KR970025688A - 천연가스형 수소발생장치 - Google Patents

천연가스형 수소발생장치 Download PDF

Info

Publication number
KR970025688A
KR970025688A KR1019960070402A KR19960070402A KR970025688A KR 970025688 A KR970025688 A KR 970025688A KR 1019960070402 A KR1019960070402 A KR 1019960070402A KR 19960070402 A KR19960070402 A KR 19960070402A KR 970025688 A KR970025688 A KR 970025688A
Authority
KR
South Korea
Prior art keywords
natural gas
pipeline
combustion
reformer
casing
Prior art date
Application number
KR1019960070402A
Other languages
English (en)
Other versions
KR100209989B1 (ko
Inventor
김태천
윤경식
정성재
한재성
형준호
Original Assignee
조규향
주식회사 유 공
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 조규향, 주식회사 유 공 filed Critical 조규향
Priority to KR1019960070402A priority Critical patent/KR100209989B1/ko
Publication of KR970025688A publication Critical patent/KR970025688A/ko
Priority to US08/988,364 priority patent/US5932181A/en
Priority to JP34900197A priority patent/JP4090097B2/ja
Application granted granted Critical
Publication of KR100209989B1 publication Critical patent/KR100209989B1/ko

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J7/00—Apparatus for generating gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/0257—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical annular shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0449—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds
    • B01J8/0453—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more cylindrical beds the beds being superimposed one above the other
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0496—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/108—Zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/116—Molecular sieves other than zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B01D2257/7025—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/40—Further details for adsorption processes and devices
    • B01D2259/40001—Methods relating to additional, e.g. intermediate, treatment of process gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
    • B01D53/0476—Vacuum pressure swing adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/26—Drying gases or vapours
    • B01D53/261—Drying gases or vapours by adsorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/0015—Controlling the temperature by thermal insulation means
    • B01J2219/00155—Controlling the temperature by thermal insulation means using insulating materials or refractories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00164—Controlling or regulating processes controlling the flow
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/042—Purification by adsorption on solids
    • C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • C01B2203/1264—Catalytic pre-treatment of the feed
    • C01B2203/127—Catalytic desulfurisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/1604—Starting up the process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16—Controlling the process
    • C01B2203/169—Controlling the feed
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
    • Y02P20/156—Methane [CH4]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

본 발명은 천연가스형 수소발생장치에 관한 것으로, 더욱 상세하게는 천연가스 및 물로 원료로 하여 고순도 수소를 자체에서 천연가스로부터 직접 생산하여 사용할 수 있도록 한 천연가스형 수소발생장치에 관한 것으로, 그 구성은 탈황장치와 리포머와 CO전환기와 피.에스.에이를 구비하는 천연가스형 수소발생장치에 있어서, 리포머(100)로부터 배출되는 고온의 연소가스를 탈황장치(200)에 공급하여 탈황장치(200)를 직접 예열시키기 위해 리포머(100)와 탈황장치(200)를 연통되게 연결시키는 파이프라인(26)과; 상기 리포머(100)에 공기를 공급하기 위한 파이프라인(25)상에 설치되어 리포머(100)로 공급되는 공기의 량을 조절하기 위한 밸브수단(302)과; 상기 밸브수단(302)을 사이에 두고 양단부가 각각 상기 파이프라인(23)과 연동되게 연결되는 파이프라인(25)과 상기 파이프라인(25)과 리포머(100)로부터 생산되어 배출되는 생산가스를 CO전환기(6)에 공급하기 위한 파이프라인(25)을 열교환시켜 고온의 생산가스를 냉각시키기 위한 열교환기(300)와; 상기 파이프라인(25)의 소정위치에 장착되어 파이프라인(25)에 공급되는 공기량을 조절하기 위한 밸브수단을 포함하는 것을 특징으로 한다.

Description

천연가스형 수소발생장치
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제2도는 본 발명에 따른 리포머의 일 실시예의 구조를 도시하는 단면도,
제3도는 본 발명에 따른 리포머의 다른 실시예의 구조를 도시하는 단면도,
제4도는 본 발명에 따른 탈환장치의 구조를 도시하는 단면도.

Claims (11)

  1. 탈황장치와 리포머와 CO전환기와 피.에스.에이를 구비하는 천연가스형 수소발생장치에 있어서, 리포머(100)로부터 배출되는 고온의 연소가스를 탈황장치(200)에 공급하여 탈황장치(200)를 직접 예열시키기 위해 리포머(100)와 탈황장치(200)를 연통되게 연결시키는 파이프라인(26)과; 상기 리포머(100)에 공기를 공급하기 위한 파이프라인(23)상에 설치되어 리포머(100)로 공급되는 공기의 량을 조절하기 위한 밸브수단(302)과; 상기 밸브수단(302)을 사이에 두고 양단부가 각각 상기 파이프라인(23)과 연동되게 연결되는 파이프라인(25)과 상기 파이프라인(25)과 리포머(100)로부터 생산되어 배출되는 생산가스를 CO전환기(6)에 공급하기 위한 파이프라인(25)을 열교환시켜 고온의 생산가스를 냉각시키기 위한 열교환기(300)와; 상기 파이프라인(25)의 소정 위치에 장착되어 파이프라인(25)에 공급되는 공기량을 조절하기 위한 밸브수단을 포함하는 것을 특징으로 하는 천연 가스형 수소발생장치.
  2. 제1항에 있어서, 상기 리포머(100)는 내부에 중공을 갖는 통형상의 케이싱(101)과; 상기 케이싱(101)의 중공의 종심방향으로 소정직경과 길이를 갖고 고정설치되는 연소관(104)과; 상기 연소관(104)과 소정간격져서 연소관(104)을 에워싸고 내측공간에 수직으로 고정설치되는 개질관(102)과; 상기 개질관(102)의 내측공간에 개질관(102)의 바닥면으로부터 소정간격지게 수직으로 고정설치되어 개질관(102)의 내부공간을 분리하는 개질관분리판(103)과; 상기 개질관(102)외 외주면에 코일형상으로 권취되어 양단부가 상기 케이싱(101)를 관통하여 외부로 연장되는 수증기생산용 코일(105)과; 상기 케이싱(101)의 정부 중앙부에 케이싱(101)의 중공과 연통되게 연결되고 상기 수증기생산용코일(105)의 일단부와 연통되게 연결되는 천연가스원료주입구(101a)와; 상기 개질관(102)의 내측면과 상기 개질관분리판(103)의 내측면 사이에 층진되는 리포머촉매(110)와; 상기 연소관(104)의 내측 상하부 소정위치에 각각 고정설치되는 연소촉매와; 상기 케이싱(101)의 하면부 중앙부에 내부중공과 연통되게 하방으로 연장형성되어 히터(24)와 연결되는 에어주입구(101d)와; 상기 에어주입구(101d)의 소정위치에 연통되게 분지되는 천연가스연료주입구(108)와; 상기 케이싱(101)의 소정위치에 개질관(102)의 외측면과 케이싱(101)의 내측면 사이의 공간과 연통되게 연결형성되는 연소가스배출구(101b)와; 상기 케이싱(101)의 소정위치에 상기 개질관(102)의 내측공간과; 연통되게 연결형성되는 생산가스배출구(101c)를 구비하는 것을 특징으로 하는 천연가스형 수소발생장치.
  3. 제1항에 있어서, 상기 탈화장치(200)는 내부에 중공을 갖고 정부 및 하부 소정위치에 각각 천연가스입구(201a) 및 천연가스출구(201b)가 각각 내부중공과 연통되게 연결형성되고 외주면 소정위치에 각각 연소가스입구(201d) 및 연소가스출구(201c)가 내부 중공과 연통되게 각각 연결형성되는 케이싱(201)과; 소정길이를 갖고 내측공간의 상부측으로부터 수첨탈황촉매층(203) 및 황화수소흡수촉매층(204)이 순차적으로 층진되고 상기 케이싱(201)의 내부중공에 수직으로 고정설치되는 다수개의 핀드 튜브(202)를 구비하는 것을 특징으로 하는 천연 가스형 수소발생장치.
  4. 제1항, 제2항 또는 제3항에 있어서, 상기 파이프라인(26)은 일단부가 상기 탈환장치(200)의 연소가스입구(201d)와 연통되게 연결되고, 타단부가 상기 리포머(100)의 연고가스출구(101b)와 연통되게 연결되는 것을 특징으로 하는 천연가스형 수소발생장치.
  5. 제2항에 있어서, 상기 연소촉매는 소정직경 및 길이를 갖는 원통형상을 갖고 상기 연소관(104)의 내측상부와 하부에 각각 소정설치되고 파라디움 및 귀금속을 첨가해 제작되는 복수의 연소촉매(106, 107)를 사용하는 것을 특징으로 하는 천연가스형 수소발생장치.
  6. 제2항에 있어서, 상기 연소촉매는 소정직경과 길이를 갖는 원통형상을 파라니움계 금속으로 피복되어 상기 연소관(104)의 하부에 고정설치되는 촉매(150b)와, 수매의 원형와이어망으로 형성되어 파라니움으로 피복되어 상기 촉매(105b)의 상측에 고정설치되는 촉매(150a)로 구성되는 연소촉매(150)를 사용하는 것을 특징으로 하는 천연가스형 수소발생장치.
  7. 제2항에 있어서, 상기 수증기생산용코일(105)은 일단부가 상기 케이싱(101)의 외주면 소정위치에 관통되어 외부로 연장되어 물입구(105a)를 형성하고, 타단부가 상기 케이싱(101)의 외주면 소정위치에 관통되어 외부로 연장되어 수증기출구(105b)를 형성하는 것을 특징으로 하는 천연가스형 수소발생장치.
  8. 제2항 또는 제8항에 있어서, 상기 수증기출구(105b)는 상기 천연가스원료주입구(101a)와 연통되게 연결되는 것을 특징으로 하는 천연가스형 수소발생장치.
  9. 제3항에 있어서, 상기 핀드 튜브(202)는 3개 이상 설치되는 것을 특징으로 하는 천연가스형 수소발생장치.
  10. 제2항 또는 제5항에 있어서, 상기 복수의 연소촉매(106, 107)를 사용하는 경우에 상기 천연가스연료주입구(108)는 소정위치에 연통되게 분기되어 상기 연소관(104)의 내측으로 소정높이를 갖고 수직으로 연장형성되고 상부 외주면에 다수개의 분사공(109a)이 관통형성되어 연소촉매에 연료를 분사하는 연료분사관(109)을 포함하는 것을 특징으로 하는 천연가스형 수소발생장치.
  11. 제9항에 있어서, 상기 연료분사관(109)은 소정위치에 연료공급의 단속 및 연료량조절을 위한 밸브수단(109b)을 구비하는 것을 특징으로 하는 천연가스형 수소발생장치.
    ※ 참고사항:최초출원 내용에 의하여 공개하는 것임.
KR1019960070402A 1996-12-23 1996-12-23 천연가스형 수소발생장치 KR100209989B1 (ko)

Priority Applications (3)

Application Number Priority Date Filing Date Title
KR1019960070402A KR100209989B1 (ko) 1996-12-23 1996-12-23 천연가스형 수소발생장치
US08/988,364 US5932181A (en) 1996-12-23 1997-12-10 Natural gas-using hydrogen generator
JP34900197A JP4090097B2 (ja) 1996-12-23 1997-12-18 天然ガス型水素発生装置

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019960070402A KR100209989B1 (ko) 1996-12-23 1996-12-23 천연가스형 수소발생장치

Publications (2)

Publication Number Publication Date
KR970025688A true KR970025688A (ko) 1997-06-24
KR100209989B1 KR100209989B1 (ko) 1999-07-15

Family

ID=19490328

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960070402A KR100209989B1 (ko) 1996-12-23 1996-12-23 천연가스형 수소발생장치

Country Status (3)

Country Link
US (1) US5932181A (ko)
JP (1) JP4090097B2 (ko)
KR (1) KR100209989B1 (ko)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100423544B1 (ko) * 2001-04-23 2004-03-18 주식회사 경동도시가스 컴팩트형 수증기 개질장치
KR100467722B1 (ko) * 2000-12-26 2005-01-24 주식회사 포스코 산성가스로부터 수분을 제거하는 장치 및 방법
WO2006109972A1 (en) * 2005-04-11 2006-10-19 Sk Energy Co., Ltd. Cylindrical steam reformer having integrated heat exchanger
CN112142006A (zh) * 2020-09-28 2020-12-29 有研工程技术研究院有限公司 一种氢气分离组件

Families Citing this family (70)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6537352B2 (en) 1996-10-30 2003-03-25 Idatech, Llc Hydrogen purification membranes, components and fuel processing systems containing the same
US6783741B2 (en) 1996-10-30 2004-08-31 Idatech, Llc Fuel processing system
US6376113B1 (en) * 1998-11-12 2002-04-23 Idatech, Llc Integrated fuel cell system
US6494937B1 (en) 2001-09-27 2002-12-17 Idatech, Llc Hydrogen purification devices, components and fuel processing systems containing the same
US6221117B1 (en) 1996-10-30 2001-04-24 Idatech, Llc Hydrogen producing fuel processing system
US7195663B2 (en) 1996-10-30 2007-03-27 Idatech, Llc Hydrogen purification membranes, components and fuel processing systems containing the same
JP3473900B2 (ja) * 1999-05-24 2003-12-08 松下電器産業株式会社 水素発生装置
BR0012768A (pt) 1999-07-27 2002-04-02 Idatech Llc Sistema de células de combustìvel
US6979507B2 (en) * 2000-07-26 2005-12-27 Idatech, Llc Fuel cell system controller
US7135048B1 (en) 1999-08-12 2006-11-14 Idatech, Llc Volatile feedstock delivery system and fuel processing system incorporating the same
US6375906B1 (en) * 1999-08-12 2002-04-23 Idatech, Llc Steam reforming method and apparatus incorporating a hydrocarbon feedstock
US6451464B1 (en) * 2000-01-03 2002-09-17 Idatech, Llc System and method for early detection of contaminants in a fuel processing system
US6465118B1 (en) 2000-01-03 2002-10-15 Idatech, Llc System and method for recovering thermal energy from a fuel processing system
US7691271B1 (en) 2007-05-30 2010-04-06 University Of Central Florida Research Foundation, Inc. Filamentous carbon particles for cleaning oil spills and method of production
US6653005B1 (en) 2000-05-10 2003-11-25 University Of Central Florida Portable hydrogen generator-fuel cell apparatus
DE10052776A1 (de) * 2000-10-25 2002-08-08 Xcellsis Gmbh Vorrichtung und Verfahren zur Brennstoffversorgung eines Gaserzeugungssystems
US6585785B1 (en) 2000-10-27 2003-07-01 Harvest Energy Technology, Inc. Fuel processor apparatus and control system
US7201783B2 (en) * 2000-11-13 2007-04-10 Idatech, Llc Fuel processing system and improved feedstock therefor
US20020108306A1 (en) * 2001-02-12 2002-08-15 Grieve Malcolm James Reformer controls
US6620537B2 (en) * 2001-02-15 2003-09-16 Ralph C. Struthers Hydrocarbon fueled hydrogen fuel generator system and apparatus in combination with hydrogen fuel cells
US6569227B2 (en) 2001-09-27 2003-05-27 Idatech, Llc Hydrogen purification devices, components and fuel processing systems containing the same
DE10119721A1 (de) * 2001-04-21 2002-10-31 Bayer Cropscience Gmbh Herbizide Mittel enthaltend Benzoylcyclohexandione und Safener
US7270688B2 (en) * 2001-04-26 2007-09-18 Texaco Inc. Compact fuel processor for producing a hydrogen rich gas
EP1306351B1 (de) * 2001-06-15 2007-09-12 Umicore AG & Co. KG Verfahren zur Herstellung eines schwefelarmen Reformatgases zur Verwendung in einem Brennstoffzellensystem
US7632321B2 (en) * 2001-11-01 2009-12-15 Idatech, Llc Fuel processing systems, fuel cell systems, and improved feedstocks therefor
US20030167690A1 (en) * 2002-03-05 2003-09-11 Edlund David J. Feedstock delivery system and fuel processing systems containing the same
US7115148B2 (en) * 2002-05-14 2006-10-03 Her Majesty The Queen In Right Of Canada, As Respresented By The Minister Of Defence Of Her Majesty's Canadian Government Compact methanol steam reformer with integrated hydrogen separation
US7341609B2 (en) 2002-10-03 2008-03-11 Genesis Fueltech, Inc. Reforming and hydrogen purification system
US20040197616A1 (en) * 2003-04-01 2004-10-07 Edlund David J. Oxidant-enriched fuel cell system
WO2005073126A1 (ja) 2004-01-30 2005-08-11 Idemitsu Kosan Co., Ltd. 改質器
CA2457609A1 (en) * 2004-02-13 2005-08-13 Alberta Research Council Inc. Heating solid oxide fuel cell stack
US20050188616A1 (en) * 2004-02-27 2005-09-01 Bizjak Travis A. Fuel processing treatment system and fuel processing systems containing the same
US7842428B2 (en) * 2004-05-28 2010-11-30 Idatech, Llc Consumption-based fuel cell monitoring and control
US8277997B2 (en) * 2004-07-29 2012-10-02 Idatech, Llc Shared variable-based fuel cell system control
US7500999B2 (en) * 2004-09-01 2009-03-10 Praxair Technology, Inc. Catalytic reactor
KR101127688B1 (ko) * 2004-12-07 2012-03-23 에스케이이노베이션 주식회사 원통형 소형 개질 장치
IL166375A (en) * 2005-01-18 2010-06-30 Menashe Rogotner Carton, blank therefor and packing arrangement thereof
GB0516697D0 (en) * 2005-08-15 2005-09-21 Voller Energy Ltd Hydrogen generator
TWI328898B (en) 2005-09-16 2010-08-11 Idatech L L C Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same
US7601302B2 (en) 2005-09-16 2009-10-13 Idatech, Llc Self-regulating feedstock delivery systems and hydrogen-generating fuel processing assemblies and fuel cell systems incorporating the same
JP2007091584A (ja) 2005-09-27 2007-04-12 Samsung Sdi Co Ltd 燃料改質装置
US7887958B2 (en) 2006-05-15 2011-02-15 Idatech, Llc Hydrogen-producing fuel cell systems with load-responsive feedstock delivery systems
US7972420B2 (en) 2006-05-22 2011-07-05 Idatech, Llc Hydrogen-processing assemblies and hydrogen-producing systems and fuel cell systems including the same
US7939051B2 (en) 2006-05-23 2011-05-10 Idatech, Llc Hydrogen-producing fuel processing assemblies, heating assemblies, and methods of operating the same
KR100823515B1 (ko) 2007-04-24 2008-04-21 삼성에스디아이 주식회사 연료 개질 장치 및 그 구동 방법
KR101300331B1 (ko) * 2007-11-01 2013-08-28 에스케이이노베이션 주식회사 용이한 초기 구동, 운전 안정성 및 높은 열효율을 갖는수소발생 장치
US8262752B2 (en) 2007-12-17 2012-09-11 Idatech, Llc Systems and methods for reliable feedstock delivery at variable delivery rates
US20090188449A1 (en) * 2008-01-24 2009-07-30 Hydrogen Technology Applications, Inc. Method to enhance and improve solid carbonaceous fuel combustion systems using a hydrogen-rich gas
FR2978961B1 (fr) * 2011-08-11 2013-08-30 Air Liquide Procede pour une production d'hydrogene a partir de biogaz
EP2950378B1 (en) * 2013-01-24 2018-12-12 Panasonic Intellectual Property Management Co., Ltd. Fuel cell system
EP2977348B1 (en) * 2013-03-19 2018-01-17 Panasonic Intellectual Property Management Co., Ltd. Hydrogen generator, fuel cell system including hydrogen generator, method of operating hydrogen generator, and method of operating fuel cell system
CN103191626A (zh) * 2013-04-01 2013-07-10 国家电网公司 一种安全脱硫试验测点装置
US10479680B2 (en) * 2015-01-14 2019-11-19 Raven Sr, Llc Electrically heated steam reforming reactor
US10476093B2 (en) 2016-04-15 2019-11-12 Chung-Hsin Electric & Machinery Mfg. Corp. Membrane modules for hydrogen separation and fuel processors and fuel cell systems including the same
CN108455527B (zh) * 2018-02-23 2019-03-08 深圳高发气体股份有限公司 一种超高纯度氢的制备装置
RU2679241C1 (ru) * 2018-03-12 2019-02-06 Андрей Владиславович Курочкин Установка производства водорода
US10787363B2 (en) * 2018-12-27 2020-09-29 Automotive Research & Testing Center Hydrogen producing apparatus with emulsifier
KR102378004B1 (ko) 2020-06-19 2022-03-24 주식회사 파나시아 수증기 탄화수소 개질기
KR102398422B1 (ko) 2020-06-19 2022-05-16 주식회사 파나시아 수증기 탄화수소 개질기
KR102398448B1 (ko) 2020-06-19 2022-05-16 주식회사 파나시아 수증기 탄화수소 개질기
KR102398474B1 (ko) 2020-06-19 2022-05-17 주식회사 파나시아 수증기 탄화수소 개질기
KR102398437B1 (ko) 2020-06-19 2022-05-16 주식회사 파나시아 수증기 탄화수소 개질기
KR102378005B1 (ko) 2020-06-19 2022-03-24 주식회사 파나시아 수증기 탄화수소 개질기
KR102378008B1 (ko) 2020-08-14 2022-03-24 주식회사 파나시아 버너를 가진 수증기 탄화수소 개질기
KR102424891B1 (ko) 2020-08-14 2022-07-26 주식회사 파나시아 버너를 가진 수증기 탄화수소 개질기
KR102416025B1 (ko) 2020-08-14 2022-07-05 주식회사 파나시아 버너를 가진 수증기 탄화수소 개질기
KR102424883B1 (ko) 2020-08-14 2022-07-26 주식회사 파나시아 버너를 가진 수증기 탄화수소 개질기
CN112209340B (zh) * 2020-10-10 2023-03-10 辽宁华融富瑞新能源科技股份有限公司 一种天然气制氢用转化装置
CN112265963A (zh) * 2020-11-20 2021-01-26 四川金星清洁能源装备股份有限公司 一种天然气站内制氢加氢一体化系统
US11712655B2 (en) 2020-11-30 2023-08-01 H2 Powertech, Llc Membrane-based hydrogen purifiers

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2135694A (en) * 1930-09-25 1938-11-08 Solvay Process Co Process for the production of hydrogen
US2890165A (en) * 1953-11-18 1959-06-09 Kellogg M W Co Hydrocarbon desulfurization process
US3679762A (en) * 1970-06-08 1972-07-25 Catalysts & Chem Inc Selective hydrogenation of acetylenes
US4468235A (en) * 1979-02-15 1984-08-28 Hill Eugene F Hydrogen separation using coated titanium alloys
EP0194067B2 (en) * 1985-03-05 1994-05-11 Imperial Chemical Industries Plc Steam reforming hydrocarbons
AU661877B2 (en) * 1990-04-03 1995-08-10 Standard Oil Company, The Endothermic reaction apparatus

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100467722B1 (ko) * 2000-12-26 2005-01-24 주식회사 포스코 산성가스로부터 수분을 제거하는 장치 및 방법
KR100423544B1 (ko) * 2001-04-23 2004-03-18 주식회사 경동도시가스 컴팩트형 수증기 개질장치
WO2006109972A1 (en) * 2005-04-11 2006-10-19 Sk Energy Co., Ltd. Cylindrical steam reformer having integrated heat exchanger
CN112142006A (zh) * 2020-09-28 2020-12-29 有研工程技术研究院有限公司 一种氢气分离组件

Also Published As

Publication number Publication date
KR100209989B1 (ko) 1999-07-15
JP4090097B2 (ja) 2008-05-28
US5932181A (en) 1999-08-03
JPH10194702A (ja) 1998-07-28

Similar Documents

Publication Publication Date Title
KR970025688A (ko) 천연가스형 수소발생장치
CN1922101B (zh) 用于分布的氢产品的集成的燃料处理装置
CN100563810C (zh) 蒸汽重整
CN100574859C (zh) 催化反应器
US7628963B2 (en) Small cylindrical reformer
USRE39675E1 (en) Reforming apparatus for making a co-reduced reformed gas
CN101432065B (zh) 固定床吸热反应内燃交换反应器
WO2003078311A1 (fr) Dispositif de reformage et son mode de fonctionnement
JP4189212B2 (ja) 水素生成装置とそれを備える燃料電池システム
WO2002098790A1 (fr) Unite de reformage a vapeur d'eau cylindrique
WO2000063114A1 (fr) Reformeur cylindrique monotube et procede pour faire fonctionner ledit reformeur
JP2002187705A (ja) 単管円筒式改質器
CA2413388A1 (en) Improved system for hydrogen generation through steam reforming of hydrocarbons and integrated chemical reactor for hydrogen production from hydrocarbons
JP2001527501A (ja) 接触式改質装置用バーナーの排気ガス捕集アセンブリ
US9044721B2 (en) Fuel injection device and method for a fuel reformer
JP2005015292A (ja) 燃料改質装置
JPH0283028A (ja) 炭化水素の改質装置
CN116986552A (zh) 紧凑型蒸汽重整装置
JP4163657B2 (ja) 燃料改質装置
US20030061764A1 (en) Method and apparatus for steam reforming of hydrocarbons
JP2003112904A (ja) 単管円筒式改質器
KR950033067A (ko) 열효율을 향상시킬 수 있도록 한 연료 개질장치
JPS62186935A (ja) 反応装置
JPH0656401A (ja) 燃料改質器
JPH069973A (ja) 触媒燃焼装置

Legal Events

Date Code Title Description
A201 Request for examination
G15R Request for early opening
N231 Notification of change of applicant
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
FPAY Annual fee payment

Payment date: 20080331

Year of fee payment: 10

LAPS Lapse due to unpaid annual fee