KR970059228A - Thermoplastic resin composition having flame retardancy - Google Patents

Thermoplastic resin composition having flame retardancy Download PDF

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Publication number
KR970059228A
KR970059228A KR1019960001869A KR19960001869A KR970059228A KR 970059228 A KR970059228 A KR 970059228A KR 1019960001869 A KR1019960001869 A KR 1019960001869A KR 19960001869 A KR19960001869 A KR 19960001869A KR 970059228 A KR970059228 A KR 970059228A
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South Korea
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weight
parts
resin composition
thermoplastic resin
resin
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KR1019960001869A
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Korean (ko)
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KR0178458B1 (en
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장복남
이규철
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유현식
제일모직 주식회사
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5313—Phosphinic compounds, e.g. R2=P(:O)OR'
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/66—Substances characterised by their function in the composition
    • C08L2666/84—Flame-proofing or flame-retarding additives

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명의 열가소성 수지 조성물은 (A)(a1) 할로겐을 함유하지 않은 열가소성 폴리카보네이트 수지 75∼96 중량%; (a2) 부타디엔 고무 40∼70 중량%에 스티렌 50∼20%, 메틸메타아크릴레이트 0∼20 중량%, 및 아크릴로니트릴 0∼20 중량%를 그라프트 중합시킨 스티렌－함유 그라프트 공중합체 수지 25∼4 중량%; 및 (A3) 스티렌 60∼85중량%와 아크릴로니트릴 40∼15 중량%로 이루어진 공중합체 수지 0∼10 중량% 중량%로 기초수지 100 중량부에 대하여 (B) 트리아릴포스페이트 30∼60 중량%와 아릴포스페이트 울리고머 70∼40 중량%의 혼합물 또는 합성된 아릴포스페이트 올리고머 5∼20 중량부의 인계 난연제 (C) 플루오로계 수지 0.1∼2.0 중량부, 및 (D) 제올라이트 0.01∼10 중량부를 혼합시킨 수지 조성물이다.The thermoplastic resin composition of the present invention (A) (a 1) a thermoplastic polycarbonate resin, 75-96% by weight which does not contain a halogen; (a 2 ) a styrene-containing graft copolymer resin having 40 to 70% by weight of butadiene rubber graft-polymerized with 50 to 20% of styrene, 0 to 20% by weight of methyl methacrylate, and 0 to 20% by weight of acrylonitrile 25 to 4% by weight; And (A3) 0 to 10% by weight of a copolymer resin comprising 60 to 85% by weight of styrene and 40 to 15% by weight of acrylonitrile, (B) 30 to 60% by weight of triaryl phosphate, (C) 0.1 to 2.0 parts by weight of a phosphorus-based flame retardant, and (D) 0.01 to 10 parts by weight of zeolite are mixed with a mixture of 70 to 40% by weight of an arylphosphate oligomer and 5 to 20 parts by weight of a synthesized aryl phosphate oligomer, Resin composition.

본 발명의 수지 조성물은 각각의 용도에 따라 무기물 첨가제, 열안정제, 광안정제, 안료 및/또는 염료가 부가될 수 있다.The resin composition of the present invention may be added with an inorganic additive, a heat stabilizer, a light stabilizer, a pigment and / or a dye depending on each application.

Description

난연성을 갖는 열가소성 수지 조성물Thermoplastic resin composition having flame retardancy

내용없음No content

Claims (5)

(A) (a1) 할로겐을 함유하지 않은 방향족 폴리카보네이트 수지 75∼96 중량%; (a2) 부타디엔 고무 40∼70 중량%에 스티랜 50∼20 중량%, 메틸메타아크릴레이트 0∼20 중량% 및 아크릴로니트릴 0∼20 중량%를 그라프트 중합시킨 스티렌－함유 그라프트 공중합체 수지 25∼4 중량%; 및 (a3) 스티렌 60∼85 중량%와 아크릴로니트릴 40∼15 중량로 이루어진 공중합체 수지 0∼10 중량%;로 이루어진 기초수진 100 중량부; (B) 상기 기초 수지 100 중량부에 대하여 트리아릴포스페이트 30∼60 중량%와 아릴포스페이트 올리고머 70∼40 중량%로 이루어진 인화합물 또는 합성된 아릴포스페이트 올리고머 5∼20 중량부; (C) 상기 기초수지 100 중량부에 대하여 플루오르계 수지 0.1∼2.0 중량부; 및 (D) 상기 기초수지 100 중량부에 대하여 제울라이트 0.05∼10 중량부;로 구성되는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.(A) 75 to 96% by weight of (a 1 ) halogen-free aromatic polycarbonate resin; (a 2 ) 40 to 70% by weight of butadiene rubber A styrene-containing graft copolymer obtained by graft-polymerizing 20 to 20% by weight of esstylene, 0 to 20% by weight of methyl methacrylate and 0 to 20% by weight of acrylonitrile 25 to 4% by weight of resin; And (a 3) 60 to 85 40-15 styrene copolymer resins 0 to 10 wt.% Consisting of by weight% by weight of acrylonitrile and acrylic; Susan based 100 parts by weight consisting of; (B) 5 to 20 parts by weight of a phosphorus compound or synthesized aryl phosphate oligomer consisting of 30 to 60% by weight of triaryl phosphate and 70 to 40% by weight of aryl phosphate oligomer based on 100 parts by weight of the base resin; (C) 0.1 to 2.0 parts by weight of a fluorine-based resin per 100 parts by weight of the base resin; And (D) 0.05 to 10 parts by weight of zeolite relative to 100 parts by weight of the base resin. 제1항에 있어서, 상기 트리아릴포스페이트와 아릴포스페이트 올리고머로 이루어진 인화합물 또는 합성된 아릴포스페이트 올리고(B)는 하기 일반식으로 표시되며, n의 값이 0.3 내지 0.8의 범위인 것을 특징으로 하는 난연성을 갖는 수지 조성물 :[Claim 3] The method according to claim 1, wherein the phosphorus compound or the aryl phosphate oligomer (B) comprising the triaryl phosphate and the aryl phosphate oligomer is represented by the following general formula and has a value of n ranging from 0.3 to 0.8. . 상기 식에서 R1, R2, R3, R4및 R5는 서로 독립적으로 할로겐을 함유하지 않은 C6－C20아릴기 또는 알킬치환된 알리기임.Wherein R 1 , R 2 , R 3 , R 4 and R 5 are, independently of each other, a C 6 -C 20 aryl group free of halogen or an alkyl-substituted ally group. 제1항에 있어서, 상기 플루오르계 수지(C)는 폴리테트라플루오로에틸렌, 폴리비닐리엔플루오라이드, 테트라플루오로에틸렌과 비닐리덴플루오라이드의 공중합체, 테트라플루오로에틸렌과 플루오로알킬비닐에테르의 공중합체, 및 테트라플루오로에틸렌과 핵사플루오로프로필렌의 공중합체로 이루어지는 군으로부터 선택된 하나 이상인 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The fluorine resin composition according to claim 1, wherein the fluorine-based resin (C) is at least one selected from the group consisting of polytetrafluoroethylene, polyvinylidene fluoride, copolymers of tetrafluoroethylene and vinylidene fluoride, tetrafluoroethylene and fluoroalkyl vinyl ether , And a copolymer of tetrafluoroethylene and hexafluoropropylene. The flame retardant thermoplastic resin composition according to claim 1, wherein the thermoplastic resin composition is a thermoplastic resin. 제1항에 있어서, 상기 제올라이트(D)는 그 공극의 크기가 3∼8A 인 제올라이트 X 또는 제올라이트 X인 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The flame-retardant thermoplastic resin composition according to claim 1, wherein the zeolite (D) is zeolite X or zeolite X having a pore size of 3 to 8A. 제1항에 있어서, 상기 수지 조성물이 무기물 첨가제, 열안정제, 산화방지제, 광안정제, 안료 및/또는 염료를 더 포함하는 것을 특징으로 하는 열가소성 수지 조성물.The thermoplastic resin composition according to claim 1, wherein the resin composition further comprises an inorganic additive, a heat stabilizer, an antioxidant, a light stabilizer, a pigment and / or a dye. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: It is disclosed by the contents of the first application.
KR1019960001869A 1996-01-29 1996-01-29 Thermoplastic resin compositions having anti-flammability KR0178458B1 (en)

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KR970059228A true KR970059228A (en) 1997-08-12
KR0178458B1 KR0178458B1 (en) 1999-05-15

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