KR910020200A - Multicolored article and its manufacturing method - Google Patents

Multicolored article and its manufacturing method Download PDF

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KR910020200A
KR910020200A KR1019910008935A KR910008935A KR910020200A KR 910020200 A KR910020200 A KR 910020200A KR 1019910008935 A KR1019910008935 A KR 1019910008935A KR 910008935 A KR910008935 A KR 910008935A KR 910020200 A KR910020200 A KR 910020200A
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coating
substrate
film
nitrides
article
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KR960008013B1 (en
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요시유끼 사또
다이스께 기나시
구니오 시부끼
노리꼬 와따나베
아끼히로 와따나베
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안도 겐이찌로
도시바 탕가로이 가부시끼가이샤
노리꼬 와따나베
가부시끼가이샤 야마또 멕끼고죠
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Priority claimed from JP2142160A external-priority patent/JPH0762257B2/en
Priority claimed from JP2141611A external-priority patent/JP2630344B2/en
Priority claimed from JP2144547A external-priority patent/JPH0765194B2/en
Application filed by 안도 겐이찌로, 도시바 탕가로이 가부시끼가이샤, 노리꼬 와따나베, 가부시끼가이샤 야마또 멕끼고죠 filed Critical 안도 겐이찌로
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C26/00Coating not provided for in groups C23C2/00 - C23C24/00
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1603Process or apparatus coating on selected surface areas
    • C23C18/1605Process or apparatus coating on selected surface areas by masking
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/005Jewels; Clockworks; Coins
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/02Electroplating of selected surface areas
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/02Electroplating of selected surface areas
    • C25D5/024Electroplating of selected surface areas using locally applied electromagnetic radiation, e.g. lasers
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrochemistry (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)
  • Physical Vapour Deposition (AREA)
  • Laminated Bodies (AREA)

Abstract

내용 없음No content

Description

다색 물품 및 그 제조방법Multicolored article and its manufacturing method

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음Since this is an open matter, no full text was included.

제1도―제4도는 본 발명에 따른 물품의 기재 표면의 요면형 표면 또는 요면형 라인의 대표적인 모양을 도시한 단면도.1 to 4 are cross-sectional views showing representative shapes of the concave surface or the concave line of the substrate surface of the article according to the invention.

Claims (11)

기재, 상기 기재한 표면의 특정 부분에 형성된 피막을 포함하고, 상기 피막이 구리(Cu), 은(Ag), 금(Au), 백금(Pt), 이리듐(Ir), 오스뮴(Os), 팔라듐(Pd), 로듐(Rh), 루테늄(Ru) 및 상기 금속(들)을 함유하는 합금 중 적어도 1종으로서 필수적으로 구성되는 단층막 및 복층막이며 가열―용융 표면상에 상기 기재의 표면에 제공된 요면형 표면 또는 라인으로 형성되어 있는 것을 특징으로 하는 다색 물품.Substrate, a coating formed on a specific portion of the surface described above, wherein the coating is copper (Cu), silver (Ag), gold (Au), platinum (Pt), iridium (Ir), osmium (Os), palladium ( Pd), rhodium (Rh), ruthenium (Ru), and a monolayer film and a multilayer film consisting essentially of at least one of the alloy containing the metal (s) and provided on the surface of the substrate on a heat-melt surface. A multicolored article, characterized in that it is formed into a mold surface or a line. 제1항에 있어서, 상기 가열 응용 표면이 상기 기재의 표면으로부터 0.5㎛ 깊이로 형성되는 것을 특징으로 하는 다색 물품.The multicolor article of claim 1, wherein the heating application surface is formed at a depth of 0.5 μm from the surface of the substrate. (i) 제1피막 면부 및 상기 제1피막 면부와 색채 및/또는 색조가 상이한 제2피막 면부, 또는 (ii) 상기 제1피막 면부, 상기 제2피막면부 및 상기 기재의 면부로 구성되는 다색 표면의 적어도 1표면에 기재를 포함하고, 상기 제2피막이 구리(Cu), 은(Ag), 금(Au), 백금(Pt), 이리듐(Ir), 오스뮴(Os), 팔라듐(Pd), 로듐(Rh), 루테늄(Ru) 및 상기 금속(들)을 함유하는 합금 중 적어도 1종으로서 필수적으로 구성되는 단층막 및 복층막이며 가열―용융 표면상에 상기 기재의 표면에 제공된 요면형 또는 라인으로 형성되어 있는 것을 특징으로 하는 다색 물품.(i) a first coating surface portion and a second coating surface portion that is different in color and / or color tone from the first coating surface portion, or (ii) a multicolored color comprising the first coating surface portion, the second coating surface portion, and the surface portion of the substrate. A base material is included on at least one surface, and the second film is copper (Cu), silver (Ag), gold (Au), platinum (Pt), iridium (Ir), osmium (Os), palladium (Pd), A concave or a monolayer film and a multilayer film consisting essentially of at least one of an alloy containing rhodium (Rh), ruthenium (Ru) and the metal (s) provided on the surface of the substrate on a heat-melt surface; Multicolored article, characterized in that formed. 제3항에 있어서, 상기 제2 피막이 0.05 내지 20㎛의 피막두께를 갖는 것을 특징으로 하는 다색물품.The multicolor article according to claim 3, wherein the second coating has a coating thickness of 0.05 to 20 mu m. 제3항에 있어서, 상기 제1피막이 금속; 합금; 주기율표 4a족[티타늄(Ti), 지르코늄(Zr) 및 하프늄(Hf)], 5a족[바나듐(V), 니오브(Nb), 및 탄탈(Ta)] 또는 6a족[크롬(Cr), 몰리브덴(Mo) 및 텅스텐(W)]의 금속의 탄화물, 질화물, 탄산화물 또는 질산화물; 알루미늄(Al) 또는 실리콘(Si)의 산화물, 탄화물 또는 질화물; 상기 것의 상호 고용체; 및 경질 탄소 중 적어도 1종으로서 필수적으로 구성되어 있는 단층막 또는 복층막인 것을 특징으로 하는 다색 물품.The method of claim 3, wherein the first coating is a metal; alloy; Periodic Tables Group 4a [Titanium (Ti), Zirconium (Zr) and Hafnium (Hf)], Group 5a [Vanadium (V), Niobium (Nb), and Tantalum (Ta)] or Group 6a [Chrome (Cr), Molybdenum ( Mo) and tungsten (W)] carbides, nitrides, carbonates or nitrides of metals; Oxides, carbides or nitrides of aluminum (Al) or silicon (Si); Mutual solid solutions of the above; And a monolayer film or a multilayer film essentially composed of at least one kind of hard carbon. 제4항에 있어서, 상기 요면형 표면 또는 요면형 라인이 적어도 0.1㎛의 넓이 및 적어도 0.5㎛의 깊이인 것을 특징으로 하는 다색 물품.The multicolor article of claim 4, wherein the concave surface or concave line is at least 0.1 μm wide and at least 0.5 μm deep. (i) 제1피막 면부 및 상기 제1피막 면부와 색채 및/또는 색조가 상이한 제2피막 면부, 또는 (ii) 제1피막 면부, 제2피막 면부 및 기재의 표면으로 구성된 다색 표면의 적어도 1표면에 기재를 포함하고, 상기 제1피막이 금속; 합금; 주기율표 [4a족[티타늄(Ti), 지르코늄(Zr) 및 하프늄(Hf)], 5a족[바나듐(V), 니오브(Nb), 및 탄탈(Ta)] 또는 6a족[크롬(Cr), 몰리브덴(Mo) 및 텅스텐(W)]의 금속의 탄화물, 질화물, 탄산화물 또는 질산화물; 알루미늄(Al) 또는 실리콘(Si)의 산화물, 탄화물 또는 질화물; 상기 것의 상호 고용체; 및 경질 탄소 중 적어도 1종으로서 필수적으로 구성되어 있는 단층막 또는 복층막이며, 상기 제2피막이 구리(Cu), 은(Ag), 금(Au), 백금(Pt), 이리듐(Ir), 오스뮴(Os), 팔라듐(Pd), 로듐(Rh), 루테늄(Ru) 및 상기 금속들을 함유하는 합금 중 적어도 1종으로서 필수적으로 구성되는 단층막 및 복층막인 것을 특징으로 하는 다색물품.at least one of (i) the first coating surface portion and the second coating surface portion that is different in color and / or color tone from the first coating surface portion, or (ii) the first coating surface portion, the second coating surface portion, and the surface of the substrate. A substrate on a surface thereof, wherein the first coating is made of metal; alloy; Periodic Table [Groups 4a [Titanium (Ti), Zirconium (Zr) and Hafnium (Hf)], Groups 5a [Vanadium (V), Niobium (Nb), and Tantalum (Ta)] or Group 6a [Chrome (Cr), Molybdenum (Mo) and tungsten (W)] carbides, nitrides, carbonates or nitrides of metals; Oxides, carbides or nitrides of aluminum (Al) or silicon (Si); Mutual solid solutions of the above; And a single layer film or a multilayer film essentially composed of at least one of hard carbons, and the second film is copper (Cu), silver (Ag), gold (Au), platinum (Pt), iridium (Ir), or osmium. (Os), palladium (Pd), rhodium (Rh), ruthenium (Ru) and a multi-colored article characterized in that it is a monolayer film and a multilayer film which consist essentially of at least 1 sort (s) of the alloy containing these metals. 제7항에 있어서, 상기 가열 용융 표면이 상기 기재의 표면으로 부터 0.5㎛깊이로 형성되어 있는 것을 특징으로 하는 다색물품.The multicolor article according to claim 7, wherein the hot melt surface is formed to a depth of 0.5 mu m from the surface of the substrate. 다색물품을 제조하기 위한 방법에 있어서, (a) 기재의 표면상에 후술 단계에서 제공될 피막에 대하여 친화성이 낮은 물질로 구성된 가설 피막을 형성하는 단계; (b) 상기 가설 피막 및 상기 부분의 기재 표면을 용융 및 제거시키기 위해 상기 가설 피막의 표면상에 레이저 비임을 조사함으로써 상기 기재의 표면상에 요면형 표면 또는 라인으로 가열―용융 표면을 형성하는 단계; (c) 구리(Cu), 은(Ag), 금(Au), 백금(Pt), 이리듐(Ir), 오스뮴(Os), 팔라듐(Pd), 로듐(Rh), 루테늄(Ru) 및 상기 금속(들)을 함유하는 합금 중 적어도 1종으로서 필수적으로 구성되는 피막을 형성하는 단계; (d) 상기 가설피막상에 잔류하는, 상기공정(c)에서 형성된 피막을 제거하는 단계; 및 (e) 상기 가설 피막을 제거하는 단계를 포함하는 것을 특징으로 하는 방법.A method for producing a multicolor article, the method comprising the steps of: (a) forming a temporary film composed of a material having a low affinity for the film to be provided in the step described later on the surface of the substrate; (b) forming a heated-melt surface with a concave surface or a line on the surface of the substrate by irradiating a laser beam on the surface of the temporary coating to melt and remove the surface of the temporary coating and the portion of the substrate; ; (c) Copper (Cu), silver (Ag), gold (Au), platinum (Pt), iridium (Ir), osmium (Os), palladium (Pd), rhodium (Rh), ruthenium (Ru) and the metal Forming a coating consisting essentially of at least one of the alloys containing (s); (d) removing the coating film formed in the step (c) remaining on the temporary coating film; And (e) removing the hypothesis coating. 다색 물품을 제조하기 위한 방법에 있어서, (a) 기재의 한 표면 또는 부분상에 건식도금법 또는 습식도금법으로 제1피막을 형성하는 단계; (b) 상기 제1피막을 부분적으로 제거하고 제1피막에 대응하는 부분의 기재 표면을 세밀하게 제거시키기 위해 상기 제1피막의 표면상에 레이저 비임을 조사함으로써 상기 기재의 표면상에 요면형 표면 또는 라인을 형성하는 단계; (c) 구리(Cu), 은(Ag), 금(Au), 백금(Pt), 이리듐(Ir), 오스뮴(Os), 팔라듐(Pd), 로듐(Rh), 루테늄(Ru) 및 상기 금속(들)을 함유하는 합금 중 적어도 1종으로서 필수적으로 구성되는 제2피막을 단층 또는 복층으로 형성하는 단계; 및 (d) 단계(b)에서 형성된 요면형 표면 또는 라인상에만 상기 제2피막이 잔류되도록 물품을 처리하여, 공정(c)에서 형성된 제2피막의 것들과 색채 및/또는 색조가 상이한 제1피막의 표면 부분과 제2피막의 표면 부분을 형성하는 단계를 포함하는 것을 특징으로 하는 방법.CLAIMS 1. A method for producing a multicolored article, comprising: (a) forming a first coating on one surface or portion of a substrate by dry plating or wet plating; (b) a concave surface on the surface of the substrate by irradiating a laser beam on the surface of the first coating to partially remove the first coating and to finely remove the surface of the substrate corresponding to the first coating. Or forming a line; (c) Copper (Cu), silver (Ag), gold (Au), platinum (Pt), iridium (Ir), osmium (Os), palladium (Pd), rhodium (Rh), ruthenium (Ru) and the metal Forming a second film composed essentially of at least one of the alloys containing (s) in a single layer or a plurality of layers; And (d) treating the article so that the second coating remains only on the concave surface or line formed in step (b), so that the first coating differs in color and / or color tone from those of the second coating formed in step (c). Forming a surface portion of the and a surface portion of the second coating. 다색 물품을 제조하기 위한 방법에 있어서, (a) 금속; 합금; 주기율표 4a족[티타늄(Ti), 지르코늄(Zr) 및 하프늄(Hf)], 5a족[바나듐(V), 니오브(Nb), 및 탄탈(Ta)] 또는 6a족[크롬(Cr), 몰리브덴(Mo) 및 텅스텐(W)]의 금속의 탄화물, 질화물, 탄산화물 또는 질산화물; 알루미늄(Al) 또는 실리콘(Si)의 산화물, 탄화물 또는 질화물; 상기 재료들의 상호 고용체; 및 경질 탄소들중 적어도 1종으로서 필수적으로 구성되는 제1피막을 단층 및 복층으로 형성하는 단계; (b) 상기 제1피막을 부분적으로 제거시키기 위해 상기 제1피막의 표면상에 레이저 비임을 조사하여 상기 제1피막을 부분적으로 제거하는 단계; (c) 구리(Cu), 은(Ag), 금(Au), 백금(Pt), 이리듐(Ir), 오스뮴(Os), 팔라듐(Pd), 로듐(Rh), 루테늄(Ru) 및 상기 금속(들)을 함유하는 합금 중 적어도 1종으로서 필수적으로 구성되는 제2 피막을 습식 도금법에 의해 단층 또는 복층으로 형성하는 단계; 및 (d) 단계(b)에서 상기 제1피막이 제거된 부분 이외의 부분에 형성된 상기 제2피막을 제거하는 단계를 포함하는 것을 특징으로 하는 방법.CLAIMS 1. A method for producing a multicolored article, comprising: (a) a metal; alloy; Periodic Tables Group 4a [Titanium (Ti), Zirconium (Zr) and Hafnium (Hf)], Group 5a [Vanadium (V), Niobium (Nb), and Tantalum (Ta)] or Group 6a [Chrome (Cr), Molybdenum ( Mo) and tungsten (W)] carbides, nitrides, carbonates or nitrides of metals; Oxides, carbides or nitrides of aluminum (Al) or silicon (Si); Mutual solid solution of the materials; And forming a first film composed of at least one of the hard carbons in a single layer and a plurality of layers; (b) irradiating a laser beam onto the surface of the first coating to partially remove the first coating to partially remove the first coating; (c) Copper (Cu), silver (Ag), gold (Au), platinum (Pt), iridium (Ir), osmium (Os), palladium (Pd), rhodium (Rh), ruthenium (Ru) and the metal Forming a second film composed essentially of at least one of the alloys containing (s) into a single layer or a multilayer by the wet plating method; And (d) removing the second coating formed in a portion other than the portion from which the first coating has been removed in step (b). ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.※ Note: This is to be disclosed by the original application.
KR1019910008935A 1990-05-31 1991-05-30 Multi-colored product and process for producing the same KR960008013B1 (en)

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JP2142160A JPH0762257B2 (en) 1990-05-31 1990-05-31 Multicolor coated surface article and method for producing the same
JP2-142160 1990-05-31
JP2141611A JP2630344B2 (en) 1990-06-01 1990-06-01 Method for producing multicolor surface articles
JP2-141611 1990-06-01
JP2-144547 1990-06-04
JP2144547A JPH0765194B2 (en) 1990-06-04 1990-06-04 Colored surface article and manufacturing method thereof

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KR20140048327A (en) * 2011-08-18 2014-04-23 애플 인크. Anodization and plating surface treatments
KR20150063602A (en) * 2004-10-25 2015-06-09 헨켈 아게 운트 코. 카게아아 Article of manufacture and process for anodically coating aluminum and/or titanium with ceramic oxides

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KR20040035530A (en) * 2002-10-22 2004-04-29 송오성 Titanium coloring with top-down selective etching
KR20150063602A (en) * 2004-10-25 2015-06-09 헨켈 아게 운트 코. 카게아아 Article of manufacture and process for anodically coating aluminum and/or titanium with ceramic oxides
KR20140048327A (en) * 2011-08-18 2014-04-23 애플 인크. Anodization and plating surface treatments

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HK1000088A1 (en) 1997-11-21
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