KR950003331A - 변형된 아크릴고무를 기초한 경화성 조성물 - Google Patents
변형된 아크릴고무를 기초한 경화성 조성물 Download PDFInfo
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- KR950003331A KR950003331A KR1019940015087A KR19940015087A KR950003331A KR 950003331 A KR950003331 A KR 950003331A KR 1019940015087 A KR1019940015087 A KR 1019940015087A KR 19940015087 A KR19940015087 A KR 19940015087A KR 950003331 A KR950003331 A KR 950003331A
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- 239000000203 mixture Substances 0.000 title claims abstract 17
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims 2
- 229920000800 acrylic rubber Polymers 0.000 title 1
- 229920000058 polyacrylate Polymers 0.000 title 1
- 239000000178 monomer Substances 0.000 claims abstract 22
- 229920001198 elastomeric copolymer Polymers 0.000 claims abstract 16
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract 6
- 125000003118 aryl group Chemical group 0.000 claims abstract 3
- 238000006116 polymerization reaction Methods 0.000 claims abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract 2
- 125000001931 aliphatic group Chemical group 0.000 claims abstract 2
- 229920001971 elastomer Polymers 0.000 claims 7
- 239000000806 elastomer Substances 0.000 claims 7
- 238000000034 method Methods 0.000 claims 6
- -1 allyl diglycidyl ether Chemical compound 0.000 claims 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 3
- 239000002253 acid Substances 0.000 claims 3
- 239000003795 chemical substances by application Substances 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- 239000011593 sulfur Substances 0.000 claims 3
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 claims 2
- 150000003863 ammonium salts Chemical class 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 claims 2
- 229920001567 vinyl ester resin Polymers 0.000 claims 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims 1
- 239000005642 Oleic acid Substances 0.000 claims 1
- 239000004952 Polyamide Substances 0.000 claims 1
- 235000021355 Stearic acid Nutrition 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 150000001447 alkali salts Chemical class 0.000 claims 1
- 230000003712 anti-aging effect Effects 0.000 claims 1
- 239000003963 antioxidant agent Substances 0.000 claims 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000006229 carbon black Substances 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 239000012990 dithiocarbamate Substances 0.000 claims 1
- 150000004659 dithiocarbamates Chemical class 0.000 claims 1
- 239000000975 dye Substances 0.000 claims 1
- XJELOQYISYPGDX-UHFFFAOYSA-N ethenyl 2-chloroacetate Chemical compound ClCC(=O)OC=C XJELOQYISYPGDX-UHFFFAOYSA-N 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 claims 1
- 150000002367 halogens Chemical class 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims 1
- 239000000314 lubricant Substances 0.000 claims 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims 1
- 239000000049 pigment Substances 0.000 claims 1
- 239000004014 plasticizer Substances 0.000 claims 1
- 229920002647 polyamide Polymers 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- 230000000750 progressive effect Effects 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229920006395 saturated elastomer Polymers 0.000 claims 1
- 235000003441 saturated fatty acids Nutrition 0.000 claims 1
- 150000004671 saturated fatty acids Chemical class 0.000 claims 1
- 239000008117 stearic acid Substances 0.000 claims 1
- 150000003852 triazoles Chemical class 0.000 claims 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims 1
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
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- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/02—Monomers containing chlorine
- C08F214/04—Monomers containing two carbon atoms
- C08F214/06—Vinyl chloride
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
- C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
- C08F216/14—Monomers containing only one unsaturated aliphatic radical
- C08F216/1416—Monomers containing oxygen in addition to the ether oxygen, e.g. allyl glycidyl ether
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- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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Abstract
탄성체 공중합물은; a) 일반식 CH2=CR´-CO-OR에서 선택된 단량체, 이때 R은 직쇄 또는 분지쇄 C1-C6알킬 라디칼에서 선택된 단기능기 라디칼; b)(매트) 아크릴로니트릴; c) c1) 염소화된 비닐 에스테르; c2) 불포화된 카르복실산과 지방족 또는 방향족 디에폭시 조성물의 혼합물; c3) 염소화된 비닐에스테르와 불포화된 카르복실산으로 구성된 혼합물의 중합반응에 의해 수득된다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (19)
- a) 단량체는 일반식 CH2=CR´-CO-OR을 가지는 것에서 선택되고, 이때 R은 직쇄 또는 분지쇄 C1-C6알킬 라디칼 그리고 C1-C6 알콕시알킬 라디칼에서 선택된 Ⅰ가 기능기 라디칼이 되고 R´는 H와 CH3에서 선택되며; b)(매트) 아크릴로니트릴; c) c1) 염소화된 비닐 에스테르; c2) 불포화된 카르복실산과 지방산 또는 방향족 디에폭시 성분물의 혼합물; c3) 불포화된 카르복실산과 염소화된 비닐에스테르로 구성된 혼합물; 탄성체 공중합물은 Mooney ML1+4점성(100℃)에서 적어도 10이 되는 중합반응에 수득되는 것을 특징으로 하는 탄성체 공중합물.
- 제1항에 있어서, 탄성체 공중합물에 R이 1가 기능 직쇄 또는 분지쇄 C2-C4 알칼 라디칼이 되는 것을 특징으로 하는 탄성체 공중합물.
- 제2항에 있어서, R이 부틸인 것을 특징으로 하는 탄성체 공중합물.
- 제1항에 있어서, R´가 H인 것을 특징으로 하는 탄성체 공중합물.
- 제1항에 있어서, 불포화 카르복실산 (c2)가 (매트) 아크릴산인 것을 특징으로 하는 탄성체 공중합물.
- 제1항에 있어서, 염소화된 비닐 에스테르(c1)는 비닐 클로로아세테이트인 것을 특징으로 하는 탄성체 공중합물.
- 제1항에 있어서, 디에폭시드가 비스페놀 A의 알릴디글리시딜 에테르인 것을 특징으로 하는 탄성체 공중합물.
- 제1항에 있어서; -단량체(a)가 중량의 50 내지 98%로; -단량체(b)가 0.1 내지 10%로; -단량체(c1)이 0.1 내지 10%로 포함된 것을 특징으로 하는 탄성체 공중합물.
- 제8항에 있어서; -단량체(a)가 중량의 70 내지 90%로; -단량체(b)가 9 내지 20%로; -단량체(c1)이 0.8 내지 5%로 포함된 것을 특징으로 하는 탄성체 공중합물.
- 제1항에 있어서; -단량체(a)가 중량의 50 내지 93$; -단량체(b)가 5 내지 40%로; -단량체(c2), 불포화산이 0.2 내지 2% 그리고 디에폭시드가 1 내지 4%의 혼합물로 구성된 것을 특징으로 하는 탄성체 공중합물.
- 제10항에 있어서; -단량체(a)가 중량의 70 내지 90$; -단량체(b)가 9 내지 20%; -단량체(c2), 불포화산이 0.5 내지 1% 그리고 디에폭시드가 2 내지 3%의 혼합물로 구성된 것을 특징으로 하는 탄성체 공중합물.
- 제1항에 있어서; -단량체(a)가 중량의 50 내지 93%; -단량체(b)가 5 내지 40%; -단량체(c3), 염소화된 비닐에스테르가 0.5 내지 10% 그리고 불포화된 카르복실산이 중량의 0.2 내지 2%의 혼합물로 구성된 것을 특징으로 하는 탄성체 공중합물.
- 제12항에 있어서; -단량체(a)가 중량의 70 내지 90%; -단량체(b)가 9 내지 20%; -단량체(c3), 염소화된 비닐에스테르가 0.5 내지 10% 그리고 불포화된 카르복실산이 중량의 0.2 내지 2% 혼합물로 구성된 것을 특징으로 하는 탄성체 공중합물.
- 제1항에 따른 탄성체 중합물의 제조과정에 있어서; -공중합된 단량체의 동일 또는 상이한 량을 포함하는 두용액을 준비하고, -두 용액중 하나는 반응기에 넣고 부분적으로 중합시키고, -제2용액을 미리 반응기에서 부분적으로 중합된 것에 첨가하고, -소요의 전환이 이루어질때까지 중합을 완성시키는 것으로 구성된 것을 특징으로 하는 제조과정.
- 경화성 탄성체 조성물에 있어서; -제1항에 따른 공중합물 단량체(a)(b)와 (c1)에 의해 수득된 탄성체 공중합물, -1) a) 7 내지 30개의 탄소원자를 가지는 포화 또는 불포화 지방산의염, 적절하게는 2-에틸 헥사노산, 스테아린산, 올레인산, 라시노레인산, n-옥탄산에서 선택된 알칼리 또는 암모니움염; b) 황 또는 황 제공 조성물의 혼합물; 2) ⅰ) 폴리티오트리아진, 적절하게는 트리티올트리아진; ⅱ) 티오우라마스, 디티오카르바메이트와 트리아졸에서 선택된 제2성분으로 구성된 조성물; 3) 2가 폴리디아민과 황으로 구성된 것을 특징으로 하는 경화성 탄성체 조성물.
- -단량체(a)(b)와 (c2)를 공중합시킴으로써 얻었던 제1항에 따른 탄성체 공중합물, -A) 일반식(R) -N+X-를 가지는 4가 암모니움염 이때 R은 1 내지 25 탄소원자를 가지는 1가 기능 탄화수소 라디칼과 X-는 1가 기능기 음이온이고, 적절하게는 할로겐, 설페이트, 바이설페이트, 하이드록시드이며; B) 지방족 또는 방향족 폴리아민과 폴리아미드와 이들의 유도체에서 선택된 경화제를 포함하는 것을 특징으로 하는 경화성 탄성체 조성물.
- -단량체 (a)(b)와 (c3)를 공중합시켜 수득된 제1항에 따른 탄성체 공중합물, -제15항과 제16항에 나열된 것중 선택된 경화제를 포함하는 것을 특징으로 하는 경화성 탄성체 중합물.
- 제15 내지 18항에 있어서, 진행보조제, 가소성제, 윤활제, 경화지연제, 항산화제와 노하저해제, 비활성 충전물 특히 카본블랙, 안료와 염료와 같은 첨가물을 포함하는 것을 특징으로 하는 경화성 탄성체 중합물.
- 제16 내지 18항에 따른 경화성 탄성체 조성물에서 수득된 것을 특징으로 하는 물품.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI93A001640 | 1993-07-23 | ||
| IT93MI001640A IT1265040B1 (it) | 1993-07-23 | 1993-07-23 | Composizioni vulcanizzabili a base di gomme acriliche modificate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR950003331A true KR950003331A (ko) | 1995-02-16 |
Family
ID=11366671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019940015087A KR950003331A (ko) | 1993-07-23 | 1994-06-29 | 변형된 아크릴고무를 기초한 경화성 조성물 |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US5496900A (ko) |
| EP (1) | EP0635522B1 (ko) |
| JP (1) | JPH0762187A (ko) |
| KR (1) | KR950003331A (ko) |
| CN (1) | CN1103070A (ko) |
| AT (1) | ATE158599T1 (ko) |
| CA (1) | CA2127063A1 (ko) |
| DE (1) | DE69405827T2 (ko) |
| IT (1) | IT1265040B1 (ko) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6140431A (en) * | 1997-02-27 | 2000-10-31 | Rohm And Haas Company | Process for preparing continuously variable-composition copolymers |
| JP5682561B2 (ja) * | 2009-07-23 | 2015-03-11 | Nok株式会社 | ハロゲン含有アクリルゴム組成物及びその加硫物 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1042754A (ko) * | 1962-06-19 | |||
| FR1399221A (fr) * | 1964-06-19 | 1965-05-14 | Thiokol Chemical Corp | Interpolymères d'acrylate et caoutchoucs vulcanisés tirés de ces produits |
| US3435010A (en) * | 1965-11-26 | 1969-03-25 | American Cyanamid Co | Curing system for halogen containing acrylic elastomers |
| US4129708A (en) * | 1977-04-18 | 1978-12-12 | American Cyanamid Company | Polyacrylate elastomer compositions |
| US4625005A (en) * | 1984-03-28 | 1986-11-25 | Japan Synthetic Rubber Co., Ltd. | Multi-component copolymer rubber, a process for producing the same, and a rubber composition containing the multi-component copolymer rubber |
| JPH0774253B2 (ja) * | 1990-07-18 | 1995-08-09 | 東ソー株式会社 | アクリル系共重合体ゴム |
-
1993
- 1993-07-23 IT IT93MI001640A patent/IT1265040B1/it active IP Right Grant
-
1994
- 1994-06-29 CA CA002127063A patent/CA2127063A1/en not_active Abandoned
- 1994-06-29 KR KR1019940015087A patent/KR950003331A/ko not_active Application Discontinuation
- 1994-07-08 AT AT94110660T patent/ATE158599T1/de active
- 1994-07-08 DE DE69405827T patent/DE69405827T2/de not_active Expired - Fee Related
- 1994-07-08 EP EP94110660A patent/EP0635522B1/en not_active Expired - Lifetime
- 1994-07-22 JP JP6191241A patent/JPH0762187A/ja not_active Withdrawn
- 1994-07-22 CN CN94108004A patent/CN1103070A/zh active Pending
-
1995
- 1995-03-30 US US08/413,884 patent/US5496900A/en not_active Expired - Lifetime
- 1995-03-30 US US08/413,893 patent/US5468817A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN1103070A (zh) | 1995-05-31 |
| CA2127063A1 (en) | 1995-01-24 |
| DE69405827T2 (de) | 1998-02-12 |
| DE69405827D1 (de) | 1997-10-30 |
| EP0635522A1 (en) | 1995-01-25 |
| ATE158599T1 (de) | 1997-10-15 |
| JPH0762187A (ja) | 1995-03-07 |
| US5468817A (en) | 1995-11-21 |
| IT1265040B1 (it) | 1996-10-28 |
| EP0635522B1 (en) | 1997-09-24 |
| US5496900A (en) | 1996-03-05 |
| ITMI931640A0 (it) | 1993-07-23 |
| ITMI931640A1 (it) | 1995-01-23 |
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