KR920008023A - 히드라진계 화합물 또는 그의 염, 이들의 제조방법 및 이들을 함유하는 살충제 - Google Patents

히드라진계 화합물 또는 그의 염, 이들의 제조방법 및 이들을 함유하는 살충제 Download PDF

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KR920008023A
KR920008023A KR1019910018961A KR910018961A KR920008023A KR 920008023 A KR920008023 A KR 920008023A KR 1019910018961 A KR1019910018961 A KR 1019910018961A KR 910018961 A KR910018961 A KR 910018961A KR 920008023 A KR920008023 A KR 920008023A
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nitro
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다다아끼 도끼
도루 고야나기
기요미쯔 요시다
가즈히로 야마모또
마사유끼 모리따
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아끼자와 다까시
이시하라 산교 가부시끼가이샤
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Abstract

내용 없음

Description

히드라진계 화합물 또는 그의 염, 이들의 제조방법 및 이들을 함유하는 살충제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 하기 일반식( I )의 히드라진 화합물 또는 그의 염.
    ( I )
    상기식에서, A는 치환될 수 있는 벤조푸라닐기, 치환될 수 있는 퀴놀리닐기, 치환될 수 있는 벤조티에닐기, 치환될 수 있는 벤조티아졸릴기, 치환될 수 있는 티에노티에닐기, 치환될 수 있는 디히드로 티에노티에닐기, 치환될 수 있는 디히드로시클로펜타티에닐기, 치환될 수 있는 테트라히드로벤조티에닐기, 치환될 수 있는 인다닐기 또는 치환될 수 있는 헥사히드로인다닐기이고, W는 수소원자, 시아노기, -COCOOR', -S-N(R")COOR' 또는 -CH2OCOR'이고, 여기서 R' 및 R"는 독립적인 것으로서, 각각 알킬기 또는 시클로알킬기이고, R은 할로겐 원자, 할로겐 원자에 의해 치환될 수 있는 알킬기, 할로겐 원자에 의해 치환될 수 있는 알콕시기, 할로겐 원자에 의해 치환될 수 있는 알킬티오기, 또는 니트로기이고, n은 0내지 5의 정수이며, 단 n이 2이상일 경우, 다수의 R은 서로 동일 또는 상이할 수 있다.
  2. 제1항에 있어서, A가 치환될 수 있는 벤조푸라닐기, 치환될 수 있는 퀴놀리닐기, 치환될수 있는 벤조티에닐기, 치환될 수 있는 벤조티아졸릴기, 치환될 수 있는 티에노에닐기, 치환될 수 있는 디히드로시클로펜타티에닐기 또는 치환될 수 있는 테트라히드로벤조티에닐기이고, W가 수소 원자임을 특징으로 하는 화합물.
  3. 제1항에 있어서, A가 치환될 수 있는 벤조티에닐기, 치환될 수 있는 티에노티에닐기, 치환될 수 있는 디히드로시클로펜타티에닐기 또는 치환될 수 있는 테트라히드로벤조티에닐기이고, W가 수소 원자이고, R이 할로겐 원자 또는 알킬기이고, n이 1 또는 2임을 특징으로 하는 화합물.
  4. 제3항에 있어서, A가 치환될 수 있는 벤조티에닐기, 치환될 수 있는 디히드로시클로펜타티에닐기 또는 치환될 수 있는 테트라히드로 벤조티에닐기임을 특징으로 하는 화합물.
  5. 제3항에 있어서, A가 치환될 수 있는 디히드로시클로펜타티에닐기 또는 치환될 수 있는 테트라히드로벤조티에닐기임을 특징으로 하는 화합물.
  6. 제1항에 있어서, N'-t-부틸-N'-3,5-디메틸벤조일-N-벤조[b]티오펜-2-카르보히드라지드인 화합물.
  7. 제1항에 있어서, N'-t-부틸-N'-3,5-디메틸벤조일-N-5,6-디히드로-4H-시클로펜타(b)티오펜-2-카르보히드라지드인 화합물.
  8. 제1항에 있어서, N'-t-부틸-N'-3,5-디메틸벤조일-N-4,5,6,7-테트라히드로벤조(b)티오펜-2-카르보히드라지드인 화합물.
  9. 하기 일반식(Ⅱ)의 화합물을 하기 일반식(Ⅲ)의 화합물과 반응시킴을 특징으로 하는 하기 일반식(I-1)의 히드라진 화합물 또는 그의 염의 제조 방법.
    (I-1)
    (Ⅱ)
    (Ⅲ)
    상기 각 식에서, A는 치환될 수 있는 벤조푸라닐기, 치환될 수 있는 퀴놀리닐기, 치환될 수 있는 벤조티에닐기, 치환될 수 있는 벤조티아졸리기, 치환될 수 있는 티에노티에닐기, 치환될 수 있는 디히드로티에노티에닐기, 치환될 수 있는 디히드로시클로펜타티에닐기, 치환될 수 있는 테트라히드로벤조티에닐기, 치환될 수 있는 안다닐기 또는 치환될 수 있는 헥사히드로인다닐기이고, R은 할로겐 원자, 할로겐 원자에 의해 치환될 수 있는 알콕기, 할로겐 원자에 의해 치환될 수 있는 알콕시기, 할로겐 원자에 의해 치환될 수 있는 알킬티오기, 또는 니트로기이고, n은 0 내지 5의 정수이며, 단 n이 2이상일 경우, 다수의 R은 서로 동일 또는 상이할 수 있고, X는 할로겐 원자, 알콕시기 또는 -OCOT이고, 여기서 T는 알킬기이다.
  10. 하기 일반식(I-1)의 히드라진 화합물을 하기 일반식(A)의 화합물과 반응시킴을 특징으로 하는 하기 일반식(I-2)의 히드라진 화합물 제조 방법.
    (I-1)
    (I-2)
    W'-G (A)
    상기식에서, A는 치환될 수 있는 벤조푸라닐기, 치환될 수 있는 퀴놀리닐기, 치환될 수 있는 벤조티에닐기, 치환될 수 있는 벤조티아졸릴기, 치환될 수 있는 티에노티에닐기, 치환될 수 있는 디히드로티에노티에닐기, 치환 될 수 있는 디히드로시클로펜타티에닐기, 치환될 수 있는 테트라히드로벤조티에닐기, 치환될 수 있는 인다닐기 또는 치환될 수 있는 헥사히드로인다닐기이고, W'는 시아노기, -COCOOR', -S-N(R")COOR' 또는 -CH2COR'이고, 여기서 R' 및 R"는 독립적인 것으로서, 각각 알킬기 또는 시클로알킬기이고, R은 할로겐 원자, 할로겐 원자에 의해 치환될 수 있는 알킬기, 할로겐 원자에 의해 치환될 수 있는 알콕시기, 할로겐원자에 의해 치환될 수 있는 알킬티오기, 또는 니트로기이고, n은 0 내지 5의 정수이며, 단 n이 2이상일 경우, 다수의 R은 서로 동일 또는 상이할 수 있고, G는 염소원자 또는 브롬원자이다.
  11. 유효성분으로서 살충 유효량의 하기 일반식( I )의 히드라진 화합물 또는 그의 염, 및 농략 보조제를 함유하는 살충 조성물.
    ( I )
    상기 식에서, A는 치환될 수 있는 벤조푸라닐기, 치환될 수 있는 퀴놀리닐기, 치환될 수 있는 벤조티에닐기, 치환될 수 있는 벤조티아졸릴기, 치환될 수 있는 티에노티에닐기, 치환될 수 있는 디히드로티에노티에닐기, 치환될 수 있는 디히드로시클로펜타티에닐기, 치환될 수 있는 테트라히드로벤조티에닐기, 치환될 수 있는 인다닐기 또는 치환될 수 있는 헥사히드로인다닐기이고, W는 수소원자, 시아노기, -COCOOR', -S-N(R")COOR' 또는 -CH2OCOR'이고, 여기서 R' 및 R"는 독립적인 것으로서, 각각 알킬기 또는 시클로알킬기이고, R은 할로겐원자, 할로겐 원자에 의해 치환될 수 있는 알킬기, 할로겐 원자에 의해 치환될 수 있는 알콕시기, 할로겐 원자에 의해 치환될 수 있는 알킬티오기, 또는 니트로기이고, n은 0내지 5의 정수이며, 단 n이 2이상일 경우, 다수의 R은 서로 동일 또는 상이할 수 있다.
  12. 유효량의 하기 일반식(I)의 히드라진 화합물 또는 그의 염을 해충에 사용함을 특징으로 하는 살충방법.
    ( I )
    상기 식에서, A는 치환될 수 있는 벤조푸라닐기, 치환될 수 있는 퀴놀리닐기, 치환될 수 있는 벤조티에닐기, 치환될 수 있는 벤조티아졸릴기, 치환될 수 있는 티에노티에닐기, 치환될 수 있는 디히드로티에노티에닐기, 치환될 수 있는 디히드로시클로펜타티에닐기, 치환될 수 있는 테트라히드로벤조티에닐기, 치환될 수 있는 인다닐기 또는 치환될 수 있는 헥사히드로인다닐기이고, W는 수소원자, 시아노기, -COCOOR', -S-N(R")COOR' 또는 -CH2OCOR'이고, 여기서 R' 및 R"는 독립적인 것으로서, 각각 알킬기 또는 시클로알킬기이고, R은 할로겐 원자, 할로겐 원자에 의해 치환될 수 있는 알킬기, 할로겐 원자에 의해 치환될 수 있는 알콕시기, 할로겐 원자에 의해 치환될 수 있는 알킬티오기, 또는 니트로기이고, n은 0내지 5의 정수이며, 단 n이 2이상일 경우, 다수의 R은 서로 동일 또는 상이할 수 있다.
  13. 하기 일반식(Ⅱ)의 화합물.
    (Ⅱ)
    상기 식에서, A는 치환될 수 있는 벤조푸라닐기, 치환될 수 있는 퀴놀리닐기, 치환될 수 있는 벤조티에닐기, 치환될 수 있는 벤조티아졸릴기, 치환될 수 있는 티에노티에닐기, 치환될 수 있는 디히드로티에노티에닐기, 치환될 수 있는 디히드로시클로펜타티에닐기, 치환될 수 있는 테트라히드로벤조티에닐기, 치환될 수 있는 인다닐기 또는 치환될 수 있는 헥사히드로인다닐기이다.
  14. 유효성분으로서 하기 일반식( I )의 히드라진 화합물 또는 그의 염 유효량, 2-(4-에톡시테릴)-2-메틸프로필-3-페녹시벤질에테르, 2-tert-부틸이미노-3-이소프로필-5-페닐-3,4,5,6-테트라히드로-2H-1,3,5-티아디아진-4-온, (4-에톡시페닐)-[3-(4-플루오로-3-페녹시페닐)프로필](디메틸)실란, 1-(6-클로로-3-피리딜메닐)-N-니트로-이미다졸리딘-2-일리덴아민, 1-[N-(6-클로로-3-피리딜메틸)-N-에틸아미노]-1-메틸아미노-2-니트로에틸렌, 2-메틸아미노-2-[N-메틸-N-(6-클로로-3-피리딜메틸)아미노]-1-니트로에틸렌, 1-(6-클로로-3-피리딜메틸)아미노-1-디메틸아미노-2-니트로에틸렌, 1-(6-클로로-3-피리딜메틸)-2-(1-니트로-2-알릴티오에틸리덴)이미다졸리딘, 1-(6-클로로-3-피리딜메틸)-2-(1-니트로-2-에틸티오에틸리덴)이미다졸리딘, 1-(6-클로로-3-피리딜메틸)-2-(1-니트로-2-β-메틸알릴티오에틸리덴)이미다졸리딘, 1-(6-클로로-3-피리딜메틸)-3-메틸-2-니트로구아니딘, 1-(6-클로로-3-피리딜메틸)-3,3-디메틸-2-니트로구아니딘, 3-(6-클로로-3-피리딜메틸)-2-니트로메틸렌-티아졸리딘, 1-(6-클로로-3-피리딜메틸)-2-(니트로메틸렌)-이미다졸리딘, 6-(6-클로로-3-피리딜메틸아미노)-1,3-디메틸-5-니트로-1,2,3,4-테트라히드로피리미딘, 및 1-(6-클로로-3-피리딜메틸)-5-니트로-3-메틸-6-메틸아미노-1,2,3,4-테트라히드로 피리미딘으로 이루어진 군으로부터 선택된 적어도 하나의 화합물 유효량, 및 농약 보조제를 함유하는 살충 조성물.
    (I)
    상기 식에서, A는 치환될 수 있는 벤조푸라닐기, 치환될 수 있는 퀴놀리닐기, 치환될 수 있는 벤조티에닐기, 치환될 수 있는 벤조티아졸릴기, 치환될 수 있는 티에노티에닐기, 치환될 수 있는 디히드로티에노티에닐기, 치환될 수 있는 디히드로시클로펜타티에닐기, 치환될 수 있는 테트라히드로벤조티에닐기, 치환될 수 있는 인다닐기 또는 치환될 수 있는 헥사히드로인다닐기이고, W는 수소원자, 시아노기, -COCOOR', -S-N(R")COOR' 또는 -CH2OCOR'이고, 여기서 R' 및 R"는 독립적인 것으로서, 각각 알킬기 또는 시클로알킬기이고, R은 할로겐 원자, 할로겐 원자에 의해 치환될 수 있는 알킬기, 할로겐 원자에 의해 치환될 수 있는 알콕시기, 할로겐 원자에 의해 치환될 수 있는 알킬티오기, 또는 니트로기이고, n은 0내지 5의 정수이며, 단 n이 2이상일 경우, 다수의 R은 서로 동일 또는 상이할 수 있다.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910018961A 1990-10-29 1991-10-28 히드라진계 화합물 또는 그의 염, 이들의 제조방법 및 이들을 함유하는 살충제 KR920008023A (ko)

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