KR950011528A - Thermoplastic Composition - Google Patents

Thermoplastic Composition Download PDF

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KR950011528A
KR950011528A KR1019940027800A KR19940027800A KR950011528A KR 950011528 A KR950011528 A KR 950011528A KR 1019940027800 A KR1019940027800 A KR 1019940027800A KR 19940027800 A KR19940027800 A KR 19940027800A KR 950011528 A KR950011528 A KR 950011528A
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following formula
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structural units
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KR1019940027800A
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KR0166982B1 (en
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히데유키 스미
유타카 나카야마
히로시 훗타
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스기야마 도모오
다이이치고교 세아야쿠 가부시키가이샤
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Priority claimed from JP5293941A external-priority patent/JPH07126446A/en
Priority claimed from JP34613893A external-priority patent/JP3420316B2/en
Application filed by 스기야마 도모오, 다이이치고교 세아야쿠 가부시키가이샤 filed Critical 스기야마 도모오
Publication of KR950011528A publication Critical patent/KR950011528A/en
Priority to KR1019980026530A priority Critical patent/KR0167048B1/en
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Publication of KR0166982B1 publication Critical patent/KR0166982B1/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0892—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms containing monomers with other atoms than carbon, hydrogen or oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2300/00—Characterised by the use of unspecified polymers
    • C08J2300/22—Thermoplastic resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 열가소성 수지조성물에 관한 것으로, 에틸렌구조단(80∼98몰%), 아크릴레이트 구조단위 (1∼15몰%), 아크릴아미드구조단위(2∼20몰%)가 선형상으로 배열되어 이루어지는 중량평균분자량 1,000∼50,000의 카티온성 공중합체를 폴리올레핀계 수지에 배합합으로써 얻어지며 가전제품부품등의 재료, 상세하게는 케이싱,용기등과 같은 입체 3차원구조를 구비한 성형체에 적합하게 사용되고 영구대전방지성, 내마찰성, 투명성 및 충격 강도가 우수한 것을 특징으로 한다.The present invention relates to a thermoplastic resin composition, wherein the ethylene structural stage (80 to 98 mol%), the acrylate structural unit (1 to 15 mol%), and the acrylamide structural unit (2 to 20 mol%) are arranged in a linear shape. It is obtained by blending a cationic copolymer with a weight average molecular weight of 1,000 to 50,000 in a polyolefin resin, and is suitably used for moldings having three-dimensional three-dimensional structures such as materials for home appliance parts, in particular casing and containers. It is characterized by excellent antistatic property, friction resistance, transparency and impact strength.

Description

열가소성수지조성물Thermoplastic Composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (8)

(A)(메타)아크린계 수지, (B)하기식(I)으로 나타낸 에틸렌구조 단위 80∼98몰%와, 하기식(Ⅲ)으로 나타낸 아크릴아미드구조 단위 2-20몰%가 선형상으로 배열되어 이루어진 중량평균 분자량 1,000-50,000의 카티온성 공중합체 및 (C)열안정제 및/또는 내후재로 이루어진 것율 특징으로 하는 (메타)아크릴계 수지조성물(A) (meth) acrylic resin, (B) 80-98 mol% of ethylene structural units represented by following formula (I), and 2-20 mol% of acrylamide structural units represented by following formula (III) are linear A (meth) acrylic resin composition characterized by a ratio consisting of a cationic copolymer having a weight average molecular weight of 1,000-50,000 and (C) a heat stabilizer and / or a weathering material arranged in the (상기 식에서, R1는 에틸렌기 또는 프로피렌기, R3및 R4는 메틸기, R5는 탄소수 1∼8의 직선사슬형상의 알킬기 또는 아릴알킬기, X-는 할로게화물 이온, CH30S03 -또는 CH3CH20S03 -를 나타낸다. 또한 R2는 구조단위마다 동일하거나 다르더라도 좋다.)(Wherein R 1 is an ethylene group or a propylene group, R 3 and R 4 are methyl groups, R 5 is a linear alkyl group or arylalkyl group having 1 to 8 carbon atoms, X − is a halide ions, CH 3 0S0 3 - or CH 3 CH 2 0S0 3 - and R 2 may be the same or different for each structural unit.) (A)(메타)아크릴계 수지 및 (B)하기식(I)으로 나타낸 에틸렌구조 단위 80∼98몰%와, 하기식(Ⅱ)으로 나타낸 아크릴레이트구조 단위 15물%이하 및 하기식 (Ⅲ)으로 나타낸 아크릴아미드구조 단위 2∼20몰%가 선형상으로 배열되어 이루어진 중량평균 분자량 1,000-50,000의 카티온성 공중합체, 및 (C)열안정재 및/또는 내후제로 이루어진 것을 특징으로 하는 (메타)아크릴계 수지조성물.(A) (meth) acrylic resin and (B) 80-98 mol% of ethylene structural units represented by following formula (I), 15 water% or less of acrylate structural units represented by following formula (II), and following formula (III) (Meth) acrylic type, characterized by consisting of a cationic copolymer having a weight average molecular weight of 1,000-50,000 in which 2 to 20 mol% of the acrylamide structural units represented by the above formula are linearly arranged, and (C) a heat stabilizer and / or a weathering agent. Resin composition. (상기 식에서, R1는 메틸기 또는 에틸기, R2는 에틴렌기 또는 프로필렌기, R3및 R4는 메틸기 R5는 탄소수 1∼8의 직선사슬형상 알킬기 또는 아릴알킬기, X-는 할로겐화물이온, CH30S03 -또는 CH3CH20S03 -를 나타낸다. R1, R2는 구조단위마다 동일하거나 다르더라도 좋다)(Wherein R 1 is a methyl group or an ethyl group, R 2 is an ethylene group or a propylene group, R 3 and R 4 are a methyl group R 5 is a linear alkyl group or an arylalkyl group having 1 to 8 carbon atoms, X − is a halide ion, CH 3 0S0 3 - or CH 3 CH 2 0S0 3 - R 1 and R 2 may be the same or different for each structural unit) 제1항 또는 제2항에 따른 (메타)아크릴계 수지조성물에 입체 3차원 구조를 가지는 성형체로 성형되어 있는 것을 특징으로하는 (메타)아크릴계 수지성형체.The (meth) acrylic resin molded body formed into the molded object which has a three-dimensional three-dimensional structure in the (meth) acrylic-type resin composition of Claim 1 or 2. (A)폴리올레핀계 수지 70∼97중량% 및 (B)하기식(I)으로 나타낸 에틸렌구조 단위 80∼98몰%와, 하기식(Ⅲ)으로 나타낸 아크릴아미드구조 단위 2∼20몰%가 선형상으로 배열되어 이루어진 중량평균 분자량 1,000∼50,000의 카티온성 공중합체, 3∼30중량이므로 이루어지는 것을 특징으로 하는 폴리올레핀계 수지 조성물.70-97 weight% of (A) polyolefin resin and (B) 80-98 mol% of ethylene structural units represented by following formula (I), and 2-20 mol% of acrylamide structural units represented by following formula (III) A polyolefin-based resin composition comprising a cationic copolymer having a weight average molecular weight of 1,000 to 50,000 and 3 to 30 weight, which are arranged in a shape. (상기 식에서, R1는 에틸렌기 또는 프로피렌기, R3및 R4는 메틸기, R5는 탄소수 1∼8의 직선사슬형상의 알킬기 또는 아릴알킬기, X-는 할로겐화물 이온, CH30S03 -또는 CH3CH20S03 -를 나타낸다. 또한 R2는 구조단위마다 동일하거나 다르더라도 좋다.)(Wherein R 1 is an ethylene or propylene group, R 3 and R 4 are methyl groups, R 5 is a linear or alkyl group having 1 to 8 carbon atoms or an arylalkyl group, X − is a halide ion, CH 3 0S0 3 - or CH 3 CH 2 0S0 3 -. In addition, the represent R 2 may be the same or different, each structural unit). (A)폴리올레핀계 수지 70∼97중량% 및 (B)하기식(I)으로 나타낸 에틸렌구조 단위 80∼98몰%와, 하기식(Ⅱ)으로 나타낸 아크릴레이트구조 단위 15몰%이하 및 하기식(Ⅲ)으로 나타낸 아크릴아미드구조 단위 2∼20몰%가 선형상으로 배열되어 이루어지는 중량평균 분자량 1,000-50,000의 카티온성 공중합체 3-30중량%로 이루어지는 것을 특징으로 하는 폴리올레핀계 수지조성물.(A) 70-97 weight% of polyolefin resin and (B) 80-98 mol% of ethylene structural units represented by following formula (I), and 15 mol% or less of acrylate structural units represented by following formula (II), and a following formula 2-20 mol% of acrylamide structural units represented by (III) consist of 3-30 weight% of cationic copolymers of the weight average molecular weight 1,000-50,000 in which linear form is arranged, The polyolefin resin composition characterized by the above-mentioned. (상기 식에서, R1는 메틸기 또는 에틸기, R2는 에틴렌기 또는 프로필렌기, R3및 R4는 메틸기 R5는 탄소수 1∼8의 직선사슬형상 알킬기 또는 아릴알킬기, X-는 할로겐화물이온, CH30S03 -또는 CH3CH20S03 -를 나타낸다. R1, R2는 구조단위마다 동일하거나 다르더라도 좋다)(Wherein R 1 is a methyl group or an ethyl group, R 2 is an ethylene group or a propylene group, R 3 and R 4 are a methyl group R 5 is a linear alkyl group or an arylalkyl group having 1 to 8 carbon atoms, X − is a halide ion, CH 3 0S0 3 - or CH 3 CH 2 0S0 3 - R 1 and R 2 may be the same or different for each structural unit) 제4항 또는 제5항에 따라 제조된 폴리올레핀계 수지조성물이 입체 3차원구조를 갖는 성형체로 성형되어 이루어지는 것을 특징으로 하는 폴리올레핀계 수지조성체.The polyolefin resin composition according to claim 4 or 5, wherein the polyolefin resin composition is formed into a molded body having a three-dimensional three-dimensional structure. 하기 식(I)으로 나타낸 에틸렌구조 단위 80∼98몰%와, 하기식(Ⅲ)으로 나타낸 아크릴아미드구조 단위 2-20몰%가 선형상으로 배열되어 이루어지는 중량평균 분자량 1,000∼50,000의 카티온성 공중합체 (B) 또는 하기식 (I)으로 나타낸 에틸렌구조 단위 80∼90몰%와, 하기식(Ⅱ)으로 나타낸 아크릴레이트구조 단위 15몰%이하 및 하기식(Ⅲ)으로 나타낸 아크릴아미드구조 단위 2∼20몰%가 선형상으로 배열되어 이루어지는 중량평균 분자량 1,000∼50,000의 카티온성 공중합체(B)를 폴리올레핀계 수지(A)에 배합해서 성형하는 것을 특징으로 하는 대전 방지 능력을 구비한 폴리올레핀계 수지성형체의 충격강도향상방법.80 to 98 mol% of ethylene structural units represented by the following formula (I) and 2-20 mol% of acrylamide structural units represented by the following formula (III) are cationic air having a weight average molecular weight of 1,000 to 50,000 80 to 90 mol% of ethylene structural units represented by the copolymer (B) or the following formula (I), 15 mol% or less of the acrylate structural units represented by the following formula (II) and acrylamide structural units represented by the following formula (III): A polyolefin-based resin having an antistatic ability, characterized by blending a cationic copolymer (B) having a weight average molecular weight of 1,000 to 50,000, in which 20 mol% is arranged in a linear form, to the polyolefin-based resin (A). Method of improving the impact strength of the molded body. (상기 식에서, R1는 메틸기 또는 에틸기, R2는 에틴렌기 또는 프로필렌기, R3및 R4는 메틸기 R5는 탄소수 1∼8의 직선사슬형상 알킬기 또는 아릴알킬기, X-는 할로겐화물이온, CH30S03 -또는 CH3CH20S03 -를 나타낸다. R1, R2는 구조단위마다 동일하거나 다르더라도 좋다)(Wherein R 1 is a methyl group or an ethyl group, R 2 is an ethylene group or a propylene group, R 3 and R 4 are a methyl group R 5 is a linear alkyl group or an arylalkyl group having 1 to 8 carbon atoms, X − is a halide ion, CH 3 0S0 3 - or CH 3 CH 2 0S0 3 - R 1 and R 2 may be the same or different for each structural unit) 하기식(I)으로 나타낸 에틸렌구조 단위 80∼98몰%와, 하기식(Ⅲ)으로 나타낸 아크릴아미드구조 단위 2∼20몰%가 선형상으로 배열되어 이루어지는 중량평균 분자량 1,000∼50,000의 카티온성 공중합체(B) 또는 하기식(I)으로 나타낸 에틸렌구조 단위 80∼90몰%와, 하기식(Ⅱ)으로 나타낸 아크릴레이트구조 단위 15몰%이하와 하기식(Ⅲ)으로 나타낸 아크릴아미드구조 단위 2∼20몰%가 선형상으로 배열되어 이루어지는 중량평균 분자량 1,000∼50,000의 카티온성 공중합체(B)로 이루어지는 것을 특징으로 하는 대전방지성 부여능력을 구비한 폴리올레핀게 수지성형체용 충격강도 향상제80 to 98 mol% of ethylene structural units represented by the following formula (I) and 2 to 20 mol% of acrylamide structural units represented by the following formula (III) are cationic air having a weight average molecular weight of 1,000 to 50,000 80 to 90 mole% of ethylene structural units represented by copolymer (B) or the following formula (I), 15 mole% or less of acrylate structural units represented by the following formula (II) and acrylamide structural unit 2 represented by the following formula (III): Impact modifier for polyolefin crab resin moldings having an antistatic property imparting ability, characterized in that the cationic copolymer (B) having a weight average molecular weight of 1,000 to 50,000, wherein 20 mol% is arranged in a linear shape. (상기 식에서, R1는 메틸기 또는 에틸기, R2는 에틴렌기 또는 프로필렌기, R3및 R4는 메틸기 R5는 탄소수 1∼8의 직선사슬형상 알킬기 또는 아릴알킬기, X-는 할로겐화물이온, CH30S03 -또는 CH3CH20S03 -를 나타낸다. R1, R2는 구조단위마다 동일하거나 다르더라도 좋다)(Wherein R 1 is a methyl group or an ethyl group, R 2 is an ethylene group or a propylene group, R 3 and R 4 are a methyl group R 5 is a linear alkyl group or an arylalkyl group having 1 to 8 carbon atoms, X − is a halide ion, CH 3 0S0 3 - or CH 3 CH 2 0S0 3 - R 1 and R 2 may be the same or different for each structural unit) ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019940027800A 1993-10-29 1994-10-28 Polyolefin resin composition KR0166982B1 (en)

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KR1019980026530A KR0167048B1 (en) 1993-10-29 1998-06-27 Thermoplastic resin composition

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JP93-293941 1993-10-29
JP5293941A JPH07126446A (en) 1993-10-29 1993-10-29 Polyolefin resin composition
JP34613893A JP3420316B2 (en) 1993-09-24 1993-12-21 (Meth) acrylic resin composition
JP93-346138 1993-12-21

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KR950011528A true KR950011528A (en) 1995-05-15
KR0166982B1 KR0166982B1 (en) 1999-03-20

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR980011333A (en) * 1996-07-09 1998-04-30 원본미기재 Memory disk case with excellent antistatic properties
KR100416514B1 (en) * 2000-08-22 2004-01-31 (주)피앤디 method for producing transparent synthetic sheet

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR980011333A (en) * 1996-07-09 1998-04-30 원본미기재 Memory disk case with excellent antistatic properties
KR100416514B1 (en) * 2000-08-22 2004-01-31 (주)피앤디 method for producing transparent synthetic sheet

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KR0167047B1 (en) 1999-03-30

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