KR920009955A - Fuel Cleaning Additives - Google Patents

Fuel Cleaning Additives Download PDF

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Publication number
KR920009955A
KR920009955A KR1019910020218A KR910020218A KR920009955A KR 920009955 A KR920009955 A KR 920009955A KR 1019910020218 A KR1019910020218 A KR 1019910020218A KR 910020218 A KR910020218 A KR 910020218A KR 920009955 A KR920009955 A KR 920009955A
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KR
South Korea
Prior art keywords
iii
formula
compound
carbon atoms
weight
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Application number
KR1019910020218A
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Korean (ko)
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KR940008390B1 (en
Inventor
가티 에밀리오
코치 파올로
톤토도나티 안토니오
Original Assignee
원본미기재
에우론 쏘시에떼 퍼 아찌오니
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Publication of KR920009955A publication Critical patent/KR920009955A/en
Application granted granted Critical
Publication of KR940008390B1 publication Critical patent/KR940008390B1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • C10L1/2225—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates hydroxy containing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds

Abstract

내용 없음No content

Description

연료용 세정 첨가제Fuel Cleaning Additives

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

Claims (6)

다음 일반식(I)의 3차아민과 다음 일반식(III)의 유기탄산염 또한 다음 일반식(III)의 알코올의 전이-에스테르화 반응으로 제조할 수 있는 것을 특징으로한 내연기관 연소물 및 연료용 세정첨가제.For internal combustion engine combustion products and fuels, characterized in that the tertiary amines of formula (I) and the organic carbonates of formula (III) can also be prepared by the transition-esterification reaction of alcohols of formula (III) Cleaning additive. R'-N-[-(CH3)n-OH]2(I)R'-N-[-(CH 3 ) n -OH] 2 (I) 여기서, n은 1내지 4의 정수이고, R'는 -(CH2)n-OH기이나 또는 1 내지 20탄소원자를 함유한 알킬기이다.N is an integer of 1 to 4, and R 'is a-(CH 2 ) n -OH group or an alkyl group containing 1 to 20 carbon atoms. R"-O-CO-O-R" (II)R "-O-CO-O-R" (II) 여기서 R"는 1 내지 4탄소원자를 함유한 알킬기 또는 아릴기이다.Wherein R ″ is an alkyl or aryl group containing 1 to 4 carbon atoms. R3-OH (III)R 3 -OH (III) 여기서 R3은 6 내지 30탄소원자의 직쇄 또는 측쇄알킬기(또는 이들의 혼합물)이다.Wherein R 3 is a straight or branched chain alkyl group (or mixture thereof) of 6 to 30 carbon atoms. 제1항에 있어서, 화합물(III)의 탄소원자에 대한 에테르형 산소원자 비율이 0.5를 넘지않도록한 에테르-알코올인 것을 특징으로 하는 세정첨가제.The cleaning additive according to claim 1, wherein the ether-alcohol of the compound (III) with respect to the carbon atom of the ether type does not exceed 0.5. 제1항 또는 2항에 있어서, 일반식(I)의 화합물은 트리에탄올아민 또는 N-부틸-디에탄올 아민(n=2이고, R'는 히드록시에틸이나 부틸)이고, 일반식(II)의 화합물은 디메틸 카보네이트나 디페닐 카보네이트이고, 일반식(III)의 화합물은 7 내지 26탄소원자의 직쇄나 측쇄 1차 지방족 알코을의 혼합물 또는 알킬사슬에 하나이상의 에테르기가 있는 1차 알코올의 혼합물이거나 혹은 폴리옥시프로필렌글리콜 모노부틸에테르인 것을 특징으로 하는 세정첨가제.The compound of formula (I) according to claim 1 or 2, wherein the compound of formula (I) is triethanolamine or N-butyl-diethanol amine (n = 2, R 'is hydroxyethyl or butyl), and The compound is dimethyl carbonate or diphenyl carbonate, and the compound of general formula (III) is a mixture of linear or branched linear aliphatic alcohols of 7 to 26 carbon atoms or a mixture of primary alcohols having one or more ether groups in the alkyl chain, or polyoxy It is propylene glycol monobutyl ether, The cleaning additive characterized by the above-mentioned. 80-200℃의 온도 특히 100-180℃의 온도에서 1 : 3 : 3 내지 1 : 10 : 5 특히 1: 5 : 3 : 5의 몰비율로된 (I)/(II)/(III) 반응물을 사용하여 전이-에스테르화 반응 촉매인 디부틸틴 디라우레이트의 존재하에서 반응시키는 것을 특징으로한 1항 내지 3항에 따른 액체 연료용 세정첨가제의 제조방법.(I) / (II) / (III) reactants in a molar ratio of 1: 3: 3 to 1: 10: 5 especially 1: 5: 3: 5 at a temperature of 80-200 ° C., in particular 100-180 ° C. A process for producing a cleaning fuel additive for liquid fuel according to claims 1 to 3, wherein the reaction is carried out in the presence of dibutyltin dilaurate as a transition-esterification catalyst. 25 내지 95중량% 특히 50 내지 70중량%의 1항 내지 3항에 따른 첨가제를 함유하는 것을 특징으로한 액체연료용 농축세정제.A concentrated detergent for liquid fuel, comprising from 25 to 95% by weight, in particular from 50 to 70% by weight, of the additive according to items 1 to 3. 0.01 내지 0.1중량% 특히 0.02 내지 0.06중량%의 1 내지 3항에 따른 첨가제를 함유하는 것을 특징으로 하는 내연기관용 액체연료 조성물.A liquid fuel composition for an internal combustion engine, characterized by containing from 0.01 to 0.1% by weight, in particular from 0.02 to 0.06% by weight, of the additives according to 1-3. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019910020218A 1990-11-15 1991-11-14 Detergent additive for fuels KR940008390B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT02207290A IT1245738B (en) 1990-11-15 1990-11-15 FUEL DETERGENT ADDITIVE.
IT22072A/90 1990-11-15

Publications (2)

Publication Number Publication Date
KR920009955A true KR920009955A (en) 1992-06-25
KR940008390B1 KR940008390B1 (en) 1994-09-14

Family

ID=11191060

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019910020218A KR940008390B1 (en) 1990-11-15 1991-11-14 Detergent additive for fuels

Country Status (17)

Country Link
EP (1) EP0486097B1 (en)
JP (1) JPH04292690A (en)
KR (1) KR940008390B1 (en)
AT (1) ATE134699T1 (en)
BR (1) BR9104962A (en)
CA (1) CA2055573A1 (en)
CZ (1) CZ282836B6 (en)
DE (1) DE69117442T2 (en)
DK (1) DK0486097T3 (en)
ES (1) ES2084092T3 (en)
GR (1) GR3019262T3 (en)
HU (1) HU210794B (en)
IT (1) IT1245738B (en)
MX (1) MX173928B (en)
PL (1) PL167977B1 (en)
RU (1) RU2036954C1 (en)
SG (1) SG54114A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005029715A (en) * 2003-07-08 2005-02-03 National Institute Of Advanced Industrial & Technology Method for producing bio-diesel fuel
RU2471858C2 (en) * 2010-12-27 2013-01-10 Игорь Анатольевич Ревенко Method of increasing rate and completeness of fuel oxidation in combustion systems
CA2789907A1 (en) * 2011-11-11 2013-05-11 Afton Chemical Corporation Fuel additive for improved performance of direct fuel injected engines

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2885274A (en) * 1956-12-11 1959-05-05 Texas Co Motor fuel composition
US2921955A (en) * 1956-12-11 1960-01-19 Texaco Inc Carbonate derivatives of ethanolamines
US3088815A (en) * 1958-03-27 1963-05-07 Sinclair Research Inc Fuel oil
FR1254518A (en) * 1960-01-13 1961-02-24 British Petroleum Co Additives for improving the cold resistance of petroleum wax fractions
US3123634A (en) * 1961-04-28 1964-03-03 Chzchsocchzchzcoh
US3426062A (en) * 1965-04-05 1969-02-04 Universal Oil Prod Co Reaction product of polyhalopolyhydropolycyclicdicarboxylic acids,anhydrides or esters thereof with n,n-dicycloalkyl-alkanolamine
US4018708A (en) * 1975-12-29 1977-04-19 Basf Wyandotte Corporation Tin-titanium complexes as esterification/transesterification catalysts
DE3482122D1 (en) * 1983-07-29 1990-06-07 Chevron Res ADDITIVES FOR REGULATING THE DEPTH OF QUATERNAEREN.

Also Published As

Publication number Publication date
HUT59441A (en) 1992-05-28
DK0486097T3 (en) 1996-04-29
GR3019262T3 (en) 1996-06-30
IT9022072A1 (en) 1992-05-15
RU2036954C1 (en) 1995-06-09
EP0486097A1 (en) 1992-05-20
PL292412A1 (en) 1992-07-27
JPH04292690A (en) 1992-10-16
DE69117442D1 (en) 1996-04-04
ATE134699T1 (en) 1996-03-15
HU913575D0 (en) 1992-01-28
ES2084092T3 (en) 1996-05-01
MX173928B (en) 1994-04-08
HU210794B (en) 1995-07-28
CA2055573A1 (en) 1992-05-16
EP0486097B1 (en) 1996-02-28
IT9022072A0 (en) 1990-11-15
CZ282836B6 (en) 1997-10-15
CS345291A3 (en) 1992-06-17
SG54114A1 (en) 1998-11-16
DE69117442T2 (en) 1996-08-14
BR9104962A (en) 1992-06-23
IT1245738B (en) 1994-10-14
PL167977B1 (en) 1995-12-30
KR940008390B1 (en) 1994-09-14

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