KR960004668B1 - Method for manufacturing injection molding product made of wastetire - Google Patents
Method for manufacturing injection molding product made of wastetire Download PDFInfo
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- KR960004668B1 KR960004668B1 KR1019930003527A KR930003527A KR960004668B1 KR 960004668 B1 KR960004668 B1 KR 960004668B1 KR 1019930003527 A KR1019930003527 A KR 1019930003527A KR 930003527 A KR930003527 A KR 930003527A KR 960004668 B1 KR960004668 B1 KR 960004668B1
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- waste tire
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Abstract
Description
본 발명은 폐타이어를 각종 약품과 혼합, 용융시켜 사출 성형하여 각종 판넬이나 관 등과 같은 여러가지 제품을 제조할 수 있는 폐타이어를 이용한 사출 성형물 제조방법에 관한 것이다.The present invention relates to a method for producing an injection molded product using waste tires, which can produce various products such as various panels and tubes by injection molding by mixing and melting waste tires with various chemicals.
타이어를 사용하고 못사용하게 된 폐타이어를 현재는 소각 처리하거나 가늘게 절단하여 로우프 등을 제조하는 용도나 고무 바구니를 만드는 용도 등으로 사용하여 왔었다.Waste tires, which have been used tires and can not be used, have now been used for incineration or thin cutting to produce ropes, or for making rubber baskets.
그러나 이와 같은 용도에는 한계가 있는 것으로 수많은 자동차에서 배출되는 타이어를 전량 사용하기란 거의 불가능하여 그중 일부만 재사용되고 나머지는 소각 처리하여 공해에 심각한 오염을 초래하게 되는 것이다.However, there is a limit to such use, and it is almost impossible to use all the tires emitted from many automobiles, only some of them are reused and others are incinerated, causing serious pollution to the pollution.
한편 폐타이어 분말을 합성수지와 혼합 재생하는 방법은 일본국 공개특허공보 소 51-17994호 및 일본국 공개특허공보 소 55-135625호에도 개시되어 있으나, 상기 방법들에서는 첨가제 및 폐타이어 분쇄물과 합성수지간의 배합비가 달라서 본 발명과 같은 경도가 강하고 내구성이 있는 제품 물성이 발현되지 못하는 문제점이 있었다.Meanwhile, a method of mixing and recycling waste tire powder with a synthetic resin is disclosed in Japanese Patent Laid-Open Publication No. 51-17994 and Japanese Patent Laid-Open Publication No. 55-135625, but in the above methods, additives, waste tire grinds, and synthetic resin are used. Since the compounding ratio of the liver is different, there is a problem in that the hardness and hardness of the product properties such as the present invention are not expressed.
본 발명은 상기와 같은 문제점을 해소하기 위하여 개발된 것으로 폐타이어를 미분쇄하여 여기에 각종 물질 및 약품을 투여한 후 용융시켜 또는 사출 성형하여 각종 산업구조물을 제조함으로써 폐타이어를 재생하여 산업에 유용한 자원으로 전환시키고자 함에 있다.The present invention was developed in order to solve the above problems, finely pulverize waste tires, and administer various materials and chemicals to them, and then melt or inject mold to manufacture various industrial structures to recycle waste tires, which are useful for industries. It's about turning it into a resource.
본 발명의 다른 목적은 폐타이어 소각에 따른 에너지 손실 및 환경공해를 방지하고자 함에 있다.Another object of the present invention is to prevent energy loss and environmental pollution caused by incineration of waste tires.
본 발명의 폐타이어를 이용한 사출 성형물 제조방법은 폐타이어 분쇄물, 합성수지 및 첨가제를 혼합하여 이루어지는 폐타이어를 이용한 사출 성형물 제조방법에 있어서, 폐타이어 분쇄물에 폴리프로필렌 수지(PP), 저밀도 폴리에틸렌 수지(LDPE) 및 고밀도 폴리에틸렌 수지(하이덴, HDPE)중 하나 이상과 아세톤, 가성소다, 유리석면 및 전지분을 혼합하여 섞은 후 약 230℃ 내지 310℃에서 용융시켜 사출 성형을 행하는 것을 특징으로 하고 있다.The injection molding method using the waste tire of the present invention is a method for producing an injection molding using waste tire, which is a mixture of waste tire pulverized product, synthetic resin and additives, wherein the waste tire pulverized product is made of polypropylene resin (PP) and low density polyethylene resin. (LDPE) and at least one of a high density polyethylene resin (Hyden, HDPE) and acetone, caustic soda, glass asbestos and battery powder are mixed and melted at about 230 ℃ to 310 ℃ characterized in that the injection molding.
상기 폐타이어 분쇄물의 입자크기는 용도에 따라 적합하게 조정하며, 통상 입경이 2 내지 3mm 정도가 적합하다. 또한 상기 폐타이어 분쇄물의 함량은 35 내지 45중량%로 하는 것이 바람직하다.The particle size of the waste tire pulverized product is suitably adjusted according to the use, and a particle size of about 2 to 3 mm is usually suitable. In addition, the content of the waste tire pulverized is preferably set to 35 to 45% by weight.
상기 폴리프로필렌 수지 및 저밀도 폴리에틸렌 수지(LDPE)는 폐수지를 이용할 수도 있으며, 그 함량은 각각 18 내지 23중량%로 하는 것이 바람직하고, 상기 고밀도 폴리에틸렌(하이덴, HDPE)은 0 내지 13중량%로 하는 것이 바람직하다.The polypropylene resin and the low density polyethylene resin (LDPE) may use waste resins, the content of which is preferably 18 to 23% by weight, and the high density polyethylene (heden, HDPE) is 0 to 13% by weight. desirable.
또한 상기 수지들 대신에 또는 부가하여 나이론 등의 수지를 사용하는 것도 가능하다. 상기 아세톤, 가성소다, 유리석면 및 전지분은 제품 목적에 따라 이들 중 하나 또는 둘 이상이 선택적으로 사용될 수 있다.It is also possible to use resins such as nylon instead of or in addition to the above resins. The acetone, caustic soda, glass asbestos and battery powder may be optionally used one or two or more of them depending on the purpose of the product.
상기 각 부가 물질의 농도는 명확히 한정할 수 있는 성질은 아니지만 대체로 아세톤은 0.01 내지 0.05중량%, 가성소자는 0.03 내지 0.08중량%, 유리석면은 4 내지 7중량%, 전지분은 3 내지 5중량%로 하는 것이 가장 바람직하다.The concentration of each additional material is not a property that can be clearly defined, but acetone is generally 0.01 to 0.05% by weight, caustic element is 0.03 to 0.08% by weight, glass asbestos is 4 to 7% by weight, battery powder is 3 to 5% by weight It is most preferable to set it as.
상기 부가 물질 중 아세톤은 용제로서 채용되는 것이며 가성소다는 성형물 내부에 다량의 미세한 기포를 형성시킴으로써 제품의 충격 흡수력을 증가시키고 제품의 탄력성을 향상시키는 역할을 한다.Acetone is used as a solvent among the additional substances, and caustic soda forms a large amount of fine bubbles in the molding, thereby increasing the impact absorption of the product and improving the elasticity of the product.
또한 유리석면은 내열성 재료로서 제품의 내열성을 증가시키는 역할을 하며, 그 함량이 과다하게 되면 제품이 조악해지고 성형성이 좋지 않게 된다. 그리고, 전지분은 전분과 같은 것으로서 본 발명의 제품이 사용되는 기간중 일정기간이 경과하면 고무성분 및 수지성분을 분해시킴으로써 환경오염을 방지하는 역할을 한다.In addition, glass asbestos serves to increase the heat resistance of the product as a heat-resistant material, when the content is excessive, the product becomes coarse and poor moldability. In addition, the battery powder is the same as starch, and serves to prevent environmental pollution by decomposing the rubber component and the resin component after a certain period of time during which the product of the present invention is used.
이하에서 본 발명의 실시예들이 상세히 기술되어질 것이다.Embodiments of the present invention will be described in detail below.
[실시예 1]Example 1
폐타이어 분쇄물 40중량%40% by weight of waste tires
폴리프로필렌(PP) 20중량%20% by weight of polypropylene (PP)
저밀도 폴리에틸렌(LDPE) 20중량%20% by weight Low Density Polyethylene (LDPE)
고밀도 폴리에틸렌(하이덴, HDPE) 11.23중량%High Density Polyethylene (Hyden, HDPE) 11.23 wt%
아세톤 0.03중량%Acetone 0.03 wt%
가성소다 0.06중량%Caustic Soda 0.06% by weight
전지분 3.05중량%Battery powder 3.05% by weight
유리석면 5.63중량%5.63 wt% glass asbestos
상기와 같이 혼합기에 넣고 300℃로 약 3분간 혼합한 다음 사출기로 사출한 결과 강도가 우수한 물품의 사출물을 얻었으며 표면이 매끄러워 각종 판재로 사용하거나 박스 등과 같이 강도가 우수한 합성수지의 대용품으로 사용할 수 있음을 알았으며 합성수지에 비해 감촉이 매우 뛰어났다.Put in the mixer as described above, and mixed for about 3 minutes at 300 ℃ and injected into the injection molding machine to obtain an injection product of excellent strength and smooth surface can be used as a variety of plate materials or as a substitute for synthetic resin with excellent strength, such as a box. It was found that the texture was excellent compared to the synthetic resin.
[실시예 2]Example 2
폐타이어 분쇄물 40중량%40% by weight of waste tires
폴리프로필렌(PP) 25중량%Polypropylene (PP) 25% by weight
저밀도 폴리에틸렌(LDPE) 25.23중량%25.23% by weight of low density polyethylene (LDPE)
아세톤 0.04중량%Acetone 0.04 wt%
가성소다 0.05중량%Caustic Soda 0.05% by weight
전지분 4.23중량%Battery powder 4.23 wt%
유리석면 5.45중량%5.45 wt% glass asbestos
상기와 같이 혼합기에 넣고 300℃로 약 3분간 혼합한 다음 사출기로 사출한 결과 강도가 우수한 물품의 사출물을 얻었으며 표면이 매끄러워 각종 판재로 사용하거나 강하지 않고 약간 연질 상태로 사용되는 박스등과 같이 강도를 필요로 하지 않는 합성수지의 대용품으로 사용할 수 있음을 알았으며 합성수지에 비해 감촉이 매우 뛰어났다.Put it in the mixer as above and mix for about 3 minutes at 300 ℃ and then injected into the injection machine to obtain an injection product of excellent strength, and the surface is smooth. It was found that it can be used as a substitute for synthetic resin that does not require strength, and the texture was very excellent compared to synthetic resin.
[실시예 3]Example 3
폐타이어 분쇄물 35중량%35% by weight of waste tires
폴리프로필렌(PP) 22중량%Polypropylene (PP) 22% by weight
저밀도 폴리프로필렌(LDPE) 22중량%22% by weight Low Density Polypropylene (LDPE)
나이론 11중량%Nylon 11% by weight
가성소다 0.06중량%Caustic Soda 0.06% by weight
전지분 4.5중량%4.5% by weight of battery
유리석면 5.44중량%5.44 wt% glass asbestos
상기와 같이 혼합기에 넣고 300℃로 약 3분간 혼합한 다음 사출기로 사출한 결과 강도가 우수한 물품의 사출물을 얻었으며 표면이 매끄러워 각종 판재로 사용하거나 박스 등과 같이 강도가 우수한 합성수지의 대용품으로 사용할 수 있음을 알았으며 합성수지에 비해 감촉이 매우 뛰어났다.Put in the mixer as described above, and mixed for about 3 minutes at 300 ℃ and injected into the injection molding machine to obtain an injection product of excellent strength and smooth surface can be used as a variety of plate materials or as a substitute for synthetic resin with excellent strength, such as a box. It was found that the texture was excellent compared to the synthetic resin.
단, 실시예 1에 비해 표면이 고르지 못하나 합성수지의 대용물로 사용이 가능하였다.However, the surface was uneven compared with Example 1, but could be used as a substitute for synthetic resin.
이상에서 본 발명에서는 사출에 의한 성형방법만을 예시하였으나 성형방법은 본 발명의 특징이 아니며 플라스틱을 성형하는 방법이라면 사출, 압출, 프레스 등 모든 공지의 성형방법이 본 발명에 채용될 수 있음은 당업자에게 있어서 자명한 일일 것이다.In the present invention described above only the molding method by injection, but the molding method is not a feature of the present invention and if it is a method of molding plastics, all known molding methods such as injection, extrusion, press can be employed in the present invention to those skilled in the art It will be obvious.
상술한 바와 같이 본 발명에 따르면 폐타이어를 재생하여 양질의 각종 산업구조물을 제조함으로써 폐타이어 소각에 따른 에너지 손실 및 환경공해를 방지하고 무용자원을 재활용할 수 있게 되는 효과가 있다.As described above, according to the present invention, by recycling waste tires to manufacture various industrial structures of high quality, it is possible to prevent energy loss and environmental pollution caused by incineration of waste tires and to recycle the useless resources.
이상에서 본 발명은 기재된 구체예에 대해서만 상세히 설명되었지만 본 발명의 기술적 사상 범위내에서 다양한 변형 및 수정이 가능함은 당업자에게 있어서 명백한 것이며 이러한 변형 및 수정이 첨부된 특허청구범위에 속함은 당연하다.Although the present invention has been described in detail only with respect to the described embodiments, it will be apparent to those skilled in the art that various modifications and variations are possible within the technical scope of the present invention, and such modifications and modifications belong to the appended claims.
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KR200299991Y1 (en) * | 2002-09-12 | 2003-01-06 | 신효섭 | External prestressing strengthening apparatus of bridge beam |
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KR200299991Y1 (en) * | 2002-09-12 | 2003-01-06 | 신효섭 | External prestressing strengthening apparatus of bridge beam |
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