KR930002837B1 - Process for the lost-foam casting under pressure of metal articles - Google Patents

Process for the lost-foam casting under pressure of metal articles Download PDF

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KR930002837B1
KR930002837B1 KR1019890018168A KR890018168A KR930002837B1 KR 930002837 B1 KR930002837 B1 KR 930002837B1 KR 1019890018168 A KR1019890018168 A KR 1019890018168A KR 890018168 A KR890018168 A KR 890018168A KR 930002837 B1 KR930002837 B1 KR 930002837B1
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metal
pressure
mpa
foam
weight
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KR1019890018168A
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KR910005953A (en
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가라뜨 미쉘
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알뤼미니옴 뻬시니
마르셀 방라에르
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D18/00Pressure casting; Vacuum casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/09Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting by using pressure
    • B22D27/13Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting by using pressure making use of gas pressure

Abstract

The invention relates to a lost foam pressure casting process for metal pieces. This process consists, after having filled the mould with metal in the liquid state and before the solidified fraction of metal exceeds 40% by weight, in applying an isostatic gaseous pressure over the entire mould/metal, of which the value is between 1.5 and 10 mPa. The invention applies to the production of pieces, particularly made from aluminium alloys, having improved mechanical characteristics and, in particular, better resistance to fatigue. <IMAGE>

Description

금속제품의 가압 로스트-포옴 주조방법Pressurized Lost-Form Casting of Metal Products

제 1 도는 열처리된 후 7MPa의 압력하에서 본 발명에 따른 A-S7G03 합금주물의 현미경 사진이다.1 is a micrograph of an A-S7G03 alloy casting according to the present invention under a pressure of 7 MPa after heat treatment.

본 발명은 금속제품, 특히 알루미늄 및 알루미늄합금 제품의 가압로스트-포옴(lost-foam) 주조방법에 관한 것이다.FIELD OF THE INVENTION The present invention relates to a pressurized roast-foam casting process for metal products, in particular aluminum and aluminum alloy products.

미합중국 특허 제3,157,924호를 통해 점착제(binder)를 함유하지 않은 건조사로 형성되어진 주형안에 넣어진 폴리스틸렌 포옴형이 주조용으로 사용되어질 수 있음이 본 기술분야에 있어 통상의 지식을 가진자에게 공지되어 있다.US Pat. No. 3,157,924 is known to those of ordinary skill in the art that polystyrene foam molds enclosed in molds formed from dry yarns that do not contain a binder can be used for casting. .

이와 같은 방법에서는, 먼저 미리 용해되어진 주조되어질 금속이 건조사를 통과하는 채널을 통하여 흘러들어가 폴리스틸렌 포옴형과 접촉되어지고, 상기 형을 연소시켜 모래의 입자들 사이로 빠져나가게 되는 증기로 변형시킴으로써 상기 주조되어질 금속이 상기 형의 자리에 채워져 서서히 대치되어지게 된다.In this method, the metal that is to be pre-dissolved first flows through a channel through the dry sand, contacts with the polystyrene foam, and burns the mold to deform into steam which escapes between the particles of sand. The metal to be made is filled in place of the mold and gradually replaced.

이와 같은 방법은 분말 내화재료들을 조밀화시키고 응집시킴으로써 채널들을 통하여 코어들까지 상당히 복잡한 구조로 연결된 단단한 주형들의 예비 성형제조의 불편을 피할 수 있고, 간단하게 주물을 회수할 수 있으며, 주물 재료를 용이하게 재순환시킬 수 있으므로, 산업적인 규모에서 사용가능한 방법으로 주목을 끌고 있다.This method densifies and coagulates the powder refractory materials, thereby avoiding the inconvenience of preforming rigid molds connected in a fairly complex structure through the channels to the cores, simplifying the recovery of castings, and facilitating the casting material. As it can be recycled, it attracts attention as a method that can be used on an industrial scale.

그러나, 이러한 방법은 다음과 같은 두가지 요인에 의해 결함을 갖게 된다 :However, this method is flawed by two factors:

-개스에 의해 발생되는 핀-호올(pin-holes)들의 형성을 촉진시키는 상대적인 응고의 완만성,The relative gentleness of the coagulation, which promotes the formation of pin-holes caused by the gas,

-각 부분의 윤곽이 공급을 복잡하게 하는 경우, 미세수축 현상을 일으킬 수 있는 열구배의 상대적인 취약성.-Relative fragility of thermal gradients that can cause microshrinkage if the contours of each part complicate the supply.

이와 같은 결함들을 해결하기 위한 목적으로, 본 출원인들은 프랑스 공화국 특허출원공고 제2,606,688호의 주제를 형성하는 로스트-포옴 주조방법을 개발하였다.For the purpose of resolving these deficiencies, the applicants have developed a lost-foam casting method which forms the subject of French Patent Application Publication No. 2,606,688.

상기 출원은 주형에 용융금속을 채운후에, 즉 형이 용융금속에 의해 완전히 쓸모없게 되고 포말에 의해 방출된 증기가 빠져나가게 될때, 평형개스압이 바람직하기로는 용융금속이 응고하기 시작전에 주형과 금속의 결합체에 가해지는 방식이 기술되어져 있다.The application states that after filling the mold with molten metal, i.e., when the mold becomes completely obsolete by the molten metal and the vapor released by the foam escapes, the equilibrium gas pressure is preferably before the molten metal begins to solidify. The manner in which the combination of is described is described.

이때의 개스압력은 금속의 침투현상을 피하도록 전시간동안 증가되어지는 값으로 가해지며, 최대값은 15초 이하에서 얻어지게 된다.At this time, the gas pressure is applied to a value that is increased for the entire time to avoid metal penetration, and the maximum value is obtained in 15 seconds or less.

이러한 상황하에서, 얻어진 주물에는 밀도가 증가되어, 기계적 특성들, 특히 강도에 있어서 개선이 이루어지게 된다.Under these circumstances, the resulting casting increases in density, resulting in improvements in mechanical properties, in particular in strength.

그러나, 본 출원인들은 본 출원서에 최대압력을 0.5~1.5MPa으로 하는 것이 바람직하며, 1.5MPa를 초과하는 것은 불필요한 일이라 생각하였다.However, the present applicants preferred that the maximum pressure in the present application be 0.5 to 1.5 MPa, and it is unnecessary to exceed 1.5 MPa.

실제로, 그후의 보다 진전된 연구에 의해, 압력이 더 이상 상승되어지면, 파괴강도(Rm), 항복응력(LE) 및 연신률(A)등과 같은 기계적 특성들뿐만 아니라 피로저항(F)도 개선되어짐을 알게 되었다.Indeed, further studies have shown that as pressure rises further, fatigue resistance (F) is improved as well as mechanical properties such as breaking strength (Rm), yield stress (LE) and elongation (A). Got to know.

따라서, 본 발명은 금속재료, 특히 알루미늄 및 알루미늄 합금의 가압 로스트-포옴 주조방법에 관한 것으로서, 이 방법은 주조되어질 제품의 유기체 포옴형이 주형의 점착제를 함유하지 않은 건조사 욕조로써 형성된 벽들안으로 담겨지고, 포옴과 대치되며 서서히 응고되어지는 용융금속으로써 주형이 채워지며, 상승되는 평형개스압이 동시에 주형과 용융금속에 이 용융금속이 채워지기 전에 가해지고, 이때의 개스압은 1.5-10MPa의 값이 되어지게 된다.The present invention therefore relates to a method for pressurizing roast-foam casting of metallic materials, in particular aluminum and aluminum alloys, in which the organic foam form of the product to be cast is contained in walls formed by a dry sand bath containing no adhesive of the mold. The mold is filled with molten metal that is crushed, replaced with foam and gradually solidified, and the rising equilibrium gas pressure is simultaneously applied before the molten metal is filled into the mold and molten metal, with a gas pressure of 1.5-10 MPa. Will be.

따라서, 본 발명은 1.5-10MPa, 바람직하기로는 5-10MPa의 개스압을 사용하도록 되어 있다.Therefore, the present invention is designed to use a gas pressure of 1.5-10 MPa, preferably 5-10 MPa.

프랑스공화국 특허 제2,606,688호에 기술된 바와 같이, 압력은 주형이 놓여지고, 적합하게 주형벽들 위에 분배되어 배치되고 가압하에서 개스공급원과 연결되어진 다수개의 노즐들이 설치되어져 있는 밀봉된 박스에 의해 가해질 수 있다.As described in French Patent No. 2,606,688, the pressure can be exerted by a sealed box in which the mold is placed, suitably distributed over the mold walls and installed with a plurality of nozzles connected to the gas source under pressure. have.

선택된 압력범위에서, 본 출원들은 압력을 가하는 중에 발생되어지는 현상들이 종래의 기술과 상당히 다르다는 것을 알게 되었다.In the selected pressure range, the present applications have found that the phenomena that occur during the application of pressure differ significantly from the prior art.

실제로 0.5-1.5MPa의 압력하에서, 이 압력은 주로 고체 네트워크가 일정진전 단계에 이를때 효과가 정지하고, 응고되는 금속의 수지상결정들 사이에서 용융금속의 흐름을 가속화시키는 역활을 하게 된다.In fact, under pressures of 0.5-1.5 MPa, this pressure stops the effect mainly when the solid network reaches a certain stage of progression, and serves to accelerate the flow of molten metal between the dendrite crystals of the solidified metal.

특히, 이것은 저압에서 어떻게 압탕기가 응고되는 금속의 수축에 기인한 수축점 현상을 효과적으로 막을 수 있는가 하는 것이다.In particular, this is how at low pressures an agitator can effectively prevent shrinkage due to shrinkage of the metal to be solidified.

다른 한편으로, 응고화 초기에 우세한 용융금속의 유동영향은 1.5MPa이상, 특히 5MPa 이상의 압력하에서 기존의 응고금속 네트워크의 열변형 효과에 의해 서서히 대치되어지고, 이러한 현상은 현저해지고, 응고율이 합금주조의 형식에 따라 50-70%의 값으로 도달되는 경우에는 제외된다.On the other hand, the flow effect of the molten metal predominantly at the beginning of solidification is gradually replaced by the heat deformation effect of the existing solidified metal network under pressure of 1.5 MPa or more, especially 5 MPa or more, and this phenomenon becomes remarkable, and the solidification rate is alloyed. It is excluded if the value of 50-70% is reached, depending on the type of casting.

따라서, 고압의 적용은 주물의 전표면에 영향을 미치게 되는 평형 열처리된 후 형태를 나타내게 된다.Thus, the application of high pressure will give shape after an equilibrium heat treatment affecting the entire surface of the casting.

첨부된 제 1 도는 7MPa 압력하에서 이 현미경 사진은 기공들을 채우는 효과를 갖는 본 발명에 따른 A-S7G03 합금 주조의 현미경 사진이고, 수지상 네트워크를 이용한 소성변형 상태를 나타내고, 금속이 본 방법에 의해 적용되어지는 단조효과를 잘 나타낸 것이다.The attached Figure 1 is a micrograph of the A-S7G03 alloy casting according to the present invention with the effect of filling pores under 7 MPa pressure, showing the plastic deformation state using a dendritic network, the metal being applied by the method Loss is good for the forging effect.

이러한 상황하에서, 제품들이 기계적 특성들이 주목할만하게 개선되고, 특히 피로저항이 개선되어짐을 알게 된다.Under these circumstances, the products find that the mechanical properties are remarkably improved, in particular the fatigue resistance is improved.

10MPa 이상의 압력값들만이 별다른 개선이 이루어지지 않게 한다.Only pressure values of 10 MPa or more do not result in much improvement.

이러한 새로운 압력범위는 응고된 금속의 양이 40%에 도달하기전에 가해져 액체 유동상태로 작용되어지게 되는 것이 바람직하다.This new pressure range is preferably applied before the amount of solidified metal reaches 40% to act as a liquid flow.

또한 변형 효과에 의해 유용하도록 응고된 금속의 양이 90%를 초과하기 이전에 가해진 최대압력이 얻어지도록 하는 것이 바람직하다.It is also desirable to obtain the maximum pressure applied before the amount of solidified metal to exceed 90% to be useful by the deformation effect.

프랑스공화국 특허 제2,606,688호에 기술된 바와 같이, 금속에 직접 가해지는 압력과 건조사에 의해 금속이 가해지는 압력사이의 순간적인 불균형으로부터 야기되는 현상인 "금속침투"를 방지하기 위하여 특히 금속이 응고되기 시작하는 시점에서 압력이 서서히 증가되어지며 가해지도록 하는 것이 바람직하다.As described in French Patent No. 2,606,688, metals in particular coagulate in order to prevent "metal penetration", a phenomenon resulting from the instantaneous imbalance between the pressure applied directly to the metal and the pressure applied to the metal by the dry sand. It is desirable to allow the pressure to gradually increase and be applied at the beginning of the process.

실제로, 건조사 욕조는 모래와 접촉하게 되는 금속부분에 있어서 상기 압력으로 모래 입자를 통하여 금속을 밀어내고, 주물을 변형시키고자 하는 압력의 전이에 있어 상대적으로 큰 충전손실을 야기시키게 된다.Indeed, the dry sand bath causes relatively large filling losses in the transition of pressure to push the metal through the sand particles at this pressure in the metal part that comes into contact with the sand and to deform the casting.

본 발명을 다음과 같은 구체적 실시예로써 설명하면 : 외측직경이 45㎜이고 벽두께가 4㎜이며 20×20×80㎜의 보스들과 인접한 리브들로 이루어진 중공원통체를 종래의 방법 및 본 발명에 따른 방법으로 주조를 행한다.The present invention will be described in the following specific embodiments: The conventional method and the present invention provide a hollow-cylindrical cylinder consisting of ribs adjacent to bosses having an outer diameter of 45 mm and a wall thickness of 4 mm and 20 × 20 × 80 mm. Casting is performed by the method according to the above.

즉, 대기압에 대응하며 1MPa, 및 10MPa에 해당하는 평형개스 압력이 각각 응고가 시작되기 바로전에 주형을 포함하고 있는 챔버의 내부에 가해지게 된다.That is, an equilibrium gas pressure corresponding to atmospheric pressure and corresponding to 1 MPa and 10 MPa is applied to the inside of the chamber containing the mold just before solidification starts, respectively.

이때에 높은 기계적 특성들을 갖는 두가지의 합금들 형식에 원통체들이 만들어지게 된다.The cylinders are then made in the form of two alloys with high mechanical properties.

-100% 중량당 조성비율로써, Fe 0.20 : Si 6.5-7.5; Cu 0.10 : Zn 0.10 : Mg 0.25-0.40 : Mn 0.10 : Ni 0.05 : Pb 0.05 : Sn 0.05 : Ti 0.05-0.20 : 나머지는 Al의 조성상태를 형성하는 A-S7G03.Composition ratio per weight -100%, Fe 0.20: Si 6.5-7.5; Cu 0.10: Zn 0.10: Mg 0.25-0.40: Mn 0.10: Ni 0.05: Pb 0.05: Sn 0.05: Ti 0.05-0.20: A-S7G03 forms the remainder of Al composition.

-Fe 0.35 : Si 0.20 : Cu 4.20-5.00 : Zn 0.10 : Mg 0.15-0.35 : Mn 0.10 : Ni 0.05 : Pb 0.05 : Sn 0.05 : Ti 0.05-0.30 : 나머지는 Al의 조성상태를 형성하는 A-U5GR-Fe 0.35: Si 0.20: Cu 4.20-5.00: Zn 0.10: Mg 0.15-0.35: Mn 0.10: Ni 0.05: Pb 0.05: Sn 0.05: Ti 0.05-0.30: A-U5GR which forms the composition of Al

A-S7G03의 경우 표준 Y23 열처리를, 그리고 A-U5GT의 경우 Y24 열처리를 행한 후 상기 양 원통체에 기계적 테스트를 한 결과 가해진 압력의 영향으로서 다음과 같은 특성들이 측정되어지게 된다.As a result of the mechanical test on both cylinders after the standard Y23 heat treatment for A-S7G03 and Y24 heat treatment for A-U5GT, the following characteristics were measured.

-A-S7G03에 있어서, 품질지표(Q)는 MPa 단위로써 Q=R+150logA로 표시되고, 이때 R은 MPa 단위의 강도이고, A는 제품의 두꺼운 부분 및 얇은 부분 양쪽에 있어서 % 단위의 연신율이다.For A-S7G03, the quality indicator (Q) is expressed as Q = R + 150 logA in MPa, where R is the strength in MPa and A is the elongation in% in both thick and thin parts of the product. to be.

-A-U5GT에 있어서, 항복응력은 MPa 단위의 "LE", 강도는 MPa 단위의 "R", 또한 연신율은 제품의 두꺼운 부분 및 얇은 부분 양쪽에 있어서의 % 단위의 "A"로 나타내진다.For -A-U5GT, yield stress is expressed as "LE" in MPa, strength as "R" in MPa, and elongation is expressed as "A" in% in both thick and thin portions of the product.

또한, 피로저항(F)는 계단방식으로 107 사이클로 기계작업된 샘플위에 비틀림 테스트로부터 가해진 각각의 압력들 및 각각의 합금들로부터 MPa 단위로 측정되어진다.In addition, the fatigue resistance (F) is measured in units of MPa from the respective pressures and respective alloys applied from the torsion test on the sample machined in stepwise 107 cycles.

피로저항(F)는 이것이 응고화율에 의존하는 것이 아니라 기공율, 즉 가해진 압력에 좌우되므로 두꺼운 부분 및 얇은 부분 양쪽에 가해지게 된다.Fatigue resistance (F) is applied to both thick and thin portions because it is not dependent on the rate of solidification but on the porosity, ie the pressure applied.

각 측정결과들이 다음의 표에 나타내져 있다.Each measurement result is shown in the following table.

[표][table]

Figure kpo00001
Figure kpo00001

측정된 모든 특성들에 있어서의 개선상태가 관찰되어지는바, 특히 상승된 피로저항에 있어서의 개선상태가 관찰되어진다.Improvements in all measured properties are observed, in particular improvements in elevated fatigue resistance.

Claims (4)

구조되어질 제품의 유기체 포옴형이 점착제를 함유하지 않는 건조사 욕조(bath of dry sand)으로써 형성되어진 벽들로 구성되고 포옴을 제거시키며 서서히 응고되는 용융금속으로 채워지는 주형안에 담겨져, 주형안에 용융금속이 채워지기 바로 직전에 주형과 용융금속에 동시에 점차로 상승되어지는 평형개스가 가해지며, 이때의 가해지는 평형개스의 압력이 1.5-10MPa 사이의 값까지 상승하는 것을 특징으로 하는 금속제품, 알루미늄 및 알루미늄 합금제품의 가압로스트-포옴 주조방법.The organic foam form of the product to be constructed consists of walls formed as a bath of dry sand containing no adhesive and is contained in a mold filled with molten metal that removes the foam and slowly solidifies, Equilibrium gas is applied to the mold and molten metal at the same time, just before filling, and the pressure of the applied balance gas rises to a value between 1.5-10 MPa. Pressurized roast-foam casting of products. 제 1 항에 있어서, 가해진 압력이 5-10MPa 사이의 값까지 상승하는 것을 특징으로 하는 방법.The method of claim 1 wherein the applied pressure rises to a value between 5-10 MPa. 제 1 항에 있어서, 응고화된 금속의 양이 최대한 중량으로 40%가 될때 압력이 가해지는 것을 특징으로 하는 방법.The method of claim 1 wherein pressure is applied when the amount of solidified metal is 40% by weight to the maximum. 제 1 항에 있어서, 최대 압력값이 응고화된 금속이 양이 중량으로 90%가 되기 이전에 얻어지게 된 것을 특징으로 하는 방법.2. A method according to claim 1, wherein the maximum pressure value is obtained before the solidified metal is 90% by weight in weight.
KR1019890018168A 1989-09-07 1989-12-08 Process for the lost-foam casting under pressure of metal articles KR930002837B1 (en)

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