KR970006265A - 내장 광개시제(photoinitiator)를 함유하는 방사선-경화성 아크릴레이트 - Google Patents

내장 광개시제(photoinitiator)를 함유하는 방사선-경화성 아크릴레이트 Download PDF

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Publication number
KR970006265A
KR970006265A KR1019960027054A KR19960027054A KR970006265A KR 970006265 A KR970006265 A KR 970006265A KR 1019960027054 A KR1019960027054 A KR 1019960027054A KR 19960027054 A KR19960027054 A KR 19960027054A KR 970006265 A KR970006265 A KR 970006265A
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South Korea
Prior art keywords
alkyl
meth
acrylate
aryl
radiation
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KR1019960027054A
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English (en)
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라이히 볼프강
베크 에리히
예거 울리히
슈발름 라인홀드
Original Assignee
슈타인호프ㆍ비베르바흐
바스프 악티엔게젤샤프트
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Publication of KR970006265A publication Critical patent/KR970006265A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/96—Esters of carbonic or haloformic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/62—Halogen-containing esters
    • C07C69/65—Halogen-containing esters of unsaturated acids
    • C07C69/653—Acrylic acid esters; Methacrylic acid esters; Haloacrylic acid esters; Halomethacrylic acid esters
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S522/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S522/904—Monomer or polymer contains initiating group
    • Y10S522/905—Benzophenone group

Abstract

본 발명은 하기 일반식 (Ⅰ)의 화합물을, 분자내에 1개 이상의 유리 히드록실기 및 2개 이상의 (메트)아크릴기를 및/또는 아크릴기를 함유하는 히드록시(메트)아크릴레이트와 반응시킴으로써 수득될 수 있는 방사선-경화성(메트) 아크릴레이트에 관한 것이다:
상기 식에서, R은 C1-C4-알킬, 아릴 또는 R1이고, R1은 하기 일반식 (Ⅱ)의 화합물이다:
R2내지 R6은 각각 독립적으로 H, C1-C4-알킬, C1-C4-알콕시, OH, 페닐, SH, SCH3, SC2H5, F, Cl, Br, CN, COOH, COO-(C1-C17-알킬), COO-(C5-C10-아릴), CF3,N(알킬)2, N((알킬) (아릴), N(아릴)2, N+(알킬)3A-, N+H(알킬)2A-이고, A-는 산의 음이온이고, 알킬 또는 아릴은 다르게 규정하지 않는 한은, 각각 C1-C10-알킬 또는 C5-C10-아릴이고, R2내지 R6중 1개 내지 3개는 하기 화학식의 기이다:

Description

내장 광개시제(photoinitiator)를 함유하는 방사선-경화성 아크릴레이트
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 하기 일반식 (Ⅰ)의 화합물을, 분자내에 1개 이상의 유리 히드록실기 및 2개 이상의 (메트)아크릴기를 함유하는 히드록시(메트)아크릴레이트와 반응시킴으로써 수득될 수 있는 방사선-경화성 (메트)아크릴레이트:
    상기 식에서, R은 C1-C4-알킬, 아릴 또는 R1이고, R1은 하기 일반식(Ⅱ)의 화합물이다:
    R2내지 R6은 각각 독립적으로 H, C1-C4-알킬, C1-C|4-알콕시, OH, 페닐, SH, SCH3, SC2H5, F, Cl, Br, CN, COOH, COO-(C1-C17-알킬), COO-(C5-C10-아릴), CF3,N(알킬)2, N((알킬) (아릴), N(아릴)2, N+(알킬)3A-, N+H(알킬)2A-이고, A-는 산의 음이온이고, 알킬 또는 아릴은 다르게 규정하지 않는 한은, 각각 C1-C10-알킬 또는 C5-C10-아릴이고, R2내지 R6중 1개 내지 3개는 하기 화학식의 기이다:
  2. 제1항에 있어서, R2내지 R6중 1개가 하기 화학식의 기인 것을 특징으로 하는 방사선-경화성(메트)아크릴레이트:
  3. 제1항에 있어서, 히드록시(메트)아크릴레이트가, 분자내에 1개 이상의 히드록실기 및 2 내지 6개의 아크릴기를 함유하는 폴리에테르 또는 폴리에스테르 (메트)아크릴레이트인 것을 특징으로 하는 방사선-경화성(메트)아크릴레이트.
  4. 제1항에 있어서, 히드록시(메트)아크릴레이트가 폴리에테르 또는 폴리에스테르 (메트)아크릴레이트이며, 여기에서 우리 히드록실기가 알칸올아민과 (메탄)아크릴기의 마이클 첨가 생성물을 통하여 수지내로 혼입되는 것을 특징으로 하는 방사선-경화성 (메트)아크릴레이트.
  5. 일반식(Ⅰ)의 화합물을, 1개 이상의 유리 히드록실기 및 2개 이상의 (메트)아크릴기를 함유하는 히드록시(메트)아크릴레이트와 반응시킴으로써, 방사선-경화성 (메트)아크릴레이트를 제조하는 방법.
  6. 방사선-경화성 조성에서의 제1항 내지 4항 중 어느 한 항에 따른 방사성-경화성 (메트)아크릴레이트의 사용 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960027054A 1995-07-07 1996-07-04 내장 광개시제(photoinitiator)를 함유하는 방사선-경화성 아크릴레이트 KR970006265A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19524812A DE19524812A1 (de) 1995-07-07 1995-07-07 Strahlungshärtbare Acrylate mit eingebautem Photoinitiatoren
DE19524812.0 1995-07-07

Publications (1)

Publication Number Publication Date
KR970006265A true KR970006265A (ko) 1997-02-19

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KR1019960027054A KR970006265A (ko) 1995-07-07 1996-07-04 내장 광개시제(photoinitiator)를 함유하는 방사선-경화성 아크릴레이트

Country Status (8)

Country Link
US (1) US5741829A (ko)
EP (1) EP0752408B1 (ko)
JP (1) JPH0920729A (ko)
KR (1) KR970006265A (ko)
AT (1) ATE198590T1 (ko)
CA (1) CA2180673A1 (ko)
DE (2) DE19524812A1 (ko)
ES (1) ES2153517T3 (ko)

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DE19526856A1 (de) * 1995-07-22 1997-01-23 Basf Ag Strahlungshärtbare Massen mit kovalent gebundenen Photoinitiatoren
DE19616984A1 (de) * 1996-04-27 1997-10-30 Basf Lacke & Farben Bindemittel sowie deren Verwendung in strahlenhärtbaren Beschichtungsmitteln
DE19653631A1 (de) * 1996-12-20 1998-06-25 Basf Coatings Ag Verfahren zum Herstellen von durch Strahlung vernetzbaren polymeren Acryl- oder Methacrylsäureestern
DE10149084A1 (de) * 2001-10-05 2003-06-18 Tesa Ag UV-vernetzbare Acrylathaftschmelzhaftkleber mit enger Molekulargewichtsverteilung
US7105207B2 (en) * 2002-08-12 2006-09-12 Ashland Licensing And Intellectual Property Llc UV curable oligomeric adhesive compositions suitable for use in flexible packaging applications
US7323290B2 (en) * 2002-09-30 2008-01-29 Eternal Technology Corporation Dry film photoresist
US7307106B2 (en) * 2004-12-10 2007-12-11 3M Innovative Properties Company Photocurable Michael addition polymers
EP2079812B1 (en) * 2006-11-07 2017-09-13 Henkel AG & Co. KGaA Acrylic hot melt adhesives
EP3552819B1 (en) 2008-10-16 2022-07-06 Zephyros Inc. Composite sound absorber
EP2344599A4 (en) 2008-10-16 2015-06-17 Zephyros Inc RIBBON AND ROLL MATERIAL COMPRISING A PRESSURE SENSITIVE ADHESIVE
CN106459313A (zh) 2014-04-21 2017-02-22 汉高知识产权控股有限责任公司 可固化粘合剂组合物及其用途
US9546439B2 (en) 2014-05-15 2017-01-17 Zephyros, Inc. Process of making short fiber nonwoven molded articles
EP3154771A1 (en) * 2014-06-16 2017-04-19 SABIC Global Technologies B.V. Crosslinkable polycarbonates for material extrusion additive manufacturing processes
EP3230536B1 (en) 2014-12-08 2022-04-27 Zephyros Inc. Vertically lapped fibrous flooring
EP3245105B1 (en) 2015-01-12 2021-03-03 Zephyros Inc. Acoustic floor underlay system
EP3247556B1 (en) 2015-01-20 2023-08-02 Zephyros Inc. Sound absorption materials based on nonwovens
EP3297821B1 (en) 2015-05-20 2022-07-06 Zephyros Inc. Multi-impedance composite

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DE3738567A1 (de) * 1987-03-12 1988-09-22 Merck Patent Gmbh Coreaktive fotoinitiatoren
DE3844444A1 (de) * 1988-12-31 1990-08-09 Basf Ag Strahlungsempfindliche, ethylenisch ungesaettigte, copolymerisierbare verbindungen und verfahren zu deren herstellung
US5248805A (en) * 1988-12-31 1993-09-28 Basf Aktiengesellschaft Radiation-senstive, ethylenically unsaturated, copolymerizable compounds and their preparation

Also Published As

Publication number Publication date
DE19524812A1 (de) 1997-01-09
CA2180673A1 (en) 1997-01-08
ATE198590T1 (de) 2001-01-15
EP0752408B1 (de) 2001-01-10
ES2153517T3 (es) 2001-03-01
JPH0920729A (ja) 1997-01-21
EP0752408A2 (de) 1997-01-08
DE59606289D1 (de) 2001-02-15
EP0752408A3 (de) 1997-09-10
US5741829A (en) 1998-04-21

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