KR960003467B1 - Preparation of a flame-retardant for fibers - Google Patents

Preparation of a flame-retardant for fibers Download PDF

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Publication number
KR960003467B1
KR960003467B1 KR1019900012026A KR900012026A KR960003467B1 KR 960003467 B1 KR960003467 B1 KR 960003467B1 KR 1019900012026 A KR1019900012026 A KR 1019900012026A KR 900012026 A KR900012026 A KR 900012026A KR 960003467 B1 KR960003467 B1 KR 960003467B1
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KR
South Korea
Prior art keywords
water
glycerin
oxalic acid
textile
antifiring
Prior art date
Application number
KR1019900012026A
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Korean (ko)
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KR920004655A (en
Inventor
백정현
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백정현
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Publication date
Application filed by 백정현 filed Critical 백정현
Priority to KR1019900012026A priority Critical patent/KR960003467B1/en
Publication of KR920004655A publication Critical patent/KR920004655A/en
Application granted granted Critical
Publication of KR960003467B1 publication Critical patent/KR960003467B1/en

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Fireproofing Substances (AREA)
  • Paper (AREA)

Abstract

The anit-firing agent for textiles is composed of 60wt.% water, 16˜40wt.% ammonia nitride, 0.3˜25wt.% glycerin and 0.1˜0.2wt.% oxalic acid. The antifiring textile is each obtained by covering the antifiring agent of 190kg water, 48kg ammonia nitride, 76kg glycerin and 0.2wt% oxalic acid on 300kg polyester or nylon textile, the antifiring agent of 190kg water, 120kg ammonia nitride, 16kg glycerin and 0.2wt.% oxalic acid on 300kg T/C spun blend textile, and the antifiring agent of 190kg water, 93kg ammonia nitride, 8.7kg glycerin and 0.1wt.% oxalic acid on 300kg cotton textile.

Description

직물용 방연제(防煙劑)의 제조방법Manufacturing method of flame retardant for fabric

본 발명은 직물지에 흡침시키거나 도포하여 직물지가 연소되는 것을 방지하도록 하는 방연제의 제조방법에 관한 것인데 보다 구체적인 것은 수산에 암모니아성질소와 그리세린을 혼합하여 조성한 방연물을 만들어 이를 직물지의 표면에 분무하거나 직물지에 흡침시켜 방연효과를 얻게한 것이다.The present invention relates to a method for manufacturing a flame retardant to prevent the fabric paper from burning by absorbing or applying it to the textile paper, and more specifically, to make a flame retardant made by mixing ammonia nitrogen and glycerine in the fishery and making it on the surface of the textile paper. Sprayed or absorbed in textile paper to obtain a flame retardant effect.

종래의 방연제는 안티모니, 포르마린산 또는 암모늄 포스퍼태이프, 수용성 무기산, 붕사, 붕산, 염화암모듐 등이 사용되고 있기 때문에 방연효과가 나쁘고 세탁하면 직물지의 표면에 흰가루가 생기는 등의 결점이 있어서 상품가치가 떨어질뿐 아니라 냄새가 많이 나는 등의 불편이 있었다.Conventional flame retardants are used for antimony, formic acid or ammonium phosphorus, water soluble inorganic acids, borax, boric acid, ammonium chloride, etc. Not only was it worth noting, there was a lot of smell, etc.

본 발명은 위와같은 여러가지 결점을 시정하기 위하여 개발한 것으로 이를 실시예별로 설명하면 다음과 같다.The present invention was developed to correct the various drawbacks as described above.

[실시예]EXAMPLE

(1) 폴리에스텔 직물지나 나일론 직물지의 경우, 총액량 300Kg에 대하여 물 190Kg, 암모니아성질소 48Kg, 그리세린 76Kg, 수산 0.2%를 혼합하여 조성하며 (2) T/C혼방직물의 경우(장식용 벽지포함) 총액량 300Kg 저면에 물 190Kg, 암모니아성질소 120Kg, 그리세린 16Kg, 수산 0.2%를 혼합하여 조성하고, (3) 면, 나이론 직물지의 경우 총액 300Kg에 물 190Kg, 암모니아성질소 93Kg, 그리세린 8.7Kg, 수산 0.1%를 혼합하여 조성한다.(1) In the case of polyester or nylon textile paper, 190 Kg of water, 48 Kg of ammonia nitrogen, 76 Kg of glycerin, and 0.2% of oxalic acid are mixed with a total amount of 300 Kg. (2) T / C blended fabric (decorative wallpaper It contains a total amount of 300Kg of water and 190Kg of water, 120Kg of ammonia nitrogen, 16Kg of glycerin, and 0.2% of oxalic acid. (3) For cotton and nylon textile paper, 300Kg of water, 190Kg of water, 93Kg of ammonia nitrogen, and glycerin 8.7Kg and 0.1% of fish acid are mixed and prepared.

이와같이 조성된 본 발명의 방연제는 직물지의 표면에 분무하여 고착시키거나 조성액 내에 직물지를 투입하였다가 조성물이 직물지에 흡침되면 인출하여 건조시키는 방법으로 간단히 도포시킬수가 있고 본 발명의 방연제가 도포된 직물지는 촉감이나 강도나 외양이 천연모습을 그대로 유지하면서 불에 타지 않는 효과를 얻도록 되는 것인데 부수적 효과로 때를 타지않는 이점도 있고 가공이 용이한 장점이 있으며 본 발명의 조성성중 수산은 P11을 조성한 부작용을 방지하는 효과가 있고 직물의 강도를 저하시키지 않으면서 소망의 목적을 달성시키는 장점이 있으며 그리세린은 암모니아성질소의 건성을 저하시키는 역할을 하며 암모니아 분자와의 결합을 완벽하게 하여 우수한 방연효과를 얻게하는 등의 효과를 내기 때문에 방연이 완벽하고 가격이 저렴하게 되는 방연제를 얻도록 되는 것이다.The flame retardant of the present invention thus formed can be sprayed onto the surface of the fabric paper to be fixed or put into the composition paper, and when the composition is absorbed into the fabric paper, the composition can be simply applied by a method of drawing out and drying the fabric to which the flame retardant of the present invention is applied. Losing touch, strength or appearance is to achieve the effect of not burning while maintaining the natural appearance as a side effect, there is an advantage that does not burn time as a side effect, and has the advantage of easy processing. It has the effect of preventing the decay, and has the advantage of achieving the desired purpose without degrading the strength of the fabric.Gryserine plays a role in reducing the dryness of ammonia nitrogen, and perfects the bond with the ammonia molecule to obtain an excellent flame retardant effect. Because it produces the effect such as that It would be to obtain a flame retardant that is the bamboo blind.

Claims (1)

총량에 대하여 물 60%, 암모니아성질소 16-40%, 그리세린 0.3-25%를 중량비로 혼합하고 수산 0.1-0.2%를 투입하여 조성됨을 특징으로 하는 직물용 방연제의 제조방법.A method for producing a fabric flame retardant, characterized in that the total amount of 60% water, ammonia nitrogen 16-40%, glycerine 0.3-25% by weight ratio and mixed with 0.1-0.2% of the fish.
KR1019900012026A 1990-08-04 1990-08-04 Preparation of a flame-retardant for fibers KR960003467B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1019900012026A KR960003467B1 (en) 1990-08-04 1990-08-04 Preparation of a flame-retardant for fibers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1019900012026A KR960003467B1 (en) 1990-08-04 1990-08-04 Preparation of a flame-retardant for fibers

Publications (2)

Publication Number Publication Date
KR920004655A KR920004655A (en) 1992-03-27
KR960003467B1 true KR960003467B1 (en) 1996-03-14

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Application Number Title Priority Date Filing Date
KR1019900012026A KR960003467B1 (en) 1990-08-04 1990-08-04 Preparation of a flame-retardant for fibers

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Publication number Publication date
KR920004655A (en) 1992-03-27

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