KR100506858B1 - Flame Retardant Thermoplastic Resin Composition having Good Weatherproof Property - Google Patents

Abstract

The flame retardant styrene resin composition having excellent weather resistance of the present invention comprises (A) 100 parts by weight of rubber-reinforced polystyrene resin prepared by mixing and polymerizing a rubber with an aromatic monoalkenyl monomer and / or an alkyl ester monomer; (B) 5 to 20 parts by weight of 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine; (C) 5 to 20 parts by weight of decabromodiphenylethane; And (D) 1 to 20 parts by weight of a flame retardant aid.

Description

Flame Retardant Thermoplastic Resin Composition Having Good Weatherproof Property}

Field of invention

The present invention relates to a flame retardant thermoplastic resin composition excellent in weatherability. More specifically, the present invention relates to rubber-reinforced polystyrene resin as a flame retardant 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine (2,4,6-Tris (2,4,6-tribromophenoxy) -1,3,5-triazine) and decabromodiphenylethane are introduced to a flame retardant thermoplastic resin composition having excellent flowability and weather resistance.

Background of the Invention

In general, styrene-based resins have good processability and mechanical strength, and are mainly used as exterior materials for electrical and electronic products. However, styrenic resins do not have flame resistance by themselves, and when the spark is ignited by an external ignition source, the resin itself acts as an energy to help burn and spread the fire continuously. Let's go. In recent years, the market of TVs among electronic products has been formed due to the trend toward larger and thinner films, and the color has also been widened from dark to light colors. Therefore, the styrene-based resins applied in these fields have a problem in that not only flame retardancy but also moldability and weather resistance must be simultaneously met.

Generally, the method of imparting flame retardancy to a resin may be divided into an additional flame retardant method of adding a flame retardant and a flame retardant aid, and a polymerization flame retardant method of preparing a resin using a special monomer containing a flame retardant atom during polymerization. Among them, polymerized flame retardation has been studied in a pilot scale stage, but commercialized products have not been released due to high cost and difficulty in achieving flame retardancy. Therefore, most commercialized flame retardant resins have been prepared by the addition flame retardant method of adding a flame retardant containing halogen or phosphorus, which is an inert element during compounding. An additional flame retardant method in which a flame retardant is added to impart flame retardancy to a styrene resin is prepared by adding one or more components selected from halogen-containing organic compounds and antimony-containing inorganic compounds to the resin.

By the way, the halogen-containing organic compound is mainly bromine or chlorine compound, when added to the styrene-based resin, the flame retardancy is very excellent, but causes serious degradation in the processability of the resin itself. Conventionally, in order to secure stable weather resistance, the problem of inferior moldability of flame retardant resins has been tried to solve with additives such as impact modifiers and lubricants. But fundamentally, it has not solved the problem of flame retardant.

Therefore, in manufacturing a flame retardant resin, a technique of minimizing the deterioration of fluidity and weather resistance while maintaining excellent flame retardancy is very important.

On the other hand, the present inventors 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine as a flame retardant in the rubber-reinforced polystyrene resin copolymer in order to overcome the above problems By simultaneously using (2,4,6-Tris (2,4,6-tribromophenoxy) -1,3,5-triazine) and decabromodiphenylethane, a thermoplastic resin composition having excellent fluidity and weather resistance while maintaining flame retardancy is produced. It is early to develop.

An object of the present invention is to provide a thermoplastic resin composition having excellent fluidity and excellent flame retardancy.

Another object of the present invention is to provide a flame retardant thermoplastic resin composition excellent in weatherability.

The above and other objects of the present invention can be achieved by the present invention described below.

The resin composition of the present invention comprises (B) 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine based on 100 parts by weight of the rubber-reinforced polystyrene resin (A). (2,4,6-Tris (2,4,6-tribromo phenoxy) -1,3,5-triazine) 5 to 20 parts by weight, (C) 5 to 20 parts by weight of decabromodiphenylethane, and (D) It consists of 1 to 20 parts by weight of flame retardant aids, the detailed description of each of these components is as follows.

(A) Rubber reinforced polystyrene resin

The rubber-reinforced polystyrene resin according to the present invention is prepared by mixing a rubber with an aromatic monoalkenyl monomer and / or an alkyl ester monomer and polymerizing it using a polymerization initiator.

The rubber is preferably 5 to 15 parts by weight as a rubber selected from the group consisting of butadiene rubbers, isoprene rubbers, copolymers of butadiene and styrene, alkyl acrylate rubbers and the like.

In addition, the monomer is preferably an aromatic monoalkenyl monomer, at least one monomer selected from the group consisting of alkyl ester monomers of acrylic acid or methacrylic acid is 85 to 95 parts by weight.

As the polymerization initiator used in the preparation of the rubber-reinforced polystyrene resin of the present invention, at least one initiator selected from benzoyl peroxide, t-butyl hydroperoxide, acetyl peroxide and cumene hydroperoxide is used.

The rubber-reinforced polystyrene resin may be prepared using bulk polymerization, suspension polymerization, emulsion polymerization or a mixture thereof.

(B) 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine

In the present invention, 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine (2,4,6-Tris (2,4,6-tribromophenoxy)- 1,3,5-triazine) is used as a flame retardant, and the 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine is a molten halogen flame retardant. It has excellent impact strength and fluidity.

The 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine is a substance represented by the following formula (1).

[Formula 1]

2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine of the present invention is 5 to 20 parts by weight based on 100 parts by weight of the rubber-reinforced polystyrene resin (A). It is preferable to use. When 5 parts by weight or less is added, the flowability and mechanical reinforcing effect is insufficient, and when 20 parts by weight or more is used, weather resistance is lowered, which impairs the balance of physical properties.

(C) decabromodiphenylethane

In the present invention, decabromodiphenylethane is added to improve weather resistance of the resin composition. The decabromodiphenylethane is a non-fusion flame retardant.

By adding the decabromodiphenyl ethane it is possible to prevent the discoloration during the long-term uv retention of the light color injection molded product while maintaining the flame retardancy.

The decabromodiphenylethane of this invention is represented by following General formula (2).

[Formula 2]

The decabromodiphenyl ethane is preferably used 5 to 20 parts by weight based on 100 parts by weight of rubber-reinforced polystyrene resin (A). When decabromodiphenylethane is used in less than 5 parts by weight, the effect of increasing weather resistance is insufficient, and when used in excess of 20 parts by weight, 2,4,6-tri (2,4,6-tribromophenoxy It is undesirable because it adversely affects the fluidity and mechanical strength enhancing effects of) -1,3,5-triazine.

In the present invention, the weight ratio of the 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine (B) and decabromodiphenylethane (C) is 1.5: Use in the range of 1 to 1: 1.5 shows the best effect.

(D) flame retardant additives

Flame retardant aids play a role in helping halogenated compounds exhibit flame retardant performance. In the present invention, antimony trioxide, paraffin chloride, potassium sulfon sulfate and the like can be used, and antimony trioxide is most preferred.

The amount of the flame retardant aid (D) is preferably 1-20 parts by weight based on 100 parts by weight of the rubber-reinforced polystyrene resin (A), and when the amount is less than 1 part by weight, the flame retardant effect is not sufficient. It is not preferable because it impairs the balance of physical properties of the resin composition.

 The flame-retardant thermoplastic resin composition of the present invention may be added in the required amount in addition to the above components in accordance with the respective olefin lubricants, inorganic additives, thermal stabilizers, antioxidants, other light stabilizers, pigments and dyes.

The invention can be better understood by the following examples, which are intended for the purpose of illustration of the invention and are not intended to limit the scope of protection defined by the appended claims.

Example

Specifications of each component used in the following Examples and Comparative Examples are as follows.

(A) Rubber reinforced polystyrene resin: HG-1760HF of Cheil Industries Co., Ltd. was used.

(B) Melt flame retardant: 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine was used.

(C) Non-melting flame retardant: decabromodiphenylethane was used.

(D) Antimony trioxide was used as a flame retardant adjuvant.

Example 1-3

The resin composition obtained by mixing according to the composition of each component shown in Table 1 was uniformly mixed with a tumbler mixer, and then extruded through a twin screw extruder to prepare pellets. After injection molding the prepared pellets, the weathering test specimens and the physical property test specimens were manufactured and evaluated.

Comparative Example 1-4

Comparative Example 1 uses only 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine (B) as a flame retardant, and Comparative Example 2 is used as a flame retardant. Only decabromodiphenyl ethane (C) is used. Comparative Examples 3 and 4 each contain 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine (B) and decabromodiphenylethane (C). It is added below the range of this invention.

ingredient Example Comparative Example One 2 3 One 2 3 4 (A) Rubber reinforced styrene resin 100 100 100 100 100 100 100 (B) 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine 8 10 12 20 - 2 18 (C) decabromodiphenyl ethane 12 10 8 - 20 18 2 (D) antimony trioxide 8 8 8 8 8 8 8

   (Unit: parts by weight)

The physical properties of the resin composition prepared by the above method were measured for Izod impact strength according to ASTM D256, and the flow index was measured according to ASTM D1238. In addition, weather resistance was measured according to ASTM D4459 (INDOOR TEST) using a weather-o-meter (Weather-O-Meter) to compare the degree of discoloration (△ E) of each sample.

The physical properties of the resins prepared in Examples 1-3 and Comparative Examples 1-4 are shown in Table 2.

ingredient Example Comparative Example One 2 3 One 2 3 4 liquidity 13 12 10 15 7 14 8 Impact strength 11 10 9 14 7 13 8 Weather resistance (△ E) 4.5 3.8 3.4 6.5 3.0 6.0 3.2

From the results in Table 2, Example 1-3 in which 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine and decabromodiphenylethane were used simultaneously The flowability, impact resistance and weather resistance at the same time were excellent, compared with 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine (B) as flame retardant Example 1 was excellent in fluidity and mechanical strength, but was found to have poor weather resistance. On the other hand, in Comparative Example 2 using only decabromodiphenylethane (C) as a flame retardant, the weather resistance was high, but the fluidity and mechanical strength were reduced.

The present invention provides fluidity by simultaneously using 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine and decabromodiphenylethane in a rubber-reinforced polystyrene resin copolymer. And a flame retardant thermoplastic resin composition having excellent weather resistance at the same time.

Simple modifications or changes of the present invention can be easily carried out by those skilled in the art, and all such modifications or changes can be seen to be included in the scope of the present invention.

Claims (4)

(A) 100 parts by weight of rubber-reinforced polystyrene resin prepared by mixing and polymerizing rubber with aromatic monoalkenyl monomer and / or alkyl ester monomer; (B) 5 to 20 parts by weight of 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine represented by Formula 1; [Formula 1] (C) 5 to 20 parts by weight of decabromodiphenylethane; And (D) 1 to 20 parts by weight of a flame retardant aid; Flame-retardant styrene resin composition, characterized in that consisting of. The rubber-reinforced polystyrene resin according to claim 1, wherein 5 to 15 parts by weight of a rubber selected from the group consisting of butadiene rubbers, isoprene rubbers, copolymers of butadiene and styrene, alkyl acrylate rubbers, monoalkenyl monomers, and acrylic acid Or 85 to 95 parts by weight of one or more monomers of the alkyl ester monomers of methacrylic acid are prepared by polymerizing a flame retardant styrene resin composition. The method of claim 1, wherein the 2,4,6-tri (2,4,6-tribromophenoxy) -1,3,5-triazine (B) and decabromodiphenylethane (C) are 1.5. A flame-retardant styrene resin composition, which is used in a weight ratio of 1: 1 to 1: 1.5. The flame-retardant styrene resin composition according to claim 1, wherein the flame retardant auxiliary agent is selected from the group consisting of antimony trioxide, paraffin chloride, potassium sulfon sulfate and the like.