GB1065680A - Improvements in or relating to coated films - Google Patents
Improvements in or relating to coated filmsInfo
- Publication number
- GB1065680A GB1065680A GB50363/64A GB5036364A GB1065680A GB 1065680 A GB1065680 A GB 1065680A GB 50363/64 A GB50363/64 A GB 50363/64A GB 5036364 A GB5036364 A GB 5036364A GB 1065680 A GB1065680 A GB 1065680A
- Authority
- GB
- United Kingdom
- Prior art keywords
- copolymers
- acid
- films
- methyl
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/044—Forming conductive coatings; Forming coatings having anti-static properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/052—Forming heat-sealable coatings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Abstract
Synthetic, organic thermoplastic films are coated with an aqueous dispersion of a heat-sealable polymer containing 0.5 to 5.0% by weight of an ionic antistatic agent comprising the metal, ammonium or amine salt of the sulphonated condensation product of formaldehyde and an aromatic hydrocarbon and thereafter dried so that a continuous layer of the heat-sealable coating is deposited on the films. The films may comprise polymers of propylene, ethylene, butene-1, 4-methyl pentene-1, or block copolymers thereof, polyesters such as polyethylene terephthalate, polyamides such as polyhexamethylene adipamide, sebacamide, or polycaprolactam, oxymethylene polymers and copolymers. The polymers or copolymers may be mixed with stabilisers, pigments. The surface of the films may be activated by say corona discharge, ozone treatment or treatment with chemical oxidizing agents such as halogen, potassium permaganate and chromic acid. The films may be oriented in one or both directions with equal or unequal orientation in these directions. The highest degree of orientation may be in the longitudinal direction. The oriented films may be heat set before or after coating. The heat sealable polymer may be: copoymers of vinylidene chloride in major amounts with another mono ethylenically unsaturated compound copolymerisable therewith such as methyl acrylate, ethyl acrylate, methyl methacrylate, methacrylamide, methyl, ethyl vinyl ether, methyl vinyl ketone, acrylonitrile e.g. copolymers containing 80 to 95% vinylidene chloride and up to 20% acrylonitrile, terepolymers of vinylidene chloride with the above monomers in the presence of 0.5 to 5% by weight of an ethylenically unsaturated monocarboxylic acid or polycarboxylic acid or a partial ester of a monoethylenically unsaturated polycarboxylic acid such as acrylic methacrylic, maleic, fumaric, itaconic, aconitic, ciltraconic, mesaconic acid; polyvinyl acetate, partially hydrolysed polyvinyl acetate; butadiene/acrylonitrile, butadiene/styrene, butadiene/methyl methacrylate, butadiene/methyl methacrylate/styrene copolymers; methyl methacrylate methacrylic acid copolymers; copolyesters of terephthalic acid and an other dicarboxylic acid with a glycol e.g. those containing up to 4.0 molecular proportions of combined terephthalic acid for one molecular proportion of combined sebacic acid; copolymers of vinylidene chloride and vinyl chloride, or with methyl, ethyl acrylate; copolymers of vinyl acetate with ethylene, vinyl proprionate; copolymers of vinyl chloride with ethylene, vinyl acetate. It is preferred to use the alkali, or alkaline earth metal salt of the sulphonated condensation product as the antistatic agent, the preferred aromatic hydrocarbons being naphthalene and alkyl naphthalenes. Up to 0.5% of other anionic or cationic surface active agents such as the alkali metal salts of sulphated or sulphonated long chain aliphatic alcohols such as the oleyl and cetyl alcohols active agent such as condensation products of ethylene oxide with fatty acids, fatty acid amides, ethylene oxide/propylene oxide copolymers, polyoxyethylated nonyl phenol, polyoxyethylated octyl cresol, polyoxyethylated alkyl alcohols such as the oleyl and cetylal cohols and hydrolysed polyvinyl acetate, may be included in the dispersion. The dispersion may also contain antioxidants, dyes, pigments, lubricants, u.v. light stabilisers, slip agents such as starch, talc, zinc oxide, calcium carbonate, magnesium carbonate, diatomaceous earths, silica, kaolin, titanium dioxide, triferric tetroxide and other inorganic oxides, carbonates, silicates, aluminates, alumino silicates, polypropylene, polyvinyl chloride, antiblocking agents such as natural waxes, paraffin wax, microcrystalline waxes, beeswax, carnauba wax, montan wax and synthetic waxes such as hydrogenated castor oil, chlorinated hydrocarbon waxes, long chain fatty acid amides. The coatings may be applied by say roller coating, spraying, doctor-knife or air-knife coating. In the Examples, the coated films are tested for heat seal strength and blocking values.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB50363/64A GB1065680A (en) | 1964-12-10 | 1964-12-10 | Improvements in or relating to coated films |
LU50032A LU50032A1 (en) | 1964-12-10 | 1965-12-10 | |
NL6516086A NL6516086A (en) | 1964-12-10 | 1965-12-10 | |
ES0320560A ES320560A1 (en) | 1964-12-10 | 1965-12-10 | Improvements in or relating to coated films |
FR41797A FR1460218A (en) | 1964-12-10 | 1965-12-10 | Process for coating the surface of a synthetic organic thermoplastic sheet |
BE673602D BE673602A (en) | 1964-12-10 | 1965-12-10 | |
CH1705365A CH438701A (en) | 1964-12-10 | 1965-12-10 | Process for coating synthetic organic thermoplastic films |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB50363/64A GB1065680A (en) | 1964-12-10 | 1964-12-10 | Improvements in or relating to coated films |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1065680A true GB1065680A (en) | 1967-04-19 |
Family
ID=10455641
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB50363/64A Expired GB1065680A (en) | 1964-12-10 | 1964-12-10 | Improvements in or relating to coated films |
Country Status (7)
Country | Link |
---|---|
BE (1) | BE673602A (en) |
CH (1) | CH438701A (en) |
ES (1) | ES320560A1 (en) |
FR (1) | FR1460218A (en) |
GB (1) | GB1065680A (en) |
LU (1) | LU50032A1 (en) |
NL (1) | NL6516086A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999023178A1 (en) * | 1997-10-31 | 1999-05-14 | Dynamit Nobel Kunststoff Gmbh | Electrically conductive covering paint |
US10435225B2 (en) | 2011-03-11 | 2019-10-08 | Advansix Resins & Chemicals Llc | Heat sealable food packing films, methods for the production thereof, and food packages comprising heat sealable food packaging films |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2618446B1 (en) * | 1987-07-24 | 1993-03-19 | Centre Nat Etd Spatiales | IONIZABLE PAINTS USEFUL IN PARTICULAR AS ANTI-LIGHTNING PAINTS |
DE69715933T2 (en) * | 1996-02-08 | 2003-08-07 | Teijin Ltd., Osaka | Adhesive polyester composite |
-
1964
- 1964-12-10 GB GB50363/64A patent/GB1065680A/en not_active Expired
-
1965
- 1965-12-10 FR FR41797A patent/FR1460218A/en not_active Expired
- 1965-12-10 BE BE673602D patent/BE673602A/xx unknown
- 1965-12-10 ES ES0320560A patent/ES320560A1/en not_active Expired
- 1965-12-10 CH CH1705365A patent/CH438701A/en unknown
- 1965-12-10 NL NL6516086A patent/NL6516086A/xx unknown
- 1965-12-10 LU LU50032A patent/LU50032A1/xx unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999023178A1 (en) * | 1997-10-31 | 1999-05-14 | Dynamit Nobel Kunststoff Gmbh | Electrically conductive covering paint |
US10435225B2 (en) | 2011-03-11 | 2019-10-08 | Advansix Resins & Chemicals Llc | Heat sealable food packing films, methods for the production thereof, and food packages comprising heat sealable food packaging films |
Also Published As
Publication number | Publication date |
---|---|
ES320560A1 (en) | 1966-12-16 |
CH438701A (en) | 1967-06-30 |
LU50032A1 (en) | 1966-02-10 |
FR1460218A (en) | 1966-11-25 |
BE673602A (en) | 1966-06-10 |
NL6516086A (en) | 1966-06-13 |
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