KR960041212A - Preparation method of epoxy acrylate and ultraviolet curing resin composition using same - Google Patents

Preparation method of epoxy acrylate and ultraviolet curing resin composition using same Download PDF

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Publication number
KR960041212A
KR960041212A KR1019950010766A KR19950010766A KR960041212A KR 960041212 A KR960041212 A KR 960041212A KR 1019950010766 A KR1019950010766 A KR 1019950010766A KR 19950010766 A KR19950010766 A KR 19950010766A KR 960041212 A KR960041212 A KR 960041212A
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KR
South Korea
Prior art keywords
meth
epoxy
resin composition
bisphenol
epoxy acrylate
Prior art date
Application number
KR1019950010766A
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Korean (ko)
Other versions
KR0160451B1 (en
Inventor
이영철
유병진
이창용
Original Assignee
김영곤
애경화학 주식회사
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Application filed by 김영곤, 애경화학 주식회사 filed Critical 김영곤
Priority to KR1019950010766A priority Critical patent/KR0160451B1/en
Publication of KR960041212A publication Critical patent/KR960041212A/en
Application granted granted Critical
Publication of KR0160451B1 publication Critical patent/KR0160451B1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Epoxy Resins (AREA)

Abstract

본 발명은 카본화이버 플라스틱소재의 접착 및 상도코팅용으로 사용되고 자외선 경화시에 접착성, 투명성, 내충격성 및 내후성등이 우수하고 새로운 에폭시 아크릴레이트를 제조하는 방법, 그리고 상기 에폭시 아크릴레이트를 이용한 자외선경화형 수지조성물에 관한 것으로, 비스페놀 A 변성 에폭시 화물과 (메타)아크릴산과의 반응물제조과정에 4차 암모늄염과 이온교환수를 조합촉매로 하여 가드너 색수 1 이하, 평균 분자량 분포 1∼1.1정도인 에폭시 아크릴레이트혼합물의 제조방법과, 비스페놀 A 변성 에폭시 화물과 (메타)아크릴산과의 반응물제조과정에 4차 암모늄염과 이온교환수를 조합촉매로 하여 가드너 색수 1 이하, 평균 분자량 분포 1∼1.1 정도로 제조되는 에폭시 아크릴레이트혼합물, 분자중에 아크릴로일기를 함유한 (메타)아크릴레이트 모노머 및, 광증감제를 함유한 자외선경화형 수지조성물.The present invention is used for the adhesion and top coating of carbon fiber plastic materials and excellent in adhesiveness, transparency, impact resistance and weather resistance during UV curing, and a method for producing a new epoxy acrylate, and an ultraviolet curing type using the epoxy acrylate A resin composition comprising epoxy acrylates having a Gardner color number of 1 or less and an average molecular weight distribution of about 1 to 1.1, using a combination catalyst of quaternary ammonium salts and ion-exchanged water during the reaction of bisphenol A-modified epoxide and (meth) acrylic acid. Epoxy acryl produced by Gardner color number of 1 or less and average molecular weight distribution of 1 to 1.1 using a combination catalyst of quaternary ammonium salt and ion-exchanged water in the preparation method of the mixture and the reaction of bisphenol A modified epoxy cargo with (meth) acrylic acid. Latex mixture, (meth) acrylate containing acryloyl group in molecule An ultraviolet curing resin composition containing a monomer and a photosensitizer.

Description

에폭시 아크릴레이트의 제조방법 및 이를 이용한 자외선경화형 수지조성물Preparation method of epoxy acrylate and ultraviolet curing resin composition using same

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (2)

비스페놀 A 변성 에폭시 화물과 (메타)아크릴산과의 반응물제조과정에 4차 암모늄염과 이온교환수를 조합촉매로 하여 가드너 색수 1 이하, 평균 분자량 분포 1∼1.1정도인 것를 특징으로 하는 에폭시 아크릴레이트혼합물의 제조방법.Epoxy acrylate mixtures having a Gardner color number of 1 or less and an average molecular weight distribution of 1 to 1.1 using a combination catalyst of quaternary ammonium salts and ion-exchanged water in the reaction of bisphenol A-modified epoxy cargo with (meth) acrylic acid. Manufacturing method. 비스페놀 A 변성 에폭시 화물과 (메타)아크릴산과의 반응물제조과정에 4차 암모늄염과 이온교환수를 조합촉매로 하여 가드너 색수 1 이하, 평균 분자량 분포 1∼1.1정도로 제조되는 에폭시 아크릴레이트혼합물(A), 분자중에 아크릴로일기(CH2=초채-, acryloy functional Group)를 함유한 (메타)아크릴레이트 모노머(B) 및, 광증감체(C)를 함유한 것을 특징으로 하는 자외선경화형 수지조성물.Epoxy acrylate mixture (A) prepared with Gardner color number of 1 or less and average molecular weight distribution of 1 to 1.1 using a combination catalyst of quaternary ammonium salt and ion-exchanged water in the reaction of bisphenol A modified epoxy cargo with (meth) acrylic acid. An ultraviolet curable resin composition comprising a (meth) acrylate monomer (B) containing an acryloyl group (CH 2 = herbaceous group, acryloy functional group) and a photosensitizer (C) in a molecule. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950010766A 1995-05-02 1995-05-02 Process for preparing epoxy acrylate and its uv curable resin composition KR0160451B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019950010766A KR0160451B1 (en) 1995-05-02 1995-05-02 Process for preparing epoxy acrylate and its uv curable resin composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019950010766A KR0160451B1 (en) 1995-05-02 1995-05-02 Process for preparing epoxy acrylate and its uv curable resin composition

Publications (2)

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KR960041212A true KR960041212A (en) 1996-12-19
KR0160451B1 KR0160451B1 (en) 1999-01-15

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KR1019950010766A KR0160451B1 (en) 1995-05-02 1995-05-02 Process for preparing epoxy acrylate and its uv curable resin composition

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180057186A (en) * 2016-11-22 2018-05-30 애경화학 주식회사 Non VOC urethane modified epoxy acrylate and the method of manufacturing the same

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100669857B1 (en) * 2005-03-08 2007-01-16 삼화페인트공업주식회사 Thermoplastic epoxy-modified acrylic resin composition or polyester resin composition, and heating dry type clear paint composition containing the same
KR20210128771A (en) 2020-04-17 2021-10-27 한국화학연구원 Acrylate monomer having hydrophilic end group and a method for preparing the same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180057186A (en) * 2016-11-22 2018-05-30 애경화학 주식회사 Non VOC urethane modified epoxy acrylate and the method of manufacturing the same

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