KR930004494A - An improved method of applying a metal film on isotropic boron nitride and articles made therefrom - Google Patents

An improved method of applying a metal film on isotropic boron nitride and articles made therefrom Download PDF

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Publication number
KR930004494A
KR930004494A KR1019920013800A KR920013800A KR930004494A KR 930004494 A KR930004494 A KR 930004494A KR 1019920013800 A KR1019920013800 A KR 1019920013800A KR 920013800 A KR920013800 A KR 920013800A KR 930004494 A KR930004494 A KR 930004494A
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South Korea
Prior art keywords
particles
boron nitride
nickel
boron
electrolessly
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KR1019920013800A
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Korean (ko)
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KR100292310B1 (en
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도미니크 이어코반젤로 찰스
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아더 엠. 킹
제네랄 일렉트릭 캄파니
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/31—Coating with metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/4584—Coating or impregnating of particulate or fibrous ceramic material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/48—Coating with alloys
    • C23C18/50—Coating with alloys with alloys based on iron, cobalt or nickel

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Chemically Coating (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Physical Vapour Deposition (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Cubic boron nitride particles are electrolessly nickel plated with a nickel alloy formed with a metalloid, such as boron. Electrolessly plated particles are then gradually heated at a steady rate from room temperature to a desired heat treatment temperature in a non-oxidizing atmosphere formed by argon containing 10% hydrogen. Exemplary articles made by the aforementioned process include a grinding wheel having uniformly dispersed abrasive cubic boron nitride particles having the Ni/B alloy coat thereon.

Description

등축정계 질화 붕소상의 금속 피막을 적용시키는 개선된 방법 및 그로부터 제조된 제품Improved method of applying metal coatings on equiaxed boron nitride and articles made therefrom

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (10)

등축정계 질화 붕소 제품을 목적하는 두께로 도금하기에 효과적인 시간동안, 금속 합금의 화합물과 붕소, 몰리브덴, 티탄, 니오브 및 크롬으로 이루어진 군으로부터 선택된 원소의 화합물을 함유한, 상기 젠품의 표면을 도금하기위한 무전해 도금조와 접촉시키는 단계, 상기 무전래적으로 도금된 제품을 비-산화 대기중에서 예정된 속도로 제1온도에서부터 목적하는 열 처리 온도까지 서서히 가열하는 단계, 및 상기 표면과 상기 금속 합금 피막 사이에서 목적하는 정도의 접착력을 이룰때까지, 상기 무전해적으로 도금된 제품을 상기 목적하는 열 처리 온도에서 유지시키는 단계를 포함하는, 등축정계 질화붕소 제품의 표면에 대한 금속 합금 피막의 접착력을 개선시키는 방법.During the time effective to plate an equiaxed boron nitride product to the desired thickness, plating the surface of the zenith containing a compound of a metal alloy and a compound of an element selected from the group consisting of boron, molybdenum, titanium, niobium and chromium Contacting an electroless plating bath for the purpose, gradually heating the electrolessly plated product from a first temperature to a desired heat treatment temperature at a predetermined rate in a non-oxidizing atmosphere, and between the surface and the metal alloy coating Maintaining the electrolessly plated product at the desired heat treatment temperature until the desired degree of adhesion is achieved at a method of improving the adhesion of the metal alloy film to the surface of an equiaxed boron nitride product. . 제 1항에 있어서, 상기 금속 합금이 붕소와 니켈의 합금인 방법.The method of claim 1 wherein the metal alloy is an alloy of boron and nickel. 제1항에 있어서, 무전해적으로 적용되거나 전해적으로 적용된 제2금속 층을 상기 금속 합금 피막의 상부에 용착시키는 단계를 추가로 포함하는 방법.The method of claim 1, further comprising depositing an electrolessly applied or electrolytically applied second metal layer on top of the metal alloy coating. 제1항에 있어서, 상기 도금조를 약 5.0내지 역 10.0의 pH로 유지시키는 방법.The method of claim 1, wherein the plating bath is maintained at a pH of about 5.0 to about 10.0. 제1항에 있어서, 상기 원소의 화합물이 약 0.005M 내지 약 0.1M농도의 디메틸아민 보란인 방법.The method of claim 1, wherein the compound of element is dimethylamine borane at a concentration of about 0.005M to about 0.1M. 제1항에 있어서, 상기 제1온도가 실온인 방법.The method of claim 1 wherein said first temperature is room temperature. 등축정계 질화붕소 입자의 표면을 니켈 합금 피막으로 도금하기에 효과적인 시간동안, 니켈 합금의 화합물과 붕소, 몰리브렌, 티탄, 니오브 및 크롬으로 이루어진 군으로부터 선택된 원소의 화합물을 또한 함유한 무전해 도금조와 상기 입자를 접촉시키는 단계, 상기 무전해적으로 도금된 입자를 비-산화 대기중에서 예저오딘 속도로제1온도에서부터 목적하는 열처리 온도까지 서서히 가열하는 단계, 및 상기 표면과 상기 니켈 합금 피막사이에서 목적하는 정도의 접착력을 이룰때까지, 상기 무전해적으로 도금된 입자를 상기 목적하는 열 처리 온도에서 유지시키는 단계를 포함하는, 등축정계 질화붕소 입자의 표면에 대한 목적하는 두께의 니켈 합금 피막의 접착력을 개선시키는 방법.An electroless plating bath which also contains a compound of a nickel alloy and a compound of an element selected from the group consisting of boron, molybdenum, titanium, niobium and chromium for a time effective for plating the surface of the equiaxed boron nitride particles with a nickel alloy film; Contacting the particles, gradually heating the electrolessly plated particles from a first temperature to a desired heat treatment temperature at a low ozone rate in a non-oxidizing atmosphere, and a desired degree between the surface and the nickel alloy film. Maintaining the electroless plated particles at the desired heat treatment temperature until they achieve an adhesion of the nickel alloy film of desired thickness to the surface of the equiaxed boron nitride particles. . 제7항에 있어서, 상기 도금조를, 상기 입자의 가교를 방지하기 위하여 상기 표면을 도금하는 동안 교반시키는 방법.8. The method of claim 7, wherein the plating bath is stirred while plating the surface to prevent crosslinking of the particles. 제8항에 있어서, 상기 무전해적으로 도금된 입자들에 무전해적으로 적용된 니켈인 합금의 제2층을 추가로 제공하는 방법.The method of claim 8, further providing a second layer of an alloy that is nickel electrolessly applied to the electrolessly plated particles. 수지상 매트릭스와 그안에 균일하게 분산되어 매립된 등축정계 질화붕소 입자를 포함하며, 상기 입자의 표면과 수지상 매트릭스 사이의 접착력을 개선시키기 위하여, 상기 입자의 표면상에 붕소, 몰리브덴, 티탄, 니오브 및 크롬으로 이루어진 군으로부터 선택된 붕소와 니켈과의 합금을 포함한 니켈 합금 피막을 무전해적으로 도금한 개선된 연마 공구.And equiaxed boron nitride particles uniformly dispersed and embedded therein, in order to improve the adhesion between the surface of the particles and the dendritic matrix, boron, molybdenum, titanium, niobium and chromium on the surface of the particles; An improved abrasive tool electrolessly plated a nickel alloy coating comprising an alloy of boron and nickel selected from the group consisting of: ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019920013800A 1991-08-01 1992-07-31 Method for preparing equiaxed boron nitride product coated with nickel alloy with improved adhesion and equiaxed boron nitride product prepared therefrom KR100292310B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US738,758 1991-08-01
US07/738,758 US5188643A (en) 1991-08-01 1991-08-01 Method of applying metal coatings on cubic boron nitride and articles made therefrom

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KR930004494A true KR930004494A (en) 1993-03-22
KR100292310B1 KR100292310B1 (en) 2001-06-01

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US (1) US5188643A (en)
EP (1) EP0526158B1 (en)
JP (1) JP3471825B2 (en)
KR (1) KR100292310B1 (en)
AT (1) ATE131218T1 (en)
CA (1) CA2072274C (en)
DE (1) DE69206510T2 (en)
ES (1) ES2082376T3 (en)
IE (1) IE73877B1 (en)
ZA (1) ZA925390B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100449223B1 (en) * 2000-06-29 2004-09-18 인터내셔널 비지네스 머신즈 코포레이션 Method for depositing copper onto a barrier layer

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5626909A (en) * 1994-12-07 1997-05-06 General Electric Company Fabrication of brazable in air tool inserts
DE10129599A1 (en) * 2001-06-20 2003-01-09 Scintilla Ag Tool for machine tools
US20040137229A1 (en) * 2003-01-09 2004-07-15 General Electric Company Autocatalytic nickel-boron coating process for diamond particles
US7311615B2 (en) * 2005-07-01 2007-12-25 Charles Hsu Golf club head with ceramic layer
CA2736753C (en) * 2008-09-16 2015-09-01 Diamond Innovations, Inc. Abrasive grains having unique features
EP2470317A4 (en) * 2009-08-27 2015-04-01 Smith International Method of forming metal deposits on ultrahard materials
US8936432B2 (en) * 2010-10-25 2015-01-20 United Technologies Corporation Low density abradable coating with fine porosity
JP5771882B2 (en) * 2010-10-28 2015-09-02 住友電工ハードメタル株式会社 Surface-coated sintered body

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3853582A (en) * 1970-02-02 1974-12-10 Raytheon Co Metallized isotropic boron nitride body and method for making same
US3762895A (en) * 1971-05-07 1973-10-02 G Keeleric Method of making metal bonded abrasives by electroless deposition
ZA781390B (en) * 1978-03-09 1979-04-25 De Beers Ind Diamond The metal coating of abrasive particles
US4381227A (en) * 1980-07-31 1983-04-26 Norton Company Process for the manufacture of abrasive-coated tools
JPS6075582A (en) * 1983-09-29 1985-04-27 Komatsu Ltd Electroless plating method of ultra abrasive
US4591363A (en) * 1985-07-31 1986-05-27 Silverman Warren J Process of making a coated abrasive for diamond grinding wheels
JPH02503696A (en) * 1987-05-12 1990-11-01 マッコーマス，チャールズ，エドワード Stabilized non-electrolytic bath for wear-resistant metal coatings
US4983428A (en) * 1988-06-09 1991-01-08 United Technologies Corporation Ethylenethiourea wear resistant electroless nickel-boron coating compositions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100449223B1 (en) * 2000-06-29 2004-09-18 인터내셔널 비지네스 머신즈 코포레이션 Method for depositing copper onto a barrier layer

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ATE131218T1 (en) 1995-12-15
DE69206510T2 (en) 1996-06-05
IE73877B1 (en) 1997-07-02
JP3471825B2 (en) 2003-12-02
EP0526158B1 (en) 1995-12-06
ES2082376T3 (en) 1996-03-16
DE69206510D1 (en) 1996-01-18
EP0526158A1 (en) 1993-02-03
IE922537A1 (en) 1993-02-10
US5188643A (en) 1993-02-23
JPH05195267A (en) 1993-08-03
ZA925390B (en) 1993-09-30
KR100292310B1 (en) 2001-06-01
CA2072274A1 (en) 1993-02-02
CA2072274C (en) 2003-04-08

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