KR940005713A - 아스파르트산으로부터 폴리숙신이미드류의 제조방법 - Google Patents
아스파르트산으로부터 폴리숙신이미드류의 제조방법 Download PDFInfo
- Publication number
- KR940005713A KR940005713A KR1019930012927A KR930012927A KR940005713A KR 940005713 A KR940005713 A KR 940005713A KR 1019930012927 A KR1019930012927 A KR 1019930012927A KR 930012927 A KR930012927 A KR 930012927A KR 940005713 A KR940005713 A KR 940005713A
- Authority
- KR
- South Korea
- Prior art keywords
- poly
- glycol
- aspartic acid
- alkylene glycol
- amino acids
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1092—Polysuccinimides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/08—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
- C08G69/10—Alpha-amino-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1046—Polyimides containing oxygen in the form of ether bonds in the main chain
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Polyamides (AREA)
- Polyethers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyrrole Compounds (AREA)
Abstract
본 발명은 폴리숙신이미드류(polysuccinimides) 의 제조방법, 특히, 폴리(알킬렌 글리콜)내에서 아스파르트산(aspartic acid), 임의로 기타 아미노산들로부터 폴리숙신이미드류를 제조하는 방법에 관한 것이다, 본 발명의 방법은 (a) 폴리(알킬렌 글리콜), 아스파르트산, 및 임의의 하나 또는 그 이상의 아미노산들의 중합 혼합물을 형성하고; (b) 그 혼합물을 고온으로 가열시키고; (c) 폴리숙신이미드류가 형성되도록 그 혼합물을 고온에서 유지시키는 단계들을 포함한다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (14)
- (a) 폴리(알킬렌 글리콜), 아스파르트산, 및 임의의 하나 또는 그 이상의 다른 아미노산들의 중합 혼합물을 형성하고; (b) 그 혼합물을 고온으로 가열시키고; (c) 폴리숙신이미드류가 형성되도록 그 혼합물을 고온에서 유지시키는 것을 특징으로 하는, 폴리숙신이미드류의 제조방법.
- 제1항에 있어서, 폴리(알킬렌 글리콜)이 폴리(테트라메틸렌 글리콜), 폴리(알킬렌 글리콜),폴리(프로필렌 글리콜); 및 한쪽 말단 또는 양쪽 말단들이 카르복시산들, 탄소수 1-30의 알킬기들, 아민들, 탄소수 1-10의알킬아민들, 및 그 조합에 의하여 종결된 폴리(테트라메틸렌 글리콜), 폴리(알킬렌 글리콜), 폴리(프로필렌 글리콜)로부터 선택된 것인 방법.
- 제1항에 있어서, 폴리(알킬렌 글리콜)이 티에틸 글리콜, 폴리(에틸렌 글리콜), 메틸-종결 폴리(알킬렌 글리콜), 및 폴리(프로필렌 글리콜)로 부터 선택된 것인 방법.
- 제1항에 있어서, 폴리(알킬렌 글리콜)이 폴리(에틸렌 글리콜)인 방법.
- 제1항에 있어서, 중합 혼합물이 아스파르트산 대비 2-90wt% 수준으로 폴리(알킬렌 글리콜)을 함유하는 것인 방법.
- 제1항에 있어서, 중합 혼합물이 아스파르트산 대비 20-90wt% 수준으로 폴리(알킬렌 글리콜)을 함유하는 것인 방법.
- 제1항에 있어서, 중합 혼합물이 아스파르트산 대비 30-85wt% 수준으로 폴리(알킬렌 글리콜)을 함유하는 것인 방법.
- 제1항에 있어서, 하나 또는 그 이상의 다른 아미노산들이 알라닌, 그리신, 리신, 아스파라긴 및 글루탐산으로부터 선택된 것인 방법.
- 제1항에 있어서, 하나 또는 그 이상의 다른 아미노산들이 알라닌인 것인 방법.
- 제1항에 있어서,중합 혼합물이 아스파르트산 기준으로 80wt%까지의 수준으로 하나 또는 그 이상의 다른 아미노산들을 함유하는 것인 방법.
- 제1항에 있어서,중합 혼합물이 아스파르트산 기준으로 5-70wt%까지의 수준으로 하나 또는 그 이상의 다른 아미노산들을 함유하는 것인 방법.
- 제1항에 있어서,중합 혼합물이 아스파르트산 기준으로 10-60wt%까지의 수준으로 하나 또는 그 이상의 다른 아미노산들을 함유하는 것인 방법.
- 제1항에 있어서, 상응하는 폴리(아미노산)이 형성되도록 폴리숙신이미드류를 가수분해시키는 것을 포함하는 방법.
- 제1항에 있어서, 혼합물이 산소가 없는 분위기에서 고온으로 유지되는 것인 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US911,866 | 1992-07-10 | ||
US07/911,866 US5380817A (en) | 1992-07-10 | 1992-07-10 | Process for preparing polysuccinimides from aspartic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
KR940005713A true KR940005713A (ko) | 1994-03-22 |
Family
ID=25431009
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019930012927A KR940005713A (ko) | 1992-07-10 | 1993-07-09 | 아스파르트산으로부터 폴리숙신이미드류의 제조방법 |
Country Status (14)
Country | Link |
---|---|
US (2) | US5380817A (ko) |
EP (1) | EP0578449B1 (ko) |
JP (1) | JPH06211982A (ko) |
KR (1) | KR940005713A (ko) |
CN (1) | CN1033861C (ko) |
AT (1) | ATE152746T1 (ko) |
AU (1) | AU666194B2 (ko) |
BR (1) | BR9302725A (ko) |
CA (1) | CA2099462A1 (ko) |
DE (1) | DE69310446T2 (ko) |
ES (1) | ES2102600T3 (ko) |
MX (1) | MX9303793A (ko) |
NZ (1) | NZ247842A (ko) |
TW (1) | TW274554B (ko) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5380817A (en) * | 1992-07-10 | 1995-01-10 | Rohm And Haas Company | Process for preparing polysuccinimides from aspartic acid |
EP0621300B1 (fr) * | 1993-04-23 | 1998-09-30 | Rhodia Chimie | Acide polyanhydroaspartique et ses hydrolysats biodégradables |
US5484945A (en) * | 1993-08-24 | 1996-01-16 | Mitsui Toatsu Chemicals, Inc. | Preparation process of polysuccinimide |
CA2132112A1 (en) * | 1993-09-21 | 1995-03-22 | David Elliott Adler | Acid catalyzed process for preparing amino acid polymers |
US5681920A (en) * | 1994-06-28 | 1997-10-28 | Donlar Corporation | Process for production of a polysuccinimide and derivatives thereof |
US5552517A (en) * | 1995-03-03 | 1996-09-03 | Monsanto Company | Production of polysuccinimide in an organic medium |
DE19545678A1 (de) | 1995-12-07 | 1997-06-12 | Goldschmidt Ag Th | Copolymere Polyaminosäureester |
JPH09165447A (ja) | 1995-12-15 | 1997-06-24 | Mitsubishi Chem Corp | ポリアスパラギン酸共重合体及びその製造方法 |
US5856427A (en) * | 1996-01-16 | 1999-01-05 | Solutia Inc. | Process for the production of polysuccinimide |
US5981691A (en) * | 1997-04-23 | 1999-11-09 | University Of South Alabama | Imide-free and mixed amide/imide thermal synthesis of polyaspartate |
DE19822600C2 (de) | 1998-05-20 | 2003-08-21 | Goldschmidt Ag Th | Copolymere, hydrophob modifizierte Polyasparaginsäureester mit erhöhter Molekularmasse |
DE19822604A1 (de) | 1998-05-20 | 1999-11-25 | Goldschmidt Ag Th | Kondensationsprodukte enthaltend polyethermodifizierte Monoester und/oder -amide alpha, beta-ungesättigter Dicarbonsäuren, ihre Herstellung und Verwendung |
DE19822603A1 (de) | 1998-05-20 | 1999-11-25 | Goldschmidt Ag Th | Pigmentpasten enthaltend hydrophob modifizierte Polyasparaginsäurederivate |
US6380350B1 (en) | 1999-09-10 | 2002-04-30 | Nippon Shokubai Co., Ltd. | Polyaspartic acid |
US6878797B2 (en) * | 2002-04-19 | 2005-04-12 | Board Of Trustees Of Michigan State University | Synthesis and applications of polymaleimide |
CN100351286C (zh) * | 2006-01-24 | 2007-11-28 | 北京化工大学 | 一种聚天门冬氨酸树脂的制备方法 |
EP2271732B1 (en) | 2008-04-28 | 2013-04-17 | Dow Global Technologies LLC | Polyalkylene glycol lubricant composition |
CN102002152B (zh) * | 2010-10-27 | 2013-06-12 | 中国科学院长春应用化学研究所 | 脂肪族二元酸-1,2-丙二醇聚酯及其制备方法 |
Family Cites Families (17)
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US2306918A (en) * | 1940-02-15 | 1942-12-29 | Research Corp | Amine reaction product |
US3052655A (en) * | 1958-08-01 | 1962-09-04 | Sidney W Fox | Thermal polymerization of amino acid mixtures containing aspartic acid or a thermal precursor of aspartic acid |
GB1064417A (en) * | 1963-12-09 | 1967-04-05 | Kyowa Hakko Kogyo Kk | Process for the preparation of copolypeptides |
US3846380A (en) * | 1972-10-31 | 1974-11-05 | M Teranishi | Polyamino acid derivatives and compositions containing same |
DE2364152A1 (de) * | 1972-12-26 | 1974-06-27 | Ajinomoto Kk | Verfahren zur herstellung einer polyaminosaeure |
JPS528873A (en) * | 1975-07-09 | 1977-01-24 | Matsushita Electric Ind Co Ltd | Maximum demand monitor indication unit |
JPS528877A (en) * | 1975-07-10 | 1977-01-24 | Canon Inc | Object detector unit |
JPS60203636A (ja) * | 1984-03-28 | 1985-10-15 | Fuso Kagaku Kogyo Kk | コポリアミノ酸の製造法 |
DE3626672A1 (de) * | 1986-08-07 | 1988-02-11 | Bayer Ag | Polyasparaginamidsaeure |
US5057597A (en) * | 1990-07-03 | 1991-10-15 | Koskan Larry P | Process for the manufacture of anhydro polyamino acids and polyamino acids |
US5319145A (en) * | 1992-07-10 | 1994-06-07 | Rohm And Haas Company | Method for preparing polysuccinimides with a rotary tray dryer |
US5371179A (en) * | 1992-07-10 | 1994-12-06 | Rohm And Haas Company | Polysuccinimide polymers and process for preparing polysuccinimide polymers |
US5371177A (en) * | 1992-07-10 | 1994-12-06 | Rohm And Haas Company | Process for preparing polysuccinimides from maleamic acid |
US5380817A (en) * | 1992-07-10 | 1995-01-10 | Rohm And Haas Company | Process for preparing polysuccinimides from aspartic acid |
US5296578A (en) * | 1992-09-18 | 1994-03-22 | Donlar Corporation | Production of polysuccinimide and polyaspartic acid from maleic anhydride and ammonia |
US5219952A (en) * | 1992-09-18 | 1993-06-15 | Donlar Corporation | Production of high molecular weight polysuccinimide and high molecular weight polyaspartic acid from maleic anhydride and ammonia |
US5393868A (en) * | 1992-10-13 | 1995-02-28 | Rohm And Haas Company | Production of polysuccinimide by thermal polymerization of maleamic acid |
-
1992
- 1992-07-10 US US07/911,866 patent/US5380817A/en not_active Expired - Fee Related
-
1993
- 1993-06-10 NZ NZ247842A patent/NZ247842A/en unknown
- 1993-06-10 AU AU40154/93A patent/AU666194B2/en not_active Ceased
- 1993-06-21 JP JP5149000A patent/JPH06211982A/ja not_active Withdrawn
- 1993-06-24 MX MX9303793A patent/MX9303793A/es not_active IP Right Cessation
- 1993-06-30 BR BR9302725A patent/BR9302725A/pt not_active Application Discontinuation
- 1993-06-30 CA CA002099462A patent/CA2099462A1/en not_active Abandoned
- 1993-07-02 ES ES93305212T patent/ES2102600T3/es not_active Expired - Lifetime
- 1993-07-02 EP EP93305212A patent/EP0578449B1/en not_active Expired - Lifetime
- 1993-07-02 DE DE69310446T patent/DE69310446T2/de not_active Expired - Fee Related
- 1993-07-02 AT AT93305212T patent/ATE152746T1/de not_active IP Right Cessation
- 1993-07-05 TW TW082105338A patent/TW274554B/zh active
- 1993-07-09 KR KR1019930012927A patent/KR940005713A/ko not_active Application Discontinuation
- 1993-07-10 CN CN93108565A patent/CN1033861C/zh not_active Expired - Fee Related
-
1994
- 1994-08-25 US US08/296,337 patent/US5484878A/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US5484878A (en) | 1996-01-16 |
US5380817A (en) | 1995-01-10 |
NZ247842A (en) | 1995-03-28 |
DE69310446D1 (de) | 1997-06-12 |
TW274554B (ko) | 1996-04-21 |
CN1082065A (zh) | 1994-02-16 |
EP0578449B1 (en) | 1997-05-07 |
AU4015493A (en) | 1994-01-13 |
DE69310446T2 (de) | 1997-10-09 |
CN1033861C (zh) | 1997-01-22 |
CA2099462A1 (en) | 1994-01-11 |
JPH06211982A (ja) | 1994-08-02 |
ES2102600T3 (es) | 1997-08-01 |
ATE152746T1 (de) | 1997-05-15 |
MX9303793A (es) | 1994-02-28 |
EP0578449A1 (en) | 1994-01-12 |
AU666194B2 (en) | 1996-02-01 |
BR9302725A (pt) | 1994-03-01 |
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