KR960001029A - Thermoplastic resin composition having flame retardancy - Google Patents

Thermoplastic resin composition having flame retardancy Download PDF

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Publication number
KR960001029A
KR960001029A KR1019940015380A KR19940015380A KR960001029A KR 960001029 A KR960001029 A KR 960001029A KR 1019940015380 A KR1019940015380 A KR 1019940015380A KR 19940015380 A KR19940015380 A KR 19940015380A KR 960001029 A KR960001029 A KR 960001029A
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South Korea
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weight
resin composition
parts
thermoplastic resin
styrene
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KR1019940015380A
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Korean (ko)
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장복남
양삼주
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유현식
제일모직 주식회사
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Priority to KR1019940015380A priority Critical patent/KR960001029A/en
Publication of KR960001029A publication Critical patent/KR960001029A/en

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Abstract

본 발명의 난연성을 갖는 열가소성 수지 조성물은 폴리카보네이트 또는 ABS를 포함하는 폴리카보네이트의 기초수지 100중량부에 대하여 할로겐 화합물 1∼14중량부, 인화합물 2∼10중량부, 플루오로계 수지 0.1∼2.0중량부 및 산화 안티몬 0.1∼3.0중량부가 포함된 수지 조성물이다. 폴리카보네이트와 함께 사용되는 ABS 수지는 스티렌, α-메틸스티렌, 아크릴로니트릴, 메틸메타아크릴레이트 및 N-페닐말레이미드 중의 두개 이상의 화합물을 중합한 공중합체 0∼60중량%와 스티렌, α-메틸스티렌, 아크릴로니트릴, 메틸메타아크릴레이트 및 N-페닐말레이미드 중의 두개 이상의 화합물의 유리전이온도가 15℃ 이하인 고무에 그라프팅시킨 그라프트 공중합체 100-40중량%로 이루어진다. 본 발명의 수지 조성물은 각각의 용도에 따라 무기물 첨가제, 열안정제, 산화방지제, 광안정제, 안료, 염료 등이 부가될 수 있다.The thermoplastic resin composition having flame retardancy according to the present invention comprises 1 to 14 parts by weight of a halogen compound, 2 to 10 parts by weight of phosphorus compound, and 0.1 to 2.0 fluororesin based on 100 parts by weight of the base resin of polycarbonate or polycarbonate containing ABS. It is a resin composition containing 0.1 parts by weight and 0.1 to 3.0 parts by weight of antimony oxide. ABS resin used with polycarbonate is 0 to 60% by weight of a copolymer of two or more compounds of styrene, α-methylstyrene, acrylonitrile, methyl methacrylate and N-phenylmaleimide and styrene, α-methyl The glass transition temperature of two or more compounds in styrene, acrylonitrile, methyl methacrylate and N-phenylmaleimide is 100-40% by weight of the graft copolymer grafted to rubber having a temperature of 15 ° C. or less. In the resin composition of the present invention, an inorganic additive, a heat stabilizer, an antioxidant, a light stabilizer, a pigment, a dye, and the like may be added according to each use.

Description

난연성을 갖는 열가소성 수지 조성물Thermoplastic resin composition having flame retardancy

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (12)

폴리카보네이트의 수지 100중량부에 대하여 1∼14중량부의 할로겐 화합물, 2∼10중량부의 인화합물, 0.1∼2.0중량부의 플로오로계 수지 및 0.1∼3.0중량부의 산화안티몬이 함유되는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.1 to 14 parts by weight of a halogen compound, 2 to 10 parts by weight of phosphorus compound, 0.1 to 2.0 parts by weight of fluororesin, and 0.1 to 3.0 parts by weight of antimony oxide based on 100 parts by weight of the resin of polycarbonate Thermoplastic resin composition having a. 제1항에 있어서, 상기 폴리카보네이트가 ABS 수지를 포함하는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The thermoplastic resin composition of claim 1, wherein the polycarbonate comprises an ABS resin. 제2항에 있어서, 상기 ABS 수지는 (ⅰ) 스티렌, α-메틸스티렌, 아크릴로니트릴, 메틸메타아크릴레이트 및 N-페닐말레이미드 중의 두개 이상의 화합물을 중합한 SAN 공중합체 0∼60중량%와 (ⅱ) 스티렌, α-메틸스티렌, 아크릴로니트릴, 메틸메타아크릴레이트 및 N-페닐말레이미드 중의 두개 이상의 화합물을 유리전이온도가 15℃ 이하인 고무에 그라프팅시킨 g-ABS 그라프트 공중합체 100∼40중량%인 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The method of claim 2, wherein the ABS resin is (i) 0 to 60% by weight of a SAN copolymer obtained by polymerizing two or more compounds of styrene, α-methylstyrene, acrylonitrile, methyl methacrylate and N-phenylmaleimide; (Ii) 100 g-ABS graft copolymers in which two or more compounds in styrene, α-methylstyrene, acrylonitrile, methyl methacrylate and N-phenylmaleimide are grafted onto rubber having a glass transition temperature of 15 ° C. or lower; It is 40 weight%, The thermoplastic resin composition which has flame retardance characterized by the above-mentioned. 제3항에 있어서, 상기 SAN 공중합체는 스티렌, α-치환스티렌 및 핵치환스티렌 중에서 선택된 하나 이상의 화합물 60∼85중량%와 메틸메타아크릴레이트 및 N-치환말레이미드 및 아크릴로니트릴 중에서 선택된 하나 이상의 화합물 40∼15중량%로 이루어진 공중합체인 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The method according to claim 3, wherein the SAN copolymer is 60 to 85% by weight of one or more compounds selected from styrene, α- substituted styrene and nuclear substituted styrene and at least one selected from methyl methacrylate, N- substituted maleimide and acrylonitrile A thermoplastic resin composition having flame retardancy, characterized in that the copolymer is composed of 40 to 15% by weight of the compound. 제3항에 있어서, 상기 g-ABS 그라프트 공중합체는 유리전이온도가 15℃ 이하인 고무 40∼70중량부에 스티렌, N-치환스티렌 및 핵치환스티렌 중에서 선택된 하나 이상의 화합물 30∼50중량부와 메틸메타아크릴레이트, N-치환말레이미드 및 아크릴로니트릴 중에서 선택된 하나 이상의 화합물 20∼10중량부를 그라프팅시킨 그라프트 공중합체로서, 그라프트율이 50 내지 90%가 되는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.According to claim 3, wherein the g-ABS graft copolymer is 30 to 50 parts by weight of one or more compounds selected from styrene, N- substituted styrene and nuclear substituted styrene 40 to 70 parts by weight of rubber having a glass transition temperature of 15 ℃ A graft copolymer obtained by grafting 20 to 10 parts by weight of at least one compound selected from methyl methacrylate, N-substituted maleimide and acrylonitrile, wherein the graft ratio is 50 to 90%. Composition. 제3항에 있어서, 상기 고무는 아크릴고무, 부타디엔 고무, 에틸렌-프로필렌 고무, 스티렌-부타디엔 고무 및 아클릴로니트릴-부타디엔 고무로 이루어진 군으로부터 선택되는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The thermoplastic resin composition of claim 3, wherein the rubber is selected from the group consisting of acrylic rubber, butadiene rubber, ethylene-propylene rubber, styrene-butadiene rubber, and acrylonitrile-butadiene rubber. 제1항에 있어서, 상기 할로겐 화합물은 브롬치환된 디페닐에테르, 브롬치환된 비스페놀-A, 염소치환된 폴리에틸렌, 및 브롬치환된 에폭시수지로 이루어진 군으로부터 선택되는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The flame retardant thermoplastic resin of claim 1, wherein the halogen compound is selected from the group consisting of brominated substituted diphenyl ether, brominated substituted bisphenol-A, chlorine substituted polyethylene, and brominated substituted epoxy resin. Composition. 제1항에 있어서, 상기 인화합물은 트리메틸 포스페이트, 트리에틸 포스페이트, 트리부틸포스페이트 및 트리옥틸 포스페이트와 같은 트리알킬포스페이트; 트리페닐포스페이트, 트리크레실 포스페이트, 트리자일레닐 포스페이트, 자이레닐 디페닐 포스페이트 및 크레실디페닐포스페이트와 같은 트리아릴포스페이트; 또는 옥틸디페닐포스페이트와 같은 트리알킬-아릴포스페이트인 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The method of claim 1, wherein the phosphorus compound is trialkyl phosphate, such as trimethyl phosphate, triethyl phosphate, tributyl phosphate and trioctyl phosphate; Triaryl phosphates such as triphenylphosphate, tricresyl phosphate, trixenyl phosphate, xylenyl diphenyl phosphate and cresyl diphenyl phosphate; Or a trialkyl-aryl phosphate such as octyl diphenyl phosphate. 제1항에 있어서, 상기 플루오로계 수지는 폴리테트라플루오로에틸렌, 테트라플루오로에틸렌과 헥사플루오로프로필렌과의 공중합체, 테트라플루오로에틸렌과 피플루오로알킬비닐에테르와의 공중합체, 테트라플루오로에틸렌과 헥사플루오로 프로필렌과의 공중합체 및 폴리비닐리덴플루오라이드로 이루어진 군으로부터 선택되는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The method of claim 1, wherein the fluoro resin is polytetrafluoroethylene, a copolymer of tetrafluoroethylene and hexafluoropropylene, a copolymer of tetrafluoroethylene and pifluoroalkyl vinyl ether, tetrafluoro A thermoplastic resin composition having flame retardancy, characterized in that it is selected from the group consisting of copolymers of roethylene and hexafluoro propylene and polyvinylidene fluoride. 제1항에 있어서, 상기 산화안티몬은 삼산화안티몬 또는 오산화안티몬인 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The thermoplastic resin composition of claim 1, wherein the antimony oxide is antimony trioxide or antimony pentoxide. 제1항에 있어서, 상기 수지조성물이 무기물 첨가제, 열안정제, 산화방지제, 광안정제, 안료 또는 염료를 더 포함하는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The thermoplastic resin composition of claim 1, wherein the resin composition further comprises an inorganic additive, a heat stabilizer, an antioxidant, a light stabilizer, a pigment, or a dye. 제11항에 있어서, 상기 무기물 첨가제는 석면, 유리섬유, 탈크 및 세라믹으로 이루어진 군으로부터 선택되는 것을 특징으로 하는 난연성을 갖는 열가소성 수지 조성물.The thermoplastic resin composition of claim 11, wherein the inorganic additive is selected from the group consisting of asbestos, glass fibers, talc, and ceramics. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940015380A 1994-06-30 1994-06-30 Thermoplastic resin composition having flame retardancy KR960001029A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030003362A (en) * 2001-06-30 2003-01-10 심대근 Door panel composed of burning resist plastics
KR100471561B1 (en) * 2001-12-28 2005-03-08 제일모직주식회사 Glass Reinforced Styrenic Thermoplastic Composition
KR100493957B1 (en) * 2001-12-27 2005-06-08 제일모직주식회사 Acrylonitrile-Butadiene-Styrene Flame Retardant Resin Composition with Good Impact Strength, Flammability and Easy Colorability
KR100706840B1 (en) * 2001-06-18 2007-04-11 주식회사 삼양사 Polycarbonate resin composition with improved flowability and impact-resistance
KR100813233B1 (en) * 2006-02-06 2008-03-13 삼성전기주식회사 Camera module and method of manufacturing the same
KR20220050724A (en) 2020-10-16 2022-04-25 엄상용 Housing assembly frame for building structure
KR20230155948A (en) 2022-05-04 2023-11-13 엄상용 Self assembly type frame structure
US11879042B2 (en) 2021-08-02 2024-01-23 B/E Aerospace, Inc. Fire resistant thermoplastic-based resin for fiber-reinforced composites
KR20240013297A (en) 2022-07-22 2024-01-30 엄상용 Manufactuting system of housing assembly for building structure
KR20240013711A (en) 2022-07-22 2024-01-30 엄상용 Self assembly type frame structure
KR20240012994A (en) 2022-07-21 2024-01-30 엄상용 Manufacturing method of housing assembly for building structure
KR20240013713A (en) 2022-07-22 2024-01-30 엄상용 Self assembly type frame structure
KR20240013712A (en) 2022-07-22 2024-01-30 엄상용 Self assembly type frame structure
KR20240012908A (en) 2022-07-21 2024-01-30 엄상용 Housing assembly for building structure
KR20240013714A (en) 2022-07-22 2024-01-30 엄상용 Self assembly type frame structure

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100706840B1 (en) * 2001-06-18 2007-04-11 주식회사 삼양사 Polycarbonate resin composition with improved flowability and impact-resistance
KR20030003362A (en) * 2001-06-30 2003-01-10 심대근 Door panel composed of burning resist plastics
KR100493957B1 (en) * 2001-12-27 2005-06-08 제일모직주식회사 Acrylonitrile-Butadiene-Styrene Flame Retardant Resin Composition with Good Impact Strength, Flammability and Easy Colorability
KR100471561B1 (en) * 2001-12-28 2005-03-08 제일모직주식회사 Glass Reinforced Styrenic Thermoplastic Composition
KR100813233B1 (en) * 2006-02-06 2008-03-13 삼성전기주식회사 Camera module and method of manufacturing the same
KR20220050724A (en) 2020-10-16 2022-04-25 엄상용 Housing assembly frame for building structure
US11879042B2 (en) 2021-08-02 2024-01-23 B/E Aerospace, Inc. Fire resistant thermoplastic-based resin for fiber-reinforced composites
KR20230155948A (en) 2022-05-04 2023-11-13 엄상용 Self assembly type frame structure
KR20240012994A (en) 2022-07-21 2024-01-30 엄상용 Manufacturing method of housing assembly for building structure
KR20240012908A (en) 2022-07-21 2024-01-30 엄상용 Housing assembly for building structure
KR20240013297A (en) 2022-07-22 2024-01-30 엄상용 Manufactuting system of housing assembly for building structure
KR20240013711A (en) 2022-07-22 2024-01-30 엄상용 Self assembly type frame structure
KR20240013713A (en) 2022-07-22 2024-01-30 엄상용 Self assembly type frame structure
KR20240013712A (en) 2022-07-22 2024-01-30 엄상용 Self assembly type frame structure
KR20240013714A (en) 2022-07-22 2024-01-30 엄상용 Self assembly type frame structure

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