기 1번째 원자와 5번째 원자사이의 결합은 이중결합이고 C3-C4원자사이의 결합은 단일 혹은 이중결합이며, n이 1이고 m이 0인 경우, 2번째와 3번째 원자 사이의 결합은 이중결합이며, C4-C5원자사이의 결합은 단일 혹은 이중결합이며 ; U는 O이고 W는 N이며, n=m=0인 경우, 1번째와 5번째 원자사이의 결합은 이중결합이고 C3-C4사이의 결합은 단일 혹은 이중결합이며;U는 N이고 W는 0, n=m=0인 경우, 2번째 원자와 3번째 원자사이의 결합은 이중결합이고 C4-C5사이의 결합은 단일 혹은 이중결합이며 ; X는 수소, 할로, (C1-C4)알킬 및 (C1-C4)알콕시로부터 독립적으로 선택되며 ; R은 수소, (C1-C12)알킬, 할로(C1-C12)알킬, (C2-C8)알케닐, (C2-C8)알키닐, (C1-C12)알콕시(C1-C12)알킬, (C3-C7)시클로알킬, (C3-C7)시클로알킬(C1-C4)알킬, 아릴, 아랄킬, 헤테로고리로부터 독립적으로 선택되며 ; R1은 수소, (C1-C8)알킬 및 아릴로부터 독립적으로 선택되고 ; Z는 (C1-C6)알킬, 할로(C1-C6)알킬, (C3-C7)시클로알킬, (C3-C7)시클로알킬(C1-C4)알킬, 아릴, 아랄킬로부터 선택된다.
  2. 제1항에 있어서, 상기 A는 CH임을 특징으로 하는 화합물.
  3. 제1항에 있어서, 상기 A는 N임을 특징으로 하는 화합물.
  4. 제2항에 있어서, 상기 V는 0임을 특징으로 하는 화합물.
  5. 제3항에 있어서, 상기 V는 0, NH임을 특징으로 하는 화합물.
  6. 제4항에 있어서, 상기 부분은의 메타위치에 결합되며, R은 (C1-C12)알킬, 할로(C1-C12)알킬, 모노할로치환된 페닐, (C1-C4)알킬 치환된 페닐 및 트리할로치환된 페닐로 구성되는 그룹으로부터 선택됨을 특징으로 하는 화합물.
  7. 제6항에 있어서, U 및 W는 N이고 R1은 H, n=1, m=0이며 2번째 원자와 3번째 원자 사이의 결합은 이중 결합임을 특징으로 하는 화합물.
  8. 제7항에 있어서, Z는 (C1-C6)알킬, 페닐, 3-할로페닐, 4-할로페닐 및 4-(C1-C4)알킬페닐로부터 선택됨을 특징으로 하는 화합물.
  9. 제8항에 있어서, R은 (C1-C4)알킬, 할로(C1-C4)알킬, 페닐, 2-할로페닐, 3-할로페닐, 4-할로페닐, 2-(C1-C4)알킬페닐, 3-(C1-C4)알킬페닐 및 4-(C1-C4)알킬페닐로 구성되는 그룹으로부터 선택됨을 특징으로 하는 화합물.
  10. 제9항에 있어서, R은 2-플루오로페닐, 3-플루오로페닐 및 4-플루오로페닐로 구성되는 그룹으로부터 선택됨을 특징으로 하는 화합물.
  11. 제5항에 있어서, 상기 부분은
    에 대하여 메타위치이며, R은 (C1-C12)알킬, 할로(C1-C12)알킬, 모노할로치환된 페닐, (C1-C4)알킬 치환된 페닐 및 트리할로치환된 페닐로 구성되는 그룹으로부터 선택됨을 특징으로 하는 화합물.
  12. 제11항에 있어서, 상기 U 및 W는 N이고 R1은 H, n=1, m=0이며 2번째 원자와 3번째 원자 사이의 결합은 이중 결합임을 특징으로 하는 화합물.
  13. 제12항에 있어서, Z는 (C1-C6)알킬, 페닐, 3-할로페닐, 4-할로페닐 및 4-(C1-C4)알킬페닐로부터 선택됨을 특징으로 하는 화합물.
  14. 제13항에 있어서, R은 (C1-C4)알킬, 할로(C1-C4)알킬, 2-할로페닐, 3-할로페닐, 4-할로페닐, 2-(C1-C4)알킬페닐, 3-(C1-C4)알킬페닐 및 4-(C1-C4)알킬페닐로 구성되는 그룹으로부터 선택됨을 특징으로 하는 화합물.
  15. 제14항에 있어서, R은 2-플루오로페닐, 3-플루오로페닐 및 4-플루오로페닐로 구성되는 그룹으로부터 선택됨을 특징으로 하는 화합물.
  16. 농경학적으로 수용가능한 캐리어와 청구범위 제1항의 화합물을 캐리어 대 화합물 99:1~1:4 중량비로 포함하는 식물성 병원(phytophathogenic)균류 제어용 살균조성물.
  17. 제16항에 있어서, 상기 농경학적으로 수용가능한 캐리어 대 화합물의 중량비는 10:1~1:3임을 특징으로 하는 조성물.
  18. 종자 서식처, 식물 혹은 토양에 청구범위 제1항의 화합물을 1ha당 0.005~50kg으로 적용함을 포함하는 식물성 병원(phytophathogenic)균류 제어방법.
  19. 제18항에 있어서, 상기 청구범위 제1항의 화합물을 1ha당 0.025~10kg으로 적용함을 특징으로 하는 방법.
  20. 청구범위 제1항의 화합물을 1ha당 0.005~10kg의 비율로 적용함을 포함하는 곤충 제어방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970023114A 1996-06-06 1997-06-04 벤질옥시치환된방향족화합물,및이를이용한균류및곤충방제방법 KR100481810B1 (ko)

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WO1999046246A1 (de) * 1998-03-09 1999-09-16 Basf Aktiengesellschaft Hetarylsubstituierte benzylphenylether, verfahren zu ihrer herstellung und ihre verwendung zur bekämpfung von schadpilzen und tierischen schädlingen
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AU2360997A (en) 1997-12-11
KR100481810B1 (ko) 2005-09-20
TW367224B (en) 1999-08-21
ID17441A (id) 1997-12-24
ATE224876T1 (de) 2002-10-15
DE69715731D1 (de) 2002-10-31
AR007292A1 (es) 1999-10-27
CN1100761C (zh) 2003-02-05
CO4560333A1 (es) 1998-02-10
EP0811614A1 (en) 1997-12-10
JPH1059944A (ja) 1998-03-03
IL120918A0 (en) 1997-09-30
CN1175575A (zh) 1998-03-11
HU9701004D0 (en) 1997-07-28
DE69715731T2 (de) 2003-02-06
AU726670B2 (en) 2000-11-16
HUP9701004A2 (hu) 1998-06-29
BR9703487A (pt) 1999-01-05
CZ169797A3 (cs) 1998-04-15
HUP9701004A3 (en) 1999-03-01
ZA974771B (en) 1997-12-08
EP0811614B1 (en) 2002-09-25
MX9703980A (es) 1997-12-31
TR199700467A2 (xx) 1997-12-21
CA2206151A1 (en) 1997-12-06

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