KR930006244A - Fabric softening products consisting of pentaerythritol compounds and bentonite and methods of softening laundry using them - Google Patents

Fabric softening products consisting of pentaerythritol compounds and bentonite and methods of softening laundry using them Download PDF

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KR930006244A
KR930006244A KR1019920015325A KR920015325A KR930006244A KR 930006244 A KR930006244 A KR 930006244A KR 1019920015325 A KR1019920015325 A KR 1019920015325A KR 920015325 A KR920015325 A KR 920015325A KR 930006244 A KR930006244 A KR 930006244A
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bentonite
pentaerythritol
composition
fabric softening
pec
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KR1019920015325A
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KR100230557B1 (en
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에 삐엔떼-브라보 에뒤아르도
에르모질라 엠 아니따
엠아쉬에프 그랑메르 쟝-뽈
에 아 따끄 비비안느
에르 뻬동 쟝
젝 질리 마르셀
엠 랑베르 삐에르
아 에끌 뽈
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로버트 시이 설리반
콜게이트-파아므올리브 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/047—Arrangements specially adapted for dry cleaning or laundry dryer related applications
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/507—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2093—Esters; Carbonates

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Saccharide Compounds (AREA)
  • Materials For Medical Uses (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
  • Dental Preparations (AREA)
  • Woven Fabrics (AREA)
  • Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
  • Hydrogenated Pyridines (AREA)
  • Peptides Or Proteins (AREA)

Abstract

A fabric softening product is a composition or article that is effective for its fabric softening purpose but preferably excludes ecotoxic quaternary ammonium salt, includes, as a fabric softening component, a PEC, which is an ester of pentaerythritol, an ester of an oligomer of pentaerythritol, an ester of a lower alkoxylated pentaerythritol or an ester of a lower alkoxylated pentaerythritol oligomer, with bentonite, which increases its fabric softening effect remarkably. The PEC is preferably a partial higher fatty acid ester of pentaerythritol or a partial higher fatty acid ester or a pentaerythritol oligomer, the bentonite is preferably sodium bentonite or swellable calcium bentonite, the fabric softening composition is a softergent or a non-detersive composition, both of which may be in solid (preferably particulate solid) or liquid state or form (preferably in aqueous suspension or gel), and the fabric softening article is an absorbent material with bentonite and PEC deposited on it or absorbed by it. Also within the invention are processes for softening fibrous materials of laundry by contacting them with such compositions and/or articles during washing, rinsing and/or drying operations. <IMAGE>

Description

펜타에리쓰리톨 화합물 및 벤토나이트로 구성되는 직물유연 제품 및 그들을 사용하여 세탁물을 유연하게 하는 방법Fabric flexible products consisting of pentaerythritol compounds and bentonite and methods of using them to soften laundry

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도는 본 명세서의 실시예 1의 기본적인 배합의 조성물의 직물 유연효과를, 벤토나이트 함량을 변화시키면서, 벤토나이트 함량을 변화시키고 PEC 함량은 0%인 유사한 조성물의 직물 유연 효과와 비교한 플롯이고; 및FIG. 1 is a plot comparing the fabric softening effect of the composition of the basic blend of Example 1 herein with the fabric softening effect of a similar composition with varying bentonite content and with a PEC content of 0% with varying bentonite content; And

제2도는 실시예(1)의 기본적인 배합의 조성물의 직물 유연효과를, PEC함량을 변화시키면서, PEC함량을 변화시키고 벤토나이트 함량이 0%인 유사한 조성물 내에서 상기 효과와 비교한 플롯이다.2 is a plot comparing the fabric softening effect of the composition of the basic formulation of Example (1) with that effect in a similar composition with varying PEC content and 0% bentonite content with varying PEC content.

Claims (27)

펜타에리쓰리톨의, 펜타에리쓰리톨 올리고머의, 펜타에리쓰리톨의 저급알킬렌옥사이드 유도체의, 또는 펜타에리쓰리톨 올리고머의 저급알킬렌옥사이드 유도체의 고급 지방산 에스테르 또는 그의 혼합물인 직물 유연성분인 PEC, 및 몬모릴로나이트 점토로 구성되는, 섬유재료에 사용하기 위한 조성물 또는 물품으로서, 그의 직물유연성분이 섬유재료 상에 부착하여 섬유재료를 유연하게 하는, 직물 유연 제품.PEC which is a fabric flexible component which is a higher fatty acid ester or mixture of pentaerythritol, pentaerythritol oligomer, lower alkylene oxide derivative of pentaerythritol, or lower alkylene oxide derivative of pentaerythritol oligomer A composition or article for use in a textile material, comprising montmorillonite clay, and montmorillonite clay, wherein the fabric flexible component adheres on the textile material to make the textile material flexible. 제1항에 있어서, 세탁주기 또는 헹굼주기 조성물, 건조제 물품 또는 유연세제로서 이들내에서 몬모릴로나이트 점토가 사용 중 팽윤할 수 있는 직물 유연 제품.The fabric softening article according to claim 1, wherein montmorillonite clay can swell in use therein as a wash cycle or rinse cycle composition, desiccant article, or softener. 제2항에 있어서, 몬모릴로나이트 점토가 나트륨, 칼륨, 칼슘 또는 마그네슘 벤토나이트 또는 이들의 둘 이상의 혼합물이고, PEC가 펜타에리쓰리톨의 또는 펜타에리쓰리톨 올리고머의 부분적인 고급 지방족 에스테르인 직물 유연 제품.The fabric softening product according to claim 2, wherein the montmorillonite clay is sodium, potassium, calcium or magnesium bentonite or a mixture of two or more thereof and the PEC is a partially higher aliphatic ester of pentaerythritol or pentaerythritol oligomer. 제3항에 있어서, 사차 암모늄 화합물 직물 유연제가 필수적으로 없는 직물 유연 제품.The fabric softening article of claim 3, essentially free of quaternary ammonium compound fabric softener. 제4항에 있어서, 음이온 및/또는 비이온 형(들)의 합성 유기세제, PEC 및 벤토나이트로 구성되는 유연세제 인, 빅물 유연 제품.The big water softener product according to claim 4, which is a softener composed of synthetic organic detergents of anionic and / or nonionic type (s), PEC and bentonite. 제5항에 있어서, 합성 유기 세제가 조성물의 3 내지 35% 이고, PEC가 조성물의 2 내지 20% 이고 벤토나이트가 조성물의 10 내지 30%인, 입상 형태의 유연세제 조성물.The softener composition of claim 5 wherein the synthetic organic detergent is 3 to 35% of the composition, the PEC is 2 to 20% of the composition and the bentonite is 10 to 30% of the composition. 제6항에 있어서, 합성 유기 세제가 음이온 및 비이온 세제의 혼합몰이며, 이의 분량이 3 내지 25%의 범위내 이고, 조성물이 10 내지 60%의 빌더로 구성되며, PEC 및 벤토나이트의 분량이 2 내지 15% 및 10 내지 25%의 범위내인 입상 유연세제 조성물.7. The synthetic organic detergent of claim 6, wherein the synthetic organic detergent is a mixed mole of anionic and nonionic detergent, the amount of which is in the range of 3 to 25%, the composition consists of 10 to 60% of the builder, and the amount of PEC and bentonite Granular softener composition in the range of 2 to 15% and 10 to 25%. 제7항에 있어서, 음이온 세제가 설페이트와 및/또는 설폰화 세제이고, 비이온 세제는 고급 지방 알코올 및 에틸렌 옥사이드의 축합 생성물이고, 빌더는 수용성 알칼리 금속 폴리인산염, 탄산염, 규산염, 붕산염, 구연산 염, 중탄산염, 글로코네이트, 니트릴로트리아세테이트 및 에틸렌디아민 테트라아세테이트, 수 불용성 물 유연 제올라이트, 및 이의 혼합물로 구성된 군으로 부터 선택되고, PEC는 펜타에리쓰리톨의 또는 펜타에리쓰리톨 올리고머의 고급 지방족 산 부분 에스테르이며, 벤토나이트인 입상 유연 세제 조성물.The method of claim 7, wherein the anionic detergent is a sulfate and / or sulfonated detergent, the nonionic detergent is a condensation product of a higher fatty alcohol and ethylene oxide, and the builder is a water soluble alkali metal polyphosphate, carbonate, silicate, borate, citrate. , Bicarbonate, gloconate, nitrilotriacetate and ethylenediamine tetraacetate, water insoluble water flexible zeolites, and mixtures thereof, PEC is a higher aliphatic acid of pentaerythritol or pentaerythritol oligomer A granular flexible detergent composition which is a partial ester and is bentonite. 제8항에 있어서, 1 내지 10%의 나트륨 고급 알킬벤젠 설포네이트, 1몰의 고급 지방알코올 및 5 내지 10몰의 에틸렌 옥사이드의 축합 생성물인, 1 내지 10%의 비이온 세제, 2 내지 10%의 규산나트륨, 15 내지 35%의 나트륨 트리폴리포스페이트, 2 내지 10%의 탄산 나트륨, 3 내지 10%의 펜타에리쓰리톨 고급 지방족 산 부분 에스테르 및 12 내지 20%의 나트륨 및/또는 칼슘 벤토나이트로 구성되는 입상 유연세제 조성물.1-10% nonionic detergent according to claim 8, which is a condensation product of 1-10% sodium higher alkylbenzene sulfonate, 1 mole higher fatty alcohol and 5-10 moles of ethylene oxide, 2-10% Consisting of sodium silicate, 15-35% sodium tripolyphosphate, 2-10% sodium carbonate, 3-10% pentaerythritol higher aliphatic acid partial ester and 12-20% sodium and / or calcium bentonite Granular softener composition. 제9항에 있어서, 펜타에리쓰리톨의 고급 지방족 산 부분 에스테르가 펜타에리쓰리톨 디스테아레이트이고 벤토나이트가 칼슘 벤토나이트인 입상 유연세제 조성물.The granular softener composition according to claim 9, wherein the higher aliphatic acid partial ester of pentaerythritol is pentaerythritol distearate and bentonite is calcium bentonite. 제5항에 있어서, 수성 메질 내에서, 3 내지 20%의 합성 유기 세제, 2 내지 20%의 PEC 및 10 내지 30%의 벤토나이트를 포함하는 액체 또는 겔 형태의 유연세제 조성물.6. The softener composition according to claim 5 in the form of a liquid or gel comprising 3-20% synthetic organic detergent, 2-20% PEC and 10-30% bentonite in aqueous medium. 제4항에 있어서, 입상 또는 분말 형태이고. 약 1 내지 40%의 PEC 및 약 60 내지 99%의 입상 또는 분말 벤토나이트로 구성되는 헹굼 주기 또는 세탁 주기 첨가제인 직물 유연 제품.The composition of claim 4 in the form of granular or powder. A fabric softening product that is a rinse cycle or wash cycle additive consisting of about 1 to 40% PEC and about 60 to 99% granular or powdered bentonite. 제12항에 있어서, PEC가 그것을 위한 운반체로서 작용하는 벤토나이트내에 환산되는 직물 유연 제품.13. The fabric softening article according to claim 12, wherein the PEC is converted into bentonite which acts as a carrier for it. 제13항에 있어서, 1 내지 10%의 펜타에리쓰리톨의 고급 지방족 산 부분 에스테르 또는 펜타에리쓰리톨 올리고머의 고급 지방족산 부분 에스테르, 또는 이들의 혼합물, 및 90 내지 99%의 벤토나이트로 구성되는 입상 또는 분말 형태의 직물 유연 제품.The granular composition of claim 13 comprising 1 to 10% of a higher aliphatic acid partial ester of pentaerythritol or a higher aliphatic acid partial ester of pentaerythritol oligomer, or a mixture thereof, and 90 to 99% of bentonite. Or fabric flexible products in powder form. 제14항에 있어서, 3 내지 7%의 펜타에리쓰리톨의 고급 지방 C12-18부분 에스테르 및 93 내지 97%의 나트륨 벤토나이트 또는 칼슘 벤토나이트로 구성되는 직물 유연 조성물.15. The fabric softening composition of claim 14 consisting of 3-7% higher fatty C 12-18 partial esters of pentaerythritol and 93-97% sodium bentonite or calcium bentonite. 제15항에 있어서, PEC는 펜타에리쓰리톨 디스테아레이트이고, 벤토나이트는 칼슘 벤토나이트이고, 어떠한 사차 암모늄 화합물도 존재하지 않으며, 이온화할 수 있는 나트륨 화합물이 조성물내에 존재하고/존재하거나 나트륨 이온이 조성물이 사용될 세탁수 또는 헹굼수내에 존재하여, 칼슘 벤토나이트를 나트륨 벤토나이트로 전환시키는 직물 유연 조성물.The composition of claim 15 wherein the PEC is pentaerythritol distearate, the bentonite is calcium bentonite, no quaternary ammonium compound is present, and an ionizable sodium compound is present in the composition and / or sodium ions are present in the composition. Fabric softening composition which is present in the wash water or rinse water to be used to convert calcium bentonite to sodium bentonite. 제16항에 있어서, 약 6%의 펜타에리쓰리톨 디스테아레이트 및 약 94%외 칼슈 벤토나이트로 구성되는 조성물.The composition of claim 16 consisting of about 6% pentaerythritol distearate and about 94% extra Kalsch bentonite. 제4항에 있어서, 액체 형태이고, 액체 매질내에 약 1 내지 40분의 PEC 및 약 60 내지 99분의 벤토나이트로 구성되는 조성물.The composition of claim 4 in liquid form and consisting of about 1 to 40 minutes of PEC and about 60 to 99 minutes of bentonite in the liquid medium. 제18항에 있어서, 1 내지 10%의, 펜타에리쓰리톨의 또는 펜타에리쓰리톨 올리고머의 고급 지방족산 부분 에스테르, 10 내지 30%의 벤토나이트 및 50 내지 89%의 수성 매질로 구성되는 조성물.19. The composition of claim 18, consisting of 1 to 10% of a higher aliphatic acid partial ester of pentaerythritol or of pentaerythritol oligomer, 10 to 30% bentonite and 50 to 89% aqueous medium. 제19항에 있어서, 3 내지 7%의 펜타에리쓰리톨의 고급 지방 C12-18부분 에스테르, 10 내지 24%의 나트륨 및/또는 칼슘 벤토나이트 및 실질적으로 물인, 60 내지 85%의 수성 매질로 구성되는 조성물.20. An aqueous medium according to claim 19 consisting of 3 to 7% higher fatty C 12-18 partial esters of pentaerythritol, 10 to 24% sodium and / or calcium bentonite and substantially water. Composition. 제20항에 있어서, 약 6%의 펜타에리쓰리톨 디스테아레이트, 약 16%의 칼슘 벤토나이트 및 65 내지 76%의 물을 포함하는 세탁 주기 첨가제인 직물 유연 조성물.The fabric softening composition of claim 20 which is a laundry cycle additive comprising about 6% pentaerythritol distearate, about 16% calcium bentonite and 65 to 76% water. 제2항에 있어서, 직물 유연 성분이 부과되거나, 그로써 직물 유연 제품을 기준으로, 약 1 내지 25%의 직물 유연 성분이 흡착되는 흡착 섬유 또는 기포 재료로 구성되는 직물 유연 건조제 물품.3. The fabric softening desiccant article of claim 2 consisting of adsorbent fibers or a foam material to which a fabric softening component is imposed, thereby adsorbing about 1 to 25% of the fabric softening component, based on the fabric softening product. 제22항에 있어서, 펜타에리쓰리톨의 고급 부분 지방에스테르, 펜타에리쓰리톨 올리고머의 부분 에스테르 또는 이들의 혼합물로 구성된 5 내지 95%의 직물 유연 성분, 및 벤토나이트가 함침된 종이 시이트로 구성되는 직물 유연 물품.23. The fabric of claim 22 wherein the fabric consists of 5 to 95% fabric softening components consisting of higher partial fatty esters of pentaerythritol, partial esters of pentaerythritol oligomers, or mixtures thereof, and paper sheets impregnated with bentonite. Flexible goods. 직물 유연 제품의, 직물 유연 성분인 세탁물에 부착되어 세탁물을 유연하게 하는 방식 및 건조하에서, 제2항의 직물 유연 제품을 세탁물에 적용하는 것으로 구성되는 세탁물을 유연하게 하는 방법.A method of softening a laundry comprising applying the fabric soft product of claim 2 to the laundry in a manner and drying in a fabric softening product attached to the laundry as the fabric softening component to soften the laundry. 제24항에 있어서, 세탁물에 적용된 직물 유연 제품이 음이온 및/또는 비이온 형(들)의 합성 유기 세제 PEC 및 벤토나이트로 구성되는, 세탁수 내에서 세탁물에 적용되는 유연세제 조성물인 방법.The method of claim 24 wherein the fabric softening product applied to the laundry is a softener composition applied to the laundry in wash water, consisting of synthetic organic detergent PEC and bentonite in anionic and / or nonionic type (s). 제24항에 있어서, 직물 유연 제품인 PEC 및 벤토나이트로 구성되는, 세탁수내에서 또는 헹굼시에 세탁물에 적용되는 헹굼 또는 세탁주기 조성물인 방법.The method of claim 24, which is a rinse or wash cycle composition applied to the laundry in or upon rinsing, consisting of PEC and bentonite, which is a fabric softening product. 제24항에 있어서, 직물 유연 제품이 PEC 및 벤토나이트를 함유하는, 세탁물 건조기 내에서 세탁물에 적용되는 건조제 물품으로, 상기 물품이 PEC 및 벤토나이트가 부착되거나 흡착되는 흡착 섬유 또는 기포 재료인 방법.The method of claim 24, wherein the fabric softening product is a desiccant article applied to the laundry in a laundry dryer containing PEC and bentonite, the article being an adsorbent fiber or foam material to which the PEC and bentonite are attached or adsorbed. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920015325A 1991-09-06 1992-08-25 Fabric softening products based on a combination of pentaery thritol compounds and bentonite KR100230557B1 (en)

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