KR950008687B1 - Making method of sintering tappet for diesel and gasoline engine and tip composite - Google Patents

Making method of sintering tappet for diesel and gasoline engine and tip composite Download PDF

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KR950008687B1
KR950008687B1 KR1019920017269A KR920017269A KR950008687B1 KR 950008687 B1 KR950008687 B1 KR 950008687B1 KR 1019920017269 A KR1019920017269 A KR 1019920017269A KR 920017269 A KR920017269 A KR 920017269A KR 950008687 B1 KR950008687 B1 KR 950008687B1
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tip
tappet
diesel
reducing atmosphere
sintering
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KR1019920017269A
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KR940006668A (en
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조정환
김길호
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대우중공업주식회사
이경훈
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product

Abstract

A green compact as a chip material, composed of (by wt.) 2.0-2.5% C, 10-14% Cr, 0.5-2.0% Mo, 0.3-0.9% P, 0.1-0.5% Nb and balance Fe with inevitable imprities and formed to disc shape, is joined to the top surface of a cold-rolled low or medium carbon alloy steel tappet body by diffusion bonding method. The method comprises putting the tip on the top surface of the tappet body and maintaining at 1110-1190 deg.C of sintering temperature for 1hr. under reducing atmosphere, and tempering for oil-cooling after maintaining at 580-630 deg.C for 1hr. under reducing atmosphere, if a cooling rate is rapid enough to appear a quenching effects.

Description

디젤 및 가솔린 엔진용 소결 태핏의 제조방법 및 팁 조성물Manufacturing method and tip composition of sintered tappet for diesel and gasoline engine

제1도의 (a) (b) (c) (d)는 본 발명의 실시예 1의 제1샘플에 대한 소결온도에 따른 250배 현미경 확대도.(A), (b), (c) and (d) of FIG. 1 are enlarged 250 times microscope views according to the sintering temperature for the first sample of Example 1 of the present invention.

제2도의 (a) (b) (c) (d)는 본 발명 및 종래의 제2테스트 후 태핏면 상태도.Figure 2 (a) (b) (c) (d) is a state of the tappet surface after the second test and the present invention.

본 발명은 우수한 내점식성과 내마모성을 갖는 태핏의 제조방법에 관한 것으로, 특히 냉간단조(Forming)로 만든 몸체와 분말성형체 팁(Tip)의 확산접합으로 제조될 수 있는 모든 엔진기종의 태핏(Tappet)에 적용될 수 있게 한 디젤 및 가솔린 엔진용 소결태핏의 제조방법 및 팁 조성물에 관한 것이다.The present invention relates to a method for producing a tappet having excellent corrosion resistance and wear resistance, and in particular, tappets of all engine types that can be manufactured by diffusion bonding of a body made of cold forging and a powder molded tip. The present invention relates to a method for preparing a sintered tappet for diesel and gasoline engines and a tip composition.

먼저 엔진 태핏이라 함은 캠 샤프트의 캠부와 선접촉하여 흡기, 배기밸브의 개폐를 이루는 부품이다.First, the engine tappet is a part which opens and closes the intake and exhaust valves by making linear contact with the cam portion of the cam shaft.

이러한 종래의 태핏으로는 회주철을 냉경판(Chill Plate) 위에서 주조하여 만든 칠 주조품이나 침탄처리한 강제품 등이 사용되고 있다. 그러나 캠 샤프트와의 반복접촉하중에 의하여 캠 샤프트 및 태핏 모두에서 접촉부위가 떨어져 나가서 생기는 점식(Pitting) 및 이상마모(Scuffing) 등의 결함이 고질적으로 발생한다. 이러한 결함들에 대한 대책수립은 매우 어렵고 이에 따른 공정제어 또한 쉽지 않다.As such a conventional tappet, a chill cast product or a carburized steel product made by casting gray cast iron on a chill plate is used. However, defects such as pitting and scuffing, which are caused by the contact portions falling off both the cam shaft and the tappet due to the cyclic contact load with the cam shaft, occur consistently. Countermeasures against these defects are very difficult and the process control is not easy.

따라서 본 발명의 목적은 종래 태핏보다 월등한 내점식성과 내마모성을 갖는 태핏을 제조하여 엔진성능을 개선할 뿐만 아니라, 몸체의 냉간단조(Forming)와 성형체 팁을 확산접합하여 제작하므로 생산성 향상과 가공량을 줄이고 가공비 절감으로 태핏의 원가절감을 이룩하는데 있다.Therefore, the object of the present invention is to improve the engine performance by manufacturing a tappet having superior corrosion resistance and wear resistance than the conventional tappet, as well as to improve productivity and throughput by manufacturing the cold forging (forming) and the molded body tip of the body by diffusion bonding To reduce costs and reduce processing costs.

이하에서 이를 첨부도면에 의해 상세히 설명하면 다음과 같다.Hereinafter, described in detail by the accompanying drawings as follows.

분 발명은 태핏 몸체의 냉간단조와 성형체 팁의 확산접합공정으로 이루어진다. 여기서 캠 샤프트와 접촉되는 부위에서 1∼3mm까지를 태핏의 팁이라 하고, 몸체부는 그 나머지를 말하는 것이다. 즉 분말성형체를 1∼3mm정도의 디스크 형태로 성형한 후, 이것을 몸체위에 놓고 환원성분위기에서 소결하면, 팁은 소결되면서몸체에 확산접합된다. 이때 P(인)의 첨가로 인해 액상소결이 이루어지기 때문에 소결부(Tip)는 아주 치밀하게 된다. 태핏 형상은 제1도에 나타내었다.The invention consists of a cold forging of the tappet body and a diffusion bonding process of the molded body tip. Here, the tip of the tappet, which is in contact with the cam shaft, from 1 to 3 mm is called the tip of the tappet, and the body part refers to the rest. In other words, after the powder compact is molded into a disk shape of about 1 to 3 mm, and then placed on the body and sintered in a reducing atmosphere, the tip is sintered and diffusion-bonded to the body. At this time, since the liquid phase sintering is performed by the addition of P (phosphorus), the sintering part (Tip) becomes very dense. The tappet shape is shown in FIG.

본 발명에서 성형체 팁의 조성(중량 %)은 다음과 같다.The composition (weight%) of the molded body tip in the present invention is as follows.

C : 2.0∼2.5% Cr : 10∼14%C: 2.0 to 2.5% Cr: 10 to 14%

Mo : 0.5∼2.0% P : 0.3∼0.9%Mo: 0.5-2.0% P: 0.3-0.9%

Nb : 0.1∼0.5% Ni : 0.2∼2.5%Nb: 0.1-0.5% Ni: 0.2-2.5%

Fe : 77∼86.9%Fe: 77-86.9%

상기에서 각 원소가 합금에 미치는 영향을 보면, C은 탄화물 형성원소로서 마멸(Abrasion) 저항과 강도를 향상시키는 것으로, 2.0% 미만일 경우 탄화물량이 적게 되고, 2.5%를 초과할 경우 다량의 탄화물 형성으로 오히려 취약해진다.In view of the effect of each element on the alloy, C is a carbide forming element to improve the abrasion resistance and strength, less than 2.0% of the carbide amount is reduced, if it exceeds 2.5% to form a large amount of carbide Rather vulnerable.

Cr은 탄화물 형성원소이면서 기지강화원소이다. 10% 미만은 소결성이 좋아서 고밀도를 얻을 수 있으나, 본 발명에서는 팁과 본체의 접합을 이루는 소결온도에서 탄화물이 조대한 망상으로 나타나기 때문에 Cr은 10% 이상 되어야 하고 14%를 초과할 경우 소결성이 극히 떨어진다.Cr is a carbide forming element and a matrix strengthening element. Less than 10% is good sintering ability to obtain a high density, but in the present invention, since the carbide appears as a coarse mesh at the sintering temperature forming the tip and the body, Cr should be more than 10% and if the sinterability is more than 14% Falls.

Mo는 Cr과 더불어 탄화물 형성 원소이면서 기지강화원소이다. 0.5% 미만은 의미가 없고, 2.0% 초과시는 내마모성에 더이상 효과가 없다.Mo, together with Cr, is a carbide forming element and a matrix strengthening element. Less than 0.5% is meaningless, and above 2.0% is no longer effective for wear resistance.

P는 Fe 등과 더불어 공정액상을 형성하는 원소로서, 0.3% 미만은 액상량이 적어 몸체와 확산접합이 일어나기 어렵고, 0.9% 초과되면 액상량이 많이 생겨 본 발명의 소결온도에서 심한치수 변화가 일어나며, 또한 취약하게 된다.P is an element that forms a process liquid phase together with Fe, etc., less than 0.3% is difficult to cause diffusion bonding with the body due to the small amount of liquid phase, when more than 0.9%, a large amount of liquid phase is generated, severe dimension change occurs at the sintering temperature of the present invention, and also fragile Done.

Nb는 탄화물 형성 및 입자미세화 원소로서 0.1% 미만은 의미가 없고 0.5% 초과시 소결성이 떨어진다.Nb is a carbide-forming and fine grain element, meaning less than 0.1% and less than 0.5% sinterability.

Ni는 기지강화 원소로서, 0.2% 미만은 의미가 없고, 2.5% 초과시 강도증가가 더 이상 일어나지 않고 내마모성이 떨어진다.Ni is a matrix-reinforced element, less than 0.2% is meaningless, and when it exceeds 2.5%, strength no longer occurs and wear resistance is inferior.

상기 언급한 조성으로된 팁분말은 1∼3mm두께의 디스크 형태로 치밀하게 한후, 냉간단조용 소재(일반 중탄소강 또는 구조용 중탄소합금강)로 냉간 단조한 몸체위에 놓고 환원성분위기에서 소결을 실시한다. 소결온도 1110∼1190℃로 하고, 환원성 분위기로는 Ar분압을 이용한 저진공이나, 분해 NH3가스 혹은 N2,H2혼합가스 등이 이용된다. 소결시간은 소결온도에서 1시간 정도면 팁은 소결되면서 동시에 몸체에 확산접합된다.The tip powder of the above-mentioned composition is compacted in the form of a disk having a thickness of 1 to 3 mm, and then placed on a cold forged body with a cold forging material (general medium carbon steel or structural medium carbon alloy steel) and sintered in a reducing atmosphere. The sintering temperature is set at 1110 to 1190 ° C, and low vacuum using Ar partial pressure, decomposed NH 3 gas or N 2, H 2 mixed gas is used as the reducing atmosphere. When the sintering time is about 1 hour at the sintering temperature, the tip is sintered and diffusion bonded to the body at the same time.

여기서 소결온도가 1110℃ 이하이면 액상형성이 불충분하여 접합불량이 초래되며 1190℃ 이상에서는 접합은 양호하나 망상탄화물이 생성되며 피로수명이 낮아진다. 이때 팁성형체의 두깨를 1mm 이하로 하면 접합후 마찰면의 두께가 바람직하지 못하게 되며, 3mm를 초과하면 원가측면에서 비경제적이므로 바람직하지 않다.If the sintering temperature is 1110 ℃ or less, the liquid phase formation is insufficient, resulting in poor bonding. Above 1190 ℃, the bonding is good, but network carbides are formed and fatigue life is low. In this case, when the thickness of the tip molded body is 1 mm or less, the thickness of the friction surface after bonding becomes undesirable, and when it exceeds 3 mm, it is not preferable because it is uneconomical in terms of cost.

이상과 같이 소결과정이 끝나면 조직을 안전시키기 위해 열처리 단게로 들어가는데, 소결후 냉각속도가 느린경우에는 진공 또는 환원성 분위기하에서 1000℃로 1시간정도 유지후 유냉시키는 담금질(Quenching)처리를 실시하는데, 1000℃ 이하에서는 기지조직이 오스테나이트화 하지 않아 냉각의 마르텐사이트가 되지 않고(펄라이트 잔존) 1050℃ 이상에서는 입자가 성장하여 취약해지고 액상이 형성되어 냉각시 균열이 발생될 수 있다.When the sintering process is completed as described above, to enter the heat treatment step to secure the structure, if the cooling rate is slow after sintering, it is subjected to a quenching process to cool the oil after maintaining for 1 hour at 1000 ℃ in a vacuum or reducing atmosphere, 1000 Below ℃, the matrix structure does not become austenite and does not become martensite of cooling (remaining pearlite). Above 1050 ℃, particles grow and become brittle, and a liquid phase is formed, which may cause cracks upon cooling.

재차 환원성 분위기하에서 580∼630℃로 1∼1.5시간 유지후 유냉시키는 템퍼링(Tempering)처리를 실시한다. 여기서 템퍼링처리를 하지 않거나, 또는 580℃ 이하온도 또는 1시간 이하의 시간으로 실시하면, 가공시 연마균열이 발생하거나 잔류응력에 의한 치수변형이 가능하며 한편, 탬퍼링을 630℃ 이상의 고온이나 장시간 실시하면 기지조직이 연화되어 내마모성 저하요인이 된다.Tempering treatment is then carried out for oil cooling after holding for 1 to 1.5 hours at 580 to 630 캜 in a reducing atmosphere. If the tempering treatment is not performed or the temperature is 580 ° C. or less or 1 hour or less, abrasive cracking may occur during processing or dimensional deformation due to residual stress may be performed. On the other hand, tempering is performed at a high temperature of 630 ° C. or higher for a long time. If the base tissue is softened, wear resistance is reduced.

한편, 소결후 냉각속도가 빠를 경우에는 상기와 같은 조건으로 테퍼링 처리만 실시한다. 이와 같이 열처리 과정을 거치게 되면 태핏은 탬퍼드 마르텐사이트(Tempered Martensite) 기지조직과 탄화물과 포어(Pore) 조직으로 형성된 본 발명이 목적하는바 양호한 제품을 얻게 된다.On the other hand, if the cooling rate after sintering is fast, only the tapering treatment is performed under the above conditions. When the heat treatment is carried out as described above, the tappet obtains a good product as desired by the present invention formed of a tampered martensite matrix and carbide and pore tissue.

실시예를 통하여 본 발명을 보다 상세히 설명한다.The present invention will be described in more detail with reference to examples.

[실시예 1]Example 1

표1과 같은 조성비율로 팁 성형체용 분말을 2mm 두께의 디스트형태로 성형한 후,After molding the powder for the tip molded body in the form of disc of 2mm thickness at the composition ratio as shown in Table 1,

[표 1]TABLE 1

냉간단조용 강(여기서는 SM 45C)을 냉간단조하여 제작한 몸체위에 상기 조성 각각의 팁 성형체를 올려 놓고 N2와 H2혼합가스 황원성 분위기하에서 표2와 같이 소결온도를 서로 달리하여 소결한 후 환원성 분위기하에서 열처리를 실시하였다.On the body made by cold forging the cold forging steel (here SM 45C), the tip molded body of each composition is placed and sintered at different sintering temperatures as shown in Table 2 under N 2 and H 2 mixed gas sulfuric atmosphere, and then reducing Heat treatment was performed in an atmosphere.

[표 2]TABLE 2

그 결과 Sample 1과 2에서는 소결온도가 1170℃와 118℃에서 접합과 조직이 가장 양호하게 나타났으며, 특히 Sample 2에서는 Ni가 첨가되므로서 기지조직이 강화되었다.As a result, in Samples 1 and 2, the sintering temperature was best at 1170 ℃ and 118 ℃, and especially the sample structure was strengthened by adding Ni.

Sample 3에서는 P를 다량(0.65%) 첨가함으로서 소결온도 1110℃와 1130℃에서도 접합이 양호하게 이루어졌다.In Sample 3, a large amount of P (0.65%) was added, thereby achieving good bonding at the sintering temperatures of 1110 ° C and 1130 ° C.

한편, Sample 1,2,3 모두 소결온도 1200℃에서는 탄화물 조직이 조대해져서 취약하게 나타났다.On the other hand, samples 1, 2, 3 showed a weak carbide structure coarse at the sintering temperature of 1200 ℃.

제1도는 Sample 1의 각각의 소결온도에 따른 몸체와 팁의 확산접합 상태를 나타내는 현미경 사진이다.1 is a micrograph showing the diffusion bonding state of the body and the tip according to the sintering temperature of each sample 1.

[실험 예]Experimental Example

실시예 1로부터 취출한 본 발명재 태핏과 종래의 태핏을 표 3과 같이 리그 테스트(Rig Test)를 실시하였다.A rig test was performed on the inventive tappet and the conventional tappet taken out from Example 1 as shown in Table 3.

[표 3]TABLE 3

상기 실험결과에 대한 태핏면 상태는 제2도에 나타내었다.Tappet surface conditions for the experimental results are shown in FIG.

상기 표 3에서와 같이 본 발명의 엔진 태핏은 종래 태핏종류들 보다 우수한 내점식성 및 내마모성을 가지고 있다. 따라서 엔진의 고성능화, 고출력화를 이룰수 있을 뿐 아니라, 종래 태핏과 캡 샤프트의 고질적인 문제점이 되고 있는 점식이나 마멸의 문제를 방지 할 수 있기 때문에 품질개선의 의미 또한 크다.As shown in Table 3, the engine tappet of the present invention has excellent corrosion resistance and wear resistance than conventional tappet types. Therefore, it is possible to achieve high performance and high output of the engine, and to improve the quality of the engine because it can prevent the problem of sticking and abrasion, which is a problem of the conventional tappet and cap shaft.

그리고 본 발명의 엔진 태핏은 제조공정이 중탄소강등의 코일 형태를 냉간단조에 의하여 만든 몸체에 갬샤프트와 접촉하는 부위만 두께 1∼3mm의 디스크 형태로 팁을 확산접합시킨 것이기 때문에, 종래 태핏에 비해 생산성도 뛰어나고 대량생산도 가능하다. 또한 거의 제품 치수에 가깝게 몸체가 냉간단조되기 때문에 종래 태핏에 비해 기계가공량도 적고 연마공정만으로 가공이 되므로 가공비도 훨씬 줄어든다. 이에따라 제작된 본 발명의 태핏은 종래 태핏에 비하여 원가절감을 이룰 수가 있다.In the engine tappet of the present invention, since the manufacturing process is diffusion-bonding a tip in the form of a disk having a thickness of 1 to 3 mm only to a part made of a cold carbon forging, such as a medium carbon steel, in contact with a gam shaft, Compared with productivity, mass production is also possible. In addition, since the body is cold forged close to the dimensions of the product, compared to the conventional tappets, the amount of machining is less, and the machining cost is much reduced because only the polishing process is performed. The tappet of the present invention produced according to this can achieve a cost reduction compared to the conventional tappet.

Claims (8)

중탄소강 또는 중탄소 합금강을 냉간단조하여 만들어진 몸체에 중량비로 C : 2.0∼2.5%, Cr : 10∼14%, Mo : 0.5∼2.0%, P : 0.3∼0.9%, Nb : 0.1∼0.5%, 나머지 Fe로 구성된 팁 성형체용 분말을 디스크 형태로 성형하여 상기 몸체의 일단부 위에 놓고 환원성 분위기하에서 1110∼1190℃의 소결온도로 1시간 정도 유지하여 상기 팁이 몸체에 확산접합되게 한 후, 냉각속도가 담금질 효과가 나타날 정도로 빠를 경우 환원성 분위기하에서 580∼630℃로 1시간 유지후 유냉시키는 탬퍼링처리를 해서 됨을 특징으로 한 디젤 및 가솔린 엔진용 소결 태핏의 제조방법.C: 2.0 to 2.5%, Cr: 10 to 14%, Mo: 0.5 to 2.0%, P: 0.3 to 0.9%, Nb: 0.1 to 0.5%, by weight ratio to the body made by cold forging of medium or heavy carbon alloy steel After forming the powder for the tip molded body consisting of the remaining Fe in the form of a disk and placed on one end of the body and maintained for 1 hour at a sintering temperature of 1110 ~ 1190 ℃ in a reducing atmosphere, the tip is diffusion-bonded to the body, the cooling rate The method of manufacturing a sintered tappet for diesel and gasoline engines, characterized in that if the quenching effect is fast enough to be tempered to maintain the oil after cooling for 1 hour at 580 ~ 630 ℃ in a reducing atmosphere. 제1항에 있어서, 팁 성형체용 분말에 Ni : 0.2∼2.5%를 첨가하는 것을 특징으로 하는 디젤 및 가솔린 엔진용 소결 태핏의 제조방법.The method for producing a sintered tappet for a diesel and gasoline engine according to claim 1, wherein Ni: 0.2% to 2.5% is added to the powder for the tip molded body. 제1항에 있어서, 팁의 두께가 1∼3mm인 것을 특징으로 하는 디젤 및 가솔린 엔진용 소결 태핏의 제조방법.The method of claim 1, wherein the tip has a thickness of 1 to 3 mm. 제1항에 있어서, 환원성 분위기는 Ar분압을 이용한 저진공분위기에 분해 NH3, 가스분위기 또는 N2와 H2혼합가스 분위기중 하나인 것을 특징으로 하는 디젤 및 가솔린 엔진용 소결 태핏의 제조방법.The method of claim 1, wherein the reducing atmosphere is one of decomposition NH 3 , gas atmosphere, or N 2 and H 2 mixed gas atmosphere in a low vacuum atmosphere using Ar partial pressure. 제1항에 있어서, 소결후의 열처리 단계는 냉각속도가 느릴 경우, 진공 또는 환원성 분위기에서 1000∼1050℃로 1시간정도 유지후 담금질 처리하는 단계를 탬퍼링 처리전에 갖는 것을 특징으로 하는 디젤 및 가솔린 엔진용 소결 태핏의 제조방법.The method of claim 1, wherein the heat treatment step after sintering is a diesel and gasoline engine having a step of quenching after holding for about 1 hour at 1000 to 1050 ° C. in a vacuum or reducing atmosphere when the cooling rate is slow. Method for producing sintered tappets 제1항에 있어서, 팁은 탬퍼드 마르텐사이트(Tempered Martensite) 기지조직과 탄화물과 포어(Pore) 조직으로 됨을 특징으로 하는 디젤 및 가솔린 엔진용 소결 태핏의 제조방법.The method of claim 1, wherein the tip is made of Tampered Martensite matrix and carbide and pores. 중량비로 C : 2.0∼2.5%, Cr : 10∼14%, Mo : 0.5∼2.0%, P : 0.3∼0.9%, Nb : 0.1∼0.5, 나머지 Fe로 조성됨을 특징으로 한 디젤 및 가솔린 엔진용 태핏의 팁 조성물.Tappet for diesel and gasoline engines, characterized by C: 2.0 to 2.5%, Cr: 10 to 14%, Mo: 0.5 to 2.0%, P: 0.3 to 0.9%, Nb: 0.1 to 0.5, remaining Fe Tip composition. 제7항에 있어서, Ni : 0.2∼2.5%를 첨가한 것을 특징으로 하는 디젤 및 가솔린 엔진용 태핏의 팁 조성물.The tip composition of the tappet for diesel and gasoline engines according to claim 7, wherein Ni is added in an amount of 0.2 to 2.5%.
KR1019920017269A 1992-09-22 1992-09-22 Making method of sintering tappet for diesel and gasoline engine and tip composite KR950008687B1 (en)

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KR20160082616A (en) * 2014-12-26 2016-07-08 주식회사 포스코 Iron-based diffusion bonded powders and method for manufacturing the same
KR20160080823A (en) * 2014-12-26 2016-07-08 주식회사 포스코 Iron-based diffusion bonded powders and method for manufacturing the same

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KR100471599B1 (en) * 2001-01-29 2005-03-07 엠.제이.테크(주) Vehicle engine tappet
KR100399315B1 (en) * 2001-03-26 2003-09-26 연우인더스트리(주) High strength abrasive wheel

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160082616A (en) * 2014-12-26 2016-07-08 주식회사 포스코 Iron-based diffusion bonded powders and method for manufacturing the same
KR20160080823A (en) * 2014-12-26 2016-07-08 주식회사 포스코 Iron-based diffusion bonded powders and method for manufacturing the same

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