KR950702587A - NON-LINEAR POTICALLY ACTIVE POLYURETHANES HAVING HIGH GLASS TRANSITION TEMPERATURES - Google Patents

NON-LINEAR POTICALLY ACTIVE POLYURETHANES HAVING HIGH GLASS TRANSITION TEMPERATURES Download PDF

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KR950702587A
KR950702587A KR1019950700049A KR19950700049A KR950702587A KR 950702587 A KR950702587 A KR 950702587A KR 1019950700049 A KR1019950700049 A KR 1019950700049A KR 19950700049 A KR19950700049 A KR 19950700049A KR 950702587 A KR950702587 A KR 950702587A
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group
optically active
donor
nonlinear optically
active polyurethane
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KR1019950700049A
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Korean (ko)
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헨리쿠스 마리아 함스 베르나르두스
코르넬리스 쟈코부스 마리아 반 베그겔 프란시스쿠스
페트루스 쟈코부스 마리아 반 데르 보르스트 코르넬리스
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피이터 코르넬리스 샬크비즈크; 귄터 페트
아크조 노벨 엔. 뷔.
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Publication of KR950702587A publication Critical patent/KR950702587A/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3836—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing azo groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/384—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing nitro groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/675—Low-molecular-weight compounds
    • C08G18/677—Low-molecular-weight compounds containing heteroatoms other than oxygen and the nitrogen of primary or secondary amino groups
    • C08G18/678—Low-molecular-weight compounds containing heteroatoms other than oxygen and the nitrogen of primary or secondary amino groups containing nitrogen
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/35—Non-linear optics
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/35—Non-linear optics
    • G02F1/355—Non-linear optics characterised by the materials used
    • G02F1/361—Organic materials
    • G02F1/3615—Organic materials containing polymers
    • G02F1/3617—Organic materials containing polymers having the non-linear optical group in a side chain

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

본 발명은 고 유리 전이 온도를 가진 비선형 광학 활성 폴리우레탄에 관한 것으로, 사이드 그룹이 중합체 주 사슬의 부분인 단단한 도너 그룹으로 구성되어 있고 단단한 도너 그룹을 비선형 광학 활성 폴리우레탄에 결합시킴에 의해 높은 유리 전이 온도가 얻어지는 결과, 열 안정성이 증가하는 것을 특징으로 한다.The present invention relates to a non-linear optically active polyurethane having a high glass transition temperature, wherein the side groups are composed of rigid donor groups that are part of the polymer main chain and the high glass is obtained by bonding the rigid donor groups to the nonlinear optically active polyurethane. As a result of obtaining the transition temperature, the thermal stability is increased.

Description

고 유리 전이 온도를 가진 비 선형 광학 활성 폴리우레탄(NON-LINEAR POTICALLY ACTIVE POLYURETHANES HAVING HIGH GLASS TRANSITION TEMPERATURES)NON-LINEAR POTICALLY ACTIVE POLYURETHANES HAVING HIGH GLASS TRANSITION TEMPERATURES

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (9)

사이드 그룹이 중합체 주 사슬의 부분인 단단한 도너 그룹으로 구성된 것을 특징으로 하는 중합체 주된 사슬 및 도너-π-억셉터 사이드그룹으로 구성된 비선형 광학 활성 폴리우레탄.A nonlinear optically active polyurethane consisting of a polymer main chain and a donor- [pi] -acceptor sidegroup, wherein the side group consists of a rigid donor group that is part of the polymer main chain. 170℃ 이상의 Tg를 가지는 것을 특징으로 하는 도너-π-억셉터 사이드그룹으로 구성된 비선형 광학 활성 폴리우레탄.A nonlinear optically active polyurethane composed of donor-π-acceptor sidegroups having a Tg of at least 170 ° C. 단단한 도너 그룹을 가지고 170℃ 이상의 Tg를 가지는 것을 특징으로 하는 도너-π-억셉터 사이드그룹으로 구성된 비선형 광학 활성 폴리우레탄.A non-linear optically active polyurethane composed of donor-π-acceptor sidegroups having a solid donor group and having a Tg of at least 170 ° C. 제1항에 있어서, 단단한 도너 그룹이 질소 또는 황 함유 지환식 그룹인 것을 특징으로 하는 도너-π-억셉터 사이드그룹으로 구성된 비선형 광학 활성 폴리우레탄.2. The nonlinear optically active polyurethane according to claim 1, wherein the hard donor group is a nitrogen or sulfur containing alicyclic group. 제4항에 있어서, 질소 또는 황 함유 지환식 그룹이 디하이드록시-작용기가 달린 것을 특징으로 하는 도너-π-억셉터 사이드그룹으로 구성된 비선형 광학 활성 폴리우레탄.5. The nonlinear optically active polyurethane according to claim 4, wherein the nitrogen or sulfur containing alicyclic group has a dihydroxy-functional group. 제1항에 있어서, 단단한 도너 그룹이 질소 원자가 π-억셉터 그룹에 직접적으로 결합되는 디하이드록시 피롤리딘 그룹인 것을 특징으로 하는 도너-π-억셉터 사이드그룹으로 구성된 비선형 광학 활성 폴리우레탄.2. The nonlinear optically active polyurethane according to claim 1, wherein the hard donor group is a dihydroxy pyrrolidine group in which the nitrogen atom is directly bonded to the π-acceptor group. 제1항에 있어서, 단단한 도너 그룹이 디하이드록시 디티아풀벤 그룹인 것을 특징으로 하는 도너-π-억셉터 사이드그룹으로 구성된 비선형 광학 활성 폴리우레탄.2. The nonlinear optically active polyurethane according to claim 1, wherein the hard donor group is a dihydroxy dithiafulbene group. 하기 일반식(6)을 만족시키는 것을 특징으로 하는 디하드록시-작용기가 달린 도너-π-억셉터 그룹Donor-π-acceptor group with a dihydroxy-functional group, characterized by satisfying the following general formula (6) (상기 식에서, X는 -CR2=CR2-, -N=N-, -CR2=N- 또는 -N=CR2-, Y는 -CN, -NO2, CR2=C(CN)2, -CF3, -CCN=C(CN)2또는 -SO2R2R1은 -할로겐, -R2, -OR2-, -COR2, COOR2, -CN 또는 -CF3, -SO2R3R2는 -H, 또는 2 내지 3개의 탄소 원자를 가진 알킬 그룹, R3은 1 내지 8개의 탄소 원자를 가진 알킬 또는 아릴 그룹, n은 0 내지 4의 정수이고, X는 n이 1보다 크다면 동일하거나 상이할 수 있음.).Wherein X is -CR 2 = CR 2- , -N = N-, -CR 2 = N- or -N = CR 2- , Y is -CN, -NO 2 , CR 2 = C (CN) 2 , -CF 3 , -CCN = C (CN) 2 or -SO 2 R 2 R 1 is -halogen, -R 2 , -OR 2- , -COR 2 , COOR 2 , -CN or -CF 3 ,- SO 2 R 3 R 2 is -H, or an alkyl group having 2 to 3 carbon atoms, R 3 is an alkyl or aryl group having 1 to 8 carbon atoms, n is an integer from 0 to 4, X is n May be the same or different if greater than 1). 제1항 내지 제7항 중 어느 한 항에 따라 제조된 비선형 광학 활성 폴리우레탄으로 구성된 것을 특징으로 하는 비선형 광학 활성 광 도파관.A nonlinear optically active optical waveguide, which is composed of a nonlinear optically active polyurethane prepared according to any one of claims 1 to 7. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950700049A 1992-07-06 1993-06-21 NON-LINEAR POTICALLY ACTIVE POLYURETHANES HAVING HIGH GLASS TRANSITION TEMPERATURES KR950702587A (en)

Applications Claiming Priority (3)

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NL9201202 1992-07-06
NL9201202 1992-07-06
PCT/EP1993/001587 WO1994001480A1 (en) 1992-07-06 1993-06-21 Non-linear optically active polyurethanes having high glass transition temperatures

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EP (1) EP0650502A1 (en)
JP (1) JPH08501811A (en)
KR (1) KR950702587A (en)
CN (1) CN1083494A (en)
CA (1) CA2139671A1 (en)
WO (1) WO1994001480A1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW296392B (en) * 1993-09-29 1997-01-21 Akzo Nobel Nv
US5688896A (en) * 1994-09-26 1997-11-18 Akzo Nobel N.V. Non-linear optically active polycarbonate
TW311990B (en) * 1995-03-13 1997-08-01 Akzo Nobel Nv
EP0780722A1 (en) * 1995-12-22 1997-06-25 Akzo Nobel N.V. Electro-optical device stable in the 600-1600 nanometer wavelength range

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* Cited by examiner, † Cited by third party
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ATE168790T1 (en) * 1988-09-08 1998-08-15 Akzo Nobel Nv INTEGRATED OPTICAL COMPONENTS
FR2636634B1 (en) * 1988-09-16 1992-11-27 Rhone Poulenc Chimie POLYURETHANES, NON-LINEAR OPTICAL ACTIVE INGREDIENTS AND MATERIALS CONTAINING THE SAME, OPTICAL DEVICE CONTAINING THE SAME, AND METHODS OF MAKING SUCH COMPOUNDS AND MATERIALS
FR2646671B1 (en) * 1989-05-03 1993-01-22 Rhone Poulenc Chimie ORGANIC MATERIAL ACTIVE IN NON-LINEAR OPTICS
DE69103555T2 (en) * 1990-03-06 1995-03-02 Akzo Nobel Nv Thermosetting NLO system and integral optical components based on it.
DE59105849D1 (en) * 1990-09-24 1995-08-03 Siemens Ag Cross-linked epoxy resins with non-linear optical properties.

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CA2139671A1 (en) 1994-01-20
WO1994001480A1 (en) 1994-01-20
EP0650502A1 (en) 1995-05-03
CN1083494A (en) 1994-03-09
JPH08501811A (en) 1996-02-27

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