KR950005963A - Alternative fuel oil, its manufacturing method and its manufacturing apparatus - Google Patents

Alternative fuel oil, its manufacturing method and its manufacturing apparatus Download PDF

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KR950005963A
KR950005963A KR1019930016613A KR930016613A KR950005963A KR 950005963 A KR950005963 A KR 950005963A KR 1019930016613 A KR1019930016613 A KR 1019930016613A KR 930016613 A KR930016613 A KR 930016613A KR 950005963 A KR950005963 A KR 950005963A
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oil
waste
weight
parts
water
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KR960014923B1 (en
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박수환
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박수환
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Lubricants (AREA)

Abstract

이 발명은 각 산업체에서 배출되는 각종의 폐유, 폐식용유, 유기폐수, 도금폐수, 염색폐수 등의 폐액을 처리하여 산업용연료유로 사용할 수 있도록 한 보일러용 대체연료유 및 그 제조방법과 그 장치에 대한 것이다.The present invention is to treat a variety of waste oil, waste edible oil, organic waste water, plating waste water, dyeing waste water discharged from each industry, alternative fuel oil for a boiler and a method for manufacturing the same and an apparatus thereof for use as industrial fuel oil will be.

산업체에서 수집한 각종의 폐액을 필터프레스에 의해 예비처리한 폐약과 저유황벙커 C유와 무기염 조성물 용액 함유물을 각각의 처리조에서 온도 80∼100℃에서약 30분간 예비처리시키고, 진공혼합기내에서 100-120rpm의 회전속도로 10∼20분간 진공혼합시켜 혼합액의 성분간의 이온결합을 용이하게 하도록 1차 유화처리를 촉진하며, 유화기내에서 고속(1200∼1500rpm)으로 1차 유화처리한 혼합용액을 스크루축의 테이퍼형성부의 간극에서 마찰에 의해 그 혼합물용액의 물분자를 더 적은 입자로 분리시켜 최종적인 유화처리로 유수분리가 장시간 발생하지 않도록 한 보일러용 대체연료유를 얻는다.Various waste liquids collected by industry were pretreated by filter press, and low sulfur bunker C oil and inorganic salt composition solution contents were pretreated in a respective treatment tank at a temperature of 80 to 100 ° C. for about 30 minutes, and mixed in a vacuum. Vacuum emulsification is carried out for 10-20 minutes at a rotational speed of 100-120rpm in the aircraft to facilitate ionic bonds between the components of the mixed solution, and the primary emulsification at high speed (1200-1500rpm) in the emulsifier The solution separates the water molecules of the mixture solution into smaller particles by friction in the gap between the tapered portions of the screw shaft, and thus obtains alternative fuel oil for boilers in which the oil-water separation does not occur for a long time by the final emulsification treatment.

폐액으로 엔진폐유, 폐식용유, 유기폐수, 도금폐수, 염색폐수, 오염폐슈등 사용하여 그 폐액 40%, 저유황 벙커 C유 30%, 무기염 조성물 용액 함유물 30%로 진공혼합시켜 유수분리가 장시간 (40)일 발생하지 않도록 한 대체연료유가 얻어진다.Using waste oil such as engine waste oil, cooking oil, organic waste water, plating waste water, dyeing waste water, polluted waste shoe, etc., vacuum mixing the waste liquid 40%, low sulfur bunker C oil 30%, inorganic salt composition solution 30% Alternative fuel oils are obtained which do not occur for a long time (40) days.

무기염 조성물 용액은 Na2Co310∼80 중량부, NaHCo310∼100 중량부, NaCl230∼90중량부, NaCl 10~90 중량부, MgC2l40∼70 중량부, 물 100 중량부로 조성되어 있다.The inorganic salt composition solution is 10 to 80 parts by weight of Na 2 Co 3, 10 to 100 parts by weight of NaHCo 3 , 30 to 90 parts by weight of NaCl 2 , 10 to 90 parts by weight of NaCl, 1 to 40 parts by weight of MgC 2 , and 100 parts by weight of water. It is formed.

이 대체연료유는 발열량 및 오염물질 농도 그리고 성분분석결과 보일러용 연료유로서 환경처가 고시한 기준에 적합하여 저유황 벙커 C유의 절약과 폐액처리에 효과적이다.The alternative fuel oil is effective for saving low sulfur bunker C oil and treating waste liquid as it meets the standards announced by the Ministry of Environment as a fuel oil for boilers as a result of calorific value, pollutant concentration, and component analysis.

Description

대체연료유 및 그 제조방법과 그 제조장치Alternative fuel oil, its manufacturing method and its manufacturing apparatus

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

첨부도면은 이 발명에 의한 처리장치의 개략사시도.The accompanying drawings are schematic perspective views of the processing apparatus according to the present invention.

Claims (10)

보일러용 대체연료유에 있어서, 필터프레스(filter press)를 장치한 진공탱크차량을 이용하여 산업체에서 수집한 각종의 폐액을 필터프레스에 의해 예비처리한 폐액과, 저유황벙커 C유와 무기염 조성물용액 함유물을 각각 처리조에 처리액 유입관을 통해서 유입시켜 히터에 의해 온도 80∼100℃에서 약 30분간 가열하고, 진공혼합기내에서 100∼120rpm의 회전속도로 10∼20분간 진공상태(7∼10㎏/㎠)에서 혼합시켜 혼합액의 성분간의 이온 결합을 용이하게 하도록 1차유화처리를 하며, 스크루마찰형 유화기내에서 1200∼1500rpm의 고속으로 그 혼합액을 스크루축말단의 테이퍼 형성부에서 마찰시켜 혼합액의 물분자를 더작은 입자로 분리시켜 최종적인 유화처리로 유수분리가 일어나지 않도록 처리하여 얻어진 위 대체연료유.In the alternative fuel oil for boiler, waste liquid obtained by pretreatment of various waste liquids collected by industry using a vacuum tank vehicle equipped with a filter press by filter press, low sulfur bunker C oil and inorganic salt composition solution The contents were respectively introduced into the treatment tank through the treatment liquid inlet tube, and heated by the heater at a temperature of 80 to 100 ° C. for about 30 minutes, and in a vacuum mixer for 10 to 20 minutes at a rotation speed of 100 to 120 rpm (7 to 10 minutes). Kg / cm 2) to facilitate ionic bonding between the components of the mixed solution, and the mixed solution is rubbed at the taper forming end of the screw shaft at high speed of 1200 to 1500 rpm in the screw friction type emulsifier. The above alternative fuel oil obtained by separating the water molecules of smaller particles into smaller particles so that no oil-water separation occurs in the final emulsion treatment. 제1항에 있어서, 위 폐액을 엔진폐유로 사용하여, 그 엔진폐유 40%, 저유황벙커 C유 30%, 무기염조성물 용액 함유물 30%로 진공혼합 처리시켜 유수분리가 장시간(40일) 발생하지 않도록 한위 대체연료유.2. The oily waste separation according to claim 1, wherein the waste gas is used as an engine waste oil, and the mixture is vacuum mixed with 40% of the waste oil, 30% of the low sulfur bunker C oil, and 30% of the inorganic salt composition solution. Alternative fuel oil to avoid occurrence. 제1항에 있어서, 위 폐액을 폐식용유로 사용하여, 그 폐식용유 40%, 저유황벙커 C유 30%, 무기염조성물용액 함유물 30%로 진공혼합 처리시켜 유수분리가 장시간(40일) 발생하지 않도록 한위 대체연류유.The gastric waste solution of claim 1, which is used as waste cooking oil, is vacuum mixed with 40% of the waste cooking oil, 30% of low sulfur bunker C oil, and 30% of the inorganic salt composition solution to separate oily water for a long time (40 days). Alternative condensed oil to avoid occurrence. 제1항에 있어서, 위 무기염 조성물용액은, Na2Co310∼80 중량부, NaHCo310∼100 중량부, NaCl230∼90중량부, NaCl 10∼90 중량부, MgCl240∼70 중량부, 물 100 중량부로 처리한 용액임을 특징으로 한 위 대체연료유.According to claim 1, The inorganic salt composition solution, Na 2 Co 3 10 to 80 parts by weight, NaHCo 3 10 to 100 parts by weight, NaCl 2 30 to 90 parts by weight, NaCl 10 to 90 parts by weight, MgCl 2 40 ~ The above alternative fuel oil, characterized in that the solution treated with 70 parts by weight, 100 parts by weight of water. 보일러용 대체연료유의 제조방법에 있어서, 필터프렝스를 장치한 진공탱크차량을 이용하여 산업체에서 수집한 각종의 폐액을 필터프렝스로 여과처리한 폐액과, 저유황벙커 C유 및 무기염 조성물 용액 함유물을 각각의 처리조에 유입시켜 80∼100℃의 온도로 약 30분간 가열처리시켜 다음의 1차유화처리를 효과적으로 수행하도록 하는 제1공정과, 제1공정에서 얻어진 처리액 각각을 진공혼합기내에 유입시켜 이온결합이 형성되도록 진공상태에서 (7∼10㎏/㎠) 100∼120rpm의 회전속도로 10∼20분간 혼합시켜 1차적인 유화처리로 유수분리가 일어나지 않도록 하는 제2공정과, 제2공정에서 얻어진 혼합액을 스크루마찰형 유화기내에서 스크루회전축의 회전을 1200∼1500rpm의 고속으로 하여 스크루 축말단의 테이퍼 형성부에서 마찰시켜 혼합액의 물분자를 더작은 입자로 더 분리시켜 최종적인 유화처리에 의해 유수분리가 장시간 일어나지 않도록 처리시키는 제3공정으로 구성함을 특징으로 하는 위 제조방법.In the method for producing alternative fuel oil for boiler, the waste liquid obtained by filtering various waste liquids collected by industry using a vacuum tank vehicle equipped with a filter strength with a filter strength, and a low sulfur bunker C oil and an inorganic salt composition solution The first step and the processing liquid obtained in the first step are introduced into the respective treatment tanks, and heated at a temperature of 80 to 100 ° C. for about 30 minutes to effectively carry out the following first emulsification treatment. A second step of mixing oil for 10 to 20 minutes at a rotational speed of 100 to 120 rpm in a vacuum state (7 to 10 kg / cm 2) to form an ionic bond by inflow, thereby preventing oil-water separation from occurring through a primary emulsion treatment; The mixed liquid obtained in the process was subjected to high speed of 1200-1500rpm in the screw friction type emulsifier, and was rubbed at the taper forming part of the screw shaft end to make the water molecules of the mixed liquid smaller. Further isolated by the above method, it characterized in that the configuration in the third step of the oil water separator to ensure that they do not occur for a long time by the final emulsification process characters. 제5항에 있어서, 위 폐액으로 엔진폐유를 사용하며, 그 엔진페유 40%, 저벙커 C유 30%, 무기염조성물 용액 함유물 30%로 처리시켜 유수분리가 장시간 발생하지 않도록 하는 위 제조방법.The method of claim 5, wherein the engine waste oil is used as the gastric waste liquid, and the engine waste oil is treated with 40% of the engine waste oil, 30% of the low bunker C oil, and 30% of the inorganic salt composition solution to prevent oil-water separation from occurring for a long time. . 제5항에 있어서, 위 폐액을 폐식용유로 사용하며 그 폐식용유 40%, 저유황벙커 C유 30%, 무기염조성물 용액 함유물 30%로 혼합처리시켜 유수분리가 장시간 일어나지 않도록 한 위 제조방법.The method according to claim 5, wherein the waste gas is used as waste cooking oil and mixed with 40% of the waste cooking oil, 30% of low sulfur bunker C oil, and 30% of an inorganic salt composition solution to prevent oil-water separation from occurring for a long time. . 제5항에 있어서, 위 무기염 조성물용액은 NaCo318∼80 중량부, NaHCo310∼100중량부, NaCl230∼90중량부, NaCl 10~90 중량부, MgCl240∼70중량부, 물 100중량부로 조성시켜 얻어진 용액을 사용함을 특징으로 하는 위 제조방법.According to claim 5, The inorganic salt composition solution is NaCo 3 18 to 80 parts by weight, NaHCo 3 10 to 100 parts by weight, NaCl 2 30 to 90 parts by weight, NaCl 10 to 90 parts by weight, MgCl 2 40 to 70 parts by weight Method for producing a stomach, characterized in that using the solution obtained by composition with 100 parts by weight of water. 보일러용 대체연료유 제조장치에 있어서, 공통으로 히터(H)를 내장하여 그 히터에 의해 80∼100℃로 유지하도록 하는 각각의 저유황 벙커 C유, 폐액 및 무기염조성물용액 함유물의 처리조(10, 10', 10")와, 진공혼합기(17)내에서 이온결합의 용이하게 이루어지도록 100∼120rpm의 회전 속도로 진공혼합시켜 휴화처리시킴으로써 유수분리가 발생하지 않게하는 진공혼합수단과, 축(23)에 정착한 스쿠르(23)가 벨트폴리(27)의 조작에 의해 1200~1500rpm의 고속으로 회전함으로서 유화처리액이 유화기(26)내 스크루축말단의 데이퍼형성부의 간극(30)에서 마찰을 발생하여 그 유화처리액의 물입자를 더작은 입자로 분리시켜 유화처리를 촉진시키며, 조절기어(20)의 조작에 의해 스크루축 전체길이를 더 길게 또는 더 짧게 조절하여 유화처리액의 최적의 유화가 되도록 하여 유수 분리가 일어나지 않도록 한 유화처리장치를 구성함을 특징으로 하는 위 대체연료유 제조장치.In the alternative fuel oil manufacturing apparatus for boilers, a treatment tank of each of the low sulfur bunker C oil, waste liquid and inorganic salt composition solution containing a heater (H) in common and maintained at 80 to 100 ° C by the heater ( 10, 10 ', 10 ") and vacuum mixing means for vacuum-mixing at a rotational speed of 100 to 120 rpm so as to facilitate ionic bonding within the vacuum mixer 17, thereby restoring oil-water separation, and shafting. The screw 23 settled in (23) rotates at a high speed of 1200 to 1500 rpm by the operation of the belt pulley 27, so that the emulsion treatment liquid has a gap 30 at the taper forming portion at the screw shaft end in the emulsifier 26. Friction is generated in the emulsion to separate the water particles into smaller particles to facilitate the emulsification process, and by adjusting the length of the screw shaft longer or shorter by operating the control gear 20 To achieve optimum oil painting Above alternative fuel oil producing system, it characterized in that the separation to configure the apparatus so that the emulsion occur. 제9항에 있어서, 그 유화처리장치에서 그 스크루축말단의 테이퍼형성부의 간극(30)은 1∼2㎜로 되게 조절시켜 유화처리액이 마찰에 의해 유수분리가 일어나지 않도록 물입자를 더 작은 입자로 분리시키며, 유화처리가 잘 되지 않을 경우 그 조절기어(20)를 조절하여 그 간극을 더 좁게 형성함으로써 그 유화처리액이 강한 마찰을 할 수 있도록 하여, 그 유화기(26)를 미세공원판(29) 쪽으로 경사지게 설치함을 특징으로 한 위 대체연료유 제조장치.10. The method of claim 9, wherein in the emulsion treatment apparatus, the gap 30 of the tapered portion at the screw shaft end is adjusted to be 1 to 2 mm so that the water particles are smaller than the oil particles so that the oil treatment does not occur by friction. If the emulsification treatment is not good, the control gear 20 is adjusted to form a narrower gap, so that the emulsifying liquid can be subjected to strong friction, and the emulsifier 26 is finely divided. The above alternative fuel oil manufacturing apparatus, characterized in that the installation inclined toward (29). ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930016613A 1993-08-25 1993-08-25 Refined fuel oil and the preparation method KR960014923B1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030095555A (en) * 2002-06-12 2003-12-24 구본석 waste oil burner system
KR100770778B1 (en) * 2006-06-05 2007-11-01 한국엑스오일 주식회사 Method of alternative fuel
KR100804574B1 (en) * 2006-06-20 2008-02-20 박수환 Manufacturing apparatus of alternative combustion fuel for industrial boiler and manufacturing meihod of alternative combustion fuel for industrial boiler

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100645982B1 (en) * 2006-04-28 2006-11-15 이명주 Method of preparing emulsified fuel from waste material
KR100952167B1 (en) * 2008-05-01 2010-04-09 주식회사 넥스오일 Vacuum agitator combined Methanol distiller for marking bio-diesel and bio-diesel manufacturing process thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030095555A (en) * 2002-06-12 2003-12-24 구본석 waste oil burner system
KR100770778B1 (en) * 2006-06-05 2007-11-01 한국엑스오일 주식회사 Method of alternative fuel
KR100804574B1 (en) * 2006-06-20 2008-02-20 박수환 Manufacturing apparatus of alternative combustion fuel for industrial boiler and manufacturing meihod of alternative combustion fuel for industrial boiler

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