KR970042360A - Composition and manufacturing method of organic and inorganic composite materials for optical devices - Google Patents

Composition and manufacturing method of organic and inorganic composite materials for optical devices Download PDF

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Publication number
KR970042360A
KR970042360A KR1019950051856A KR19950051856A KR970042360A KR 970042360 A KR970042360 A KR 970042360A KR 1019950051856 A KR1019950051856 A KR 1019950051856A KR 19950051856 A KR19950051856 A KR 19950051856A KR 970042360 A KR970042360 A KR 970042360A
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South Korea
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organic
solution
inorganic composite
vinylene
optical device
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KR1019950051856A
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Korean (ko)
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KR0185656B1 (en
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한원백
윤영권
이병우
황태진
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이진주
생산기술연구원
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Priority to KR1019950051856A priority Critical patent/KR0185656B1/en
Publication of KR970042360A publication Critical patent/KR970042360A/en
Priority to KR1019980032464A priority patent/KR100188042B1/en
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00—Methods for coating glass
    • C03C2218/10—Deposition methods
    • C03C2218/11—Deposition methods from solutions or suspensions
    • C03C2218/111—Deposition methods from solutions or suspensions by dipping, immersion

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Glass Melting And Manufacturing (AREA)

Abstract

본원에서는 유기물질과 매질유리로서 이루어지는 광소자용 유기·무기 복합재료 및 그의 제조방법을 개시한다. 매질유리로서 붕산성분 첨가량이 0∼40몰%인 붕규산염계 유리를 사용한다. 유기물질로서는 폴리 폐닐렌 비닐렌, 폴리 벤조 티오펜 및 폴리 벤조 푸란 비닐렌으로이루어진 그룹에서 선택된 폴리머가 사용한다. 매질 유리의 제조를 위한 복합 금속 알크옥사이드 용액과 유기 물질 프리커서 용액을 물, 알코올 및 염산과 혼합하여 유기·무기 복합 용액을 제조한 후, 그 혼합물을 건조, 성형 및 소성시켜서 광소자용 유기·무기 복합재료를 제조한다.The present application discloses an organic / inorganic composite material for an optical device composed of an organic material and medium glass, and a manufacturing method thereof. As the medium glass, borosilicate glass having a boric acid component addition amount of 0 to 40 mol% is used. As the organic substance, a polymer selected from the group consisting of polypentylene vinylene, polybenzothiophene and polybenzofuran vinylene is used. A mixed metal alkoxide solution and an organic precursor solution for the preparation of medium glass are mixed with water, alcohol and hydrochloric acid to prepare an organic / inorganic composite solution, and then the mixture is dried, molded and calcined for organic and inorganic optical devices. Manufacture a composite material.

Description

광소자용 유기·무기 복합재료의 조성과 제조방법Composition and manufacturing method of organic and inorganic composite materials for optical devices

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

무기물질성분으로서, 실리카 유리와, 유기물질성분으로서, 폴리 벤조 티오펜비닐렌, 및 폴리 벤조 푸란 비닐렌으로 이루어진 그룹으로부터 선택된 폴리머가 복합되어 있는 것을 특징으로 하는 광소자용 유기 무기 복합재료.An organic inorganic composite material for an optical device, characterized in that a polymer selected from the group consisting of silica glass as an inorganic material component and polybenzothiophene vinylene and polybenzofuran vinylene as an organic material component is compounded. 무기물질성분으로서, 붕규산염계 유리와, 유기물질성분으로서 폴리 페닐렌 비닐렌, 폴리 벤조 티오펜 비닐렌, 폴리 벤조 푸란 비닐렌, 폴리 디 아세틸렌, 폴리 아세틸렌, 폴리 티오펜, 폴리 페닐렌 벤조 비스티아졸, 및 폴리 페닐렌 벤조 비소크시졸로 이루어진 그룹으로부터 선택된 폴리머가 복합되어 있는 것을 특징으로 하는 광소자용 유기 ·무기 복합재료.Borosilicate glass as an inorganic substance component, and polyphenylene vinylene, polybenzothiophene vinylene, polybenzofuran vinylene, polydiacetylene, polyacetylene, polythiophene, polyphenylene benzobisti as an organic substance component An organic-inorganic composite material for an optical device, characterized in that a polymer selected from the group consisting of azoles and polyphenylene benzobisoxazoles is compounded. (가) 복합용액의 전체부피를 기준으로 10-50 부피%의 규산염 용액과, 10∼50 부피%의 알코을과, 1∼15부피%의 물과, 0∼3000 ppm의 염산을 혼합한 후, 그 혼합물중의 규산염 용액을 가수분해하는 단계; (나) 상기 혼합물에, 실리카:보레이트의 몰 비가 10 : 0 내지 6 : 4가 되도록 붕산염 용액을 첨가하여 매질유리의 형성을 위한 복합 금속 알크옥사이드 용액을 제조하는 단계; (다) 상기의 복합금속 알크옥사이드 용액에 유기물질 프리커서 용액을 5 : 1 내지 10 : 1의 부피비로 혼합하여 유기 · 무기 복합용액을 제조하는 단계; (라) 상기의 유기 ·무기 복합용액을 이용하여 성형하는 단계; (마) 상기의 유기 · 무기 복할성형물을 건조시키는 단계; (바 )상기의 성형물을 소성하는 단계를 포함하는 것을 특징으로 하는 광소자용 유기 · 무기 복합재료의 제조방법.(A) After mixing 10-50 vol% silicate solution, 10-50 vol% alcohol, 1-15 vol% water, and 0-3000 ppm hydrochloric acid based on the total volume of the composite solution, Hydrolyzing the silicate solution in the mixture; (B) adding a borate solution to the mixture such that the molar ratio of silica: borate is from 10: 0 to 6: 4 to prepare a composite metal alkoxide solution for forming medium glass; (C) preparing an organic / inorganic composite solution by mixing the organic material precursor solution with the complex metal alkoxide solution in a volume ratio of 5: 1 to 10: 1; (D) molding using the organic-inorganic composite solution; (E) drying the organic and inorganic complexed products; (F) The method for producing an organic / inorganic composite material for an optical device, comprising the step of firing the molded product. 제 3 항에 있어서, 상기 유기물질 프리커서 용액은 폴리 페닐렌 비닐렌, 폴리벤조 티오렌 비닐렌 및 폴리벤조 푸란 비닐렌으로 이루어진 그룹에서 선택되는 것을 특징으로 하는 광소자용 유기 ·무기 복합재료의 제조방법.The organic-inorganic composite material for an optical device according to claim 3, wherein the organic precursor solution is selected from the group consisting of polyphenylene vinylene, polybenzothioene vinylene, and polybenzofuran vinylene. Way. 제 3 항에 있어서, 상기의 단계 (가) 내지 (마)에서, 공정분위기의 습도는 20∼30%로 유지하는 것을 특징으로 하는 광소자용 유기 ·무기 복합재료의 제조방법.The method according to claim 3, wherein in the above steps (a) to (e), the humidity of the process atmosphere is maintained at 20 to 30%. 제 3 항에 있어서, 상기 규산염 용액은 테트라에틸오르토실리케이트인 것을 특징으로 하는 광소자용 유기 ·무기 복합재료의 제조방법.The method for producing an organic-inorganic composite material for an optical device according to claim 3, wherein the silicate solution is tetraethylorthosilicate. 제 3 항에 있어서, 상기 붕산염 용액은 트리메틸보레이트인 것을 특징으로 하는 광소자응 유기 ·무기 복합 재료의 제조방법.4. The method of producing an optical device-coated organic / inorganic composite material according to claim 3, wherein the borate solution is trimethyl borate. 제 3 항에 있어서, 상기의 단계 (라)에서의 성형은 복합용액을 이용하여 유리 기판상에 3∼10m/분의 속도로 딥 코팅(dip coating)하여 유기 · 무기 복합 박막을 형성함으로써 수행되는 것을 특징으로 하는 광소자용 유기 ·무기 복합재료의 제조방법.4. The molding according to claim 3, wherein the molding in step (d) is performed by dip coating at a rate of 3 to 10 m / min on a glass substrate using a composite solution to form an organic / inorganic composite thin film. A method for producing an organic / inorganic composite material for an optical device, characterized in that. 제 3 항에 있어서, 상기의 단계(마)에서의 건조는 30-5Ot에서 약 30분간 실시되는 것을 특징으로 하는 광소자용 유기 ·무기 복합재료의 제조방법.The method of manufacturing an organic-inorganic composite material for an optical device according to claim 3, wherein the drying in said step (e) is performed at 30-5Ot for about 30 minutes. 제 3 항에 있어서, 상기의 단계(바)에서의 소성은 0.1 Toor 이하의 진공 및 200∼300t의 온도에서 1∼5시간동안 실시하는 것을 특징으로 하는 광소자용 유기 ·무기 복합박막의 제조방법.4. The method according to claim 3, wherein the firing in the step (bar) is performed for 1 to 5 hours at a vacuum of 0.1 Toor or less and a temperature of 200 to 300 tons.
KR1019950051856A 1995-12-19 1995-12-19 Method for manufacturing an optical element KR0185656B1 (en)

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Application Number Priority Date Filing Date Title
KR1019950051856A KR0185656B1 (en) 1995-12-19 1995-12-19 Method for manufacturing an optical element
KR1019980032464A KR100188042B1 (en) 1995-12-19 1998-08-10 An organic and inorganic-composite material for photodevice and preparing method thereof

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KR1019950051856A KR0185656B1 (en) 1995-12-19 1995-12-19 Method for manufacturing an optical element

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KR0185656B1 KR0185656B1 (en) 1999-04-15

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