KR970073958A - Adhesive Polyester Film Laminate - Google Patents

Adhesive Polyester Film Laminate Download PDF

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Publication number
KR970073958A
KR970073958A KR1019970003798A KR19970003798A KR970073958A KR 970073958 A KR970073958 A KR 970073958A KR 1019970003798 A KR1019970003798 A KR 1019970003798A KR 19970003798 A KR19970003798 A KR 19970003798A KR 970073958 A KR970073958 A KR 970073958A
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KR
South Korea
Prior art keywords
polyester film
fatty acid
laminated body
layer
bisamide
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Application number
KR1019970003798A
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Korean (ko)
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KR100332724B1 (en
Inventor
도시후미 이시가와
신이찌로 오까다
마사유끼 후꾸다
히로시 토미타
Original Assignee
이따가끼 히로시
데이진 가부시끼가이샤
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Priority claimed from JP8022419A external-priority patent/JPH09216962A/en
Priority claimed from JP12457496A external-priority patent/JP3732574B2/en
Priority claimed from JP13173296A external-priority patent/JPH09314775A/en
Application filed by 이따가끼 히로시, 데이진 가부시끼가이샤 filed Critical 이따가끼 히로시
Publication of KR970073958A publication Critical patent/KR970073958A/en
Application granted granted Critical
Publication of KR100332724B1 publication Critical patent/KR100332724B1/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/412—Transparent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/08—Dimensions, e.g. volume
    • B32B2309/10—Dimensions, e.g. volume linear, e.g. length, distance, width
    • B32B2309/105—Thickness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2405/00—Adhesive articles, e.g. adhesive tapes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
    • Y10T428/2495—Thickness [relative or absolute]
    • Y10T428/24967—Absolute thicknesses specified
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]
    • Y10T428/31794—Of cross-linked polyester

Abstract

(1)폴리에스테르 필름의 한쪽 면 또는 양면에 ⒤ 이차 전이점이 40∼85℃인 수성 폴리에스테르 및 (ⅱ) 지방 산의 아미드 및/또는 지방산의 비스아미드를 주성분으로 하는 조성물로 이루어진 도막층이 형성되어 있는 것을 특징으로 하는 이접착성 폴리에스테르 필름 적층체〔A〕, (2) 이 적층체〔A〕의 도막층이 형성된 면 위에 하드코트층이 적층된 폴리에스테르 필름 적층체〔B〕, 및 (3) 이 적층체〔B〕의 하드코트층이 형성된 면 위에 반사방지층이 적층된 폴리에스테르 필름 적층체〔C〕.(1) A coating film layer composed of a composition composed mainly of an aqueous polyester having a secondary transition point of 40 to 85 ° C. and (ii) an amide of a fatty acid and / or a bisamide of a fatty acid on one or both sides of the polyester film. Easily-adhesive polyester film laminate [A], (2) Polyester film laminate [B], in which a hard coat layer is laminated on the surface on which the coating layer of this laminate [A] is formed, and (3) Polyester film laminated body [C] in which the antireflection layer was laminated on the surface on which the hard coat layer of this laminated body [B] was formed.

이들 적층체는 접착성이 뛰어나며, 투명성 및 이활성이 뛰어나고, 또한 반사 방지능도 가지고 있기 때문에, 유리, 디스플레이 등의 표면 보호재로서 유리하게 사용된다.Since these laminated bodies are excellent in adhesiveness, are excellent in transparency and diactivation, and also have anti-reflective ability, they are advantageously used as surface protective materials, such as glass and a display.

Description

접착성 폴리에스테르 필름 적층체Adhesive Polyester Film Laminate

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (15)

폴리에스테르 필름의 한쪽 면 또는 양면에 ⒤ 이차 전이점이 40∼85℃인 수성 폴리에스테르 및 (ⅱ) 지방산의 아미드, 지방산의 비스아미드 또는 지방산의 아미드 및 지방산의 비스아미드를 주성분으로 하는 조성물로 이루어진 도막층이 형성되어 있는 것을 특징으로 하는 이접착성 폴리에스테르 필름 적층체〔A〕.A coating film composed of an aqueous polyester having a secondary transition point of 40 to 85 ° C. on one or both sides of a polyester film, and (ii) a amide of a fatty acid, a bisamide of a fatty acid or an amide of a fatty acid and a bisamide of a fatty acid. A layer is formed, The easily-adhesive polyester film laminated body [A] characterized by the above-mentioned. 폴리에스테르 필름의 한쪽 면 또는 양면에 ⒤ 이차 전이점이 40∼85℃인 수성 폴리에스테르 및 (ⅱ) 지방산의 아미드, 지방산의 비스아미드 또는 지방산의 아미드 및 지방산의 비스아미드를 주성분으로 하는 조성물로 이루어진 도막층이 형성된 폴리에스테르 필름 적층체로서, 헤이즈값이 1.5％ 이하이며 또한 마찰계수(㎲)가 0.8 이하인 것을 특징으로 하는 폴리에스테르 필름 적층체〔A〕.A coating film composed of an aqueous polyester having a secondary transition point of 40 to 85 ° C. on one or both sides of a polyester film, and (ii) a amide of a fatty acid, a bisamide of a fatty acid or an amide of a fatty acid and a bisamide of a fatty acid. As a polyester film laminated body with a layer, a haze value is 1.5% or less and the friction coefficient is 0.8 or less, The polyester film laminated body [A] characterized by the above-mentioned. 제1항 또는 제2항에 있어서, 조성물에서의 (ⅱ) 지방산의 아미드, 지방산의 비스아미드 또는 지방산의 아미드 및 지방산의 비스아미드의 함유량이 2∼10중량％인 것을 특징으로 하는 폴리에스테르 필름 적층체〔A〕.The polyester film laminate according to claim 1 or 2, wherein the content of (ii) the amide of the fatty acid, the bisamide of the fatty acid or the amide of the fatty acid and the bisamide of the fatty acid in the composition is from 2 to 10% by weight. Sieve [A]. 제1항 또는 제2항에 있어서, 조성물은 ⒤ 상기 수성 폴리에스테르 및 (ⅱ) 지방산의 비스아미드를 주성분으로 하는 조성물로 이루어진 것을 특징으로 하는 폴리에스테르 필름 적층체〔A〕.The polyester film laminate [A] according to claim 1 or 2, wherein the composition is composed of (i) a composition mainly comprising bisamides of the aforementioned aqueous polyesters and (ii) fatty acids. 제1항 또는 제2항에 있어서, 조성물은 ⒤ 상기 수성 풀리에스테르 및 (ⅱ) 하기 화학식(2)로 표시되는 지방산의 비스아미드.The bisamide of claim 1 or 2, wherein the composition comprises (i) the aqueous pulley ester and (ii) a fatty acid represented by the following formula (2). R1CONHR3NHOCR2 R 1 CONHR 3 NHOCR 2 (식 중 R1및 R2는 독립하여 탄소수 6∼22인 1가우 지방족기를 나타내고, R1는 탄소수 1∼2인 2가의 지방족기를 나타낸다)를 주성분으로 하는 조성물로 이루어진 것을 특징으로 하는 폴리에스테르 필름 적층체〔A〕.A polyester film comprising a composition comprising (in formula, R 1 and R 2 independently represent a monovalent aliphatic group having 6 to 22 carbon atoms, and R 1 represents a divalent aliphatic group having 1 to 2 carbon atoms). Laminate [A]. 제1항 또는 제2항에 있어서, 조성물은 또한 평균입경 0.15㎛이하인 미립자를 5∼30중량％ 함유하고 있는 것을 특징으로 하는 폴리에스테르 필름 적층체〔A〕.The polyester film laminate [A] according to claim 1 or 2, wherein the composition further contains 5 to 30% by weight of fine particles having an average particle diameter of 0.15 µm or less. 제1항 또는 제2항에 있어서, 폴리에스테르 필름의 두께가 25∼200㎛이고, 또한 도막층의 두께가 0.01∼0.2㎛인 것을 특징으로 하는 폴리에스테르 필름 적층체〔A〕.The thickness of a polyester film is 25-200 micrometers, and the thickness of a coating film layer is 0.01-0.2 micrometer, The polyester film laminated body [A] of Claim 1 or 2 characterized by the above-mentioned. 폴리에스테르 필름 적층체〔A〕의 도막층이 형성된 면 위에 하드코트층이 적층된 것을 특징으로 하는 폴리에스테르 필름 적층체〔B〕.The polyester film laminated body [B] characterized by the hard-coat layer laminated | stacked on the surface in which the coating film layer of the polyester film laminated body [A] was formed. 제8항에 있어서, 하드코트층이 방사선 경화수지로 이루어진 것을 특징으로 하는 폴리에스테르 필름 적층체〔B〕.The polyester film laminate [B] according to claim 8, wherein the hard coat layer is made of a radiation curable resin. 제8항에 있어서, 하드코트층의 두께가 3∼30㎛인 것을 특징으로 하는 폴리에스테르 필름 적층체〔B〕.The thickness of a hard-coat layer is 3-30 micrometers, The polyester film laminated body [B] of Claim 8 characterized by the above-mentioned. 폴리에스테르 필름 적층체〔A〕의 도막층이 형성된 면 위에 하드코트층 및 반사방지층이 이 순서대로 적층된 것을 특징으로 하는 폴리에스테르 필름 적층체〔C〕.A polyester film laminate [C], wherein a hard coat layer and an antireflection layer are laminated in this order on the surface on which the coating film layer of the polyester film laminate [A] is formed. 제11항에 있어서, 하드코트층이 방사선 경화수지로 이루어진 것을 특징으로 하는 폴리에스테르 필름 적층체〔C〕.The polyester film laminate [C] according to claim 11, wherein the hard coat layer is made of a radiation curable resin. 제11항에 있어서, 하드코트층의 두께가 3∼30㎛이고, 또한 반사방지층의 두께가 0.05∼0.5㎛인 것을 특징으로 하는 폴리에스테르 필름 적층체〔C〕.The polyester film laminate [C] according to claim 11, wherein the hard coat layer has a thickness of 3 to 30 µm and the antireflection layer has a thickness of 0.05 to 0.5 µm. 제11항에 기재된 폴리에스테르 필름 적층체 〔C〕를 표면에 붙인 디스플레이용 브라운과관.The brown tube for display which stuck the polyester film laminated body [C] of Claim 11 to the surface. 디스플레이용 브라운관 표면보호를 위해 사용되는 제11항에 기재된 폴리에스테르 필름 적층체〔C〕.The polyester film laminated body [C] of Claim 11 used for CRT surface protection for displays. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019970003798A 1996-02-08 1997-02-06 Adhesive Polyester Film Laminate KR100332724B1 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
JP96-022,419 1996-02-08
JP8022419A JPH09216962A (en) 1996-02-08 1996-02-08 Easily bondable polyester film
JP96-124,574 1996-05-20
JP12457496A JP3732574B2 (en) 1996-05-20 1996-05-20 Polyester film laminate
JP13173296A JPH09314775A (en) 1996-05-27 1996-05-27 Easily adherent film and laminate using the same
JP96-131,732 1996-05-27

Publications (2)

Publication Number Publication Date
KR970073958A true KR970073958A (en) 1997-12-10
KR100332724B1 KR100332724B1 (en) 2002-10-04

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KR1019970003798A KR100332724B1 (en) 1996-02-08 1997-02-06 Adhesive Polyester Film Laminate

Country Status (5)

Country Link
US (1) US5910356A (en)
EP (1) EP0789051B1 (en)
KR (1) KR100332724B1 (en)
DE (1) DE69715933T2 (en)
TW (1) TW448106B (en)

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KR100547452B1 (en) * 1997-12-12 2006-02-01 데이진 가부시키가이샤 Laminated film for glass shattering prevention
JPH11218745A (en) * 1998-01-30 1999-08-10 Sony Corp Plasma beam emitting device and display device
EP1033319A4 (en) * 1998-04-28 2001-05-16 Gunze Kk Shrink package
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EP0789051A2 (en) 1997-08-13
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EP0789051A3 (en) 1998-04-29
EP0789051B1 (en) 2002-10-02
US5910356A (en) 1999-06-08

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