KR970010861A - Styrene-based flame retardant resin composition with excellent fluidity and flame retardancy - Google Patents

Styrene-based flame retardant resin composition with excellent fluidity and flame retardancy Download PDF

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Publication number
KR970010861A
KR970010861A KR1019950026583A KR19950026583A KR970010861A KR 970010861 A KR970010861 A KR 970010861A KR 1019950026583 A KR1019950026583 A KR 1019950026583A KR 19950026583 A KR19950026583 A KR 19950026583A KR 970010861 A KR970010861 A KR 970010861A
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South Korea
Prior art keywords
weight
parts
flame retardant
resin composition
styrene
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KR1019950026583A
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Korean (ko)
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KR0155055B1 (en
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정종훈
이규철
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유현식
제일모직 주식회사
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Priority to KR1019950026583A priority Critical patent/KR0155055B1/en
Publication of KR970010861A publication Critical patent/KR970010861A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 수지의 물성저하가 거의 없고, 유동성과 난연성이 우수한 스티렌계 난연수지 조성물을 제공하기 위한 것으로, 본 발명의 스티렌계 난연수지 조성물은 (A) 방향족 모노알케닐 단량체, 비닐시안 단량체, 아크릴산 또는 메타크릴산의 알킬에스테르 단량체 중에서 선택된 1종 또는 1종이상의 단량체를 디엔형 고무성분 또는 알킬아크릴레이트 고무성분과 괴상, 현탁 또는 유화중합시켜 얻은 그라프트 공중합체 100중량부와, (B) 테트라브로모비스페놀 A 또는 테트라브로모비스페놀 A의 디글리시닐 에테르 중합체인 브롬화에폭시 수지 또는 염소화 폴리에틸렌수지 등의 지방족 화합물 또는 염화비닐수지 중에서 선택된 유기난연제 0.5 내지 30중량부와, (C) 데카브로모디페닐에테르, 옥타브로모디페닐에테르 중에서 선택된 보조난연제 1 내지 20중량부와, (D) 삼산화 안티몬 1 내지 10중량부로 구성된 것임을 특징으로 한다.The present invention is to provide a styrenic flame-retardant resin composition with almost no physical property degradation of the resin, excellent fluidity and flame retardancy, the styrene-based flame-retardant resin composition of the present invention is (A) aromatic monoalkenyl monomer, vinyl cyan monomer, acrylic acid Or 100 parts by weight of a graft copolymer obtained by bulk, suspending or emulsion polymerizing one or more monomers selected from alkyl ester monomers of methacrylic acid with a diene rubber component or an alkyl acrylate rubber component, and (B) tetra 0.5 to 30 parts by weight of an organic flame retardant selected from an aliphatic compound such as brominated epoxy resin or chlorinated polyethylene resin or vinyl chloride resin, which is a diglycinyl ether polymer of bromobisphenol A or tetrabromobisphenol A, and (C) decabromod 1 to 20 parts by weight of an auxiliary flame retardant selected from phenyl ether and octabromodiphenyl ether; , (D) It is characterized by consisting of 1 to 10 parts by weight of antimony trioxide.

Description

유동성과 난연성이 우수한 스티렌계 난연수지 조성물Styrene-based flame retardant resin composition with excellent fluidity and flame retardancy

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (3)

(A) 방향족 모노알케닐 단량체, 비닐시안 단량체, 아크릴산 또는 메타크릴산의 알킬에스테르 단량체 중에서 선택된 1종 또는 1종이상의 단량체를 디엔형 고무성분 또는 알킬아크릴레이트 고무성분과 괴상, 현탁 또는 유화중합시켜 얻은 그라프트 공중합체 100중량부와, (B) 테트라브로모비스페놀 A 또는 테트라브로모비스페놀 A의 디글리시닐 에테르 중합체인 브롬화에폭시 수지 또는 염소화 폴리에틸렌수지 등의 지방족 화합물 또는 염화비닐수지 중에서 선택된 유기난연제 0.5 내지 30중량부와, (C) 데카브로모디페닐에테르, 옥타브로모디페닐에테르 중에서 선택된 보조난연제 1 내지 20중량부와, (D) 삼산화 안티몬 1 내지 10중량부로 구성된 것임을 특징으로 하는 유동성과 난연성이 우수한 스티렌계 난연수지 조성물.(A) one or more monomers selected from aromatic monoalkenyl monomers, vinyl cyan monomers, alkyl ester monomers of acrylic acid or methacrylic acid are bulked, suspended or emulsion-polymerized with diene rubber components or alkyl acrylate rubber components 100 parts by weight of the obtained graft copolymer and an organic compound selected from (B) an aliphatic compound such as brominated epoxy resin or chlorinated polyethylene resin or vinyl chloride resin, which is a diglycinyl ether polymer of tetrabromobisphenol A or tetrabromobisphenol A It is composed of 0.5 to 30 parts by weight of a flame retardant, (C) 1 to 20 parts by weight of an auxiliary flame retardant selected from decabromodiphenyl ether and octabromodiphenyl ether, and (D) 1 to 10 parts by weight of antimony trioxide. Styrene-based flame retardant resin composition excellent in flame retardancy. 제1항에 있어서, 그라프트 공중합체는 고무입자직경이 1∼3㎛인 것을 특징으로 하는 유동성과 난연성이 우수한 스티렌계 난연수지 조성물.The styrene-based flame retardant resin composition of claim 1, wherein the graft copolymer has a rubber particle diameter of 1 to 3 µm. 제1항에 있어서, 테트라브로모비스페놀 A의 디글리시딜 에테르 중합체인 브롬화에폭시수지는 분자량이 500∼3000이며, 하기 일반식(I) 또는 (II)로 표시됨을 특징으로 하는 유동성과 난연성이 우수한 스티렌계 난연 수지 조성물.The brominated epoxy resin of claim 1, which is a diglycidyl ether polymer of tetrabromobisphenol A, has a molecular weight of 500 to 3000, and is characterized by the following general formula (I) or (II). Excellent styrene flame retardant resin composition. 상기 일반식에서, n은 0 이상의 정수이며, R1은(X=1 내지 5의 정수임)이다.In the above general formula, n is an integer of 0 or more, and R 1 is (An integer of X = 1 to 5). ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950026583A 1995-08-25 1995-08-25 Non-flammable styrenic resin composition having good rheological and antiflammable properties KR0155055B1 (en)

Priority Applications (1)

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KR1019950026583A KR0155055B1 (en) 1995-08-25 1995-08-25 Non-flammable styrenic resin composition having good rheological and antiflammable properties

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Application Number Priority Date Filing Date Title
KR1019950026583A KR0155055B1 (en) 1995-08-25 1995-08-25 Non-flammable styrenic resin composition having good rheological and antiflammable properties

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KR970010861A true KR970010861A (en) 1997-03-27
KR0155055B1 KR0155055B1 (en) 1998-12-01

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100373212B1 (en) * 2000-09-26 2003-02-25 주식회사 엘지화학 Fire retardant styrene based resin composition having superior impact resistance
KR100449360B1 (en) * 2001-10-23 2004-09-18 제일모직주식회사 Flame Retardant Styrenic Resin Composition Having Good Heat Stability
KR100506858B1 (en) * 2001-12-27 2005-08-05 제일모직주식회사 Flame Retardant Thermoplastic Resin Composition having Good Weatherproof Property
KR100472023B1 (en) * 2002-10-24 2005-03-10 주식회사 엘지화학 Flame retardant styrene resin composition

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