KR930023449A - Use of amorphous silicoaluminum salt as scavenger for calcium precipitate - Google Patents

Use of amorphous silicoaluminum salt as scavenger for calcium precipitate Download PDF

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Publication number
KR930023449A
KR930023449A KR1019930009118A KR930009118A KR930023449A KR 930023449 A KR930023449 A KR 930023449A KR 1019930009118 A KR1019930009118 A KR 1019930009118A KR 930009118 A KR930009118 A KR 930009118A KR 930023449 A KR930023449 A KR 930023449A
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alkali metal
detergent composition
amorphous
calcium
carbonate
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KR1019930009118A
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Korean (ko)
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KR960001012B1 (en
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뵈띠오 빠뜨릭
꾸브레 비르지니
쥬베르 다니예
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베아트리스 떼지에-에르만
롱-쁠랑 쉬미
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Removal Of Specific Substances (AREA)
  • Catalysts (AREA)
  • Silicon Compounds (AREA)
  • Analysing Materials By The Use Of Radiation (AREA)

Abstract

The subject of the present invention is the use, in a detergent composition, of an alkali metal amorphous silicoaluminate as agents for capturing calcium-containing precipitates. The invention also relates to a detergent composition comprising at least one alkali metal amorphous silicoaluminate, alkali metal carbonate, the alkali metal is preferably sodium, and at least one inhibitor of calcium carbonate crystalline growth, the alkali metal carbonate being present especially as the main agent for removing ionic calcium.

Description

칼슘 침전물용 스캐빈져로서의 무정질 실리코알루미늄산염의 용도Use of amorphous silicoaluminum salt as scavenger for calcium precipitate

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (16)

세제 조성물내에서의 무정질 알칼리 금속 실리코알루미늄산염의 칼슘 침전물용 스캐빈져로서의 용도.Use as an scavenger for calcium precipitates of amorphous alkali metal silicoaluminates in detergent compositions. 제1항에 있어서, 칼슘침전물이 세제 조성물내에 존재하는 알칼리금속 탄산염, 바람직하게는 탄산 나트륨과 칼슘의 침전의 의해 수득되는 것을 특징으로 하는 용도.Use according to claim 1, characterized in that the calcium precipitate is obtained by precipitation of alkali metal carbonates, preferably sodium carbonate and calcium, present in the detergent composition. 제1항 또는 제2항에 있어서, 무정질 알칼리 금속 실리코알루미늄산염의 하기 구조식(1)을 갖는 것을 특징으로 하는 용도 :Use according to claim 1 or 2, characterized by having the following structural formula (1) of amorphous alkali metal silicoaluminate: XM2OㆍyAL2O3ㆍO3ㆍSiO26WH2O(1) X M 2 O ・y AL 2 O 3 ㆍ O 3 ㆍ SiO 2 6 W H 2 O (1) 〔상기식에서, M은 알칼리금속, 바람직하게는 나트륨을 나타내고, X는 0.2 내지 2 이고 y는 1 이고 z는 0.2 내지 15 이고, w는 0이 아니 양의 실수이다.〕[Wherein M represents an alkali metal, preferably sodium, X is 0.2 to 2, y is 1, z is 0.2 to 15, w is not zero and is a positive real number.] 제3항에 있어서, 무정질 실리코알루미늄산염이 x가 0.8 내지 1.2 이고, z는 8 내지 15이고, w는 0.3 내지 9인 구조식(1)인 것을 특징으로 하는 용도.4. The use according to claim 3, wherein the amorphous silicoaluminate is structural formula (1) wherein x is 0.8 to 1.2, z is 8 to 15, and w is 0.3 to 9. 제1항 또는 제2항에 있어서, 무정질 알칼리금속 실리코알루미늄산염이 50㎎CaCO3/g무수 실리코알루미늄산염 이상의 칼슘 교환능 및/또는 100㎖/100g 이상, 바람직하게는 150㎖/g 이상의 흡수능을 갖는 것을 특징으로 하는 용도.The amorphous alkali metal silicoarate of claim 1 has a calcium exchange capacity of at least 50 mg CaCO 3 / g anhydrous silicoarate and / or an absorption capacity of at least 100 ml / 100 g, preferably at least 150 ml / g. Use characterized by having. 1종 이상의 무정질 알칼리 금속 실리코알루미늄산염, 칼슘이온을 제거하기 위한 주요성분인 알칼리 금속탄산염-알칼리 금속은 바람직하게는 나트륨이다.-및 1종 이상의 탄산 칼슘 결정 성장 억제제를 포함하는 것을 특징으로 하는 조성물.The at least one amorphous alkali metal silicoaluminum salt, the alkali metal carbonate-alkali metal, which is the main component for removing calcium ions, is preferably sodium-and at least one calcium carbonate crystal growth inhibitor. Composition. 제6항에 있어서, 인산염 및 제올라이트를 포함하지 않는 것을 특징으로 하는 세제 조성물.7. The detergent composition of claim 6, wherein the detergent composition is free of phosphate and zeolite. 제6항 또는 제7항에 있어서, 무정질 알칼리 금속 실리코알루미늄산염이 하기 구조식(1)을 갖는 것을 특징으로 하는 세제 조성물.The detergent composition according to claim 6 or 7, wherein the amorphous alkali metal silicoaluminate has the following structural formula (1). XM2O·yAL2O3·O3·SiO26WH2O(1) X M 2 O · y AL 2 O 3 · O 3 · SiO 2 6 W H 2 O (1) 〔상기식에서, M은 알칼리금속, 바람직하게는 나트륨을 나타내고, X는 0.2 내지 2 이고 y는 1이고 z는 0.2 내지 15이고, w는 0이 아니 양의 실수이다.〕[Wherein M represents an alkali metal, preferably sodium, X is 0.2 to 2, y is 1, z is 0.2 to 15, w is not zero and is a positive real number.] 제8항에 있어서, 무정질 실리코알쿠미늄산염이 x 가 0.8내지 1.2이고, z는 8 내지 15 이고, w는 0.3 내지 9인 구조식(1)인 것을 특징으로 하는 세제 조성물.9. A detergent composition according to claim 8, wherein the amorphous silicoalkumitrate is of formula (1) wherein x is 0.8 to 1.2, z is 8 to 15 and w is 0.3 to 9. 제6항 또는 제7항에 있어서, 무정질 알칼리금속 실리코알루미늄산염이 50㎎ CaCO3/g 무수 실리코알루미늄산염 이상의 칼슘 교환능 및/또는 100㎖/100g 이상, 바람직하게는 150㎖/g 이상의 흡수능을 갖는 것을 특징으로 하는 세제 조성물.8. A method according to claim 6 or 7, wherein the amorphous alkali metal silicoarate has a calcium exchange capacity of at least 50 mg CaCO 3 / g anhydrous silicoarate and / or an absorption capacity of at least 100 ml / 100 g, preferably at least 150 ml / g. Detergent composition characterized in that it has. 제6항 또는 제7항에 있어서, 탄산 칼슘의 결정 성장 억제제가 바람직하게는 분자량이 2,000 내지 10,000인 시트르산, 타르타르산 및 포스폰산 및 그들의 염, 바람직하게는 분자량이 50,000 내지 70,000 인 아크릴 - 말레익 또는 - 비닐 공중합체산 및 그들의 염, 폴리아스파르트산 및 그들의 염, 0 내지 5×10-4몰/g 중합체일 수 있는 COO-전하 밀도를 나타내고 세척욕내에서의 가수분해에 의해 10-3몰/g 중합체이상의 COO-전하밀도를 얻을 수 있는 폴리이미드 생중합체로부터 선택되는 것을 특징으로 하는 세제 조성물.8. The crystal growth inhibitor of calcium carbonate is preferably citric acid, tartaric acid and phosphonic acid having a molecular weight of 2,000 to 10,000 and their salts, preferably acrylic-maleic or having a molecular weight of 50,000 to 70,000. -vinyl copolymer acids and their salts, polyaspartic acid and salts thereof, from 0 to 5 × 10 -4 mol / g polymer that can be COO - by hydrolysis in the washing yoknae 10 -3 mol / g represents a charge density Detergent composition, characterized in that it is selected from a polyimide biopolymer capable of obtaining a COO - charge density above the polymer. 제6항 또는 제7항에 있어서, 2 내지 10%의 무정질 알칼리 금속 실리코알루미늄산염, 10 내지 30%의 알칼리 금속 탄산염 및 3 내지 15%의 탄산칼슘의 결정 성장 억제제를 포함하는 것을 특징으로 하는 세제 조성물.8. Crystal growth inhibitor according to claim 6 or 7, comprising 2 to 10% amorphous alkali metal silicoaluminate, 10 to 30% alkali metal carbonate and 3 to 15% calcium carbonate. Detergent composition. 제12항에 있어서, 2 내지 10%의 알칼리 금속 실리코알루미늄산염, 15 내지 25%의 알칼리 금속 탄산염 및 3 내지 6%의 탄산칼슘의 결정 성장 억제제를 포함하는 것을 특징으로 하는 세제 조성물.13. The detergent composition according to claim 12, comprising 2 to 10% alkali metal silicoaluminate, 15 to 25% alkali metal carbonate and 3 to 6% calcium carbonate. 제6항 또는 제7항에 있어서, 알칼리 금속 규산염, 바람직하게는 규산 나트륨을 포함하는 것을 특징으로 하는 세제 조성물.8. Detergent composition according to claim 6 or 7, comprising an alkali metal silicate, preferably sodium silicate. 제6항 또는 제7항에 있어서, 무정질 실리코알루미늄산염, 탄산칼슘의 결정 성장 억제제 및 알칼리 금속 규산염 수화물 및 알칼리 금속 탄산염을 기재한 구형 코그래뉼레이트를 포함하는 것을 특징으로 하는 세제 조성물.8. Detergent composition according to claim 6 or 7, comprising amorphous silicoaluminate, crystal growth inhibitors of calcium carbonate and spherical cognateates based on alkali metal silicate hydrates and alkali metal carbonates. 제6항 또는 제7항에 있어서, 8 내지 30%의 양으로 1종 이상의 계면 활성제를 또한 포함하는 것을 특징으로 하는 세제조성물.8. A detergent composition according to claim 6 or 7, further comprising at least one surfactant in an amount of 8 to 30%. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019930009118A 1992-05-26 1993-05-25 Utilization of amorphous silico-aluminates as calcium-containing KR960001012B1 (en)

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Application Number Priority Date Filing Date Title
FR9206419A FR2691715A1 (en) 1992-05-26 1992-05-26 Use of amorphous silico-aluminate as sensors for calcium precipitates.
FR92-06419 1992-05-26

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KR930023449A true KR930023449A (en) 1993-12-18
KR960001012B1 KR960001012B1 (en) 1996-01-17

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CA2096909A1 (en) 1993-11-27
NO931871D0 (en) 1993-05-24
EP0572288A1 (en) 1993-12-01
JPH0649485A (en) 1994-02-22
EE9400075A (en) 1995-12-15
NO931871L (en) 1993-11-29
RO114631B1 (en) 1999-06-30
FI932375A0 (en) 1993-05-25
PL299048A1 (en) 1994-02-21
DE69319664T2 (en) 1999-01-28
BG97766A (en) 1994-05-27
HUT66731A (en) 1994-12-28
DK0572288T3 (en) 1998-10-26
BR9302020A (en) 1993-11-30
DE69319664D1 (en) 1998-08-20
EP0572288B1 (en) 1998-07-15
LV10300B (en) 1995-04-20
KR960001012B1 (en) 1996-01-17
YU35293A (en) 1996-02-19
CN1079251A (en) 1993-12-08

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