KR920701215A - N-포스포노메틸이미노디아세트산의 산화에 의한 n-포스포노메틸글리신의 제조방법 - Google Patents
N-포스포노메틸이미노디아세트산의 산화에 의한 n-포스포노메틸글리신의 제조방법Info
- Publication number
- KR920701215A KR920701215A KR1019910701582A KR910701582A KR920701215A KR 920701215 A KR920701215 A KR 920701215A KR 1019910701582 A KR1019910701582 A KR 1019910701582A KR 910701582 A KR910701582 A KR 910701582A KR 920701215 A KR920701215 A KR 920701215A
- Authority
- KR
- South Korea
- Prior art keywords
- improved process
- carried out
- process according
- phosphonomethylglycine
- flushing
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 5
- AZIHIQIVLANVKD-UHFFFAOYSA-N N-(phosphonomethyl)iminodiacetic acid Chemical compound OC(=O)CN(CC(O)=O)CP(O)(O)=O AZIHIQIVLANVKD-UHFFFAOYSA-N 0.000 title claims 2
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 title claims 2
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 8
- 238000011010 flushing procedure Methods 0.000 claims 4
- 229910052757 nitrogen Inorganic materials 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000007789 gas Substances 0.000 claims 1
- 229910000510 noble metal Inorganic materials 0.000 claims 1
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000010970 precious metal Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (4)
- 일단 반응을 완료시킨 후 이를 냉각시키기 전에, 약한 압력하에 반응 온도와 동일한 온도 또는 다소 높은 온도에서 한정된 시간 동안 질소 플러싱(flushing)을 수행하여, 용액중 촉매로 사용된 귀금속의 손실이 감소됨을 특징으로 하여, 활성탄상에 지지된 귀금속 촉매의 존재하에서, N-포스포노메틸 이미노디아세트산을 산소 또는 산소-함유 기체로 산화시켜 N-포스포노메틸글리신을 제조하는 개선된 방법.
- 제1항에 있어서, 질소 플러싱을 20 내지 120℃의 온도범위에서 수행함을 특징으로 하는 개선된 방법.
- 제1항에 있어서, 질소 플러싱을 15분 내지 1시간 이하의 시간 동안 지속적으로 수행함을 특징으로 하는 개선된 방법.
- 제1항에 있어서, 질소 플러싱을 반응 용액의 압력이 0.5 내지 5Kg/cm2범위임을 특징으로 하는 개선된 방법.※참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES9000732A ES2021229A6 (es) | 1990-03-12 | 1990-03-12 | Perfeccionamientos introducidos en un procedimiento de obtencion de n-fosfonometilglicina por oxidacion de n-fosfonometiliminodiacetico. |
ESP9000732 | 1990-03-12 | ||
PCT/ES1991/000013 WO1991013893A1 (es) | 1990-03-12 | 1991-03-12 | Preparacion de n-fosfonometilglicina por oxidacion de acido n-fosfonometiliminodiacetico |
Publications (1)
Publication Number | Publication Date |
---|---|
KR920701215A true KR920701215A (ko) | 1992-08-11 |
Family
ID=8266371
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019910701582A KR920701215A (ko) | 1990-03-12 | 1991-03-12 | N-포스포노메틸이미노디아세트산의 산화에 의한 n-포스포노메틸글리신의 제조방법 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5179228A (ko) |
EP (1) | EP0472693B1 (ko) |
KR (1) | KR920701215A (ko) |
AU (1) | AU637896B2 (ko) |
DE (1) | DE69114610T2 (ko) |
DK (1) | DK0472693T3 (ko) |
ES (1) | ES2021229A6 (ko) |
GR (1) | GR3018731T3 (ko) |
WO (1) | WO1991013893A1 (ko) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6232494B1 (en) * | 1998-02-12 | 2001-05-15 | Monsanto Company | Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine |
WO1999041260A1 (en) * | 1998-02-12 | 1999-08-19 | Monsanto Company | Process for making glyphosate by oxidizing n-substituted glyphosates |
US6417133B1 (en) | 1998-02-25 | 2002-07-09 | Monsanto Technology Llc | Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
US5962729A (en) * | 1998-05-14 | 1999-10-05 | Calgon Carbon Corporation | Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon |
US5942643A (en) * | 1998-05-14 | 1999-08-24 | Calgon Carbon Corporation | Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a low temperature catalytic carbon |
IL140488A0 (en) * | 1998-07-06 | 2002-02-10 | Syngenta Participations Ag | Preparation of n-phosphonomethylglycine salts |
IES980552A2 (en) | 1998-07-09 | 1999-08-11 | Agritech Chemical Ltd | Improved process for preparing N-phosphonomethyl iminodiacetic acid |
WO2000014093A1 (en) * | 1998-09-08 | 2000-03-16 | Hampshire Chemical Corp. | Synthesis of phosphonomethyliminodiacetic acid with reduced effluent |
WO2001007447A1 (de) * | 1999-07-23 | 2001-02-01 | Basf Aktiengesellschaft | Verfahren zur herstellung von glyphosate oder eines salzes davon |
MX240933B (es) | 1999-12-21 | 2006-10-09 | Monsanto Technology Llc | Uso de un promotor suplementario en conjunto con un catalizador que contiene metal noble, soportado en carbon, en reacciones de oxidacion en fase liquida. . |
DE10007702A1 (de) * | 2000-02-19 | 2001-08-23 | Sueddeutsche Kalkstickstoff | Verfahren zur Herstellung von N-(Phosphonomethyl)glycin |
US6376708B1 (en) * | 2000-04-11 | 2002-04-23 | Monsanto Technology Llc | Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts |
AU2001264605C1 (en) | 2000-05-15 | 2005-10-06 | Monsanto Technology Llc | Preparation of iminodiacetic acid compounds from monoethanolamine substrates |
EP1283841B1 (en) * | 2000-05-22 | 2005-11-16 | Monsanto Technology LLC | Reaction systems for making n-(phosphonomethyl)glycine compounds |
US6927304B2 (en) | 2000-05-22 | 2005-08-09 | Monsanto Technology Llc | De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions |
WO2002095373A1 (en) * | 2001-05-22 | 2002-11-28 | Monsanto Technology Llc | Use of infrared spectroscopy for on-line process control and endpoint detection |
CA2463776A1 (en) | 2001-10-18 | 2003-04-24 | Monsanto Technology Llc | Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts |
MX261990B (es) * | 2002-02-14 | 2008-11-07 | Monsanto Technology Llc | Catalizador de oxidacion y procedimiento para su preparacion y procedimiento para oxidacion mediante el uso del mismo. |
US7390920B2 (en) * | 2002-02-14 | 2008-06-24 | Monsanto Technology Llc | Oxidation catalyst and process |
US6921834B2 (en) | 2002-05-22 | 2005-07-26 | Dow Agrosciences Llc | Continuous process for preparing N-phosphonomethyl glycine |
JP4202047B2 (ja) * | 2002-05-24 | 2008-12-24 | 富士通株式会社 | ヘッド位置制御方法及びデイスク記憶装置 |
AR040319A1 (es) * | 2002-06-28 | 2005-03-23 | Monsanto Technology Llc | Uso de telurio en catalizadores con contenido de metales nobles y con soporte de carbon para reacciones de oxidacion en fase liquida |
EP1684900B1 (en) | 2003-08-14 | 2013-02-27 | Monsanto Technology LLC | Process for oxidation of N-(phosphonomethyl)iminodiacetic acid or salt thereof |
WO2005028487A1 (en) * | 2003-09-17 | 2005-03-31 | Monsanto Technology Llc | Process for recovering a crystalline product from solution |
TW200624171A (en) * | 2004-09-15 | 2006-07-16 | Monsanto Technology Llc | Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
AR054096A1 (es) | 2004-11-12 | 2007-06-06 | Monsanto Technology Llc | Recuperacion de metales nobles de corrientes de proceso acuosas y proceso de preparacion de n-(fosfonometil)-glicina |
MX2007010066A (es) * | 2005-02-17 | 2007-11-07 | Monsanto Technology Llc | Catalizadores que contienen metales de transicion y combinaciones de catalizadores que incluyen catalizadores que contienen metales de transicion y procedimientos para su preparacion y uso como catalizadores de oxidacion. |
BRPI0607713A2 (pt) | 2005-04-01 | 2009-09-22 | Monsanto Technology Llc | métodos para monitorar ou detectar a conversão do ácido n-(fosfonometil) iminodiacético para n-(fosfonometil)glicina ou outro intermediário para n-(fosfonometil)glicina no curso da oxidação catalìtica de ácido n-(fosfonometil)iminodiacético em um meio aquoso |
BRPI0708081A2 (pt) * | 2006-02-17 | 2011-05-17 | Monsanto Technology Llc | catalisadores contendo metal de transição e processos para a sua preparação e uso como catalisadores de pilha termoelétrica |
US7771494B2 (en) * | 2007-01-31 | 2010-08-10 | Monsanto Technology Llc | Process for selective removal of water and impurities from N-(phosphonomethyl)glycine |
US8252953B2 (en) | 2008-05-01 | 2012-08-28 | Monsanto Technology Llc | Metal utilization in supported, metal-containing catalysts |
WO2010135141A1 (en) | 2009-05-18 | 2010-11-25 | Monsanto Technology Llc | Recovery of phosphorus values and salt impurities from aqueous waste streams |
BR112019027682A2 (pt) | 2017-06-26 | 2020-09-15 | Monsanto Technology Llc | controle de fósforo para fluxos de resíduos provenientes de processos de produção de glifosato |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3950402A (en) * | 1972-05-31 | 1976-04-13 | Monsanto Company | Process for producing N-phosphonomethyl glycine |
MX4703E (es) * | 1976-12-20 | 1982-08-04 | Monsanto Co | Procedimiento mejorado para la preparacion de mono y disales de n-fosfonometilglicina |
US4579689A (en) * | 1985-02-11 | 1986-04-01 | Monsanto Company | Oxidation with coated catalyst |
US4582650A (en) * | 1985-02-11 | 1986-04-15 | Monsanto Company | Oxidation with encapsulated co-catalyst |
US4853159A (en) * | 1987-10-26 | 1989-08-01 | Monsanto Company | Process for producing N-phosphonomethylglycine |
US4952723A (en) * | 1989-07-31 | 1990-08-28 | Monsanto Company | Process for producing N-phosphonomethylglycine |
-
1990
- 1990-03-12 ES ES9000732A patent/ES2021229A6/es not_active Expired - Lifetime
-
1991
- 1991-03-12 AU AU74973/91A patent/AU637896B2/en not_active Ceased
- 1991-03-12 EP EP91905864A patent/EP0472693B1/en not_active Expired - Lifetime
- 1991-03-12 DK DK91905864.4T patent/DK0472693T3/da active
- 1991-03-12 US US07/778,842 patent/US5179228A/en not_active Expired - Fee Related
- 1991-03-12 KR KR1019910701582A patent/KR920701215A/ko not_active Application Discontinuation
- 1991-03-12 WO PCT/ES1991/000013 patent/WO1991013893A1/es active IP Right Grant
- 1991-03-12 DE DE69114610T patent/DE69114610T2/de not_active Expired - Fee Related
-
1996
- 1996-01-18 GR GR960400118T patent/GR3018731T3/el unknown
Also Published As
Publication number | Publication date |
---|---|
ES2021229A6 (es) | 1991-10-16 |
DK0472693T3 (da) | 1996-01-02 |
GR3018731T3 (en) | 1996-04-30 |
WO1991013893A1 (es) | 1991-09-19 |
AU637896B2 (en) | 1993-06-10 |
DE69114610T2 (de) | 1996-05-02 |
EP0472693A1 (en) | 1992-03-04 |
AU7497391A (en) | 1991-10-10 |
US5179228A (en) | 1993-01-12 |
DE69114610D1 (de) | 1995-12-21 |
EP0472693B1 (en) | 1995-11-15 |
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Legal Events
Date | Code | Title | Description |
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WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |