KR950023676A - Flame Retardant Polystyrene Resin Composition - Google Patents

Flame Retardant Polystyrene Resin Composition Download PDF

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Publication number
KR950023676A
KR950023676A KR1019940000500A KR19940000500A KR950023676A KR 950023676 A KR950023676 A KR 950023676A KR 1019940000500 A KR1019940000500 A KR 1019940000500A KR 19940000500 A KR19940000500 A KR 19940000500A KR 950023676 A KR950023676 A KR 950023676A
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South Korea
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flame retardant
weight
parts
resin composition
polystyrene resin
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KR1019940000500A
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Korean (ko)
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이종면
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이준범
주식회사 화인
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Priority to KR1019940000500A priority Critical patent/KR950023676A/en
Publication of KR950023676A publication Critical patent/KR950023676A/en

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Abstract

본 발명은 아크릴로니트릴 부타디엔 스티렌 공중합성수지와 브롬으로 합성한 브롬계 고분자화합물과 염소를 함유한 염소계 염소화합물, 그리고 난연 상승효과를 갖는 무리물계 난연 상승제;그리고 내열안정제 및 기타 안정제 및 무기를 안료로 이루어진 난연성 스티렌계 조성물이다.The present invention provides a bromine polymer compound synthesized from acrylonitrile butadiene styrene copolymer resin and bromine, a chlorine-containing chlorine compound containing chlorine, and a group-based flame retardant synergist having a flame retardant synergistic effect; and a heat stabilizer and other stabilizers and inorganic pigments. It is a flame retardant styrene-based composition consisting of.

이 조성물은 스티렌계 조성물로서 제반물성이 뛰어나면서도 우수한 난연성 및 내열성, 내후성을 가지며, 난연성이 요구되는 전기, 전자부품등의 제조 및 사무자동화기기등의 제조에 매우 유용하다.This composition is a styrene-based composition that is excellent in general properties, has excellent flame retardancy, heat resistance, and weather resistance, and is very useful for the manufacture of electrical and electronic parts and the like for which office equipment is required for flame retardancy.

Description

난연성 폴리스티렌계 수지 조성물Flame Retardant Polystyrene Resin Composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

ABS 공중합수지, 고분자브롬계 화합물, 고분자 염소화 파라핀계화합물 및 기타 첨가제로 이루어진 난연성 스티렌계수지 조성물로서, (가) 아크릴로니트릴 5 내지 30%, 부타디엔 고무 5 내지 30%, 스티렌 20 내지 80% 범위로 구성되는 ABS 공중합체수지 100중량부, (나) 다음 일반식(Ⅰ):Flame retardant styrenic resin composition comprising ABS copolymer resin, high molecular bromine compound, high molecular chlorinated paraffin compound and other additives, comprising: (a) 5-30% acrylonitrile, 5-30% butadiene rubber, 20-80% styrene ABS copolymer resin consisting of 100 parts by weight, (b) the following general formula (I): 로 나타내는 브롬화 에폭시수지 5 내지 40중량부 또는 다음 일반식(Ⅱ):Brominated epoxy resin represented by 5 to 40 parts by weight or the following general formula (II): 로 나타내는 브롬화 스티렌 화합물 5 내지 40중량부, (다) 염소를 10 내지 80% 함유한 염소화폴리에틸렌수지 5 내지 40중량부 또는 염소를 10 내지 90%함유한 사이크로알리파틱 또는 아로마틱구조의 염소화 파라핀계화합물 1 내지 40중량부, (라) 무기물계 난연상승제 2 내지 20중량부로 구성되는 난연성 폴리스티렌계 수지 조성물.5-40 parts by weight of a brominated styrene compound, (c) 5 to 40 parts by weight of chlorinated polyethylene resin containing 10 to 80% of chlorine or a cycloaliphatic or aromatic chlorinated paraffinic system containing 10 to 90% of chlorine Flame retardant polystyrene resin composition comprising 1 to 40 parts by weight of the compound, and (d) 2 to 20 parts by weight of the inorganic flame retardant increasing agent. 제1항에 있어서, (마) 무기물계 안료 1 내지 20중량부, (바) 내열안정제 0.05 내지 10중량부, (사) UV안정제 0.05 내지 10중량부, (아) 활제 0.05 내지 10중량부, (사) 올레핀계왁스 0.05 내지 10중량부, (자) 실리콘계 오일 0.01 내지 3중량부를 더욱 포함하여 구성되는 난연성 폴리스티렌계 수지 조성물.According to claim 1, (E) 1 to 20 parts by weight of inorganic pigments, (F) 0.05 to 10 parts by weight of heat stabilizer, (G) 0.05 to 10 parts by weight of UV stabilizer, (A) 0.05 to 10 parts by weight of lubricant, (G) Flame retardant polystyrene resin composition comprising 0.05 to 10 parts by weight of olefin wax and 0.01 to 3 parts by weight of silicone oil. 제1항에 있어서, 상기 브롬화 에폭시 수지 또는 브롬화 스티렌 화합물은, 그 수평균분자량이 1000 내지 500,000범위를 갖는 난연성 폴리스티렌계 수지 조성물.The flame retardant polystyrene resin composition of claim 1, wherein the brominated epoxy resin or brominated styrene compound has a number average molecular weight in the range of 1000 to 500,000. 제1항에 있어서, 상기 염소화폴리에틸렌 수지 또는 염소화 팔아핀계화합물은 그 수평균분자량이 3,000 내지 200,000범위를 갖는 난연성 폴리스티렌계 수지 조성물.The flame retardant polystyrene resin composition according to claim 1, wherein the chlorinated polyethylene resin or chlorinated palpine-based compound has a number average molecular weight in the range of 3,000 to 200,000. 제1항에 있어서, 상기 무기물계 난연상승제는 삼산화안티몬 또는 오산화안티몬인 난연성 폴리스티렌계 수지 조성물.The flame retardant polystyrene resin composition of claim 1, wherein the inorganic flame retardant synergist is antimony trioxide or antimony pentoxide. 제2항에 있어서, 상기 내열안정제는 틴말레이트계, 하이드록시페닐계, 포스페이트계의 화합물중 1종 혹은 2종 이상을 혼합한 것인 난연성 폴리스티렌계 수지 조성물.The flame retardant polystyrene resin composition according to claim 2, wherein the heat stabilizer is a mixture of one or two or more of thimalate, hydroxyphenyl and phosphate compounds. 제2항에 있어서, 상기 UV안정제는 벤조페논계나 벤조트리아졸계 또는 힌더스아민계 화합물인 난연성 폴리스티렌계 수지 조성물.The flame retardant polystyrene resin composition according to claim 2, wherein the UV stabilizer is a benzophenone-based, benzotriazole-based, or hindersamine-based compound. 제2항에 있어서, 상기 활제는 스테아린산 칼슘, 스테아린산 아연, 스테아린산 마그네슘, 또는 스테아린산 바륨인 난연성 폴리스티렌계 수지 조성물.The flame retardant polystyrene resin composition according to claim 2, wherein the lubricant is calcium stearate, zinc stearate, magnesium stearate, or barium stearate. 제2항에 있어서, 상기 올레핀계왁스는 에틸렌비스스테라마이드, 비스스티렌디아민 또는 저분자 염소화 파라핀인 난연성 폴리스티렌계 수지 조성물.The flame-retardant polystyrene resin composition according to claim 2, wherein the olefin wax is ethylene bissteramide, bisstyrenediamine or low molecular chlorinated paraffin. 제2항에 있어서, 상기 무기물계 안료는 이산화 티탄인 난연성 폴리스티렌계 수지 조성물.The flame retardant polystyrene resin composition of claim 2, wherein the inorganic pigment is titanium dioxide. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940000500A 1994-01-13 1994-01-13 Flame Retardant Polystyrene Resin Composition KR950023676A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030025690A (en) * 2001-09-22 2003-03-29 금호석유화학 주식회사 The development of transparency flame retardant high impact poly-styrene
KR100407702B1 (en) * 2000-12-27 2003-12-01 제일모직주식회사 Acrylonitrile-Butadiene-Styrene Flame Retardant Resin Compositions Having Excellent Heat Stability and Whetherability
KR100506123B1 (en) * 2001-12-27 2005-08-03 제일모직주식회사 UL 94 V-2 Rating Acrylonitrile-Butadiene-Styrene Flame Retardant Resin Composition with Good Thermal Stability, Heat Resistance, UV Resistance and Easy Colorability
KR100546787B1 (en) * 1999-12-27 2006-01-25 제일모직주식회사 Acryllonitrile-butadiene-styrene resin composition with good heat stability

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100546787B1 (en) * 1999-12-27 2006-01-25 제일모직주식회사 Acryllonitrile-butadiene-styrene resin composition with good heat stability
KR100407702B1 (en) * 2000-12-27 2003-12-01 제일모직주식회사 Acrylonitrile-Butadiene-Styrene Flame Retardant Resin Compositions Having Excellent Heat Stability and Whetherability
KR20030025690A (en) * 2001-09-22 2003-03-29 금호석유화학 주식회사 The development of transparency flame retardant high impact poly-styrene
KR100506123B1 (en) * 2001-12-27 2005-08-03 제일모직주식회사 UL 94 V-2 Rating Acrylonitrile-Butadiene-Styrene Flame Retardant Resin Composition with Good Thermal Stability, Heat Resistance, UV Resistance and Easy Colorability

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