KR910700268A - 아민을 제조하기 위한 방법 및 촉매 - Google Patents

아민을 제조하기 위한 방법 및 촉매

Info

Publication number
KR910700268A
KR910700268A KR1019900702269A KR900702269A KR910700268A KR 910700268 A KR910700268 A KR 910700268A KR 1019900702269 A KR1019900702269 A KR 1019900702269A KR 900702269 A KR900702269 A KR 900702269A KR 910700268 A KR910700268 A KR 910700268A
Authority
KR
South Korea
Prior art keywords
catalyst
zirconium
component
mixtures
cobalt
Prior art date
Application number
KR1019900702269A
Other languages
English (en)
Inventor
지. 바우만 로버트
Original Assignee
리챠드 지. 워터맨
더 다우 케미칼 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 리챠드 지. 워터맨, 더 다우 케미칼 캄파니 filed Critical 리챠드 지. 워터맨
Publication of KR910700268A publication Critical patent/KR910700268A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/24—Preparation of compounds containing amino groups bound to a carbon skeleton by reductive alkylation of ammonia, amines or compounds having groups reducible to amino groups, with carbonyl compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/02—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms containing only hydrogen and carbon atoms in addition to the ring hetero elements
    • C07D295/023—Preparation; Separation; Stabilisation; Use of additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/16—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation

Abstract

내용 없음.

Description

아민을 제조하기 위한 방법 및 촉매
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (11)

  1. 산화물-비함유 기준으로 계산하여 (1) 코발트 1 내지 20%미만; (2) 구리 75 내지 95%; 및 (3) 철, 아연, 지르코늄 또는 이의 혼합물인 제3성분 1 내지 16%를 포함함을 특징으로 하는, 적어도 하나의 알콜, 알데히드 또는 케톤, 또는 이의 혼합물로 아민을 제조하기 위한 촉매.
  2. 제1항에 있어서, 5 내지 6%의 지르코늄을 포함하는 촉매.
  3. 제1항에 있어서, 제3성분이 철인 촉매.
  4. 제1항에 있어서, 제3성분이 아연인 촉매.
  5. 제1항에 있어서, 6 내지 17%의 코발트를 포함하는 촉매 상기 제3성분이 지르코늄인 촉매.
  6. 산화물-비함유 기준으로 계산하여 (1) 코발트 1 내지 17%; (2) 구리 75 내지 95%; 및 (3) 철, 아연, 지르코늄 또는 이의 혼합물인 제3성분 1 내지 16%를 포함하는 촉매를 사용함을 특징으로 하여, 촉매 존재하의 반응조건에서 적어도 하나의 알콜, 알데히드 또는 케톤, 또는 이의 혼합물을 아민화제와 접촉시켜 아민을 제조하는 방법.
  7. 제6항에 있어서, ㎡당 전환률이 적어도 70%인 방법.
  8. 제6항에 있어서, 상기 조건의 온도가 적어도 75℃인 방법.
  9. 제6항에 있어서, 상기 조건의 압력이 50 내지 100psi(345 내지 6900kPa)인 방법.
  10. 제6항에 있어서, 용매 존재하에서 수행하는 방법.
  11. 제6항에 있어서, 상기 촉매가 (1) 코발트 1 내지 17%; (2) 구리 79 내지 89%; 및 (3) 지르코늄 5 내지 6%인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900702269A 1985-05-13 1989-12-17 아민을 제조하기 위한 방법 및 촉매 KR910700268A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/732,978 US4806690A (en) 1985-05-13 1985-05-13 Method of producing amines
PCT/US1989/000694 WO1990009368A1 (en) 1985-05-13 1989-02-17 Method and catalyst for producing amines

Publications (1)

Publication Number Publication Date
KR910700268A true KR910700268A (ko) 1991-03-14

Family

ID=24945701

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019900702269A KR910700268A (ko) 1985-05-13 1989-12-17 아민을 제조하기 위한 방법 및 촉매

Country Status (7)

Country Link
US (1) US4806690A (ko)
EP (1) EP0384047A1 (ko)
JP (1) JPH03503977A (ko)
KR (1) KR910700268A (ko)
CN (1) CN1045039A (ko)
BR (1) BR8907390A (ko)
WO (1) WO1990009368A1 (ko)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4806690A (en) * 1985-05-13 1989-02-21 The Dow Chemical Company Method of producing amines
US5001267A (en) * 1987-12-21 1991-03-19 Texaco Chemical Company Secondary alkyl amine derivatives of ethylenediamine
US4950791A (en) * 1988-03-30 1990-08-21 Brown Herbert C Novel process of producing phenyl or substituted phenylalkylamine pharmaceutical agents and novel chiral intermediates of high enantiomeric purity useful therein
US5331101A (en) * 1990-01-05 1994-07-19 The Dow Chemical Company Process for preparation of amines from alcohols, aldehydes or ketones
DE4010227A1 (de) * 1990-03-30 1991-10-02 Basf Ag Verfahren zur herstellung von 3-aminomethyl-3,5,5-trimethyl-cyclohexylamin
DE4116367A1 (de) * 1991-05-18 1992-11-19 Basf Ag Verfahren zur herstellung von aminen
DE4137013A1 (de) * 1991-11-11 1993-05-13 Basf Ag Verfahren zur herstellung von aminen durch reduktive aminierung
CN1044689C (zh) * 1994-04-22 1999-08-18 中国石油化工总公司 制备脂肪胺的催化剂及工艺
CA2191919C (en) 1995-12-19 2006-02-21 James A. Gray Reductive amination process for manufacturing a fuel additive from polyoxybutylene alcohol with ethylene diamine
DE69608401T2 (de) 1995-12-19 2001-01-11 Chevron Chem Co Alkylphenylpolyoxyalkylenamine mit sehr langen Ketten, und die selben enthaltende Kraftstoffzusammensetzungen
AR043078A1 (es) 1998-09-14 2005-07-20 Dow Agrosciences Llc Procesos para preparar acidos carboxilicos
US6147261A (en) * 1998-11-23 2000-11-14 Shell Oil Corporation Diaminoalkane syntheses via selective amination of hydroxyaldehydes
US6191310B1 (en) 1998-11-23 2001-02-20 Shell Oil Company Diaminoalkane syntheses via selective amination of dihydric alcohols
WO2010031719A1 (de) * 2008-09-19 2010-03-25 Basf Se Verfahren zur kontinuierlichen herstellung eines amins unter verwendung eines aluminium-kupfer-katalysators
JP5342887B2 (ja) * 2009-01-29 2013-11-13 花王株式会社 α−アミノケトン化合物の製造方法
RU2013144822A (ru) * 2011-03-08 2015-04-20 Басф Се Способ получения ди-, три- и полиаминов аминированием спиртов при гомогенном катализе
WO2018085957A1 (en) 2016-11-09 2018-05-17 Rhodia Operations Process for production of aromatic compounds comprising at least two amine functions
WO2018224316A1 (de) * 2017-06-09 2018-12-13 Basf Se Verfahren zur herstellung von ethylenaminen
CN110709380A (zh) * 2017-06-09 2020-01-17 巴斯夫欧洲公司 制备亚乙基胺的方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3347926A (en) * 1964-04-15 1967-10-17 Atlas Chem Ind Ammonolysis process for producing aliphatic amines
US3520933A (en) * 1966-10-28 1970-07-21 Basf Ag Production of amines
US4014933A (en) * 1969-10-23 1977-03-29 Basf Aktiengesellschaft Production of amines from alcohols
US3654370A (en) * 1970-08-28 1972-04-04 Jefferson Chem Co Inc Process for preparing polyoxyalkylene polyamines
US4153581A (en) * 1977-09-01 1979-05-08 The Dow Chemical Company Method of producing amines from alcohols, aldehydes, ketones and mixtures thereof
US4152353A (en) * 1977-08-29 1979-05-01 The Dow Chemical Company Method of producing amines from alcohols, aldehydes, ketones and mixtures thereof
JPS5912106B2 (ja) * 1979-02-21 1984-03-21 花王株式会社 脂肪族アミンの製造方法
US4409399A (en) * 1981-12-09 1983-10-11 Millmaster Onyx Group, Inc. Process for producing aliphatic amines
US4440668A (en) * 1982-07-06 1984-04-03 Mobil Oil Corporation Catalyst for the conversion of synthesis gas to higher alcohols
US4806690A (en) * 1985-05-13 1989-02-21 The Dow Chemical Company Method of producing amines
US4772750A (en) * 1985-06-14 1988-09-20 The Dow Chemical Company Method of producing amines

Also Published As

Publication number Publication date
US4806690A (en) 1989-02-21
JPH03503977A (ja) 1991-09-05
CN1045039A (zh) 1990-09-05
BR8907390A (pt) 1991-05-14
EP0384047A1 (en) 1990-08-29
WO1990009368A1 (en) 1990-08-23

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