KR930004403A - Process for preparing diarylidene pigment - Google Patents

Process for preparing diarylidene pigment Download PDF

Info

Publication number
KR930004403A
KR930004403A KR1019920010755A KR920010755A KR930004403A KR 930004403 A KR930004403 A KR 930004403A KR 1019920010755 A KR1019920010755 A KR 1019920010755A KR 920010755 A KR920010755 A KR 920010755A KR 930004403 A KR930004403 A KR 930004403A
Authority
KR
South Korea
Prior art keywords
acetoacet
coupling component
treatment
coupling
component
Prior art date
Application number
KR1019920010755A
Other languages
Korean (ko)
Inventor
모덴트 앨리슨
턱 브라이언
Original Assignee
베르너 발데크
시바-가이기 아게
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 베르너 발데크, 시바-가이기 아게 filed Critical 베르너 발데크
Publication of KR930004403A publication Critical patent/KR930004403A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B31/00—Disazo and polyazo dyes of the type A->B->C, A->B->C->D, or the like, prepared by diazotising and coupling
    • C09B31/16—Trisazo dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
    • C09B35/02—Disazo dyes
    • C09B35/039—Disazo dyes characterised by the tetrazo component
    • C09B35/08—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of biphenyl
    • C09B35/10—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of biphenyl from two coupling components of the same type
    • C09B35/105—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of biphenyl from two coupling components of the same type from two coupling components with reactive methylene groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0001—Post-treatment of organic pigments or dyes
    • C09B67/0004—Coated particulate pigments or dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0046—Mixtures of two or more azo dyes
    • C09B67/0055—Mixtures of two or more disazo dyes

Abstract

내용 없음.No content.

Description

디아릴리드 안료의 제조방법Process for preparing diarylidene pigment

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (30)

a) 화학량론적 양의 커플링 성분 1개 이상과 테트라아조 성분을 커플링시키고; b)이렇게 수득한 안료 반응 혼합물에서, 화학량론적 양의 커플링 성분 1개 이상과 테트라아조 성분을 커플링시키며, 단 단계 a)와 b)에 사용되는 커플링 성분의 총 수가 3개 이상이고; 또 c)이렇게 수득한 안료를 후처리시키는 것을 포함하는, 디아릴 리드 안료의 제조방법.a) coupling at least one stoichiometric amount of coupling component with a tetraazo component; b) in the pigment reaction mixture thus obtained, at least one stoichiometric amount of coupling component and a tetraazo component are coupled, provided that the total number of coupling components used in steps a) and b) is at least 3; And c) a post-treatment of the pigment thus obtained. 제1항에 있어서, 단계 a)와 b)각각에 사용되는 테트라아조 성분이 동일한 화합물인 방법.The process of claim 1 wherein the tetraazo component used in each of steps a) and b) is the same compound. 제2항에 있어서, 테트라아조 성분이 3, 3′－디클로로벤지딘인 방법.The method according to claim 2, wherein the tetraazo component is 3, 3'-dichlorobenzidine. 제1항 내지 제3항중 어느 하나에 있어서, 단계 a) 및 b)에 사용되는 각각의 커플링 성분이 아세토아세트아릴리드 또는 아릴피라졸론인 방법.The process according to claim 1, wherein each coupling component used in steps a) and b) is acetoacetalilide or arylpyrazolone. 제4항에 있어서, 아세토아세트아릴리드 커플링 성분이 하기 일반식(Ⅰ)의 화합물인 방법.The method according to claim 4, wherein the acetoacetalilide coupling component is a compound of formula (I): 상기식에서 치환기 각각은 동일하거나 또는 상이하고 수소 클로로 브로모 니트로 아미노 C1－C6알콕시 페닐 또는 페녹시이며 n은 1 내지 5이다.Wherein each substituent is the same or different and is hydrogen chloro bromo nitro amino C 1 -C 6 alkoxy phenyl or phenoxy and n is 1-5. 제5항에 있어서, 일반식(Ⅰ)의 커플링 성분이 아세토아세트아닐리드, 아세토아세트－m－크실리디드, 아세토아세트－o－톨루이디드, 아세토아세트－p－톨루이디드, 아세토아세트－o－아니시디드, 아세토아세트－o－클로로아닐리드, 또는 아세토아세트－2, 5－디메톡시－4－클로로아닐리드인 방법.The coupling component of formula (I) is acetoacetanilide, acetoacet-m-xylide, acetoacet-o-toluided, acetoacet-p-toluid, acetoacet- o-anisidide, acetoacet-o-chloroanilide, or acetoacet-2, 5-dimethoxy-4-chloroanilide. 제4항에 있어서, 아릴피라졸론 커플링 성분이 하기 일반식(Ⅱ)의 화합물인 방법;The method according to claim 4, wherein the arylpyrazolone coupling component is a compound of the following general formula (II); 상기 식에서, Z 및 n은 제5항에서 정의한 바와 같고, W는 메틸 또는 카르복시에틸이다.Wherein Z and n are as defined in claim 5 and W is methyl or carboxyethyl. 제7항에 있어서, 일반식(Ⅱ)의 커플링 성분이 3－메틸－1－페닐－5－피라졸론 또는 3－메틸－1－p－톨릴－5－피라졸론인 방법.The method according to claim 7, wherein the coupling component of formula (II) is 3-methyl-1-phenyl-5-pyrazolone or 3-methyl-1-p-tolyl-5-pyrazolone. 제4항 내지 제6항중 어느 하나에 있어서, 단계 a) 또는 단계 b)에 사용되는 커플링 성분이 아세토아세트－2, 5－디메톡시－4－클로로아닐리드 및/또는 아세토아세트－m－크실리디드인 방법.The coupling component used in step a) or step b) is acetoacet-2, 5-dimethoxy-4-chloroanilide and / or acetoacet-m-xyl. Did-In Method. 제4항 내지 제9항중 어느 하나에 있어서, 본 방법의 단계 a)에 사용되는 커플링 성분중 1개를 본 방법의 단계 b)에도 사용하는 방법.10. The method according to any one of claims 4 to 9, wherein one of the coupling components used in step a) of the process is also used in step b) of the process. 제4항 내지 제10항중 어느 하나에 있어서, 본 방법의 단계 a)와 b)각각에 2개의 커플링 성분을 사용하는 방법.The method according to any one of claims 4 to 10, wherein two coupling components are used in each of steps a) and b) of the method. 제11항에 있어서, 커플링 성분의 쌍이 아세토아세트－m－크실리디드와 아세토아세트－2, 5－디메톡시－4－클로로아닐리드; 아세토아세트－m－크실리디드와 아세토아세트아닐리드 : 아세토아세트－m－크실리디드와 아세토아세토－o－톨루이디드, 아세토아세트－m－크실리디드와 아세토아세트－o－클로로아닐리드; 또는 아세토아세트－m－크실리디드와 아세토아세트－o－아니시디드인 방법.12. The composition of claim 11, wherein the pair of coupling components comprises: acetoacet-m-xylide and acetoacet-2, 5-dimethoxy-4-chloroanilide; Acetoacet-m-xylide and acetoacetanilide: acetoacet-m-xylide and acetoaceto-o-toluid, acetoacet-m-xylide and acetoacet-o-chloroanilide; Or acetoacet-m-xylide and acetoacet-o-anisidide. 제1항 내지 제12항중 어느 하나에 있어서, 각 단계에 2개의 커플링 성분을 사용하고, 각 단계에서 제2커플링 성분에 대한 제1커플링 성분의 몰비가 1 내지 99 : 99 내지 1인 방법.The method according to any one of claims 1 to 12, wherein two coupling components are used in each step, and the molar ratio of the first coupling component to the second coupling component in each step is 1 to 99:99 to 1. Way. 제13항에 있어서, 각각의 단계에서 제2커플링 성분에 대한 제1커플링 성분의 몰비가 5 내지 95 : 95내지 5인 방법.The method of claim 13, wherein the molar ratio of the first coupling component to the second coupling component in each step is between 5 and 95: 95 and 5. 제1항 내지 제14항중 어느 한 항에 있어서, 단계 b)에서의 총 커플링 성분에 대한 단계 a)에서의 총 커플링 성분의 비가 1 내지 99 : 99내지 1인 방법.The method according to any one of claims 1 to 14, wherein the ratio of the total coupling component in step a) to the total coupling component in step b) is 1 to 99:99 to 1. 제15항에 있어서, 단계 b)에서의 총 커플링 성분에 대한 단계 a)에서의 총 커플링 성분의 비가 5 내지 95;95내지 5인 방법.The method of claim 15, wherein the ratio of the total coupling component in step a) to the total coupling component in step b) is from 5 to 95; 95 to 5. 제1항 내지 제16항중 어느 한 항에 있어서, 후처리방법이 가열처리; 유기 용매를 사용한 처리; 음이온성, 양이온성, 양쪽성 또는 비이온성 계면활성제를 사용한 처리; 지방족 1차 아민을 사용한 처리; 수지를 사용한 처리 및/또는 수용성 아조 염료를 사용한 처리중 1개 이상인 방법.The post-treatment method according to any one of claims 1 to 16, wherein the post-treatment method is heat treatment; Treatment with an organic solvent; Treatment with anionic, cationic, amphoteric or nonionic surfactants; Treatment with aliphatic primary amines; At least one of treatment with resin and / or treatment with water-soluble azo dyes. 제17항에 있어서, 후처리방법이 천연 또는 합성 수지를 사용한 처리를 포함하는 방법.18. The method of claim 17, wherein the post-treatment method comprises treatment with natural or synthetic resins. 제18항에 있어서, 수지가 목재 로진 또는 화학적 방법에 의해 개질된 로진인 방법.19. The method of claim 18, wherein the resin is wood rosin or rosin modified by chemical methods. 제17항 내지 제19항중 어느 한 하나에 있어서, 후처리하는데 사용되는 수지의 비율이 제조된 최종 디아릴리드 안료의 중량에 대해 1 내지 60중량%인 방법.20. The process according to any one of claims 17 to 19, wherein the proportion of resin used for workup is 1 to 60% by weight relative to the weight of the final diarylidene pigment prepared. 제20항에 있어서, 후처리하는데 사용되는 수지의 비율이 제조된 최종 디아릴리드 안료의 중량에 대해 25 내지 45중량%인 방법.21. The process of claim 20, wherein the proportion of resin used for workup is from 25 to 45% by weight relative to the weight of the final diarylidene pigment prepared. 제17항 내지 제21항중 어느 하나에 있어서, 후처리방법이 수용성 아조 염료를 사용한 처리를 포함하는 방법.The method according to any one of claims 17 to 21, wherein the post-treatment method includes a treatment using a water-soluble azo dye. 제1항 내지 제22항중 어느 하나에 따른 방법에 의해 제조된 디아릴리드 안료.Diarylidene pigments prepared by the process according to claim 1. 제23항에 따른 안료를 착색제로서 함유하는 표면 도료 또는 플라스틱.Surface paints or plastics containing the pigment according to claim 23 as a colorant. 제23항에 따른 안료를 착색제로서 함유하는 인쇄 잉크.A printing ink containing the pigment according to claim 23 as a colorant. ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.※ Note: This is to be disclosed by the original application.
KR1019920010755A 1991-08-09 1992-06-18 Process for preparing diarylidene pigment KR930004403A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9117292.4 1991-08-09
GB919117292A GB9117292D0 (en) 1991-08-09 1991-08-09 Coupling process

Publications (1)

Publication Number Publication Date
KR930004403A true KR930004403A (en) 1993-03-22

Family

ID=10699793

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920010755A KR930004403A (en) 1991-08-09 1992-06-18 Process for preparing diarylidene pigment

Country Status (5)

Country Link
EP (1) EP0529849A1 (en)
JP (1) JPH05202308A (en)
KR (1) KR930004403A (en)
CA (1) CA2075608A1 (en)
GB (1) GB9117292D0 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100437773B1 (en) * 2001-09-28 2004-06-30 엘지전자 주식회사 Refrigerator for storing kimchi

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5792249A (en) * 1995-01-25 1998-08-11 Canon Kabushiki Kaisha Liquid composition, ink set, image-forming method and apparatus using the same
EP0957136B1 (en) * 1998-05-11 2001-12-05 Dainippon Ink And Chemicals, Inc. Additive for a pigment containing disazo compounds, and pigment compositions containing it
KR100596717B1 (en) 2005-01-19 2006-07-10 대한스위스화학 주식회사 Manufacturing method of diarylide yellow pigments with good rheology
JP4892898B2 (en) * 2005-09-09 2012-03-07 東洋インキＳｃホールディングス株式会社 Disazo pigment composition and method for producing the same
JP4816219B2 (en) * 2006-04-20 2011-11-16 Ｄｉｃ株式会社 Method for producing disazo pigment composition
CN104263002A (en) * 2014-08-19 2015-01-07 上虞市东海化工有限公司 Preparation method of yellow pigment
CN106349735B (en) * 2016-08-30 2017-09-05 上虞市东海化工有限公司 A kind of preparation method of yellow uitramarine

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH105849A (en) * 1922-02-13 1924-07-01 Farbenfab Vorm Bayer F & Co Process for the preparation of an azo dye.
DE1813522A1 (en) * 1968-12-09 1970-06-25 Hoechst Ag Dye mixtures from water-insoluble disazo dyes and processes for their preparation
GB1356253A (en) * 1970-05-06 1974-06-12 Ciba Geigy Uk Ltd Azo pigment compositions
US4341701A (en) * 1979-11-07 1982-07-27 Ciba-Geigy Corporation Production of pigments
DE3329846A1 (en) * 1983-08-18 1985-02-28 Basf Farben + Fasern Ag, 2000 Hamburg MODIFIED DIARYLIDE PIGMENTS AND METHOD FOR THE PRODUCTION THEREOF
US4648907A (en) * 1985-04-12 1987-03-10 Basf Corporation High color strength diarylide yellow pigment compositions

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100437773B1 (en) * 2001-09-28 2004-06-30 엘지전자 주식회사 Refrigerator for storing kimchi

Also Published As

Publication number Publication date
CA2075608A1 (en) 1993-02-10
JPH05202308A (en) 1993-08-10
EP0529849A1 (en) 1993-03-03
GB9117292D0 (en) 1991-09-25

Similar Documents

Publication Publication Date Title
KR890006769A (en) Use of colorants for use in recording fluids
KR890006759A (en) Pigment Compositions Based on Aceto Acetalilide Derivatives
KR930004403A (en) Process for preparing diarylidene pigment
DK165337C (en) PROCEDURE FOR TRICHROMY COLORING OR PRINTING OF NATURAL OR SYNTHETIC POLYAMIDE MATERIALS
KR940014690A (en) Dye mixtures containing azo dyes with diaminopyridine-based coupling components
FR2413447A1 (en) AQUEOUS TINCTORIAL PREPARATIONS OF COLORANTS DIFFICULT TO SOLUBLE IN WATER
ES8201621A1 (en) Aqueous dispersions of colouring materials and the derived print pastes.
CA2026959A1 (en) Dye mixtures and their use in trichromatic dyeing processes
KR950032474A (en) Phthalimidyl azo dyes, preparation method thereof and use thereof
JPS5928590B2 (en) water-based ink composition
ATE130626T1 (en) UNIVERSAL COLOR PASTE.
KR950018935A (en) Tricolor dyeing or printing method
CN107760104A (en) A kind of colour flash ink and preparation method thereof
GB1434162A (en) Disazo pigments processes for their manufacture and use
KR950032477A (en) Water-insoluble red monoazo dyes, preparation method thereof and use thereof
IE41484L (en) Monoazo compounds; dyes
US3718428A (en) Alcoholic composition of a cationic dye-alkyl aryl sulfonic acid complex and process of dyeing therewith
KR910003030A (en) Fiber-reactive formazan dyes, methods of making and uses thereof
KR910012095A (en) How to dye polyacrylonitrile materials
KR900018185A (en) Fiber-Reactive Formarzan Dye, Method for Making and Use thereof
US4108812A (en) Aqueous printing inks
KR830010150A (en) Dye
KR910003029A (en) Fiber-reactive formazan dyes, methods of making and uses thereof
GB1428633A (en) Monoazo pigment mixtures from acetoacetarylamide coupling components
SU711074A1 (en) Dye for flexographic printing on polyurethan

Legal Events

Date Code Title Description
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid