KR960007584A - 옥사졸리논계 유도체 및 그의 제조방법과 용도 - Google Patents
옥사졸리논계 유도체 및 그의 제조방법과 용도 Download PDFInfo
- Publication number
- KR960007584A KR960007584A KR1019940020300A KR19940020300A KR960007584A KR 960007584 A KR960007584 A KR 960007584A KR 1019940020300 A KR1019940020300 A KR 1019940020300A KR 19940020300 A KR19940020300 A KR 19940020300A KR 960007584 A KR960007584 A KR 960007584A
- Authority
- KR
- South Korea
- Prior art keywords
- group
- halogen
- lower alkyl
- general formula
- following general
- Prior art date
Links
- UPULOMQHYQDNNT-UHFFFAOYSA-N 5h-1,3-oxazol-2-one Chemical class O=C1OCC=N1 UPULOMQHYQDNNT-UHFFFAOYSA-N 0.000 title claims abstract 5
- 238000000034 method Methods 0.000 title claims abstract 3
- 229910052736 halogen Inorganic materials 0.000 claims abstract 9
- 150000002367 halogens Chemical class 0.000 claims abstract 9
- 125000000217 alkyl group Chemical group 0.000 claims abstract 6
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims abstract 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract 3
- -1 carbomethoxy Chemical group 0.000 claims abstract 3
- 229910052799 carbon Chemical group 0.000 claims abstract 3
- 230000002363 herbicidal effect Effects 0.000 claims abstract 3
- 239000004009 herbicide Substances 0.000 claims abstract 3
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims abstract 3
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract 3
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims abstract 2
- 235000008206 alpha-amino acids Nutrition 0.000 claims 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 claims 1
- 125000003275 alpha amino acid group Chemical group 0.000 claims 1
- 150000001370 alpha-amino acid derivatives Chemical class 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 239000002699 waste material Substances 0.000 claims 1
- 230000035784 germination Effects 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
- A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
- A01N43/76—1,3-Oxazoles; Hydrogenated 1,3-oxazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
- C07D263/08—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
- C07D263/16—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D263/18—Oxygen atoms
- C07D263/20—Oxygen atoms attached in position 2
- C07D263/22—Oxygen atoms attached in position 2 with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, directly attached to other ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
- C07D263/30—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D263/34—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D263/36—One oxygen atom
- C07D263/42—One oxygen atom attached in position 5
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Pyridine Compounds (AREA)
Abstract
본 발명은 다음 일반식(I)을 가진 옥사졸리논계 유도체 및 그의 제조방법과 제초제로서의 용도를 개시한다 :
상기 식에서 R은 저급 알킬기 또는 할로겐, 저급 알킬 또는 트리플루오로메틸기를 함유하는 페닐기를 나타내며, X는 같거나 서로 다르고, 할로겐. 카보메톡시, 니트로기 또는 할로겐이나 트리플루오로메틸기가 치환된 페녹시기를 나타내며, A는 질소 또는 탄소를 나타내고, n은 1-3의 정수를 나타낸다. 본 발명의 제초제는 발아전 처리 또는 발아후 처리에서 쌍자엽 식물에 대해 제초효과가 우수하다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (3)
- 다음 일반식(I)의 옥사졸리논계 유도체.상기 식에서 R은 저급 알킬기 또는 할로겐, 저급 알킬 또는 트리플루오로메틸기를 함유하는 페닐기를 나타내며, X는 같거나 서로 다르고, 할로겐, 카보메톡시, 니트로기 또는 할로겐이나 트리플루오로메틸기가 치환된 폐녹시기를 나타내며, A는 질소 또는 탄소를 나타내며, n은 1-3의 정수를 나타낸다.
- 출발물질로서 다음 일반식(II)의 α-아미노산을 치환기가 있는 다음 일반식(Ⅲ)의 산 클로라이드와 축합반응시켜 다음 일반식(IV)의 아미노가 치환된 α-아미노산을 얻은 다음 무수초산과 반응시킨 후 탈수반응시키는 것으로 이루어진 제1항의 옥사졸리논계 유도체의 제조방법 :상기 식에서 R은 저급 알킬기 또는 할로겐, 저급 알킬 또는 트리플루오로메틸기를 함유하는 페닐기를 나타내며, X는 같거나 서로 다르고, 할로겐, 카보메톡시, 니트로기 또는 할로겐이나 트리플루오로메틸기가 치환된 페녹시기를 나타내며, A는 질소 또는 탄소를 나타내고, n은 1-3의 정수를 나타낸다.
- 유효 성분으로서 제1항의 옥사졸리논계 유도체를 함유한 제초제.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940020300A KR0125130B1 (ko) | 1994-08-17 | 1994-08-17 | 옥사졸리논계 유도체 및 그의 제조방법과 용도 |
| DE19530123A DE19530123C2 (de) | 1994-08-17 | 1995-08-16 | Oxazolinon-Derivate, Verfahren zu deren Herstellung und deren Verwendung |
| JP7208607A JP2735816B2 (ja) | 1994-08-17 | 1995-08-16 | オキサゾリノン系誘導体、その製造方法及び除草剤 |
| US08/515,608 US5691278A (en) | 1994-08-17 | 1995-08-16 | Oxazolinone derivatives, process for preparing the same, and use of the same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019940020300A KR0125130B1 (ko) | 1994-08-17 | 1994-08-17 | 옥사졸리논계 유도체 및 그의 제조방법과 용도 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR960007584A true KR960007584A (ko) | 1996-03-22 |
| KR0125130B1 KR0125130B1 (ko) | 1997-12-05 |
Family
ID=19390560
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019940020300A KR0125130B1 (ko) | 1994-08-17 | 1994-08-17 | 옥사졸리논계 유도체 및 그의 제조방법과 용도 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5691278A (ko) |
| JP (1) | JP2735816B2 (ko) |
| KR (1) | KR0125130B1 (ko) |
| DE (1) | DE19530123C2 (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6130337A (en) * | 1997-04-11 | 2000-10-10 | Board Of Trustees Of Leland Stanford Junior University | Enantiomerically enriched α,α-distributed amino acids and method |
| US6551777B1 (en) | 1999-02-25 | 2003-04-22 | Exact Sciences Corporation | Methods for preserving DNA integrity |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2139641A1 (de) | 1971-08-07 | 1973-02-15 | Bayer Ag | 2-(p-chlorbenzoylamino)-carbonsaeureamide, verfahren zu ihrer herstellung sowie ihre verwendung als arzneimittel |
-
1994
- 1994-08-17 KR KR1019940020300A patent/KR0125130B1/ko not_active IP Right Cessation
-
1995
- 1995-08-16 JP JP7208607A patent/JP2735816B2/ja not_active Expired - Fee Related
- 1995-08-16 DE DE19530123A patent/DE19530123C2/de not_active Expired - Fee Related
- 1995-08-16 US US08/515,608 patent/US5691278A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JP2735816B2 (ja) | 1998-04-02 |
| KR0125130B1 (ko) | 1997-12-05 |
| DE19530123A1 (de) | 1996-02-22 |
| DE19530123C2 (de) | 1997-02-20 |
| US5691278A (en) | 1997-11-25 |
| JPH0859637A (ja) | 1996-03-05 |
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| E701 | Decision to grant or registration of patent right | ||
| GRNT | Written decision to grant | ||
| FPAY | Annual fee payment |
Payment date: 20020813 Year of fee payment: 6 |
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| LAPS | Lapse due to unpaid annual fee |