KR930001965A - 가변 수요 패턴에 따라 기체상 산소를 공급하기 위한 공기분리 방법 - Google Patents

가변 수요 패턴에 따라 기체상 산소를 공급하기 위한 공기분리 방법 Download PDF

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KR930001965A
KR930001965A KR1019920013071A KR920013071A KR930001965A KR 930001965 A KR930001965 A KR 930001965A KR 1019920013071 A KR1019920013071 A KR 1019920013071A KR 920013071 A KR920013071 A KR 920013071A KR 930001965 A KR930001965 A KR 930001965A
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nitrogen
liquid
stream
low pressure
oxygen
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KR950010557B1 (ko
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에이. 모스텔로 로버트
클리기스 비토
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로버트 아이. 펄만
더 비오씨 그룹, 인코포레이티드
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04472Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the cold from cryogenic liquids produced within the air fractionation unit and stored in internal or intermediate storages
    • F25J3/04496Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the cold from cryogenic liquids produced within the air fractionation unit and stored in internal or intermediate storages for compensating variable air feed or variable product demand by alternating between periods of liquid storage and liquid assist
    • F25J3/04503Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the cold from cryogenic liquids produced within the air fractionation unit and stored in internal or intermediate storages for compensating variable air feed or variable product demand by alternating between periods of liquid storage and liquid assist by exchanging "cold" between at least two different cryogenic liquids, e.g. independently from the main heat exchange line of the air fractionation and/or by using external alternating storage systems
    • F25J3/04509Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using the cold from cryogenic liquids produced within the air fractionation unit and stored in internal or intermediate storages for compensating variable air feed or variable product demand by alternating between periods of liquid storage and liquid assist by exchanging "cold" between at least two different cryogenic liquids, e.g. independently from the main heat exchange line of the air fractionation and/or by using external alternating storage systems within the cold part of the air fractionation, i.e. exchanging "cold" within the fractionation and/or main heat exchange line
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04078Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
    • F25J3/0409Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04284Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/04309Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04333Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/04351Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04406Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
    • F25J3/04412Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00Processes or apparatus using other separation and/or other processing means
    • F25J2205/02Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Separation Of Gases By Adsorption (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

내용 없음.

Description

가변 수요 패턴에 따라 기체상 산소를 공급하기 위한 공기분리 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 따른 공기 분리 장치의 개략도이다.

Claims (9)

  1. 작동가능하게 연결된 고압 및 저압탑(high and low pressure column)을 사용하는 이중탑 저온 정류 공정에 의해 공기를 정류하여 질소-풍부 증기 및 액체 산소를 각각 생성시키는 단계, 질소-풍부 증기 및 액체 산소를 고압 및 저압탑으로부터 회수하는 단계, 회수된 질소-풍부 증기를 부분가열하고 엔진 팽창(engin expanding)시켜 열을 수행시키고, 엔진 팽창 후, 전체 수용 패턴(demand pattern)에 걸쳐 열평형이 유지되도록, 회수된 질소-풍부 증기를 장치 냉매로서 저온 정류 공정에 도입시키는 단계, 기체상 산소에 대한 수요가 있을 경우, 회수된 액체 산소로부터 형성된 생성물 스트림을 수요를 충족시키기에 충분한 속도로 송출압력으로 펌핑시키고, 부분적으로 가열 팽창되어 나오는 회수된 질소-풍부 증기의 적어도 일부를 생성물 스트림을 기화시키기에 충분한 속도로 분류(diverted, 分流)시켜 분류된 질소-풍부 증기를 완전히 가열시키고 압축시킨 다음에, 이를 응축시키면서 생성물 스트림은 기화시킴으로써 기체상 산소를 형성시키는 단계, 분류된 질소-풍부 증기로부터 응축된 액체 질소를 플래시(flash)시켜 액상 및 증기상을 함유하는 질소의 2상 흐름을 생성시키고, 액상 및 증기상을 서로 분리하는 단계, 증기상으로 이루어진 증기상 스트림을 분류된 질소-풍부 증기에 부가하여 기체상 산소의 생성을 증가시키고, 액상으로 이루어진 액체 질소 스트림을 환류(reflux)로서 저압탑에 부가하여 저압탑으로부터 액체 산소를 회수하는 단계, 및 저압탑에 도입되지 않은 상기 액상 및 생성물 스트림의 형성시에 사용되지 않은 회수된 액체 산소의 특정 과량을 저장하는 단계를 포함하여, 가변 수요 패턴(variable demand pattern)의 요건을 충족시키는 기체상 산소의 공급방법.
  2. 제1항에 있어서, 액체 산소가 필수적으로 정속으로 저압탑내에서 형성되도록 액체 질소 스트림을 변하는 속도로 저압탑에 부가하여 장치 냉매를 도입시키고, 질소-풍부 증기 및 액체 산소를 필수적으로 정속으로 고압탑 및 저압탑으로부터 회수하는 방법.
  3. 제1항에 있어서, 상기 저온 정류 공정에 냉각단을 또한 사용하여 공기를 그의 정류에 적합한 온도까지 냉각시키고, 생성물 스트림을 냉각단(colling stage)에 도입시키고, 질소-풍부 증기를 냉각단내에서 부분적으로 가열하고, 또한 분류된 질소-풍부 증기를 냉각단에서 완전히 가열한 다음, 완전히 가열되고 압축된 후에는, 이를 냉각단에서 응축 시키는데 반해, 생성물 스트림은 기화시키는 방법.
  4. 제1항에 있어서, 저온 정류 공정에 냉각단을 또한 사용하여 공기를 정류단 내에서 정류하는데 적합한 온도로 냉각시키고, 팽창된 질소-풍부 증기 스트림을 냉각단에 부가하여 장치 냉매를 저온 정류 공정에 도입시킴으로써 정류할 공기의 앤탈피를 저하시키는 방법.
  5. 제1항에 있어서, 액체 질소를 플래시 탱크(flash tank)내로 플래시시켜 액체 및 증기상을 서로 분리하는 방법.
  6. 제2항에 있어서, 저온 정류 공정에 냉각단을 또한 사용하여 공기를 그의 정류에 적합한 온도를 냉각시키고, 생성물 스트림을 냉각단내로 도입시키고, 질소-풍부 증기를 냉각단내에서 부분적으로 가열하고, 또한 분류된 질소-풍부 증기를 냉각단에서 완전히 가열한 다음, 완전히 가열되고 압축된 후에는, 이를 냉각단에서 응축 시키는데 반해, 생성물 스트림은 기화시키는 방법.
  7. 제6항에 있어서, 팽창된 질소-풍부 증기 스트림을 냉각단에 부가하여 장치 냉매를 저온 정류 공정에 도입시킴으로써 정류할 공기의 엔탈피를 저하시키는 방법.
  8. 제7항에 있어서, 액체 질소를 플래시 탱크로 플래시시켜 액상 및 증기상의 질소를 생성시키는 방법.
  9. 제7항에 있어서, 저압탑에서 저압 질소 증기를 생성시키고, 저압 질소 증기로 이루어진 폐기 스트림(waste stream)을 저압탑으로부터 추출하고, 상기 폐기 스트립을 냉각단에 도입시켜 공기를 냉각시키고, 팽창된 질소-풍부 증기 스트림을 상기 폐기 스트림과 합한 다음 냉각단에 도입시켜 저온 정류 공정에 냉매를 부가하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920013071A 1991-07-23 1992-07-22 가변 수요 패턴에 따라 기체상 산소를 공급하기 위한 공기 분리 방법 KR950010557B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US734,705 1991-07-23
US07/734,705 US5152149A (en) 1991-07-23 1991-07-23 Air separation method for supplying gaseous oxygen in accordance with a variable demand pattern

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KR930001965A true KR930001965A (ko) 1993-02-22
KR950010557B1 KR950010557B1 (ko) 1995-09-19

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US (1) US5152149A (ko)
EP (1) EP0524785B1 (ko)
JP (1) JPH07109347B2 (ko)
KR (1) KR950010557B1 (ko)
CN (1) CN1068883A (ko)
AT (1) ATE135457T1 (ko)
AU (1) AU644962B2 (ko)
CA (1) CA2067427C (ko)
CZ (1) CZ227892A3 (ko)
DE (1) DE69208962T2 (ko)
HU (1) HU215195B (ko)
IE (1) IE74402B1 (ko)
MX (1) MX9202922A (ko)
SG (1) SG50506A1 (ko)
TR (1) TR27165A (ko)
ZA (1) ZA923090B (ko)

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FR2681415B1 (fr) * 1991-09-18 1999-01-29 Air Liquide Procede et installation de production d'oxygene gazeux sous haute pression par distillation d'air.
CN1071444C (zh) * 1992-02-21 2001-09-19 普拉塞尔技术有限公司 生产气体氧的低温空气分离系统
US5228297A (en) * 1992-04-22 1993-07-20 Praxair Technology, Inc. Cryogenic rectification system with dual heat pump
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SG50506A1 (en) 1998-07-20
DE69208962D1 (de) 1996-04-18
MX9202922A (es) 1993-01-01
EP0524785B1 (en) 1996-03-13
AU1615092A (en) 1993-01-28
KR950010557B1 (ko) 1995-09-19
DE69208962T2 (de) 1996-07-25
ATE135457T1 (de) 1996-03-15
ZA923090B (en) 1993-03-31
JPH07109347B2 (ja) 1995-11-22
HU215195B (hu) 1998-10-28
AU644962B2 (en) 1993-12-23
CN1068883A (zh) 1993-02-10
US5152149A (en) 1992-10-06
TR27165A (tr) 1994-11-10
JPH05203344A (ja) 1993-08-10
CA2067427C (en) 1995-06-27
HUT64619A (en) 1994-01-28
IE74402B1 (en) 1997-07-30
IE922375A1 (en) 1993-01-27
EP0524785A1 (en) 1993-01-27
CZ227892A3 (en) 1993-02-17
HU9201841D0 (en) 1992-09-28

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