KR920001456B1 - Hair dye composition - Google Patents

Abstract

No content.

Description

Hair coloring composition

The present invention relates to temporary hair coloring compositions, commonly referred to as hair colors, and more particularly to hair coloring compositions for temporary hair toning or gray hair coloring for beauty.

Hair coloring preparations are generally classified into temporary, semi permanent and permanent preparations depending on the persistence of the color pigmented to the hair.

Temporary toning is a cosmetic means of transforming the appearance by coloring all or part of the hair in a lighter or more youthful color. And, the cosmetic coloring of gray hair weakens gray by changing the appearance of mixed gray hair by giving a constant color tone by darkening gray hair or lightening black hair.

In general, cosmetic temporary hair coloring products filled with an aerosol sprayer having a pressurized container are known. These hair coloring products include binders such as alkanolamine solutions of polyvinylrrolidone, polyacrylates or polymethacrylates; Solvents such as ethanol; Propellants such as freons; And inorganic pigments with a hiding power such as mica, mica treated or coated with titanium oxide (hereinafter referred to as titanium mica), titanium oxide mica treated with iron oxide, titanium oxide, aluminum powder, copper powder or iron oxide, organic And colorants including pigments and / or dyes. These known temporary hair coloring products used for hair give the hair a rough feeling after drying, after brushing and combing because the hair fibers adhere to each other due to the resin present as a binder. A low resin content may slightly reduce the roughness, but there is another problem that the colorant on the hair can come in contact with the clothes and hands and dye the clothes and hands. In addition, when using organic pigments or dyes as colorants, the colorant in contact with the clothes penetrates the fibers of the clothes, and cannot be washed when washing.

If inorganic pigments with good bleeding power are used alone as colorants, their high specific gravity produces phase separation and cakes in the spraying vessel, and the vessel is repeated several times to redistribute the ingredients, even with the use of a stirring boil. You have to shake it.

It is also possible to use temporary hair coloring products which contain the same ingredients as in aerosol preparations, i.e. colorants, binders and solvents, and which are contained in a container so as to color the hair by brush or the like. However, these products also have the same drawbacks as aerosol products.

Temporary hair coloring products in the form of creams are known to blend kneaded, high-negative inorganic pigments into oils such as petroleum, such as low fluidity and high viscosity. These products are sticky, easily adhere to the back of the hand, not only have a natural effect on the appearance, but also cannot make the hair satisfactorily beautiful.

It is an object of the present invention to provide temporary hair coloring compositions which can give a natural appearance and a good feeling after use.

Another object of the present invention is to provide a temporary hair coloring composition that cannot be easily shed in contact with clothes, hands, and the like.

Another object of the present invention is to provide a temporary coloring composition which can be easily washed at the time of washing even if it penetrates clothes or the like.

It is a further object of the present invention to provide a temporary hair coloring composition which can be easily redispersed by shaking the spray container several times even with less cake and phase separation.

Still other objects and aspects of the present invention are shown in more detail by the following description.

The present invention relates to a hair coloring composition containing 100 parts by weight of colored mica, 20 to 100 parts by weight of a silicone oil having a dynamic viscosity of 10 to 50 cSt (centistoke) at 20 ° C. and 350 to 3000 parts by weight of a solvent (hereinafter, the present invention). It is referred to as the first composition of).

The present invention also provides hair coloring containing 100 parts by weight of colored mica, 20 to 100 parts by weight of silicone oil having a dynamic viscosity of 10 to 50 cSt at 20 ° C., 100 to 2000 parts by weight of solvent and 100 to 10000 parts by weight of propellant. A composition (hereinafter referred to as second composition of the present invention) is provided.

The present invention also relates to 100 parts by weight of colorant containing 20 to 70% by weight of colored mica and 80 to 30% by weight of iron oxide powder, 40 to 160 parts by weight of silicone oil having a dynamic viscosity of 10 to 50 cSt at 20 ° C, and A hair coloring composition (hereinafter referred to as a third composition of the present invention) containing 300 to 5000 parts by weight of a solvent is provided.

In addition, the present invention provides 100 parts by weight of colored body containing 20 to 70% by weight of colored mica and 80 to 30% by weight of iron oxide powder, 40 to 160 parts by weight of silicone oil having a dynamic viscosity of 10 to 50 cSt at 20 ° C. And a hair coloring composition (hereinafter referred to as a fourth composition of the present invention) containing 100 to 3000 parts by weight of a solvent and 100 to 10000 parts by weight of a propellant.

The study of the present inventors has found that hair coloring compositions incorporating colored mica or a mixture of colored mica and iron oxide powder as a colorant, and a silicone oil having a specific kinematic viscosity significantly or substantially overcome the above-mentioned problems of known hair coloring products. It shows that it can be overcome. It has also been found that these hair coloring compositions, which further contain propellants, exhibit significant properties. Based on these novel findings, the present invention has been completed.

The hair coloring composition of the 1st-4th of this invention is demonstrated in detail below.

I. First Composition of the Invention

(i) Examples of colored mica that can be used in the present invention include titanium mica, iron oxide treated titanium mica, chromium oxide treated titanium mica, Prussian blue treated titanium mica and the like. These compounds may be used alone or in a mixture of two or more. Useful colored mica is a sheet crystalline form having a maximum diameter of about 5 to 60 μm and a thickness of about 0.1 μm. Titanium mica has a titanium dioxide layer formed on the surface of thin flake mica crystals as a substrate and the thickness of the two layers is controlled within a limited range. Although white in appearance, these micas can produce disturbing colors such as yellow, red, blue or green, and in particular can form significant colors on black background (eg black hair). The iron oxide treated titanium mica has a layer of this titanium oxide and triiron tetraoxide and / or sesqui iron oxide, and may exhibit a bright light yellow to brown color depending on the thickness of the layer. Chromium oxide treated or Prussian blue treated titanium mica is obtained by coating titanium mica with chromium oxide or Prussian blue (iron ferrocyanide and iron ferricyanide). Among these colored micas, for example, titanium mica under the names "Timiron" and "Soloron" and iron oxide treatment under the trade names "Coloron", chromium oxide treatment and Prussian blue treatment Titanium mica is commercially available (product: German E.Merck Co.).

The colored mica treated with the surface to impart lipophilic can be highly redispersed in the coloring composition. Known methods of surface treatment of colored mica to impart lipophilic include the method of rubbing colored mica with a mixture of hydrocarbons, higher fatty acids and silicone oil and baking coated mica (Japanese Patent Publication No. 29512/1981) and coloring There is a method of coating mica with silicone oil and baking the coated mica.

(ii) The silicone oil used in the present invention has a dynamic viscosity of 10 to 50 cSt at 20 ° C. Examples of suitable silicone oils are dimethylpolysiloxane, methylphenylpolysiloxane and the like. More preferred silicone oils are those having a dynamic viscosity of 15 to 30 cSt at 20 ° C.

(iii) Examples of the solvent used in the present invention include ethanol and isopropyl alcohol. Alcohols which may be used as the solvent may contain up to 40% by weight of water. The presence of more than 40% by weight of water leads to longer drying time of the hair after use of the composition, and the composition cannot be sprayed uniformly because the silicone oil is separated and suspended on top of the composition when the composition is introduced into the non-gas spray.

(iv) The first composition of the present invention usually contains 100 parts by weight of colored mica, 20 to 100 parts by weight of silicone oil and 350 to 3000 parts by weight of solvent, preferably 100 parts by weight of colored mica, 30 to 70 parts by weight of silicone. Oil and 500 to 1500 parts by weight of solvent. If the silicone oil per 100 parts by weight of colored mica is less than 20 parts by weight, the composition after use is easily removed by combing and gives a rough feeling to the hands because it cannot be satisfactorily applied by combing. Hair using a composition containing more than 100 parts by weight of silicone oil is sticky, heavy, and dirty hands. The use of solvents of 350 parts by weight or less per 100 parts by weight of the colorant makes it impossible to spray the composition uniformly due to its high concentration and may be blocked by the valve. If the amount is more than 3000 parts by weight, the coloring effect is reduced due to the low concentration.

II. Second composition of the present invention

The second composition of the present invention contains the same components as the first composition of the present invention, colored mica, silicone oil and solvent, as well as propellants such as freon and liquefied petroleum gas, which are commonly used as gases for aerosol spraying.

The second composition usually contains 100 parts by weight of colored mica, 20 to 100 parts by weight of silicone oil, 100 to 2000 parts by weight of solvent and 100 to 10000 parts by weight of propellant, preferably 100 parts by weight of colored mica, 30 to 70 parts by weight. Parts of silicon oil, 300 to 1000 parts by weight of solvent and 1000 to 5000 parts by weight of propellant.

In the second composition, it is desirable to reduce the amount of solvent while increasing the amount of propellant.

III. Third composition of the present invention

(i) The third composition of the present invention contains 20 to 70% by weight of colored mica and 80 to 30% by weight of iron oxide powder as in the first composition, preferably 30 to 60% by weight of colored mica and 70 to 40%. A colorant containing a weight percent iron oxide powder. Examples of the iron oxide powder to be used are those usually used as pigments, for example, cubic structures having a diameter of about 0.1 to 2.0 mu m, and needle structures having a width of about 0.01 to 1.0 mu m and a length of about 0.1 to 2.0 mu m. Iron oxides used as pigments may have various colors such as black, pale yellow to yellow brown, light red to red brown and the like. According to the invention, all of these iron oxides can be used and, if necessary, can be used alone or in mixtures. They can use commercially available trade names “MAPICO Yellow LL-XLO”, “MAPICO Red R-516-L” and “MAPICO Black BL-100” made by Titan Kogyo Kabushiki Kaisha, Japan. have.

(ii) the third composition contains 100 parts by weight of colorant containing 20 to 70% by weight of colored mica and 80 to 30% by weight of iron oxide powder, 40 to 160 parts by weight of silicone oil and 300 to 5000 parts by weight of solvent, Preferably it contains 100 parts by weight of colorant, 60 to 100 parts by weight of silicone oil and 1000 to 2000 parts by weight of solvent. When used in hair, the use of a composition containing a large proportion of oxide powder outside the range of mica-iron oxide mixtures does not produce the same gloss as in healthy hair, and the appearance is unnatural.

In the third composition, since the iron oxide powder having a higher bulk density is present, a larger amount of silicon oil is blended than in the first composition.

IV. 4th composition of this invention

The fourth composition further contains propellants, such as freon and liquefied petroleum gas, in addition to the same components as in the third composition, ie colorants, silicone oils and solvents.

The fourth composition comprises 100 parts by weight of colorant containing 20 to 70% by weight of colored mica and 80 to 30% by weight of iron oxide powder, 40 to 160 parts by weight of silicone oil, 100 to 3000 parts by weight of solvent and 100 to 10000 parts by weight of spray It preferably contains 100 parts by weight of colorant, 60 to 100 parts by weight of silicone oil, 500 to 1500 parts by weight of solvent and 1000 to 5000 parts by weight of propellant.

In the fourth composition, it is preferable to increase the amount of propellant and to reduce the amount of solvent.

As long as it does not interfere with the remarkable properties of the composition of the present invention, additives such as fragrances, wetting agents, binders, oils and vegetable extracts generally used in the preparation of hair coloring preparations can be blended into the compositions of the present invention. Examples of useful humectants include propylene glycol, 1,3-butylene glycol, sodium dl-pyrrolidone carboxylate, and the like. Examples of useful binders include polyvinyl pyrrolidone, vinylpyrrolidone-vinylacetate copolymers, methylacetate-maleic anhydride copolymers, alkanol amine solutions of acrylic resins, methacrylic acid derivative copolymers, vinyl pyrrolidone- Dimethylaminoethyl methacrylate copolymer and the like. Examples of plant extracts used include lily extract, aloe extract and the like. Examples of oils used include hydrocarbons such as liquid paraffins and petrolatum, esters such as isopropyl myristate, lanolin and derivatives thereof, polyethylene glycol and derivatives thereof, polypropylene glycol and derivatives thereof.

The hair coloring composition of the present invention can achieve the following remarkable results.

(1) After using the composition, there is no roughness of hair even when dried, and brushing and combing can be performed smoothly.

(2) This composition gives the hair a natural luster and a fascinating color tone.

(3) The composition does not penetrate into the fibers of the clothes even when it is on the clothes, and can be washed relatively easily at the time of washing.

(4) When deposited on human skin, the composition can be easily removed without giving a sticky feeling.

(5) Various color tones can be produced by changing the ratio of colored mica and iron oxide powder or by mixing two or more kinds of colored mica and granular iron oxide.

(6) The composition used for spraying does not produce cake and can be easily redispersed by shaking the spray container several times when solids in the composition are deposited in the container.

(7) The composition brought into the hair can be easily removed by the shampoo so that the hair can be regenerated to its original color.

The following examples and comparative examples illustrate the invention in detail.

In the following examples and comparative examples, the composition was placed in a beaker with the components (100 g total weight calculated), the components were stirred to obtain a homogeneous dispersion, and the dispersion was 100 mesh screen (mesh size = 149 mu m). It is manufactured by passing through.

Example 1

A non-gaseous spray spray capable of preparing six types of hair coloring compositions (Samples 1-1 to 1-6) using the components listed in Table 1 and spraying about 0.1 g of aerosol at each sample Volume 50 ml). Shake the spray container several times before use to obtain a uniform dispersion, and spray the sample evenly 40 times on a human black short hair wig (amount of about 100 g). Comb your hair about 50 times. The results are shown in Table 2 below.

The asterisks described in the table indicate the compositions of the present invention and the results obtained by the compositions.

TABLE 1

TABLE 2

Example 2

Five kinds of hair coloring compositions (Samples 2-1 to 2-5) were prepared using the components shown in Table 3 below. Table 4 shows the results obtained when the composition was tested in the same manner as in Example 1.

TABLE 3

TABLE 4

Example 3

Eight kinds of hair coloring compositions (Samples 3-1 to 3-8) were prepared using the ingredients shown in Table 5 below. 50 ml of each sample is placed in a 100 ml glass bottle, capped and left for one month at room temperature. The appearance of the composition is observed, the apparent amount of sedimentation of the colored mica is measured, and the glass bottle is shaken by hand to obtain uniform dispersion while counting the number of vibrations required for redispersion. The results are shown in Table 6 below.

TABLE 5

TABLE 6

Example 4

Three kinds of hair coloring compositions were prepared from the components shown in the following Table 7, and 30 g of each sample and 70 g of a propellant (the same amount of dichlorodifluoromethane and trichlorofluoromethane were mixed) in a 120 ml glass container. It is left for 1 month at normal temperature. The container is then shaken by hand to obtain a uniform dispersion while counting the number of vibrations. The results are shown in Table 8 below.

TABLE 7

TABLE 8

Example 5

A hair coloring composition was prepared from the ingredients set forth in Table 9 below.

TABLE 9

The composition thus prepared is filled into a non-gas spray as used in Example 1 and shaken 4 or 5 times. The composition is then sprayed evenly 50 times over the entire hair except for the hair in the forehead portion of the slightly wavy female hair (standard amount of hair). Combing the entire hair, including the forehead part about 80 times, results in uniformly colored tan hair.

The composition does not fall off by combing. Hair is combed smoothly, gives no grease or feel, and is not contaminated when the hair is touched by hand. The hair will be restored to its original color after it has been wound once.

Example 6

A hair coloring composition was prepared in the same manner as in Example 5 except for using 80% ethanol.

The composition is slightly longer in drying time but less alcoholic and therefore more convenient to use. In other properties the composition is similar to that of the composition prepared in Example 5.

Example 7

A hair coloring composition is prepared from the ingredients set forth in Table 10, and 30 g of the composition is fed into an aerosol spray with 70 g of propellant (as used in Example 4).

When the composition thus prepared is sprayed onto a portion of black female straight hair (having a standard amount), only the sprayed portion is colored in light blue. The colorant does not fall off by combing. Hair is combed smoothly and does not feel dirty and greasy when touched by hand.

TABLE 10

Example 8

A hair coloring composition was prepared from the ingredients set forth in Table 11, which was packed into a non-gas spray capable of spraying about 0.12 g of aerosol at a time.

TABLE 11

Shake the spray 4 or 5 times before use and spray the composition evenly 30 times over the entire male short hair (about 80% gray hair).

After about 20 combs, the entire hair becomes evenly glossy grey. The colored mica deposited on the skin of the hair is easily removed with soft paper without falling off the composition by combing.

Combed hair does not feel greasy and does not contaminate your hands.

Example 9

A hair coloring composition was prepared from the components set forth in Table 12, which was packed into a non-gas spray that could spray about 0.08 g of aerosol at a time.

The spray was shaken 4 or 5 times before use and evenly sprayed 60 times over the entire female hair (about 20% gray hair).

After drying, the mica colored by combing the hair 100 times was distributed evenly throughout the hair, but did not fall off.

The hair was colored burgundy and gray hair was almost invisible at a distance of about 2 m. In other properties, the composition is similar to the sample obtained in the previous example.

TABLE 12

Example 10

The hair coloring composition was prepared by the same method as above from the components shown in the following Table 13, which was filled into a non-gas spray capable of spraying 0.1 g of aerosol at a time. Shake the spray several times to uniformly disperse the composition, and then short wigs and 10% gray hair of a person with 50% gray hair (amount of total hair is about 100g, gray hair is distributed evenly among black hair). Another short wig stomach of another person with a total amount of hair (about 100 g and evenly distributed gray hair between black hairs) was sprayed evenly 40 times each and then combed about 50 times. Table 14 shows the results. The evaluation obtained by observing the wig at a distance of about 30 cm is shown in the "A" column of Table 14, and the evaluation obtained by observing at a distance of 100 cm is shown in the "B" column of Table 14. The color given to the wig was evaluated according to the following six grades.

-2: less gloss than healthy hair

-1: slightly less gloss than healthy hair

0: Gloss is the same as healthy hair.

1: better gloss than healthy hair

2: Shiny as if gold powder was applied.

3: Shiny as if gold powder was applied.

TABLE 13

TABLE 14

Example 11

(1) Fourteen kinds of hair coloring compositions (Samples 11-1 to 11-4) were prepared from the ingredients listed in the following Table 15, and 25 ml of each sample was centrifuged in a centrifuge (30 mm in diameter, 96 mm in height and 62 ml in volume). ) And then 20 minutes at 1000 rpm. The phase separated composition is shaken with a vibrator with a stroke distance of 20 mm and a vibration frequency of 50 times / 18 sec. And then observed for redispersion at a given interval. The results are shown in the following table 16-1, in which “A” means that the system is uniformly dispersed, and “B” means that the system is not uniformly dispersed.

TABLE 15

Table 16-1

(2) Each sample used in (1) above is filled into a vinyl chloride cylinder vessel having an outer diameter of 30 mm, a height of 78 mm, and a capacity of 50 ml, then sealed with a cap and left at room temperature for one month. Next, shake the container by hand until the entire system is uniformly dispersed. Table 16-2 below shows the number of vibrations required to obtain a homogeneous dispersion.

Table 16-2

Example 12

(1) Four kinds of hair coloring compositions (Samples 12-1 to 12-4) were prepared from the components shown in the following Table 17 ((1), (4), (9) and (10) Are as defined above.), And treated with a centrifuge in the same manner as in Example 11- (1). The phase separated composition was then shaken in the same manner as in Example 11- (1) and the redispersion was observed at a given interval. The results are shown in the following Table 18-1, where “A” and “B” are as mentioned in Table 16-1 above.

TABLE 17

Table 18-1

(2) Each sample prepared as in (1) was shaken in the same manner as in Example 11- (1) while counting the number of vibrations as shown in Table 18-2.

Table 18-2

Example 13

Five kinds of hair coloring compositions (Samples 13-1 to 13-5) were prepared from the components shown in Table 19, in which (1), (2), (9), (10) and (11) ) Is as defined above. Each sample was filled with a non-gas spray as in Example 10, shaken and sprayed uniformly 40 times on 100 g of human short-haired wig. Then, combed about 50 times. Table 20 below shows the properties of the samples as colorants.

TABLE 19

TABLE 20

Example 14

Six kinds of hair coloring compositions (Samples 14-1 to 14-6) were prepared from the ingredients shown in the following Table 21, and the properties as colorants were examined in the same manner as in Example 13, and the results are shown in the following Table 22. . In this table, (1), (2), (9), (10) and (11) are as defined above and the dynamic viscosity of the silicone oil is measured at 20 ° C.

TABLE 21

Table 22

Example 15

Nine kinds of hair coloring compositions (Samples 15-1 to 15-9) were prepared from the components shown in the following Table 23, 50 ml of each sample was placed in a 100 ml glass bottle, and the appearance of the samples was observed. The results are shown in Table 24 below.

TABLE 23

TABLE 24

Example 16

A hair coloring composition is prepared from 100 parts by weight of the components shown in Table 25 and placed in a non-gas spray that can spray about 0.1 g of aerosol at a time. Shake several times before using the spray to disperse the components homogeneously and spray the composition evenly 50 times (about 5 g) onto the waved female short hair (about 10% gray hair, standard amount of hair). Next, combing the hair about 80 times will color the hair reddish dark brown. The composition is hardly removed from the hair by combing.

Hair is soft to comb, and hands that come in contact with the hair don't feel oil at all, and hands are not contaminated.

The composition attached to the hair is easily removed with a single shampoo.

TABLE 25

Example 17

The hair coloring composition is prepared from 100 parts by weight of the components shown in the following Table 26 and filled into a non-gas spray. Shake several times before using the spray to disperse it homogeneously, spray it evenly 50 times (about 5 g) all over the woman's single hair (about 10% gray hair, standard amount of hair) and comb about 60 times.

The hair exhibits the usual dark chestnut brown and the composition is not removed by combing.

Hair is soft to comb, and hands that come in contact with it can't feel sticky or oily at all.

TABLE 26

Example 18

The hair coloring composition prepared from 100 parts by weight of the components exemplified in Table 27 is filled into a non-gas spray that can spray about 0.1 g of aerosol at a time. Shake several times before using the spray to obtain a homogeneous dispersion, and then spray the composition uniformly 60 times (approximately 6 g) throughout the waved women's short hair (50% gray hair, standard amount of hair), about 100 times Combing the hair makes the hair uniformly dark natural brown. Little or no composition is removed by combing. The combing is smooth and not sticky at all, and hands are not contaminated.

The composition is easily removed with a single shampoo.

TABLE 27

Example 19

A hair coloring composition was prepared from the components specified in Table 28 below and sprayed 40 times (about 4 g) over the entire male short hair (about 50% gray hair) as described in Example 16. Combing 20 times will give your hair a uniform dark brown color.

It can be seen that the composition has the same properties as those prepared in Example 16.

TABLE 28

Example 20

The hair coloring composition is prepared from the ingredients shown in the following Table 29.

TABLE 29

Subsequently, 70 parts by weight of the same mixture of dichlorodifluoromethane and trichloromonofluoromethane and 30 parts by weight of the prepared composition were filled in an aerosol spray, and short-wave hair (50% gray hair, standard amount of hair) of a female was waved. Spray about 10g evenly.

Comb your hair 60 times to get a dark natural brown color.

It can be seen that the composition has other excellent properties comparable to that of the product obtained in Example 16.

Example 21

A hair coloring composition is prepared from the ingredients set forth in Table 30 below.

TABLE 30

The composition contained in the non-gas spray is shaken several times to disperse homogeneously and evenly sprayed 50 times (about 5 g) all over black hair (standard amount of hair) of a woman with a slight wave. Continue combing about 80 times to make the hair evenly dark tan.

It can be seen that the composition has the same properties as those obtained in Example 16.

Example 22

The hair coloring composition is prepared from the ingredients specified in the following Table 31.

Table 31

The composition filled with the non-gas spray is shaken several times to uniformly disperse and evenly sprayed 50 times (about 5 g) all over the women's short hair (standard amount of hair) with waves. After about 80 combs, the hair becomes evenly dark brown.

It can be seen that the composition has the same good properties as that of the sample obtained in Example 16.

Claims (28)

Hair coloring composition containing (1) 100 weight part of colored mica, (2) 20-100 weight part of silicone oil which has a dynamic viscosity of 10-50 cSt at 20 degreeC, and (3) 350-3000 weight part of solvent. The hair according to claim 1, comprising (1) 100 parts by weight of colored mica, (2) 30 to 70 parts by weight of silicone oil having a dynamic viscosity of 10 to 50 cSt at 20 ° C, and (3) 500 to 1500 parts by weight of hair. Coloring composition. The hair coloring composition according to claim 1 or 2, wherein the silicone oil has a dynamic viscosity of 15 to 30 cSt at 20 ° C. The hair coloring composition according to claim 1 or 2, wherein the silicone oil is at least one of dimethylpolysiloxane and methylphenylpolysiloxane. The hair coloring composition according to claim 1 or 2, wherein the solvent is at least one of ethanol and isopropyl alcohol. The hair coloring composition according to claim 1 or 2, wherein the solvent contains up to 40% by weight of water. (1) 100 parts by weight of colored mica, (2) 20 to 100 parts by weight of silicone oil having a dynamic viscosity of 10 to 50 cSt at 20 ° C, (3) 100 to 2000 parts by weight of solvent and (4) 100 to 1000 parts by weight Hair coloring composition containing a propellant. The method according to claim 7, wherein (1) 100 parts by weight of colored mica, (2) 30 to 70 parts by weight of silicone oil having a dynamic viscosity of 10 to 50 cSt at 20 ° C., (3) 300 to 1000 parts by weight of solvent, and (4) A hair coloring composition containing 1000 to 5000 parts by weight of propellant. The hair coloring composition according to claim 7 or 8, wherein the dynamic viscosity of the silicone oil at 20 ° C. is 15 to 30 cTt. The hair coloring composition of claim 7 wherein the silicone oil is at least one of dimethylpolysiloxane and methylphenylpolysiloxane. The hair coloring composition according to claim 7 or 8, wherein the solvent is at least one of ethanol and isopropanol. The hair coloring composition according to claim 7 or 8, wherein the solvent contains up to 40% by weight of water. The hair coloring composition according to claim 7 or 8, wherein the propellant is a freon or liquefied petroleum gas. (1) 100 parts by weight of a colorant consisting of 20 to 70% by weight of colored mica and 80 to 30% by weight of iron oxide powder, (2) 40 to 160 parts by weight of silicone oil having a dynamic viscosity of 10 to 50 cSt at 20 ° C, ( 3) Hair coloring composition containing 300-5000 weight part of solvent. 15 to 100 parts by weight of a colorant comprising (1) 20 to 70% by weight of colored mica and 80 to 30% by weight of iron oxide powder, and (2) 60 to 100% by weight having a dynamic viscosity of 10 to 50 cSt at 20 ° C. Hair coloring composition containing negative silicone oil and (3) 1000-2000 weight part of solvents. The hair coloring composition according to claim 14 or 15, wherein the colorant contains 30 to 60% by weight colored mica and 70 to 40% by weight iron oxide powder. The hair coloring composition according to claim 14 or 15, wherein the silicone oil has a dynamic viscosity of 15 to 30 cSt at 20 ° C. The hair coloring composition according to claim 14 or 15, wherein the silicone oil is at least one of dimethylpolysiloxane and methylphenylpolysiloxane. The hair coloring composition according to claim 14 or 15, wherein the solvent is at least one of ethanol and isopropanol. The hair coloring composition according to claim 14 or 15, wherein the solvent contains up to 40% by weight of water. (1) 100 parts by weight of a colorant consisting of 20 to 70% by weight of colored mica and 80 to 30% by weight of iron oxide powder, (2) 40 to 160 parts by weight of silicone oil having a dynamic viscosity of 10 to 50 cSt at 20 ° C, ( 3) Hair coloring composition containing 100-3000 weight part solvent and (4) 100-10000 weight part propellant. (1) 100 parts by weight of a colorant consisting of 20 to 70% by weight of colored mica and 80 to 30% by weight of iron oxide powder, (2) 60 to 100 parts by weight of silicone oil having a dynamic viscosity of 10 to 50 cSt at 20 ° C, ( 3) Hair coloring composition containing 500-1500 weight part solvent and (4) 1000-5000 weight part propellant. The hair coloring composition according to claim 21 or 22, wherein the colorant contains 30 to 60% by weight colored mica and 70 to 40% by weight iron oxide powder. The hair coloring composition according to claim 21 or 22, wherein the dynamic viscosity of the silicone oil oil at 20 ° C. is 15 to 30 cSt. 23. The hair coloring composition of claim 21 or 22, wherein the silicone oil is at least one of dimethylpolysiloxane and methylphenylpolysiloxane. 23. The hair coloring composition of claim 21 or 22, wherein the solvent is at least one of ethanol and isopropanol. The hair coloring composition according to claim 21 or 22, wherein the solvent contains up to 40% by weight of water. 23. The hair coloring composition of claim 21 or 22, wherein the propellant is a freon or liquefied petroleum gas.