KR940009325A - New Laundry Liquid Detergent Composition - Google Patents

New Laundry Liquid Detergent Composition Download PDF

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Publication number
KR940009325A
KR940009325A KR1019930021145A KR930021145A KR940009325A KR 940009325 A KR940009325 A KR 940009325A KR 1019930021145 A KR1019930021145 A KR 1019930021145A KR 930021145 A KR930021145 A KR 930021145A KR 940009325 A KR940009325 A KR 940009325A
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South Korea
Prior art keywords
liquid detergent
detergent composition
soap
surfactant
alkyl
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KR1019930021145A
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Korean (ko)
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하우킨즈 존
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로져 고든 매드윅 새비지
알브라이트 앤드 윌슨 리미티드
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Priority claimed from GB929221377A external-priority patent/GB9221377D0/en
Priority claimed from GB929224870A external-priority patent/GB9224870D0/en
Application filed by 로져 고든 매드윅 새비지, 알브라이트 앤드 윌슨 리미티드 filed Critical 로져 고든 매드윅 새비지
Publication of KR940009325A publication Critical patent/KR940009325A/en

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08—Liquid soap, e.g. for dispensers; capsuled
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/08—Polycarboxylic acids containing no nitrogen or sulfur
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/92—Sulfobetaines ; Sulfitobetaines

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

본 발명은 새로운 새탁용 액성 세제 조성물에 관한 것으로, 낮은 점성도의 농축시킨 액성 세제 조성물, 특히 세탁용 세제로 사용하기에 적합한 액성 세제 조성물을 제공한다.The present invention relates to a new suspension liquid detergent composition, which provides a low viscosity concentrated liquid detergent composition, in particular a liquid detergent composition suitable for use as a laundry detergent.

이 조성물은 2-20%의 용해시킨 중강제염 및 적어도 12%는 모노-, 디-, 또는 트리에탄올아민 비누이고, 적?? 5%는 에톡시화 비이온성 계면활성제이며 나머지는 음이온성 및/또는 양쪽성 계면활성제인 35%내지 60%의 전체 계면활성제를 포함한다. 특히, 본 발명의 조성물은 산업용 및 기업용 자동 투입체계에서 사용하기에 적합하다.This composition comprises 2-20% dissolved neutralizer and at least 12% is mono-, di-, or triethanolamine soap. 5% is an ethoxylated nonionic surfactant and the remainder comprises between 35% and 60% total surfactant, anionic and / or amphoteric surfactants. In particular, the compositions of the present invention are suitable for use in industrial and commercial automatic dosing systems.

Description

새로운 세탁용 액성 세제 조성물New Laundry Liquid Detergent Composition

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (19)

다음을 포함함을 특징으로 하는 액성 세제 조성물(여기서, 모든 %는 조성물의 전체 중량에 기초한 중량비이다.) : (A) 12%내지 55%의 모노-, 디-, 또는 트리-에탄올아민 비누, 0%내지 43%의 비-비누 음이온성 게면 활성제 및/또는 양쪽성 계면활성제, 및 5%내지 48%의 비이온성 계면활성제를 포함하는 35%내지 60%의 전체 계면활성제. (B) 주로 중강제 염으로 구성된 2%내지 20%의 용해시킨 전해질; 및 (C) 적어도 20%의 물.Liquid detergent compositions, wherein all percentages are by weight based on the total weight of the composition, comprising: (A) 12% to 55% mono-, di-, or tri-ethanolamine soap, 35% to 60% total surfactant, including 0% to 43% non-soap anionic surfactant and / or amphoteric surfactant, and 5% to 48% nonionic surfactant. (B) 2% to 20% of a dissolved electrolyte, consisting primarily of medium force salts; And (C) at least 20% water. 다음을 포함함을 특징으로 하는 액성 세제 조성물(여기서, 모든 %는 조성물의 전체중량에 기초한 중량비이다). : (A) 12%내지 50%의 모노-, 디-, 또는 트리-에탄올아민 비누, 0%내지 38%의 비-비누 음이온성 및/또는 양쪽성 계면활성제, 및 5%내지 43%의 비이온성 계면활성제를 포함하는 35%내지 55%의 전체 계면활성제; (B) 주로 증강제 염으로 구성된 2%내지 20%의 용해시킨 전해질; 및 (C) 적어도 20%의 물.Liquid detergent compositions, wherein all percentages are weight ratios based on the total weight of the composition, comprising: (A) 12% to 50% mono-, di-, or tri-ethanolamine soap, 0% to 38% non-soap anionic and / or amphoteric surfactant, and 5% to 43% 35% to 55% total surfactant, including warm surfactants; (B) 2% to 20% dissolved electrolyte, consisting mainly of enhancer salts; And (C) at least 20% water. 다음을 포함함을 특징으로 하는 액성 세제 조성물(여기서, 모든 %는 조성물의 전체 중량에 기초한 중량비이다). : (a) 적어도 20%의 물, (b) 2%내지 20%의 술폰산 알킬 벤젠, (c) 0%내지 15%의 황산 알킬 에테르, (d) 15%내지 40%의 모노-, 디- 또는 트리-에탄올아민 비누, (e)5%내지 15%의 비이온성 알콕시화 계면활성제, 및 (f) 2%내지 20%의 전체 용해시킨 전해질, 여기서 이 전해질은 다음 성분을 포함한다.: (i) 2%내지 10%의 시트르산염, (ii) 0%내지 10%의 탄산염, 및 (iii) 0%내지 4%의 포스폰산염.Liquid detergent compositions, wherein all percentages are weight ratios based on the total weight of the composition, comprising: (a) at least 20% water, (b) 2% to 20% alkyl sulfonate benzene, (c) 0% to 15% alkyl sulfate sulfate, (d) 15% to 40% mono-, di- Or tri-ethanolamine soap, (e) 5% to 15% nonionic alkoxylated surfactant, and (f) 2% to 20% totally dissolved electrolyte, wherein the electrolyte comprises the following components: i) 2% to 10% citrate, (ii) 0% to 10% carbonate, and (iii) 0% to 4% phosphonate. 전술한 항 중 어느 한 항에 있어서, 술폰산 C8-C18알킬벤젠, 술폰산 C8-C22파라핀, 황산 C8-C22알킬, 폴리카르복시산 C8-C22알킬 에테르 및/또는 황산 C10-C18알킬 폴리옥시에틸렌을 포함하는 5내지 30%의 비-비누 음이온성 계면활성제를 포함함을 특징으로 하는 액성 세제 조성물.The sulfonic acid C 8 -C 18 alkylbenzene, sulfonic acid C 8 -C 22 paraffin, sulfuric acid C 8 -C 22 alkyl, polycarboxylic acid C 8 -C 22 alkyl ether and / or sulfuric acid C 10 A liquid detergent composition comprising 5 to 30% of a non-soap anionic surfactant comprising a C 18 alkyl polyoxyethylene. 제4항에 있어서, 비-비누 음이온성 계면활성제가 술폰산 C10-C14알킬 벤젠을 포함함을 특징으로 하는 액성 세제 조성물.5. The liquid detergent composition of claim 4, wherein the non-soap anionic surfactant comprises sulfonic acid C 10 -C 14 alkyl benzene. 전술한 항 중 어느 한 항에 있어서, 비누는 C8-C22포화 또는 불포화, 직쇄 또는 측쇄, 천연 또는 합성지방산의 염임을 특징으로 하는 액성 세제 조성물.The liquid detergent composition of claim 1, wherein the soap is a C 8 -C 22 saturated or unsaturated, straight or branched chain, salt of a natural or synthetic fatty acid. 제6항에 있어서, 비누의 농도는 전체 조성물에 대한 비누의 중량에 기초하여 적어도 12%임을 특징으로 하는 액성 세제 조성물.7. The liquid detergent composition of claim 6, wherein the concentration of soap is at least 12% based on the weight of soap relative to the total composition. 제7항에 있어서, 비누의 전체 농도는 15%-40%임을 특징으로 하는 액성 세제 조성물.8. A liquid detergent composition according to claim 7, wherein the total concentration of soap is 15% -40%. 전술한 항 중 어느 한 항에 있어서, 비이온성 게면 활성제는 분자당 평균 5내지 50개의 에틸렌옥시기를 가지는 에톡시화 C8-C20알콜 또는 지방산을 포함함을 특징으로 하는 액성 세제 조성물.The liquid detergent composition of claim 1, wherein the nonionic surfactant is an ethoxylated C 8 -C 20 alcohol or fatty acid having an average of 5 to 50 ethyleneoxy groups per molecule. 제9항에 있어서, 비이온성 계면활성제의 비율은 전체 조성물의 7%내지 35%임을 특징으로 하는 액성 세제 조성물.10. The liquid detergent composition of claim 9, wherein the proportion of nonionic surfactant is 7% to 35% of the total composition. 전술한 항 중 어느 한 항에 있어서, 0.5%내지 5%의 양쪽성 계면활성제를 포함함을 특징으로 하는 액성 세제 조성물.The liquid detergent composition according to any one of the preceding claims, comprising 0.5% to 5% amphoteric surfactant. 제11항에 있어서, 양쪽성 계면활성제는 C8-C18알킬디메틸 베타인, 아미도 아민 배타인, 알킬 이미다졸린 배타인 및/또는 술포베타인, 바람직하게는 C8-C10알킬 디메틸 배타인을 포함함을 특징으로 하는 액성 세제 조성물.12. The amphoteric surfactant according to claim 11, wherein the amphoteric surfactant is C 8 -C 18 alkyldimethyl betaine, amido amine betaine, alkyl imidazoline betaine and / or sulfobetaine, preferably C 8 -C 10 alkyl dimethyl A liquid detergent composition, characterized in that it comprises an exclusive. 제1항 내지 제2항 중 어느 한 항에 있어서, 용해시킨 전해질은 수용성 시트르산염 및/또는 탄산염 및/또는 포스폰산염임을 특징으로 하는 액성 세제 조성물.The liquid detergent composition according to any one of claims 1 to 2, wherein the dissolved electrolyte is a water soluble citrate and / or a carbonate and / or a phosphonate. 전술한 항 중 어느 한 항에 있어서, 용해시킨 전해질이 적어도 5%의 시트르산염 및 적어도 2%의 탄산염, 및 선택적으로 4% 까지의 포스폰산염을 포함함을 특징으로 하는 액성 세제 조성물.The liquid detergent composition of claim 1, wherein the dissolved electrolyte comprises at least 5% citrate and at least 2% carbonate, and optionally up to 4% phosphonate. 전술한 항 중 어느 한 항에 있어서, 7%내지 15%의 용해시킨 전해질을 포함함을 특징으로 하는 액성 세제 조성물.The liquid detergent composition according to any one of the preceding claims, comprising 7% to 15% dissolved electrolyte. 전술한 항 중 어느 한 항에 있어서, 향수성 물질(hydrotropes), 불투명제(opacifiers), 향수, 착색제, 광학광택제, 방부제, 효소, 재침전 방지제 및/또는 기타 중합체를 5%까지 상당한 양으로 포함함을 특징으로 하는 액성 세제 조성물.The process of claim 1, comprising up to 5% significant amounts of hydrotropes, opacifiers, perfumes, colorants, optical varnishes, preservatives, enzymes, anti-precipitation agents and / or other polymers. Liquid detergent composition, characterized in that. 전술한 항 중 어느 한 항에 있어서, 뉴우튼성 흐름특성 및 20℃에서 0.03Pa·S 및 0.6Pa·S의 점성도를 가짐을 특징으로 하는 액성 세제 조성물.The liquid detergent composition according to any one of the preceding claims, having Newtonian flow characteristics and viscosity of 0.03 Pa.S and 0.6 Pa.S at 20 ° C. 전술한 항 중 어느 한 항에 있어서, 세탁용 세제로 사용하기 위한 것임을 특징으로 하는 액성 세제 조성물.The liquid detergent composition according to any one of the preceding claims, for use as a laundry detergent. 전술한 항 중 어느 한 항에 있어서, 자동 측정 장치와 함께 사용하기 위한 것임을 특징으로 하는 액성 세제 조성물.The liquid detergent composition according to any one of the preceding claims, for use with an automatic measuring device. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930021145A 1992-10-12 1993-10-12 New Laundry Liquid Detergent Composition KR940009325A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB9221377.6 1992-10-12
GB929221377A GB9221377D0 (en) 1992-10-12 1992-10-12 Novel liquid cleaning preparations
GB9224870.7 1992-11-27
GB929224870A GB9224870D0 (en) 1992-11-27 1992-11-27 Novel cleaning preparations

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KR940009325A true KR940009325A (en) 1994-05-20

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CN (1) CN1088972A (en)
AU (1) AU673000B2 (en)
CA (1) CA2108116A1 (en)
GB (1) GB2271574A (en)
MY (1) MY118467A (en)
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CN109852495A (en) * 2018-12-28 2019-06-07 北京绿伞化学股份有限公司 A kind of detergent and preparation method thereof based on natural material

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BE794713A (en) * 1972-01-31 1973-07-30 Procter & Gamble LIQUID DETERGENT COMPOSITIONS
DE3232616A1 (en) * 1982-09-02 1984-03-08 Henkel KGaA, 4000 Düsseldorf LIQUID, INORGANIC FRUIT SALT, IN ESSENTIAL FREE DETERGENT AND CLEANING AGENT
US4486328A (en) * 1983-05-03 1984-12-04 Colgate-Palmolive Company Betaine-soap shampoo composition
US4507219A (en) * 1983-08-12 1985-03-26 The Proctor & Gamble Company Stable liquid detergent compositions
DE3668330D1 (en) * 1985-05-04 1990-02-22 Henkel Kgaa NO-SALT-FREE LIQUID DETERGENT WITH TEXTILE SOFTENING PROPERTIES.
MA22118A1 (en) * 1990-04-10 1991-12-31 Huntsman Internat Llc Etat De HIGHLY CONCENTRATED LIQUID DETERGENT COMPOSITION WITH SURFACTANTS
DE4028850A1 (en) * 1990-09-11 1992-03-12 Johannes Kiehl Kg Low viscosity liq. washing compsn. concentrate - contains anionic and nonionic surfactants, copolymer of acrolein, acrylic¨ acid and/or maleic acid, etc. and fatty acid soap
DE4039223A1 (en) * 1990-12-08 1992-06-11 Huels Chemische Werke Ag LIQUID DETERGENT

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MY118467A (en) 2004-11-30
EP0592947A1 (en) 1994-04-20
CA2108116A1 (en) 1994-04-13
AU673000B2 (en) 1996-10-24
JPH06192686A (en) 1994-07-12
CN1088972A (en) 1994-07-06
GB9320802D0 (en) 1993-12-01
AU4896093A (en) 1994-04-28
GB2271574A (en) 1994-04-20
TW232709B (en) 1994-10-21

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